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K.R. Ludwig

Publications and source records attributed to K.R. Ludwig.

47 records · Page 3Linked to original sources
USGS1982

Uranium-lead isochron age and preliminary sulfur isotope systematics of the Felder uranium deposit, south Texas

Uranium-lead isotope systematics of roll-front ores in Miocene sandstone at the Felder and McLean uranium deposits (south Texas coastal plain) give a well-defined 207 Pb/ 204 Pb- 235 U/ 204 Pb isochron age of 5.07 + or - 0.15 m.y. The relatively slight degree of scatter of the points defining the isochron is probably due to initial Pb isotope inhomogeneity, and the resulting inferred persistence of closed system behavior for U and Pb is probably the result of the long-term presence of U- and Pb-immobilizing H 2 S. 206 Pb/ 238 U systematics are badly scattered owing to long-term migration of radioactive daughters of 238 U. Beta- and gamma-activity systematics of the ores consistently identify those with grossly anomalous Pb isotope systematics, however, and proved highly useful in identifying ores that have gained gross amounts of uranium daughters.FeS 2 minerals in the altered tongue of the host sandstone are characterized by abundant postore pyrite and heavy delta 34 S values, whereas FeS 2 minerals in mineralized and unaltered, barren rock are characterized by abundant ore-stage marcasite and by light delta 34 S values. The delta 34 S values of FeS 2 minerals in the altered tongue are similar to those defined for sour gas from the underlying Edwards Limestone of Cretaceous age, indicating the probable source for the sulfur of an inferred resulfidization event. The 5.07-m.y. isochron age probably reflects the end of roll-front development; we believe that the end was due to the resulfidization and does not preclude significant earlier periods of mineralization. Modern ground water in the area is also sulfide bearing (thus helping preserve the deposit), but with delta 34 S values distinct from those of sulfides in the resulfidized zone of the host rock.

Texas↗
USGS1981

U-Pb isotope systematics and age of uranium mineralization, Midnite mine, Washington.

Uranium ores at the Midnite mine, near Spokane, Washington, occur in phyllites and calcsilicates of the Proterozoic Togo Formation, near the margins of an anomalously uraniferous, porphyritic quartz monzonite of Late Cretaceous age. The present geometry of the ore zones is tabular, with the thickest zones above depressions in the pluton-country rock contact. Analyses of high-grade ores from the mine define a 207 Pb/ 204 Pb- 235 U/ 204 Pb isochron indicating an age of mineralization of 51.0 + or - 0.5 m.y. This age coincides with a time of regional volcanic activity (Sanpoil Volcanics), shallow intrusive activity, erosion, and faulting. U-Th-Pb isotopic ages of zircons from the porphyritic quartz monzonite in the mine indicate an age of about 75 m.y., hence the present orebodies were formed about 24 m.y. after its intrusion. The 51-m.y. time of mineralization probably represents a period of mobilization and redeposition of uranium by supergene ground waters, perhaps aided by mild heating and ground preparation and preserved by a capping of newly accumulated, impermeable volcanic rocks. It seems most likely that the initial concentration of uranium occurred about 75 m.y. ago, probably from relatively mild hydrothermal fluids in the contact-metamorphic aureole of the U-rich porphyritic quartz monzonite.Pitchblende, coffinitc, pyrite, marcasite, and hisingerite are the most common minerals in the uranium-bearing veinlets, with minor sphalerite and chalcopyrite. Coffinitc with associated marcasite is paragenetically later than pitchblende, though textural and isotopic evidence suggests no large difference in the times of pitchblende and colfinite formation.The U-Pb isotope systematics of total ores and of pitchblende-coffinite and pyrite-marcasite separates show that whereas open system behavior for U and Pb is essentially negligible for large (200-500 g) ore samples, Pb migration has occurred on a scale of 1 to 10 mm (out of pitchblende and coffinite and into pyrite and marcasite). Also, long-term continuous leakage of radioactive daughters of 238 U (probably 222 Rn) has occurred on scales of from approximately 100 mu m approximately 10 cm. The isotopic composition of unsupported radiogenic Pb in pyrite-marcasite seems to depend on the mineralogical microenvironment of the grains, so that the radiogenic Pb in pyrite-marcasite intimately intermixed with pitchblende-coffinite tends to be deficient in 206 Pb, and the radiogenic Pb in pyrite-marcasite in gangue tends to have excess 206 Pb. These systematics probably reflect differences between the average distances of Pb and 222 Rn diffusion since the formation of the ores.

Washington↗
USGS1980

U-Pb ages of uraniferous opals and implications for the history of beryllium, fluorine, and uranium mineralization at Spor Mountain, Utah

The U-Pb isotope systematics of uraniferous opals from Spor Mountain, Utah, were investigated to determine the suitability of such material for geochronologic purposes, and to estimate the timing of uranium and associated beryllium and fluorine mineralization. The results indicate that uraniferous opals can approximate a closed system for uranium and uranium daughters, so that dating samples as young as ∼1 m.y. should be possible. In addition, the expected lack of initial 230 Th and 231 Pa in opals permits valuable information on the initial 234 U/ 238 U to be obtained on suitable samples of ≲10 m.y. age. The oldest 207 Pb/ 235 U apparent age observed, 20.8 ± 1m.y., was that of the opal-fluorite core of a nodule from a beryllium deposit in the Spor Mountain Formation. This age is indistinguishable from that of fission-track and K-Ar ages from the host rhyolite, and links the mineralization to the first episode of alkali rhyolite magmatism and related hydrothermal activity at Spor Mountain. Successively younger ages of 13 m.y. and 8–9 m.y. on concentric outer zones of the same nodule indicate that opal formed either episodically or continuously for over 10 m.y. Several samples of both fracture-filling and massive-nodule opal associated with beryllium deposits gave 207 Pb/ 235 U apparent ages of 13–16 m.y., which may reflect a restricted period of mineralization or perhaps an averaging of 21−and<13−m.y. periods of opal growth. Several samples of fracture-filling opal in volcanic rocks as young as 6 m.y. gave 207 Pb/ 235 U ages of 3.4–4.8 m.y. These ages may reflect hot-spring activity after the last major eruption of alkali rhyolite.

Utah↗
USGS1975

Absolute age of disseminated uraninite in Wheeler Basin, Grand County, Colorado

Uranium and lead isotopic analyses of monazlte and uraninite from the disseminated uraninite occurrence at Wheeler Basin, Grand County, Colo., indicate that these minerals formed 1,446±20 m.y. ago. This time correlates well with intrusion of the Silver Plume Granite. The uraninite and monazite were also affected by a later disturbance at 880±130 m.y., but show essentially no effects of subsequent events. This secondary disturbance may have been due to intrusion of dikes related to the Pikes Peak batholith, dated at 1,041±13 m.y. ago.

Colorado↗