Geology topics

K. E. Schilling

Publications and source records attributed to K. E. Schilling.

At least 19 recordsLinked to original sources

USGS2011

Impacts of Land-Cover Change on Suspended Sediment Transport in Two Agricultural Watersheds

Suspended sediment is a major water quality problem, yet few monitoring studies have been of sufficient scale and duration to assess the effectiveness of land-use change or conservation practice implementation at a watershed scale. Daily discharge and suspended sediment export from two 5,000-ha watersheds in central Iowa were monitored over a 10-year period (water years 1996-2005). In Walnut Creek watershed, a large portion of land was converted from row crop to native prairie, whereas in Squaw Creek land use remained predominantly row crop agriculture. Suspended sediment loads were similar in both watersheds, exhibiting flashy behavior typical of incised channels. Modeling suggested that expected total soil erosion in Walnut Creek should have been reduced 46% relative to Squaw Creek due to changes in land use, yet measured suspended sediment loads showed no significant differences. Stream mapping indicated that Walnut Creek had three times more eroding streambank lengths than did Squaw Creek suggesting that streambank erosion dominated sediment sources in Walnut Creek and sheet and rill sources dominated sediment sources in Squaw Creek. Our results demonstrate that an accounting of all sources of sediment erosion and delivery is needed to characterize sediment reductions in watershed projects combined with long-term, intensive monitoring and modeling to account for possible lag times in the manifestation of the benefits of conservation practices on water quality.

Iowa↗

USGS2011

Temporal scaling of groundwater level fluctuations near a stream

Temporal scaling in stream discharge and hydraulic heads in riparian wells was evaluated to determine the feasibility of using spectral analysis to identify potential surface and groundwater interaction. In floodplains where groundwater levels respond rapidly to precipitation recharge, potential interaction is established if the hydraulic head (h) spectrum of riparian groundwater has a power spectral density similar to stream discharge (Q), exhibiting a characteristic breakpoint between high and low frequencies. At a field site in Walnut Creek watershed in central Iowa, spectral analysis of h in wells located 1 m from the channel edge showed a breakpoint in scaling very similar to the spectrum of Q (∼20 h), whereas h in wells located 20 and 40 m from the channel showed temporal scaling from 1 to 10,000 h without a well‐defined breakpoint. The spectral exponent (β) in the riparian zone decreased systematically from the channel into the floodplain as groundwater levels were increasingly dominated by white noise groundwater recharge. The scaling pattern of hydraulic head was not affected by land cover type, although the number of analyses was limited and site conditions were variable among sites. Spectral analysis would not replace quantitative tracer or modeling studies, but the method may provide a simple means of confirming potential interaction at some sites.

Iowa↗

USGS2011

Effects of slow recovery rates on water column geochemistry in aquitard wells

Monitoring wells are often installed in aquitards to verify effectiveness for preventing migration of surface contaminants to underlying aquifers. However, water sampling of aquitard wells presents a challenge due to the slow recovery times for water recharging the wells, which can take as long as weeks, months or years to recharge depending on the sample volume needed. In this study, downhole profiling and sampling of aquitard wells was used to assess geochemical changes that occur in aquitard wells during water level recovery. Wells were sampled on three occasions spanning 11 years, 1 year and 1 week after they were purged and casing water showed substantial water chemistry variations. Temperature decreased with depth, whereas pH and specific conductance increased with depth in the water column after 11 years of water level recovery. Less stable parameters such as dissolved O 2 (DO) and Eh showed strong zonation in the well column, with DO stratification occurring as the groundwater slowly entered the well. Oxidation of reduced till groundwater along with degassing of CO 2 from till pore water affects mineral solubility and dissolved solid concentrations. Recommendations for sampling slowly recovering aquitard wells include identifying the zone of DO and Eh stratification in the well column and collecting water samples from below the boundary to better measure unstable geochemical parameters.

Iowa↗

USGS2011

Rating curve estimation of nutrient loads in Iowa rivers

Accurate estimation of nutrient loads in rivers and streams is critical for many applications including determination of sources of nutrient loads in watersheds, evaluating long-term trends in loads, and estimating loading to downstream waterbodies. Since in many cases nutrient concentrations are measured on a weekly or monthly frequency, there is a need to estimate concentration and loads during periods when no data is available. The objectives of this study were to: (i) document the performance of a multiple regression model to predict loads of nitrate and total phosphorus (TP) in Iowa rivers and streams; (ii) determine whether there is any systematic bias in the load prediction estimates for nitrate and TP; and (iii) evaluate streamflow and concentration factors that could affect the load prediction efficiency. A commonly cited rating curve regression is utilized to estimate riverine nitrate and TP loads for rivers in Iowa with watershed areas ranging from 17.4 to over 34,600 km 2 . Forty-nine nitrate and 44 TP datasets each comprising 5–22 years of approximately weekly to monthly concentrations were examined. Three nitrate data sets had sample collection frequencies averaging about three samples per week. The accuracy and precision of annual and long term riverine load prediction was assessed by direct comparison of rating curve load predictions with observed daily loads. Significant positive bias of annual and long term nitrate loads was detected. Long term rating curve nitrate load predictions exceeded observed loads by 25% or more at 33% of the 49 measurement sites. No bias was found for TP load prediction although 15% of the 44 cases either underestimated or overestimate observed long-term loads by more than 25%. The rating curve was found to poorly characterize nitrate and phosphorus variation in some rivers.

Iowa↗

USGS2011

From agricultural intensification to conservation: Sediment transport in the Raccoon River, Iowa, 1916-2009

Fluvial sediment is a ubiquitous pollutant that negatively aff ects surface water quality and municipal water supply treatment. As part of its routine water supply monitoring, the Des Moines Water Works (DMWW) has been measuring turbidity daily in the Raccoon River since 1916. For this study, we calibrated daily turbidity readings to modern total suspended solid (TSS) concentrations to develop an estimation of daily sediment concentrations in the river from 1916 to 2009. Our objectives were to evaluate longterm TSS patterns and trends, and relate these to changes in climate, land use, and agricultural practices that occurred during the 93-yr monitoring period. Results showed that while TSS concentrations and estimated sediment loads varied greatly from year to year, TSS concentrations were much greater in the early 20th century despite drier conditions and less discharge, and declined throughout the century. Against a backdrop of increasing discharge in the Raccoon River and widespread agricultural adaptations by farmers, sediment loads increased and peaked in the early 1970s, and then have slowly declined or remained steady throughout the 1980s to present. With annual sediment load concentrated during extreme events in the spring and early summer, continued sediment reductions in the Raccoon River watershed should be focused on conservation practices to reduce rainfall impacts and sediment mobilization. Overall, results from this study suggest that eff orts to reduce sediment load from the watershed appear to be working. ?? 2011 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America.

Journal of Environmental Quality↗

USGS2010

Targeting land-use change for nitratenitrogen load reductions in an agricultural watershed

The research was conducted as part of the USDA's Conservation Effects Assessment Project. The objective of the project was to evaluate the environmental effects of land-use changes, with a focus on understanding how the spatial distribution throughout a watershed influences their effectiveness.The Soil and Water AssessmentTool (SWAT) water quality model was applied to the Squaw Creek watershed, which covers 4,730 ha (11,683 ac) of prime agriculture land in southern Iowa. The model was calibrated (2000 to 2004) and validated (1996 to 1999) for overall watershed hydrology and for streamflow and nitrate loadings at the watershed outlet on an annual and monthly basis. Four scenarios for land-use change were evaluated including one scenario consistent with recent land-use changes and three scenarios focused on land-use change on highly erodible land areas, upper basin areas, and floodplain areas. Results for the Squaw Creek watershed suggested that nitrate losses were sensitive to land-use change. If land-use patterns were restored to 1990 conditions, nitrate loads may be reduced 7% to 47% in the watershed and subbasins, whereas converting row crops to grass in highly erodible land, upper basin, and floodplain areas would reduce nitrate loads by 47%, 16%, and 8%, respectively. These SWAT model simulations can provide guidance on how to begin targeting land-use change for nitrate load reductions in agricultural watersheds.

Journal of Soil and Water Conservation↗

USGS2010

Conservation practice establishment in two northeast Iowa watersheds: Strategies, water quality implications, and lessons learned

Coldwater trout streams are important natural resources in northeast Iowa. Extensive efforts have been made by state and federal agencies to protect and improve water quality in northeast Iowa streams that include Sny Magill Creek and Bloody Run Creek, which are located in Clayton County. A series of three water quality projects were implemented in Sny Magill Creek watershed during 1988 to 1999, which were supported by multiple agencies and focused on best management practice (BMP) adoption. Water quality monitoring was performed during 1992 to 2001 to assess the impact of these installed BMPs in the Sny Magill Creek watershed using a paired watershed approach, where the Bloody Run Creek watershed served as the control. Conservation practice adoption still occurred in the Bloody Run Creek watershed during the 10-year monitoring project and accelerated after the project ended, when a multiagency supported water quality project was implemented during 2002 to 2007. Statistical analysis of the paired watershed results using a pre/post model indicated that discharge increased 8% in Sny Magill Creek watershed relative to the Bloody Run Creek watershed, turbidity declined 41%, total suspended sediment declined 7%, and NOx-N (nitrate-nitrogen plus nitrite-nitrogen) increased 15%. Similar results were obtained with a gradual change statistical model.The weak sediment reductions and increased NOx-N levels were both unexpected and indicate that dynamics between adopted BMPs and stream systems need to be better understood. Fish surveys indicate that conditions for supporting trout fisheries have improved in both streams. Important lessons to be taken from the overall study include (1) committed project coordinators, agency collaborators, and landowners/producers are all needed for successful water quality projects; (2) smaller watershed areas should be used in paired studies; (3) reductions in stream discharge may be required in these systems in order for significant sediment load decreases to occur; (4) long-term monitoring on the order of decades can be required to detect meaningful changes in water quality in response to BMP implementation; and (5) all consequences of specific BMPs need to be considered when considering strategies for watershed protection.

Journal of Soil and Water Conservation↗

USGS2010

Groundwater nutrient concentrations during prairie reconstruction on an Iowa landscape

One anticipated benefit of ecosystem restoration is water quality improvement. This study evaluated NO3-N and phosphorus in subsurface waters during prairie establishment following decades of row-crop agriculture. A prairie seeding in late 2003 became established in 2006. Wells and suction cup samplers were monitored for NO3-N and phosphorus. Nitrate-N varied with time and landscape position. Non-detectable NO3-N concentrations became modal along ephemeral drainageways in 2006, when average concentrations in uplands first became <10mg NO3-NL-1. This decline continued and upland groundwater averaged near 2mg NO3-NL-1 after 2007. The longer time lag in NO3-N response in uplands was attributed to greater quantities of leachable N in upland subsoils. Spatial differences in vadose-zone travel times were less important, considering water table dynamics. Phosphorus showed a contrasting landscape pattern, without any obvious temporal trend. Phosphorus was greatest along and near ephemeral drainageways. Sediment accumulation from upland agricultural erosion provided a source of P along drainageways, where shallow, reductive groundwater increased P solubility. Phosphorus exceeded eutrophication risk thresholds in these lower areas, where saturation-excess runoff could readily transport P to surface waters. Legacy impacts of past agricultural erosion and sedimentation may include soluble phosphorus in shallow groundwater, at sites prone to saturation-excess runoff. ?? 2010.

Agriculture, Ecosystems and Environment↗

USGS2009

Modeling nitrate-nitrogen load reduction strategies for the des moines river, iowa using SWAT

The Des Moines River that drains a watershed of 16,175 km 2 in portions of Iowa and Minnesota is impaired for nitrate-nitrogen (nitrate) due to concentrations that exceed regulatory limits for public water supplies. The Soil Water Assessment Tool (SWAT) model was used to model streamflow and nitrate loads and evaluate a suite of basin-wide changes and targeting configurations to potentially reduce nitrate loads in the river. The SWAT model comprised 173 subbasins and 2,516 hydrologic response units and included point and nonpoint nitrogen sources. The model was calibrated for an 11-year period and three basin-wide and four targeting strategies were evaluated. Results indicated that nonpoint sources accounted for 95% of the total nitrate export. Reduction in fertilizer applications from 170 to 50 kg/ha achieved the 38% reduction in nitrate loads, exceeding the 34% reduction required. In terms of targeting, the most efficient load reductions occurred when fertilizer applications were reduced in subbasins nearest the watershed outlet. The greatest load reduction for the area of land treated was associated with reducing loads from 55 subbasins with the highest nitrate loads, achieving a 14% reduction in nitrate loads achieved by reducing applications on 30% of the land area. SWAT model results provide much needed guidance on how to begin implementing load reduction strategies most efficiently in the Des Moines River watershed. ?? 2009 Springer Science+Business Media, LLC.

Environmental Management↗

USGS2009

Water uptake and nutrient concentrations under a floodplain oak savanna during a non-flood period, lower Cedar River, Iowa

Floodplains during non-flood periods are less well documented than when flooding occurs, but non-flood periods offer opportunities to investigate vegetation controls on water and nutrient cycling. In this study, we characterized water uptake and nutrient concentration patterns from 2005 to 2007 under an oak savanna located on the floodplain of the Cedar River in Muscatine County, Iowa. The water table ranged from 0.5 to 2.5 m below ground surface and fluctuated in response to stream stage, plant water demand and rainfall inputs. Applying the White method to diurnal water table fluctuations, daily ET from groundwater averaged more than 3.5 mm/day in June and July and approximately 2 mm/day in May and August. Total annual ET averaged 404 mm for a growing season from mid-May to mid-October. Savanna groundwater concentrations of nitrate-N, ammonium-N, and phosphate-P were very low (mean <0.18, <0.14, <0.08 mg/l, respectively), whereas DOC concentrations were high (7.1 mg/l). Low concentrations of N and P were in contrast to high nutrient concentrations in the nearby Cedar River, where N and P averaged 7.5 mg/ l and 0.13, respectively. In regions dominated by intensive agriculture, study results document valuable ecosystem services for native floodplain ecosystems in reducing watershed-scale nutrient losses and providing an oasis for biological complexity. Improved understanding of the environmental conditions of regionally significant habitats, including major controls on water table elevations and water quality, offers promise for better management aimed at preserving the ecology of these important habitats. Copyright ?? 2009 John Wiley & Sons, Ltd.

Hydrological Processes↗

USGS2009

Time-series modeling of reservoir effects on river nitrate concentrations

Saylorville Reservoir is a 24.1 km 2 impoundment of the Des Moines River located approximately 10 km north of the City of Des Moines, Iowa, USA. Surface water from the Des Moines River used for drinking water supply is impaired for nitrate-nitrogen. Monthly mean nitrate concentration data collected upstream and downstream of the reservoir for a 30-year period (1977-2006) were selected for time-series analysis. Our objectives were to (1) develop a model describing nitrate concentrations downstream of the reservoir as a function of the concentrations entering the reservoir and (2) use the model to provide a 1-month ahead forecast for downstream water quality. Results indicated that downstream nitrate can be effectively modeled using a transfer function approach that utilized inflow concentrations during the current and previous month as input variables. Inflow concentrations were modeled using an AR(20) model, with the higher order model consistent with temporal correlation noted by others. The transfer function model suggested that the reservoir is reducing nitrate concentrations by 22 ?? 6%, a reduction that greatly exceeds previous estimates. Monthly nitrate forecasted with the model were nearly all within a 95% prediction interval of their actual measured values and did not appear greatly affected by flow variations. ?? 2009 Elsevier Ltd. All rights reserved.

Advances in Water Resources↗

USGS2009

Vertical distribution of total carbon, nitrogen and phosphorus in riparian soils of Walnut Creek, southern Iowa

Subsurface lithology plays an important role in many riparian zone processes, but few studies have examined how sediment nutrient concentrations vary with depth. In this study, we evaluated concentrations of nutrients (N, C and P) with depth in a riparian zone of the glaciated Midwest. A total of 146 sediment samples were collected from 24 cores that extended to a maximum depth of 3.6??m at eight sites in the riparian zone of Walnut Creek. Subsurface deposits were predominantly silt loam, becoming coarser and more variable with depth. Nitrogen and carbon content ranged from < 0.01 to 0.42% and < 0.01 to 7.08%, respectively, and exhibited a strong trend of decreasing nutrient content with depth. In contrast, P concentrations averaged 574??mg/kg and did not vary systematically. Systematic variations in texture and nutrient content with depth largely corresponded to stratigraphic differentiation among the Camp Creek, Roberts Creek and Gunder members of the regionally recognized Holocene-age DeForest Formation. Variations in subsurface nutrient content were not found to be significantly related to present land cover, but land cover may have influenced nutrient content at the time of original sediment accumulation. Subsurface lithology and stratigraphy should be considered an important component in riparian zone studies where nutrient losses to streams via streambank erosion or groundwater discharge are assessed. ?? 2009 Elsevier B.V. All rights reserved.

Catena↗

USGS2009

Temporal variations of Escherichia coli concentrations in a large Midwestern river

The Raccoon River used by the Des Moines Water Works to serve more than 400,000 people in central Iowa is threatened by contamination from Escherichia coli bacteria from point and nonpoint sources. The 9389 km2 watershed is highly agricultural, with 73% of the land in row crop production and widespread animal production. Results from 2155 grab samples from 1997 to 2005 for E. coli analysis were examined for temporal variations. E. coli concentrations were found to vary across years, seasons, and flow conditions, with a 9-year mean value of 1156 most probable number (MPN)/100 ml. Monthly concentrations exhibited clear seasonality with highest values in May through July. Although E. coli concentrations were higher during periods of greater discharge, the relation of log E. coli to log discharge was not particularly strong (r2 = 0.35). The variogram of E. coli concentrations showed temporal correlation within a span of 4 days suggesting that concentrations measured on 1 day may be related in time to concentrations measured up to 3 days later and beyond 4 days the concentrations vary randomly. The spectral analysis of the time series of E. coli was also carried out and was fitted well with the spectrum of an exponential covariance function. Deciphering temporal patterns and correlation of E. coli bacteria in streams may be useful for developing future monitoring strategies to track concentration patterns and loads. ?? 2008 Elsevier B.V. All rights reserved.

Journal of Hydrology↗

USGS2009

A simple approach to distinguish land-use and climate-change effects on watershed hydrology

Impacts of climate change on watershed hydrology are subtle compared to cycles of drought and surplus precipitation (PPT), and difficult to separate from effects of land-use change. In the US Midwest, increasing baseflow has been more attributed to increased annual cropping than climate change. The agricultural changes have led to increased fertilizer use and nutrient losses, contributing to Gulf of Mexico hypoxia. In a 25-yr, small-watershed experiment in Iowa, when annual hydrologic budgets were accrued between droughts, a coupled water-energy budget (ecohydrologic) analysis showed effects of tillage and climate on hydrology could be distinguished. The fraction of PPT discharged increased with conservation tillage and time. However, unsatisfied evaporative demand (PET - Hargreaves method) increased under conservation tillage, but decreased with time. A conceptual model was developed and a similar analysis conducted on long-term (>1920s) records from four large, agricultural Midwest watersheds underlain by fine-grained tills. At least three of four watersheds showed decreases in PET, and increases in PPT, discharge, baseflow and PPT:PET ratios (p < 0.10). An analysis of covariance showed the fraction of precipitation discharged increased, while unsatisfied evaporative demand decreased with time among the four watersheds (p < 0.001). Within watersheds, agricultural changes were associated with ecohydrologic shifts that affected timing and significance, but not direction, of these trends. Thus, an ecohydrologic concept derived from small-watershed research, when regionally applied, suggests climate change has increased discharge from Midwest watersheds, especially since the 1970s. By inference, climate change has increased susceptibility of nutrients to water transport, exacerbating Gulf of Mexico hypoxia.

Journal of Hydrology↗

USGS2008

Investigating local variation in groundwater recharge along a topographic gradient, Walnut Creek, Iowa, USA

Groundwater recharge is an important component to hydrologic studies but is known to vary considerably across the landscape. The purpose of this study was to examine 4 years of water-level behavior in a transect of four water-table wells installed at Walnut Creek, Iowa, USA to evaluate how groundwater recharge varied along a topographic gradient. The amount of daily water-table rise (WTR) in the wells was summed at monthly and annual scales and estimates of specific yield (Sy) were used to convert the WTR to recharge. At the floodplain site, Sy was estimated from the ratio of WTR to total rainfall and in the uplands was based on the ratio of baseflow to WTR. In the floodplain, where the water table is shallow, recharge occurred throughout the year whenever precipitation occurred. In upland areas where the water table was deeper, WTR occurred in a stepped fashion and varied by season. Results indicated that the greatest amount of water-table rise over the 4-year period was observed in the floodplain (379 mm), followed by the upland (211 mm) and sideslopes (122 mm). Incorporating spatial variability in recharge in a watershed will improve groundwater resource evaluation and flow and transport modeling. ?? Springer-Verlag 2008.

Hydrogeology Journal↗

USGS2008

Groundwater nutrient concentrations near an incised midwestern stream: Effects of floodplain lithology and land management

It has been recognized that subsurface lithology plays an important role in controlling nutrient cycling and transport in riparian zones. In Iowa and adjacent states, the majority of alluvium preserved in small and moderate sized valleys consists of Holocene-age organic-rich, and fine-grained loam. In this paper, we describe and evaluate spatial and temporal patterns of lithology and groundwater nutrient concentrations at a riparian well transect across Walnut Creek at the Neal Smith National Wildlife Refuge in Jasper County, Iowa. Land treatment on one side of the stream reduced the grass cover to bare ground and allowed assessment of the effects of land management on nutrient concentrations. Results indicated that groundwater in Holocene alluvium is very nutrient rich with background concentrations of nitrogen, phosphorus and dissolved organic carbon that exceed many environmentally sensitive criteria. Average concentrations of ammonium exceeded 1 mg/l in several wells under grass cover whereas nitrate concentrations exceeded 20 mg/l in wells under bare ground. Phosphate concentrations ranged from 0.1 to 1.3 mg/l and DOC concentrations exceeded 5 mg/l in many wells. Denitrification, channel incision, land management and geologic age of alluvium were found to contribute to variable nutrient loading patterns at the site. Study results indicated that riparian zones of incised streams downcutting through nutrient-rich Holocene alluvium can potentially be a significant source of nutrient loadings to streams. ?? 2008 Springer Science+Business Media B.V.

Biogeochemistry↗

USGS2008

Tile drainage as karst: Conduit flow and diffuse flow in a tile-drained watershed

The similarity of tiled-drained watersheds to karst drainage basins can be used to improve understanding of watershed-scale nutrient losses from subsurface tile drainage networks. In this study, short-term variations in discharge and chemistry were examined from a tile outlet collecting subsurface tile flow from a 963 ha agricultural watershed. Study objectives were to apply analytical techniques from karst springs to tile discharge to evaluate water sources and estimate the loads of agricultural pollutants discharged from the tile with conduit, intermediate and diffuse flow regimes. A two-member mixing model using nitrate, chloride and specific conductance was used to distinguish rainwater versus groundwater inputs. Results indicated that groundwater comprised 75% of the discharge for a three-day storm period and rainwater was primarily concentrated during the hydrograph peak. A contrasting pattern of solute concentrations and export loads was observed in tile flow. During base flow periods, tile flow consisted of diffuse flow from groundwater sources and contained elevated levels of nitrate, chloride and specific conductance. During storm events, suspended solids and pollutants adhered to soil surfaces (phosphorus, ammonium and organic nitrogen) were concentrated and discharged during the rapid, conduit flow portion of the hydrograph. During a three-day period, conduit flow occurred for 5.6% of the time but accounted for 16.5% of the total flow. Nitrate and chloride were delivered primarily with diffuse flow (more than 70%), whereas 80-94% of total suspended sediment, phosphorus and ammonium were exported with conduit and intermediate flow regimes. Understanding the water sources contributing to tile drainage and the manner by which pollutant discharge occurs from these systems (conduit, intermediate or diffuse flow) may be useful for designing, implementing and evaluating non-point source reduction strategies in tile-drained landscapes. ?? 2007 Elsevier B.V. All rights reserved.

Journal of Hydrology↗

USGS2007

Walnut creek watershed monitoring project, Iowa: Monitoring water quality in response to prairie restoration

Land use and surface water data for nitrogen and pesticides (1995 to 1997) are reported for the Walnut Creek Watershed Monitoring Project, Jasper County Iowa. The Walnut Creek project was established in 1995 as a nonpoint source monitoring program in relation to watershed habitat restoration and agricultural management changes implemented at the Neal Smith National Wildlife Refuge by the U.S. Fish and Wildlife Service. The monitoring project utilizes a paired-watershed approach (Walnut and Squaw creeks) as well as upstream/downstream comparisons on Walnut for analysis and tracking of trends. From 1992 to 1997, 13.4 percent of the watershed was converted from row crop to native prairie in the Walnut Creek watershed. Including another 6 percent of watershed farmed on a cash-rent basis, land use changes have been implemented on 19.4 percent of the watershed by the USFWS. Nitrogen and pesticide applications were reduced an estimated 18 percent and 28 percent in the watershed from land use changes. Atrazine was detected most often in surface water with frequencies of detection ranging from 76-86 percent. No significant differences were noted in atrazine concentrations between Walnut and Squaw Creek. Nitrate-N concentrations measured in both watersheds were similar; both basins showed a similar pattern of detection and an overall reduction in nitrate-N concentrations from upstream to downstream monitoring sites. Water quality improvements are suggested by nitrate-N and chloride ratios less than one in the Walnut Creek watershed and low nitrate-N concentrations measured in the subbasin of Walnut Creek containing the greatest amount of land use changes. Atrazine and nitrate-N concentrations from the lower portion of the Walnut Creek watershed (including the prairie restoration area) may be decreasing in relation to the upstream untreated component of the watershed. The frequencies of pesticide detections and mean nitrate-N concentrations appear related to the percentage of row crop in the basins and subbasins. Although some results are encouraging, definitive water quality improvements have not been observed during the first three years of monitoring. Possible reasons include: (1) more time is needed to adequately detect changes; (2) the size of the watershed is too large to detect improvements; (3) land use changes are not located in the area of the watershed where they would have greatest effect; or (4) water quality improvements have occurred but have been missed by the project monitoring design. Longer-term monitoring will allow better evaluation of the impact of restoration activities on water quality.An overview is given on the Walnut Creek Watershed Monitoring Project established as a nonpoint source monitoring program in relation to watershed habitat restoration and agricultural management changes implemented at the Neal Smith National Wildlife Refuge by the U.S. Fish and Wildlife Services. Focus is on land use and surface water data for nitrogen and pesticides. Initial results obtained for the first three years of monitoring are discussed.

Iowa↗