Geology topics

Josef P. Werne

Publications and source records attributed to Josef P. Werne.

4 recordsLinked to original sources

USGS2026

Temperature and precipitation source variability and glacial dynamics in the southwestern United States at Fish Lake, Utah, since late MIS 4

An improved understanding of hydroclimate response to natural climate forcings is needed to evaluate impacts of changing seasonal circulation patterns on current and future drought in the southwestern United States (‘the Southwest’). However, few terrestrial records from the Southwest preserve changes in moisture availability continuously prior to the Last Glacial Maximum (LGM, ∼24.5 ka). Fish Lake, in the Upper Colorado River Basin, preserves a long (∼67 ka), continuous, high-resolution (∼3.3 cm/century) sedimentary record spanning from late Marine Isotope Stage (MIS) 4 to present. Here, we investigate the relative contributions of seasonal precipitation and moisture source using the hydrogen isotope value of the n -C 29 leaf wax alkane and changes in temperature using branched glycerol dialkyl glycerol tetraethers (brGDGTs). During the warm post glacial period (14 ka to present), a greater contribution of annual precipitation is sourced from the North American Monsoon (NAM) in response to declining winter insolation and rising greenhouse gases, weakening westerly storms and shifting them northward. MIS 3 (∼61 to 29 ka) is also influenced by NAM inputs, however, to a smaller magnitude than during the post glacial period when temperatures were warmer. However, stadial periods (MIS 2, 29 to 14.1 ka) show 2 H-enriched values, suggesting warm conditions and large contributions of NAM precipitation during the LGM, contradicting other proxies and regional records. The LGM is the only period in the record where glaciers are present in the catchment, thus we hypothesize glacial erosion reworked pre-LGM aged soil organic matter and biased the record during this time.

Utah↗

USGS2025

A 400-k.y. perspective on arc volcanism: An exceptional explosive eruption record from Central Mexico

Volcanic eruption records provide key information for hazard planning but suffer from a time-dependent loss of resolution, hindering long-term evaluations of volcano behavior. Here, we investigate an exceptional sedimentary sequence from Lake Chalco, on the SE edge of Mexico City, which provides a perspective on volcanic activity over hundred-thousand-year time scales, and we develop a methodological and analytical protocol applicable to core datasets globally. The lava-dominated base of the sequence (~105 m) is followed by ~155 m of lateral-collapse derived deposits and overlain by ~295 m of lacustrine sediments containing at least 450 visible tephra fall deposits (TFDs), spanning 400 k.y. These TFDs include 205 events sourced from large-magnitude (predominantly volcanic explosivity index [VEI] ≥5) silicic explosive eruptions, principally from regional polygenetic sources, and 205 deposits from the nearby Sierra Chichinautzin volcanic field (SCVF). A gradual decline in both frequency and apparent magnitude in the silicic eruption record is consistent with the gradual migration of volcanism south along the adjacent Sierra Nevada volcanic range, toward Popocatépetl. In contrast, the SCVF-derived deposits imply persistent but episodic activity, on time scales of 40–70 k.y., suggesting that the SCVF has been more continuously active than previously recognized. Decoupled trends between the SCVF and regional silicic sources implies that the total magmatic flux is not dictated at the arc scale, or by external (e.g., climatic) drivers, but instead reflects the independent development of individual volcanic systems. The records indicate a minimum long-term frequency of impactful eruptions on Mexico City to be one per 900 years (>1 cm tephra deposited) or 9000 years (≥10 cm tephra).

Central Mexico↗

USGS2025

Reaction kinetics and accelerant effects of sulfides in early mature hydrocarbon generation using hydrous pyrolysis

Hydrocarbon generation in organic-rich sediments is influenced by the molecular organic composition and relative abundance of associated minerals. Certain mineral-derived elements act as catalysts and reaction intermediaries, facilitating early-stage hydrocarbon formation in potential source rocks. This study investigated the role of sulfur contributed from pyrite as an accelerant in thermal reaction, focusing on its effects on early maturation and consequent hydrocarbon generation from gilsonite (low-sulfur solid petroleum). Hydrous pyrolysis (HP) experiments were conducted on mixtures of gilsonite and pyrite in varying ratios (1:0.1, 1:0.5, 1:1, 1:2, and 1:10 w/w gilsonite:pyrite) at 320, 350, and 370 °C for 72 h. Untreated and thermally altered residues were analyzed using solid bitumen reflectance (BR o , %), total organic carbon (TOC) content, programmed temperature pyrolysis, scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS), and X-ray diffraction (XRD) to evaluate the potential accelerant role of pyritic sulfur in hydrocarbon formation. The results show HP residues at 320 and 350 °C with greater pyrite concentrations had higher BR o , while reflectance values were similar in the 370 °C residues, regardless of pyrite concentration, suggesting enhanced reaction at lower thermal conditions. Increasing pyrite content systematically decreased hydrogen index (HI) values while increasing the transformation ratio (TR) and production index (PI), indicating enhanced conversion of organic matter to hydrocarbons with increasing pyrite concentrations. Gas yields increased with pyrite addition, particularly at 350 °C, confirming secondary cracking effects. However, gas production stabilized or declined at higher pyrite loadings (1:10), suggesting alternative reaction pathways such as coke formation. Our data indicate the presence of pyrite lowers the activation energy for thermal cracking, shifting peak experimental hydrocarbon generation temperatures downward by 20–30 °C, with the most pronounced accelerant effects observed at moderate pyrite concentrations (1:0.5 and 1:1). The thermodynamic framework reveals that pyrite stability is influenced by experimental conditions, with pyrrhotite formation favored in the presence of gilsonite due to reduced oxygen fugacity. Pyrite transformation to pyrrhotite, as observed through XRD, SEM-EDS, and predicted by thermodynamic data, further supports the accelerant role of S, as pyrrhotite exhibits a higher hydrogen transfer potential, promoting early oil generation. These findings highlight the importance of pyrite in modulating hydrocarbon generation pathways in organic-rich systems.

Journal of Analytical and Applied Pyrolysis↗

USGS2024

Decoding paleomire conditions of Paleogene superhigh-organic-sulfur coals

Superhigh-organic‑sulfur (SHOS) coals (coals with organic sulfur content >4 wt%) are unique coal deposits found at a few notable locations in the world. Specific peat accumulation and preservation conditions must be met to form SHOS coals. Organic sulfur is a major constituent of such coals, and it may have various sources depending on the prevailing paleomire conditions. Understanding such paleomire conditions sheds light on the formation mechanisms of SHOS coals. This investigation decodes the paleomire conditions of the Paleogene SHOS coals from Meghalaya, India, using sulfur isotopic compositions ( δ 34 S) of organic sulfur ( δ 34 S OS ) and pyritic sulfur ( δ 34 S Py ) along with organic petrography, pyrite morphology and trace element ratios. Thirty coal samples were collected from the Jaintia Hills in the east, Khasi Hills in the middle, and Garo Hills in the west of Meghalaya. The organic sulfur content in the Garo, Khasi, and Jaintia coals varies from 1.0 to 3.3 wt%, 1.4 to 13.8 wt%, and 1.0 to 7.2 wt%, respectively. Further, after separation from pyritic sulfur and sulfate sulfur phases, the organic sulfur content ranges from 54.4 to 69.2%, 63.8 to 79.9%, and 59.3 to 73.8%, in the Garo, Khasi, and Jaintia Hills, respectively, suggesting the SHOS nature of these coal samples. The δ 34 S Py varies from −29.3 ‰ to +5.7 ‰, −21.3 ‰ to +27.3 ‰, and −12.1 ‰ to −4.3 ‰, in the Jaintia, Khasi, and Garo Hills, respectively, while the δ 34 S OS fluctuates from −4.6 ‰ to +3.7 ‰, −9.3 ‰ to +7.8 ‰, and − 9.0 ‰ to −5.0 ‰, respectively. The δ 34 S values of pyrite and organic sulfur (OS) in Jaintia coals are 34 S depleted compared to seawater sulfate (+22 ‰), leading to fractionations in the range of −51.3 ‰ to −16.3 ‰ (mean − 31.6 ‰) and − 26.6 ‰ to −18.3 ‰ (mean − 23.1 ‰) for pyritic and organic sulfur (OS), respectively. Pyrite in Khasi coals show a relatively heavier δ 34 S composition averaging at −20.5 ‰, whereas organic sulfur (OS) isotope compositions range from −31.3 ‰ to −14.2 ‰ with a mean of −22.6 ‰. Pyrite and OS in the Garo coals are depleted compared to seawater sulfate. Isotope variations in the Jaintia, Khasi, and Garo coals indicate microbial sulfate reduction (MSR) of seawater sulfate. Large isotopic fractionations between Eocene seawater sulfate and pyritic sulfur ( Δ 34 S SO4Eocene – pyrite = up to −51.3 ‰; mean − 31.6 ‰) in Jaintia coals indicate their possible formation in the water column/near the sediment-seawater interface (open system) and also hint toward dissimilatory sulfate reduction pathways that prevailed under anoxic redox conditions. However, mean values of Δ 34 S SO4Eocene – pyrite (−20.5 ‰) in the Khasi coals imply pyrite formation deeper in the sediments (more closed system) under dysoxic conditions. The dominance of OS over pyritic sulfur, framboidal pyrite, and its microcrystal size distributions in Jaintia coals may suggest syngenetic pyrite formation in open water reducing/anoxic conditions under paralic environments. Elevated Sr/Ba and U/Th values in these coals further confirm the anoxic conditions. Nevertheless, the presence of euhedral pyrite with the alleviated pyrite framboids in the Khasi coals and their complete absence in the Garo coals may suggest dysoxic-suboxic and suboxic-oxic depositional conditions, respectively. The isotopic signatures of the Garo coals suggest sulfur contribution from the parent paleobiota and MSR under a freshwater-oxic environment. Insignificant fractionations between δ 34 S Py and δ 34 S OS indicate limited iron and sulfate availability for additional sulfur cycling and disproportionation reactions, typical of oxic conditions. The absence of framboidal pyrite, elevated sulfate concentration, and mean Sr/Ba and U/Th values of 0.5 and 0.3, respectively, further suggest the freshwater peat deposition in the Garo Hills under limnotelmatic to telmatic freshwater conditions. Moreover, high inertinite content (I mmf = 9.77–33.16 vol%), possibly induced by atmospheric peat exposure, supports the interpretation of suboxic-oxic paleomire conditions in Garo Hills. Gradually decreasing mineral matter content from Jaintia (mean 13.6 vol%) to Garo coals (mean 7.4 vol%) additionally projects a transition from mesotrophic brackish to freshwater limnotelmatic environment, complementing the shift in the paleomire condition from eastern (Jaintia) to western (Garo) Meghalayan Hills.

International Journal of Coal Geology↗