Brown, yellow, orange, and greenish-black thorites from the Seerie pegmatite, Colorado
Four types of thorite - brown, yellow, orange, and greenish-black - occur together in narrow fracture fillings rich in brown fluorite near the outer edge of the Seerie pegmatite. The brown thorite is by far the most abundant. The thorites are remarkably similar in composition except for their Fe 2 O 3 and UO 2 contents. The common brown thorite contains about 5 percent Fe 2 O 3 , but the other types have only about 0.3 percent. The greenish-black thorite contains about 15 percent UO 2 ; the yellow and orange, about 7 percent; and the brown, about 3 percent. All four thorites have high total rare-earth oxide contents, which vary from 17.3 to 20 percent. The rare-earth assemblage is unusual in that the heavy rare earths predominate, ytterbium being the most abundant lanthanide. Unheated brown and yellow thorites gave thorite X-ray patterns, but the orange and greenish-black types are metamict. All the thorites gave a ThO 2 -UO 2 X-ray pattern as well as a thorite pattern after heating in air for 1- and 2-hour periods at 1,000°C. In addition, the pattern of the greenish-black thorite contained peaks which we ascribe to a second UO 2 compound. Minute black inclusions present in the greenish-black thorite were identified as uraninite by microprobe analysis.