Geology topics

Jorge A. Vazquez

Publications and source records attributed to Jorge A. Vazquez.

At least 37 records · Page 2Linked to original sources

USGS2021

U–Pb zircon eruption age of the Old Crow tephra and review of extant age constraints

Eruption of the Old Crow tephra deposited ~200 km 3 of volcanic ash throughout Alaska and the northwestern Yukon (eastern Beringia), providing an isochronous marker across the region on a scale unique in the Pleistocene. The Old Crow tephra represents a critical temporal piercing point used extensively to link geographically disparate stratigraphic sections and the paleo-environmental records they contain. Although the canonical age of the Old Crow suggests eruption during the transition between the glacial and interglacial periods of Marine Isotope Stages (MIS) 5 and 6 at ~125 ka, recent U–Th–Pb and (U–Th)/He zircon dating of the tephra suggests eruption at ~200 ka, within MIS 7. If accurate, this revised eruption age begets significant change to existing models describing the geologic and biotic evolution of Beringia in the Pleistocene. Thus, confidently knowing the age of the tephra is critical to its time-stratigraphic utility and for past and future work in the region where the tephra has been found. With this contribution, we review existing Old Crow age constraints and present an eruption age for the tephra determined via high spatial resolution ion microprobe U–Pb surface analysis on zircon crystals isolated from source-proximal (<500 km from plausible source) pumiceous pyroclasts of the tephra. By dating only glass-mantled crystals isolated from discrete pumice clasts, we limit the potential for sample contamination from exotic crystals and resulting age bias. The young population of dates from this dataset corroborate previous radiometric dates and confirm Old Crow eruption within late MIS 7 at 207 ± 13 ka.

Alaska↗

USGS2021

Stop 3 – The Petersburg “Granite” redefined: Recognition and implications of Silurian to Devonian rocks in central-eastern Virginia

Introduction Although the Petersburg Granite had long been in practical use as a building stone since the 1830s (Watson, 1906; 1907; 1910; Darton, 1911; Steidtmann, 1945), it was first formally defined as a geologic unit by Anna Jonas on the 1928 geologic map of Virginia. Anna Jonas defined this unit as a Precambrian coarse-grained porphyritic biotite granite that was intruded by finer grained granite and cut by pegmatite (Nelson, 1928). This belt of mostly granitic rocks extends from near Ashland, Virginia north of Richmond, to near Stony Creek, south of Petersburg, Virginia (e.g., Virginia Division of Mineral Resources, 1993) and is bounded by the Hylas fault zone to the northwest, the Mesozoic Richmond basin to the west, and the newly recognized Nottoway River fault zone to the southwest (e.g., Carter and others, 2020; 2021). The eastern boundary of this belt is covered by Coastal Plain sediments, but geophysical and deep borehole data suggest an orogen-scale suture separates it from the Neoproterozoic Chesapeake block to the east (Figure 1; Carter and others, 2021).

Virginia↗

USGS2020

Photoluminescence imaging of whole zircon grains on a petrographic microscope—An underused aide for geochronologic studies

The refractory nature of zircon to temperature and pressure allows even a single zircon grain to preserve a rich history of magmatic, metamorphic, and hydrothermal processes. Isotopic dating of micro-domains exposed in cross-sections of zircon grains allows us to interrogate this history. Unfortunately, our ability to select the zircon grains in a heavy mineral concentrate that records the most geochronologic information is limited by our inability to predict internal zonation from observations of whole grains. Here we document the use of a petrographic microscope to observe and image the photoluminescence (PL) response of whole zircon grains excited under ultraviolet (UV) light, and the utility of this PL response in selecting grains for geochronology. While zircon fluorescence has long been known, there is limited documentation of its utility for and application to geochronologic studies. Our observations of zircon from an un-metamorphosed igneous rock, two meta-igneous rocks, and a placer deposit show that variations in the PL color are readily observable in real-time, both among grains in a population of zircons and within single grains. Analyses of cross-sections of the same grains demonstrate that the changes in PL correlate with zoning in backscattered electron (BSE) and cathodoluminescence (CL) images as well as with changes in U + Th concentration and spectroscopic proxies for radiation damage. In other words, the whole grain PL provides a low-resolution preview of the U + Th zoning expected in a cross-sectioned grain. We demonstrate the usefulness of this “preview” in identifying and selecting the subset of zircon grains in a heavy mineral separate that has metamorphic rims of sufficient width to date by secondary ionization mass spectrometry (SIMS). The data are also used to place preliminary constraints on the age and U + Th concentrations at which a yellow PL response is observed in natural samples. The PL response of zircon is well-known among spectroscopists, and these simple applications demonstrate several ways in which the response might be more effectively used by geochronologists.

Minerals↗

USGS2020

The remarkable volcanism of Shastina, a stratocone segment of Mount Shasta, California

Mount Shasta, a 400 km 3 volcano in northern California (United States), is the most voluminous stratocone of the Cascade arc. Most Mount Shasta lavas vented at or near the present summit; relatively smaller volumes erupted from scattered vents on the volcano’s flanks. An apron of pyroclastic and debris flows surrounds it. Shastina, a large and distinct cone on the west side of Mount Shasta, represents a brief but exceptionally vigorous period of eruptive activity. Its volume of ∼13.5 km 3 would make Shastina itself one of the larger Holocene Cascade stratovolcanoes. Its andesite-dacite lavas average 63 wt% SiO 2 and have little compositional or petrographic variation; they erupted almost entirely from one central vent, although a single vent below Shastina’s north side erupted a flow of the same composition. Eruptions ended with explosive enlargement and breaching of the central crater and successive emplacement of four, more-silicic dacite domes within the crater and pyroclastic flows down its flank. Black Butte, a large volcanic dome and pyroclastic complex below the west flank of Shastina, is petrographically and chemically distinct but only slightly younger than Shastina itself, part of a nearly continuous Shastina–Black Butte eruptive episode. Shastina overlies the widespread pumice of Red Banks, erupted from the Mount Shasta summit area and 14 C dated at ca. 10,900 yr B.P. (calibrated). Shastina and Black Butte pyroclastic deposits have calibrated 14 C ages indistinguishable from one another at ca. 10,700 cal. yr B.P. A cognate granitic-textured inclusion in a late Shastina lava flow yields a 238 U- 230 Th date on zircons within error of those ages. Our conclusion that the entire, voluminous Shastina–Black Butte episode lasted no more than a few hundred years is confirmed by almost identical remanent magnetic directions of all of the lavas and pyroclastic deposits. Although extremely similar, the remanent magnetic directions do reveal a short path of secular variation through the eruptive sequence. We conclude that the entire Shastina–Black Butte eruptive episode lasted no more than ∼200 yr. The magmas that produced the Shastina and Black Butte eruptions were separate individual bodies at different crustal levels. Each of these eruptive sequences probably represents magma approximating a liquid composition that experienced only minimal differentiation or crustal contamination and remained separated from the main central conduit for most eruptions of Mount Shasta. The probability of another rapidly developing, brief but voluminous eruptive episode at Mount Shasta is low but should not be ignored in evaluating future possible eruptive hazards.

California↗

USGS2020

Timescales of magmatic processes in post-collisional potassic lavas, northwestern Tibet

Post-collisional potassic volcanic rocks on the Tibetan Plateau are widespread, but geologically young (<375 ka) volcanism suitable for 238 U- 230 Th geochronology is rare on the plateau. The geologically young Ashikule volcanic field from northern Tibet offers an excellent opportunity for studying high-resolution timescales of magmatism in continental collision zones. Here we report U-Th crystallization ages of zircons from Ashishan volcano and Wulukeshan volcano within the Ashikule volcanic field. In this study, we have identified 3 pulses of zircon crystallization at circa 70 ka, 105 ka, and 290 ka for Ashishan volcanic rocks and 1 pulse of zircon crystallization at circa 115 ka for Wulukeshan. Comparison of high-resolution zircon crystallization ages of 70 ka and 105 ka with respective eruption ages indicate that the zircon crystal residence time for the Ashishan volcano is short (<5 kyr). The presence of 290-ka zircon in a different Ashishan lava flow suggests the 270-ka volcanic pulse previously reported for other volcanoes in Ashikule volcanic field also occurred at Ashishan. The zircon crystallization age of ~115 ka for Wulukeshan volcano suggests that Wulukeshan volcano erupted later than previously inferred. Similar zircon age spectrums of ~105–115 ka for Ashishan and Wulukeshan volcanoes suggest a common interconnected subsurface magma reservoir for these two young volcanoes during Pleistocene time. Our new high-resolution U-Th zircon age data reveal that post-collisional potassic magmas below northern Tibet erupted soon after their formation (<5 kyr), in spite of their passage through thick continental crust. The high abundance (~60%) of geologically old (>375 ka) zircons demands for crystal-scale isotope studies of the widespread post-collisional lavas in continental collision zones, as the complexities cannot be resolved by bulk analysis methods alone.

LITHOS↗

USGS2019

Coexisting discrete bodies of rhyolite and punctuated volcanism characterize Yellowstone's post‐Lava Creek Tuff caldera evolution

Ion‐microprobe 206 Pb/ 238 U geochronology and trace element geochemistry of the unpolished rims and sectioned interiors of zircons from Yellowstone caldera's oldest post‐caldera lavas provide insight into the magmatic system during the prelude and aftermath of the caldera‐forming Lava Creek supereruption. The post‐caldera lavas compose the Upper Basin Member of the Plateau Rhyolite and fall into two groups based on zircon crystallization age: early lavas with zircon ages between ~750 and 550 ka and late lavas with zircon ages between ~350 and 250 ka. Zircons from the early‐erupted East Biscuit Basin flow yield U‐Pb dates and trace element compositions, which when considered with the Pb isotopic compositions of their coexisting feldspars and pyroxenes, point to an isotopically distinct parental melt present during crystallization of the Lava Creek magma but untapped by the supereruption. Distinct zircon crystallization ages and Pb‐isotope compositions of major minerals between the early and late Upper Basin Member groups suggest contrasting sources in the magma reservoir. As proxies for melt evolution, the zircons indicate that Yellowstone's post‐caldera rhyolites became more evolved between mid‐ to late‐Pleistocene time, during the same interval that melting of hydrothermally altered wall rock and recharge by new silicic magmas changed in their relative roles. The results from this study indicate that discrete and ephemeral bodies of silicic magma, at times within a mush dominated reservoir and including during the prelude to the Lava Creek eruption, have characterized Yellowstone's subvolcanic reservoir.

Wyoming↗

USGS2019

Geochronologic, isotopic, and geochemical data from igneous rocks in the Lane Mountain area, San Bernardino County, California

We present new geochronologic, isotopic, and geochemical data for selected igneous rocks in the Lane Mountain area, California. We determined SHRIMP-RG U-Pb zircon ages for the following units: (1) Larrea complex (~253 Ma and ~149–146 Ma); (2) Daisy granodiorite (~151 Ma); (3) Jack Spring quartz monzonite (~85–82 Ma); (4) unnamed porphyritic dikes and stocks (~80–73 Ma); and (5) Lane Mountain volcanics (~22 Ma). These results confirm and refine previous age determinations for the Larrea complex, Jack Spring quartz monzonite, and Lane Mountain volcanics, and provide the first reliable ages for the Daisy granodiorite and the unnamed porphyritic rocks. Sri of the plutonic rocks increases from ~0.704 to ~0.705–0.706 to ~0.708–0.709 for samples dated as ~250, ~150, and ~85–70 Ma, respectively, which indicates progressively greater involvement of Precambrian continental lithosphere in magma generation through time. The Sri and geochemical data suggest that the most significant change in magmatic source occurred between ~150 and 85 Ma.

California↗

USGS2019

Diverse late‐stage crystallization and storage conditions in melt domains from the Youngest Toba Tuff revealed by age and compositional heterogeneity in the last increment of accessory phase growth

The chemical record contained within the nal increment of growth on crystals is utilized to reveal the dynamics and time- scales of magma assembly and storage before eruption of the cataclysmic 2800 km3 Youngest Toba Tu (YTT), Indonesia. In situ U–Th disequilibrium dates and trace element concentrations were obtained via secondary ionization mass spectrometry (SIMS) on unsectioned and unpolished faces of individual zircon and allanite crystals. The six high-silica (> 73 wt% SiO2) pumices from which crystals were derived are among the more evolved and lower crystallinity (< 25 wt%) pumices from the YTT eruption, and likely represent the melt-dominated portion of the magma system. Discrete SIMS measurement cycles were coupled with statistical treatments to detect zircon and allanite surface zoning domains at the ~ 1 μm scale. Coupled r-MELTS and accessory phase saturation modeling indicates that at the granite ternary minimum or ‘eutectoid’ conditions that de ne this portion of the YTT, zircon and allanite crystallization is dependent on and proportionate to major phase crystallization, and is more limited than at pre-eutectoid conditions. A lower proportion of near-eruption zircon surface ages in the comparatively cool and wet YTT relative to other hotter and drier voluminous silicic eruptions could re ect the in u- ence of eutectoid storage conditions on magmatic responses to remobilization-related magmatic recharge.

Youngest Toba Tuff↗

USGS2019

Constraining the early eruptive history of the Mono Craters rhyolites, California, based on 238U–230Th isochron dating of their explosive and effusive products

The Mono Craters are an overlapping chain of at least 28 domes and coulees located south of Mono Lake, east central California, and represent the most recent eruptions of high‐silica rhyolite magma in the Mono Lake‐Long Valley volcanic region. Regionally widespread tephra fall deposits from the Mono Craters serve as important chronostratigraphic markers for correlations of late Quaternary terrestrial archives in the western United States. A well‐resolved eruption chronology for the Mono Craters is thus not only critical for volcanic hazard considerations but also for paleoclimatic and paleomagnetic studies. Here we constrain the timing of early Mono Craters volcanism using ion microprobe 238 U‐ 230 Th dating of unpolished crystal faces of autocrystic zircon and allanite microphenocrysts, which samples the final stage of crystallization prior to eruption. The stratigraphically oldest domes (biotite‐bearing rhyolites) yield 238 U‐ 230 Th isochron dates between ca. 42 and ca. 19 ka and are unambiguously linked to dated tephras in the Wilson Creek formation of ancestral Mono Lake via coupled 238 U‐ 230 Th geochronology and titanomagnetite geochemistry. The second oldest set of domes (orthopyroxene‐bearing rhyolites) have overlapping 238 U‐ 230 Th isochron dates that are within uncertainty of published K/Ar and 40 Ar/ 39 Ar dates for the fayalite‐bearing rhyolite domes, suggesting a period of intense effusive activity for the Mono Craters near the Pleistocene‐Holocene boundary. Our new and previously published 238 U‐ 230 Th dates for tephras in the Wilson Creek formation provide robust geochronologic constraints for the controversial geomagnetic excursion recorded in the Wilson Creek formation.

California↗

USGS2019

On the eruption age and provenance of the Old Crow tephra

Tephrochronology is used to correlate and reconstruct geographically disparate sedimentary records of changing environment, climate, and landscape throughout geologic time. Single tephra layers represent isochronous markers across broad regions, thus accurate and precise radiometric constraints on the timing of eruption are critical to their utility. The Old Crow tephra is found throughout eastern Beringia and represents the largest preserved Pleistocene ashfall event in the region. Despite its volume and significance as a stratigraphic marker, the provenance of this tephra is debated, and the interpreted eruption age of marine isotope stage (MIS) 5 at ∼125 ka has vacillated. To investigate provenance and eruption age, we develop a geochemical fingerprint for the Old Crow tephra via titanomagnetite geochemistry, and zircon crystallization/cooling age via coupled U/Pb, U/Th, and (U Th)/He zircon geochronology. Our results indicate that Old Crow oxides are geochemically distinct from the commonly assumed source-caldera system at the Emmons Lake Volcanic Center (ELVC). Zircon crystals from the Old Crow tephra range in age from Proterozoic to Pleistocene, with concordant zircon U/Pb, U/Th, and (U Th)/He dates on the youngest population of grains suggesting crystallization in their parent magma, and in turn eruption, at 202.9 ± 9.5 ka. We discuss strengths and shortcomings of our radiogenic datasets in light of this result and review the far-reaching implications of a change in Old Crow eruption age.

Alaska↗

USGS2018

Trace element characterisation of MAD‐559 zircon reference material for ion microprobe analysis

We document the composition of a natural zircon gemstone sourced from Madagascar, MAD‐559 – a new reference material for calibrating trace element mass fractions in zircon measured by SIMS. The composition of MAD‐559 was quantified by calibration relative to the well‐documented zircon reference material 91500, for which we compiled existing published data (Mg, Al, Y, rare earth elements, Hf, U, Th) and performed new measurements to characterise the mass fraction of less commonly measured elements (Li, Be, B, F, Na, P, K, Ca, Sc, Ti, Fe, Nb). Measurement results of SL13, CZ3 and MAD‐1 zircons and NIST SRM glasses were performed as quality control materials to test measurement bias and repeatability. We show the intermediate precision for most trace element measurement results of MAD‐559 to be between ± 3% and ± 5% RSD based on 139 measurements by SIMS on twenty‐five individual polished zircon chips measured during a 24‐h period, as well as repeat measurements performed over five separate analytical sessions. Trace element mass fractions were also measured by LA‐ICP‐MS in two different laboratories, and major element compositions measured by electron microprobe, to compare with results measured by SIMS. Based on laser Raman and hyperspectral cathodoluminescence spectroscopy, we show MAD‐559 to have high crystal disorder due to radiation damage relative to crystalline zircon (e.g., SL13 and 91500 zircon). Although the high cumulative alpha dose of MAD‐559 zircon makes it a poor reference material for geochronology, the consistency of the trace element mass fraction results measured in multiple sessions and by various measurement methods shows that it is an ideal reference material for microanalytical trace element mass fraction quantification of zircon.

Geostandards and Geoanalytical Research↗

USGS2017

A field trip guide to the petrology of Quaternary volcanism on the Yellowstone Plateau

The Yellowstone Plateau is one of the largest manifestations of silicic volcanism on Earth, and marks the youngest focus of magmatism associated with the Yellowstone Hot Spot. The earliest products of Yellowstone Hot Spot volcanism are from ~17 million years ago, but may be as old as ~32 Ma, and include contemporaneous eruption of voluminous mafic and silicic magmas, which are mostly located in the region of northwestern Nevada and southeastern Oregon. Since 17 Ma, the main locus of Yellowstone Hot Spot volcanism has migrated northeastward producing numerous silicic caldera complexes that generally remain active for ~2–4 million years, with the present-day focus being the Yellowstone Plateau. Northeastward migration of volcanism associated with the Yellowstone Hot Spot resulted in the formation of the Snake River Plain, a low relief physiographic feature extending ~750 kilometers from northern Nevada to eastern Idaho. Most of the silicic volcanic centers along the Snake River Plain have been inundated by younger basalt volcanism, but many of their ignimbrites and lava flows are exposed in the extended regions at the margins of the Snake River Plain .

Wyoming↗

USGS2017

Geologic map of the Providence Mountains in parts of the Fountain Peak and adjacent 7.5' quadrangles, San Bernardino County, California

Introduction The Providence Mountains are in the eastern Mojave Desert about 60 km southeast of Baker, San Bernardino County, California. This range, which is noted for its prominent cliffs of Paleozoic limestone, is part of a northeast-trending belt of mountainous terrain more than 100 km long that also includes the Granite Mountains, Mid Hills, and New York Mountains. Providence Mountains State Recreation Area encompasses part of the range, the remainder of which is within Mojave National Preserve, a large parcel of land administered by the National Park Service. Access to the Providence Mountains is by secondary roads leading south and north from Interstate Highways 15 and 40, respectively, which bound the main part of Mojave National Preserve. The geologic map presented here includes most of Providence Mountains State Recreation Area and land that surrounds it on the north, west, and south. This area covers most of the Fountain Peak 7.5′ quadrangle and small adjacent parts of the Hayden quadrangle to the north, the Columbia Mountain quadrangle to the northeast, and the Colton Well quadrangle to the east. The map area includes representative outcrops of most of the major geologic elements of the Providence Mountains, including gneissic Paleoproterozoic basement rocks, a thick overlying sequence of Neoproterozoic to Triassic sedimentary rocks, Jurassic rhyolite that intrudes and overlies the sedimentary rocks, Jurassic plutons and associated dikes, Miocene volcanic rocks, and a variety of Quaternary surficial deposits derived from local bedrock units. The purpose of the project was to map the area in detail, with primary emphasis on the pre-Quaternary units, to provide an improved stratigraphic, structural, and geochronologic framework for use in land management applications and scientific research.

California↗

USGS2017

Fitful and protracted magma assembly leading to a giant eruption, Youngest Toba Tuff, Indonesia

The paroxysmal eruption of the 74 ka Youngest Toba Tuff (YTT) of northern Sumatra produced an extraordinary 2800 km 3 of non-welded to densely welded ignimbrite and co-ignimbrite ash-fall. We report insights into the duration of YTT magma assembly obtained from ion microprobe U-Th and U-Pb dates, including continuous age spectra over >50% of final zircon growth, for pumices and a welded tuff spanning the compositional range of the YTT. A relatively large subpopulation of zircon crystals nucleated before the penultimate caldera-related eruption at 501 ka, but most zircons yielded interior dates 100-300 ka thereafter. Zircon nucleation and growth was likely episodic and from diverse conditions over protracted time intervals of >100 to >500 ka. Final zircon growth is evident as thin rim plateaus that are in Th/U chemical equilibrium with hosts, and that give crystallization ages within tens of ka of eruption. The longevity and chemical characteristics of the YTT zircons, as well as evidence for intermittent zircon isolation and remobilization associated with magma recharge, is especially favored at the cool and wet eutectoid conditions that characterize at least half of the YTT, wherein heat fluxes could dissolve major phases but have only a minor effect on larger zircon crystals. Repeated magma recharge may have contributed to the development of compositional zoning in the YTT but, considered together with limited allanite, quartz, and other mineral dating and geospeedometry, regular perturbations to the magma reservoir over >400 ka did not lead to eruption until 74 ka ago.

Lake Toba↗

USGS2017

Secondary ionization mass spectrometry analysis in petrochronology

The goal of petrochronology is to extract information about the rates and conditions at which rocks and magmas are transported through the Earth’s crust. Garnering this information from the rock record greatly benefits from integrating textural and compositional data with radiometric dating of accessory minerals. Length scales of crystal growth and diffusive transport in accessory minerals under realistic geologic conditions are typically in the range of 1–10’s of μm, and in some cases even substantially smaller, with zircon having among the lowest diffusion coefficients at a given temperature (e.g., Cherniak and Watson 2003 ). Intrinsic to the compartmentalization of geochemical and geochronologic information from intra-crystal domains is the requirement to determine accessory mineral compositions using techniques that sample at commensurate spatial scales so as to not convolute the geologic signals that are recorded within crystals, as may be the case with single grain or large grain fragment analysis by isotope dilution thermal ionization mass spectrometry (ID-TIMS; e.g., Schaltegger and Davies 2017 , this volume; Schoene and Baxter 2017 , this volume). Small crystals can also be difficult to extract by mineral separation techniques traditionally used in geochronology, which also lead to a loss of petrographic context. Secondary Ionization Mass Spectrometry, that is SIMS performed with an ion microprobe, is an analytical technique ideally suited to meet the high spatial resolution analysis requirements that are critical for petrochronology ( Table 1 ).

Book chapter↗

USGS2016

Geologic history of Martian regolith breccia Northwest Africa 7034: Evidence for hydrothermal activity and lithologic diversity in the Martian crust

The timing and mode of deposition for Martian regolith breccia Northwest Africa (NWA) 7034 were determined by combining petrography, shape analysis, and thermochronology. NWA 7034 is composed of igneous, impact, and brecciated clasts within a thermally annealed submicron matrix of pulverized crustal rocks and devitrified impact/volcanic glass. The brecciated clasts are likely lithified portions of Martian regolith with some evidence of past hydrothermal activity. Represented lithologies are primarily ancient crustal materials with crystallization ages as old as 4.4 Ga. One ancient zircon was hosted by an alkali-rich basalt clast, confirming that alkalic volcanism occurred on Mars very early. NWA 7034 is composed of fragmented particles that do not exhibit evidence of having undergone bed load transport by wind or water. The clast size distribution is similar to terrestrial pyroclastic deposits. We infer that the clasts were deposited by atmospheric rainout subsequent to a pyroclastic eruption(s) and/or impact event(s), although the ancient ages of igneous components favor mobilization by impact(s). Despite ancient components, the breccia has undergone a single pervasive thermal event at 500–800°C, evident by groundmass texture and concordance of ~1.5 Ga dates for bulk rock K-Ar, U-Pb in apatite, and U-Pb in metamict zircons. The 1.5 Ga age is likely a thermal event that coincides with rainout/breccia lithification. We infer that the episodic process of regolith lithification dominated sedimentary processes during the Amazonian Epoch. The absence of pre-Amazonian high-temperature metamorphic events recorded in ancient zircons indicates source domains of static southern highland crust punctuated by episodic impact modification.

Journal of Geophysical Research E: Planets↗

USGS2016

The role of crystallization-driven exsolution on the sulfur mass balance in volcanic arc magmas

The release of large amounts of sulfur to the stratosphere during explosive eruptions affects the radiative balance in the atmosphere and consequentially impacts climate for up to several years after the event. Quantitative estimations of the processes that control the mass balance of sulfur between melt, crystals, and vapor bubbles is needed to better understand the potential sulfur yield of individual eruption events and the conditions that favor large sulfur outputs to the atmosphere. The processes that control sulfur partitioning in magmas are (1) exsolution of volatiles (dominantly H 2 O) during decompression (first boiling) and during isobaric crystallization (second boiling), (2) the crystallization and breakdown of sulfide or sulfate phases in the magma, and (3) the transport of sulfur-rich vapor (gas influx) from deeper unerupted regions of the magma reservoir. Vapor exsolution and the formation/breakdown of sulfur-rich phases can all be considered as closed-system processes where mass balance arguments are generally easier to constrain, whereas the contribution of sulfur by vapor transport (open system process) is more difficult to quantify. The ubiquitous “excess sulfur” problem, which refers to the much higher sulfur mass released during eruptions than what can be accounted for by amount of sulfur originally dissolved in erupted melt, as estimated from melt inclusion sulfur concentrations (the “petrologic estimate”), reflects the challenges in closing the sulfur mass balance between crystals, melt, and vapor before and during a volcanic eruption. In this work, we try to quantify the relative importance of closed- and open-system processes for silicic arc volcanoes using kinetic models of sulfur partitioning during exsolution. Our calculations show that crystallization-induced exsolution (second boiling) can generate a significant fraction of the excess sulfur observed in crystal-rich arc magmas. This result does not negate the important role of vapor migration in sulfur mass balance but rather points out that second boiling (in situ exsolution) can provide the necessary yield to drive the excess sulfur to the levels observed for crystal-rich systems. In contrast, in crystal-poor systems, magma recharge that releases sulfur-rich bubbles is necessary and most likely the primary contributor to sulfur mass balance. Finally, we apply our model to account for the effect of sulfur partitioning during second boiling and its impact on sulfur released during the Cerro Galan supereruption in Argentina (2.08 Ma) and show the potential importance of second boiling in releasing a large amount of sulfur to the atmosphere during the eruption of large crystal-rich ignimbrites.

Journal of Geophysical Research B: Solid Earth↗

USGS2016

Chemical abrasion-SIMS (CA-SIMS) U-Pb dating of zircon from the late Eocene Caetano caldera, Nevada

Zircon geochronology is a critical tool for establishing geologic ages and time scales of processes in the Earth's crust. However, for zircons compromised by open system behavior, achieving robust dates can be difficult. Chemical abrasion (CA) is a routine step prior to thermal ionization mass spectrometry (TIMS) dating of zircon to remove radiation-damaged parts of grains that may have experienced open system behavior and loss of radiogenic Pb. While this technique has been shown to improve the accuracy and precision of TIMS dating, its application to high-spatial resolution dating methods, such as secondary ion mass spectrometry (SIMS), is relatively uncommon. In our efforts to U-Pb date zircons from the late Eocene Caetano caldera by SIMS (SHRIMP-RG: sensitive high resolution ion microprobe, reverse geometry), some grains yielded anomalously young U-Pb ages that implicated Pb-loss and motivated us to investigate with a comparative CA and non-CA dating study. We present CA and non-CA 206 Pb/ 238 U ages and trace elements determined by SHRIMP-RG for zircons from three Caetano samples (Caetano Tuff, Redrock Canyon porphyry, and a silicic ring-fracture intrusion) and for R33 and TEMORA-2 reference zircons. We find that non-CA Caetano zircons have weighted mean or bimodal U-Pb ages that are 2–4% younger than CA zircons for the same samples. CA Caetano zircons have mean U-Pb ages that are 0.4–0.6 Myr older than the 40 Ar/ 39 Ar sanidine eruption age (34.00 ± 0.03 Ma; error-weighted mean, 2σ), whereas non-CA zircons have ages that are 0.7–1.3 Myr younger. U-Pb ages do not correlate with U (~ 100–800 ppm), Th (~ 50–300 ppm) or any other measured zircon trace elements (Y, Hf, REE), and CA and non-CA Caetano zircons define identical trace element ranges. No statistically significant difference in U-Pb age is observed for CA versus non-CA R33 or TEMORA-2 zircons. Optical profiler measurements of ion microprobe pits demonstrate consistent depths of ~ 1.6 μm for CA and non-CA Caetano, R33 and TEMORA-2 zircons, and do not indicate variations in secondary ion sputtering rates due to chemical or structural changes from the CA treatment. Our new data underscore the potential for cryptic Pb-loss to go unrecognized in other geologically young magmatic centers that do not have zircons with high U, statistically discordant isotope ratios, high common Pb, or metamict textures.

Nevada↗