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Kaitlin L. Laabs

Publications and source records attributed to Kaitlin L. Laabs.

5 recordsLinked to original sources

Base-flow sampling to enhance understanding of the groundwater flow component of nitrogen loading in small watersheds draining into Long Island Sound

Excessive nitrogen discharge is a major concern for the Long Island Sound. Programs have been implemented to reduce point sources of nitrogen to the sound, but little is known about the nonpoint sources. This study aims to better understand the current groundwater contributions of nitrogen from nonpoint sources in the Long Island Sound watershed. During the spring and summer of 2022, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, collected water-quality samples to analyze nutrients (nitrogen and phosphorus), chloride, and bromide at 45 stations in the Long Island Sound watershed in Connecticut, New York, and Rhode Island. The stations were in small drainage watersheds (5 to 30 square kilometers) in the southern part of the Long Island Sound watershed. During two separate synoptic sampling events, water-quality samples and instantaneous streamflow measurements were collected under base-flow conditions (where the streamflow is dominated by groundwater inputs rather than overland flow or runoff flow). One sampling event was in the nongrowing season (April 24–25, 2022), and the other was in the growing season (June 30–July 1, 2022). To calculate instantaneous nitrogen loads and yields, streamflow was measured at the time of sample collection. Nitrogen concentrations, loads, and yields varied among sampling stations and by season. Total filtered nitrogen concentrations were generally lower in the nongrowing season (from less than 0.14 to 1.9 milligrams per liter) than in the growing season (from less than 0.23 to 3.0 milligrams per liter). Nitrate plus nitrite concentrations showed little variation between the nongrowing and growing seasons. Unfiltered ammonia plus organic nitrogen concentrations were generally lower in the nongrowing season (from less than 0.07 to 0.83 milligram per liter) than in the growing season (from 0.11 to 0.98 milligram per liter). In contrast, total filtered and unfiltered nitrogen loads and yields were higher in the nongrowing season than during the growing season, likely because streamflows were higher during the nongrowing season. Total unfiltered nitrogen yields during the nongrowing season ranged from less than 0.15 to 5.0 kilograms per square kilometer per day. Total unfiltered nitrogen yields during the growing season ranged from less than 0.12 to 2.5 kilograms per square kilometer per day. Total filtered nitrogen yields during the nongrowing season ranged from less than 0.13 to 5.2 kilograms per square kilometer per day. Total filtered nitrogen yields during the growing season ranged from less than 0.06 to 2.5 kilograms per square kilometer per day.

Connecticut, New York, Rhode Island↗

Evaluating water-quality conditions in the mainstem and tidal reaches of the Merrimack River in Massachusetts, June to September 2020

In summer and early fall (June to September) 2020, water-quality data were collected at 13 stations along the mainstem of the Merrimack River and into the Merrimack River estuary. The data are allocated among three different datasets: discrete water sample data, discrete vertical profile data, and continuous data. The collective purpose of these datasets is to enable assessment of the overall water-quality conditions in the Merrimack River and estuary and to identify areas for potentially more targeted water-quality monitoring in the future. The highest concentrations of nutrients—nitrogen and phosphorus—were found at the stations downstream from wastewater treatment plants in Lowell, Lawrence, and Haverhill. Nutrient concentrations measured in the Merrimack River estuary were not as high as those measured in the Merrimack River, indicating that other processes are affecting nutrient concentrations in the system. These data were collected coincident with a severe flash drought in New England. Analysis of the vertical profile and continuous data indicated that, for intermittent periods up to 5 days, water quality in some sections of the Merrimack River may not support designated uses for the waterbody as established in the Massachusetts surface water quality standards.

Massachusetts↗

Water-quality monitoring of the Merrimack River watershed in Massachusetts

The U.S. Geological Survey has been working in collaboration with the Massachusetts Department of Environmental Protection on a project to collect water-quality data from the Merrimack River watershed since April 2020. Twelve locations in the Merrimack River watershed are being sampled for nutrients (such as nitrogen), metals (such as aluminum), Escherichia coli bacteria, and other measures.

Massachusetts↗

Surface-water-quality data to support implementation of revised freshwater aluminum water-quality criteria in Massachusetts, 2018–19

The U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Protection, performed a study to inform the development of the department’s guidelines for the collection and use of water-chemistry data to support calculation of site-dependent aluminum criteria values. The U.S. Geological Survey collected and analyzed discrete water-quality samples at four wastewater-treatment facilities and seven water-treatment facilities in eastern and central Massachusetts from April 2018 through May 2019. For each of the 11 facilities considered, water-quality samples were collected from treatment-plant effluent and receiving-water bodies. Samples were collected for laboratory analysis of major ions (calcium and magnesium ions are used to calculate total hardness), dissolved organic carbon (DOC), total organic carbon (TOC), and total recoverable aluminum. Field parameters for pH, temperature, and specific conductance were measured in situ concurrently with sample collection. Water-quality conditions differed among monitoring stations. The highest pH values were observed for stations on the Assabet River that receive effluent discharges from wastewater-treatment facilities (the Westborough, Marlborough, Hudson, and Maynard wastewater-treatment facilities). High DOC concentrations (greater than 10 mg/L) were measured in water bodies associated with large areas of riparian wetlands—Lily Pond (Cohasset) and Third Herring Brook (Hanover), and low DOC concentrations (less than 2.5 mg/L) were measured at three water bodies in central Massachusetts—Hocomonco Pond (Westborough), Wyman Pond (Fitchburg), and Monoosnoc Brook (Leominster). Wyman Pond (Fitchburg), Monoosnoc Brook (Leominster), and Lily Pond (Cohasset) also had low pH values and low total hardness concentrations. The monthly discrete pH, DOC, and total hardness data for selected stations on receiving-water bodies were used in the U.S. Environmental Protection Agency Aluminum Criteria Calculator Version 2.0 to estimate site-dependent total recoverable aluminum concentrations that—if not exceeded—would be expected to protect fish, invertebrates, and other aquatic life from adverse effects associated with acute and chronic aluminum exposures. The U.S. Environmental Protection Agency Calculator output provides values for the acute criterion, defined as the criterion maximum concentration (CMC), an estimate of the highest aluminum concentration in surface water to which an aquatic community can be exposed briefly without resulting in an unacceptable effect. This output also provides values for the chronic criterion, defined as the criterion continuous concentration (CCC), an estimate of the highest concentration of aluminum in surface water to which an aquatic community can be exposed indefinitely without resulting in an unacceptable effect. To determine aluminum criteria values typically evaluated for use as protective water-quality criteria, the monthly instantaneous CMC and CCC values were used to calculate the minimum, 5th percentile, and 10th percentile CMC and CCC values for selected monitoring stations. The monthly instantaneous aluminum CMC and CCC values generated using the EPA Calculator varied among stations. Aluminum CMC and CCC values were highest for four ambient (upstream) stations on the Assabet River associated with wastewater-treatment facilities (Westborough, Marlboro, Hudson, and Maynard). Aluminum CMC and CCC values were lower for stations associated with water-treatment facilities, and lowest for selected ambient stations on Lily Pond, Monoosnoc Brook, and Wyman Pond associated with water-treatment facilities in Cohasset, Leominster, and Fitchburg, respectively. For many stations, the highest CMC and CCC instantaneous aluminum criteria values generated using the U.S. Environmental Protection Agency Calculator were for months during the growing season for algae and aquatic macrophytes (April or May through September or October) and the lowest values were for months during the nongrowing season (October or November through March or April), indicating the importance of collecting water-quality data during the nongrowing season. Aluminum CMC and CCC values generated by the U.S. Environmental Protection Agency Calculator are sensitive to variations in the input parameters (pH, DOC, and total hardness). Aluminum solubility is particularly affected by pH. To characterize diel and seasonal variations in pH, multiparameter water-quality monitors recording continuous (15-minute interval) water temperature and pH were installed in the receiving-water body for one station near each facility upstream from the effluent discharge (in rivers) or at a station outside the immediate effect of effluent discharge (in ponds). Continuous water temperature and pH data were collected from April or May 2018 through November or December 2018. Continuous pH data indicated that the pond stations and Assabet River stations had large diel variations in pH during the growing season. Continuous pH data were used together with discrete DOC and total hardness data to evaluate the potential effect of diel variations in pH on calculated site-dependent aluminum criteria values. For the 11 stations, diel variations in pH were determined to correspond to differences in the 10th percentile of CMC values by a median of 160 μg/L, ranging from 0 to 610 μg/L, and differences in the 10th percentile of CCC values by a median of 40 μg/L, ranging from 15 to 210 μg/L. The low monthly instantaneous CMC and CCC values that have the greatest effect on the minimum, 5th percentile, and 10th percentile aluminum values tend to result during the nongrowing season (October or November through March or April) when the range of diel variations in pH is small, thus minimizing the effect of diel variations in pH on the lowest CMC and CCC values. Historical water-quality data on organic carbon in Massachusetts streams were investigated using data retrieved from the USGS National Water Information System database. An assessment of the availability of historical pH, DOC, and hardness data indicated that more data were available for TOC than for DOC. A linear regression equation was developed for the relation between DOC and TOC concentrations to inform the potential use of available data to evaluate water-quality conditions at additional sites across Massachusetts where only pH, hardness, and TOC data are available. DOC and TOC concentrations were well correlated in the 223 samples in which both constituents were analyzed, and the equation had a coefficient of determination ( R 2 ) equal to 0.93.

Massachusetts↗

Hydrogeology and interactions of groundwater and surface water near Mill Creek and the Herring River, Wellfleet, Massachusetts, 2017–18

Groundwater levels and stream stage were monitored by the U.S. Geological Survey, in cooperation with the Friends of Herring River, at 19 sites in the Mill Creek Basin, a tributary of the Herring River in Wellfleet, Massachusetts, on outer Cape Cod, to provide baseline data prior to a proposed restoration of tidal flow to the Herring River estuary at the Cape Cod National Seashore. Tidal flow in the Herring River has been restricted by a tide-control structure since 1909. Baseline data are necessary to understand current conditions and provide information on water levels for comparison to future water levels under the proposed Herring River restoration, which includes restoration of salt marshes by enhancing tidal flow to the Herring River and construction of a tide-control structure on Mill Creek to prevent the flooding of upstream private properties, including a golf course. Analysis of data collected during monitoring-well installation at eight locations on or near the golf course and Mill Creek, along with analysis of existing information, determined that parts of the study area are underlain by salt marsh deposits up to 18 feet (ft) thick. These marsh deposits are directly underlain by estuarine sediments, and adjacent upland areas are underlain by medium to very coarse sand. The freshwater lens on the golf course is 70 ft thick or more. Groundwater levels at individual wells in the study area fluctuated by 1.3 to 2.6 ft during the study period (June 1, 2017, to June 14, 2018). Total precipitation during this period was 60.8 inches, about 10 inches greater than the long-term (2000–17) annual average (50.3 inches). Groundwater levels on Cape Cod generally were normal to above normal during the study owing to the higher than normal precipitation. Tidal amplitudes of groundwater levels caused by daily fluctuations at nearby tidal waterbodies (M2 tidal harmonic) were as large as 0.12 ft at a well 105 ft from the tidally restricted Herring River and as large as 0.06 ft at a well 575 ft from Wellfleet Harbor. Tidal fluctuations in groundwater levels were generally limited to areas about 1,500 ft from the nearest tidal waterbody. Under the initial proposed restoration, where mean tides would be maintained similar to current conditions, tidal fluctuations would be restored to parts of Mill Creek, and subsequent tidal fluctuations in groundwater levels could increase at some of the areas closest to the proposed tide-control structure, but the fluctuations would be less than about 0.06 ft in magnitude. Regression models were used to describe the variability of daily mean tidally filtered groundwater levels and daily maximum stream stage in Mill Creek. Significant independent variables for the groundwater-level model included daily tidally filtered Wellfleet Harbor stage with a lag time of zero to 2 days, 7-day precipitation, the growing degree days (50 degrees Fahrenheit), and the quartile of groundwater levels relative to a long period of record at a nearby observation well. Significant independent variables to predict the Mill Creek stage included daily mean groundwater levels in nearby wells, 7-day precipitation, growing degree days (50 degrees Fahrenheit), and a binary indicator of either a flooded or nonflooded condition on the golf course near Mill Creek. Flooding in Mill Creek occurred primarily when groundwater levels at nearby wells reached certain thresholds, when the precipitation in the preceding 7 days was at least 0.92–1.04 inches, and during the nongrowing season.

Massachusetts↗