Geology topics

Julia A. McIntosh

Publications and source records attributed to Julia A. McIntosh.

7 recordsLinked to original sources

USGS2026

Tetraphenylborate-assisted extraction of K and Ar from micaceous clay minerals: A promising method for the geochronology of diagenetic illite

Tetraphenylborate (TPB)-assisted exchange of Na + for structural K was explored to establish the extent to which K and radiogenic Ar were removed from mixed-layer illite-smectite (Ilt-Sme) and detrital muscovite in various clay fractions (<1, 1–2 and 2–5 µm) of three Illinois Basin palaeosols and of Ilt-Sme from a K-bentonite (<2 µm) clay. The K–Ar age value of the treated Ilt-Sme was virtually the same as that of the untreated material regardless of TPB exchange duration in the K-bentonite. Interlayer K is extracted quickly but not completely from fine illitic material. Interlayer K is extracted more slowly but more completely from coarser clay-sized muscovite based on changes in X-ray diffraction traces, K contents and K–Ar age values of the palaeosol size fractions upon TPB treatment. One hour of TPB treatment revealed that (1) detrital Ilt-Sme was predominant over diagenetic Ilt-Sme in one palaeosol and (2) relatively more of the K in R0 Ilt-Sme is resistant to TPB treatment than in illite-rich, ordered Ilt-Sme, which indicates that the single illite layers hold K + against TPB exchange in the fine Ilt-Sme. The age values of all palaeosol size fractions treated for several weeks converged into a narrow range (mean value 247 ± 5 Myr), consistent with the remaining K and Ar being predominantly in illitic interlayers of diagenetic origin. TPB treatment is a promising technique to isolate diagenetic (or pedogenic) illite in clay fractions containing detrital components for K–Ar age determinations.

Clay Minerals↗

USGS2026

Geochemical, mineralogical, and isotopic evidence for multi-stage genesis of the Hicks Dome REE + Y-HFSE-fluorite deposit, Illinois, USA

Hicks Dome hosts breccias enriched in rare earth elements (REE), Y, Th, F, Ba, Ti, Nb, and Be, alongside spatially associated lamprophyre dikes (ca. 271 Ma). Hicks Dome is located within the Illinois–Kentucky Fluorspar District, which hosts fluorite, Pb–Zn, and barite resources. This study investigates the genetic relationships between Hicks Dome mineralization in breccias, alkaline magmatism, and Illinois–Kentucky Fluorspar District mineralization. Lamprophyre dikes are light REE–enriched with chondrite-normalized abundances decreasing from La to Lu. The Host Breccia exhibits middle and heavy REE–enriched patterns that mirror those of the principal REE–Th host minerals, including fluorapatite, xenotime, and thorite. Textural evidence suggests recrystallization of phosphates, sulfates, and Ti–Nb oxides in the Host Breccia. U–Pb geochronology constrains multiple mineralizing events, with ages of 277 ± 18 Ma from low-Th apatite interpreted as main-stage mineralization, and 121.6 ± 9.7 Ma from high-Th apatite indicating later overprinting. O–H–C stable isotope data provide evidence for multiple stages of fluid-rock interaction and fluid mixing: (1) early magmatic fluids dissolved limestone country rock, (2) mixing between magmatic fluids and basinal brines led to main-stage mineralization in the Host Breccia, and (3) late-stage mineralization occurred following mixing of meteoric water and basinal brine. These results indicate that heavy REEs, high field strength elements, and fluorine precipitated proximal to its alkaline magmatic source because of fluid–rock interactions and fluid mixing. Subsequent fluid mixing drove late-stage recrystallization and additional fluorite formation, a process that may be similar to mineralization in the Illinois-Kentucky Fluorspar District.

Illinois↗

USGS2026

First vertebrate assemblage from the middle member of the Fremouw Formation (Lower Triassic) of Antarctica

The Fremouw Formation of the Central Transantarctic Mountains preserves the southernmost record of Early to Middle Triassic terrestrial ecosystems that developed in the aftermath of the end-Permian mass extinction. Although the well-studied vertebrate fossil assemblage in the lower member of the Fremouw Formation provides a detailed snapshot of subpolar ecosystems immediately following the end-Permian mass extinction, the nature of how long these earliest Triassic communities persisted at the southern extremes of Pangaea is virtually unknown. Importantly, the timing and extent of the major faunal turnover between the lower and upper members of the Fremouw Formation have been obscured by the paucity of fossil specimens historically recovered from the middle member. Here, we describe the first vertebrate assemblage from the middle member of the Fremouw Formation, including occurrences of procolophonids (including Procolophon trigoniceps ) and archosauromorphs (including Prolacerta broomi ), as well as infilled vertebrate burrow casts referrable to the ichnogenus Reniformichnus . We also summarize and expand on lithostratigraphic shifts between the lower, middle and upper members of the Fremouw Formation. Although the sample size of vertebrate body fossils is small compared to the lower and upper members of the Fremouw Formation, we discuss the evidence for a taphonomic shift between the lower and middle members of the Fremouw Formation that favours preservation of smaller-bodied taxa and individuals in the latter. Together, these preliminary data add crucial context to the persistence of subpolar vertebrate communities in the earliest Mesozoic.

Antarctic Science↗

USGS2026

Estimating paleotemperature using stable isotopes of soil-formed phyllosilicates from paleosols: A review

Fossilized soils, or paleosols, contain soil-formed phyllosilicates whose stable isotopic compositions may be used to calculate paleotemperature and thus reconstruct ancient terrestrial environments. Though paleosols are common in the geologic record, the use of phyllosilicates as paleotemperature proxies is limited in the literature owing to difficulties with selecting optimal paleosols, isolation from non-clay minerals and organic materials, mixtures of phyllosilicates in natural samples, wide variations of chemical compositions for phyllosilicates, and limited to undefined equilibrium fractionation factors between phyllosilicates-water. Here, we address these challenges by examining and comparing methods used for sample selection, mineral isolation, pretreatments, mineral identification, conventional and developing methods for oxygen and hydrogen isotopic analyses, and determination of phyllosilicate-water equilibrium fractionation factors, concluding with recommendations for best approaches for paleotemperature estimation. Additionally, we discuss how to identify and avoid detrital phyllosilicates, the impacts of diagenesis, comparison of stable isotope and non-isotope paleosol paleotemperature proxies, and challenges and opportunities for broadly using paleosols as paleoclimate archives. With ongoing efforts to refine this multi-faceted paleotemperature approach, the stable isotope geochemistry of soil-formed phyllosilicates continues to be an invaluable proxy system, enhancing our understanding of terrestrial paleoenvironments and paleoclimate.

Kansas↗

USGS2025

The impact of burial diagenesis on soil-formed minerals in paleosols using stable isotopes of phyllosilicates and carbonate clumped isotopes

To understand the effects of burial diagenesis on the stable isotope geochemistry of soil-formed clay and carbonate minerals in paleosols, samples were collected from seven cores, spanning middle- to upper-Pennsylvanian strata of the Illinois Basin, with varied maximum burial depths of 1–3 km. Mixed-layer illite-smectite and kaolinite mixtures give δ 2 H and δ 18 O values of −83 ‰ to −36 ‰ and 11.9 ‰ to 21.1 ‰ (VSMOW), respectively. After carbonates were screened petrographically for diagenetic textures using transmitted light and cathodoluminescence, measured clumped isotope Δ 47 values range from 0.504 to 0.563 ‰ (I-CDES). Resulting mineral formation temperatures for phyllosilicate mineral mixtures are 28 to 66 °C (mean = 47 °C), whereas T(Δ 47 ) estimates for calcites are 36 to 61 °C (mean = 45 °C). Calculated δ 18 O water values from which phyllosilicate minerals and calcites precipitated under isotopic equilibrium ranges from −7.1 to −1.2 ‰ and − 1.4 to +4.9 ‰, respectively. Closed and open-system phyllosilicate-fluid exchange modeling indicates that phyllosilicate alteration occurred in the presence of a low temperature brine or meteoric water and is interpreted to occur in a layer-by-layer illitization transformation. Due to the lack of diagenetic textures and positively correlated T(Δ 47 ) and δ 18 O water , calcites are interpreted to have undergone solid-state bond reordering. Despite low to moderate temperatures (<125 °C) and varying depths of shallow burial (1–3 km), solid-state transformation of phyllosilicates and calcites indicates paleosols had prolonged exposure to burial conditions which has implications for the use of paleosol minerals for paleoenvironmental reconstructions.

Illinois, Indiana, Kentucky↗

USGS2025

Comparing magmatism and hydrothermal alteration using magnetic modelling and stable isotopes at the Clementine porphyry copper prospect, Montana, USA

Recent mapping of the underexplored Clementine prospect in southwestern Montana has revealed evidence of hydrothermal alteration and mineralized breccia vein gossan interpreted to represent the upper expression of a Cretaceous, sediment-hosted copper porphyry system. The prospect is at the nexus of several Cretaceous granites, including the pre-mineralization Butte Granite and Big Hole Canyon plutons and local pre- to post-mineralization granite intrusions. Here, 3D magnetic inversions and stable isotope data are used to evaluate the spatial and genetic relationship of mineralization and Cretaceous magmatism. Magnetic inversions reveal a zone of high magnetic susceptibility beneath the prospect that is related to an exposure of unaltered, likely post-mineralization granite. The granite appears to connect to the Big Hole Canyon pluton at depth, suggesting it is a late-stage differentiate of the cooling, pre-mineralization pluton that may have been one of several potential heat sources for the mineral system at Clementine. This is supported by carbon isotope values of graphite that indicate organic material in shale of the Cretaceous Kootenai Formation was subject to metamorphism. Preliminary light hydrogen isotope values of actinolite hydrothermal orbs suggest formation following magmatic outgassing during thermal advection from an underlying intrusion.

Montana↗

USGS2023

Stable isotope constraints on the source of ore fluids for the Hicks Dome REE+Y-HFSE-fluorspar deposit

Hicks Dome is comprised of coarse crystalline Mississippi Valley Type deposits at shallow levels and an enigmatic, fine-grained fluorite, rare earth elements, Y, high field strength elements, Be, and Ba rich deposit at deeper levels. Phyllosilicates from a lamprophyre dike and a breccia from two Hicks Dome drill cores were sampled to resolve the fluid history of the entire deposit using light stable isotopes. Silicate fluorination coupled with isotope ratio mass spectrometry give δ18O values from +6.9 to +16.0 ‰ (Vienna Standard Mean Ocean Water). Temperature conversion elemental analyzer and gas chromatography-isotope ratio mass spectrometry give δ2H values from -54 to -33 ‰ (Vienna Standard Mean Ocean Water). Muscovite from metasomatized dikes and breccias are relatively enriched in 18O compared to phlogopite from lamprophyre. Calculated isotopic compositions of the fluids from which the phyllosilicates precipitated indicate that phlogopite retained a magmatic composition while muscovite likely formed from magmatic fluids that exchanged with carbonate host rocks or from magmatic fluids that mixed with basinal brines. Enrichment of deuterium in fluids calculated from muscovite suggest that fluids were derived from hypothesized carbonatites or were acidic. These data demonstrate that the Hicks Dome critical mineral resource is magmatic hydrothermal in origin.

Illinois↗