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John L. Fio

Publications and source records attributed to John L. Fio.

11 recordsLinked to original sources

Groundwater flow and solute movement to drain laterals, western San Joaquin Valley, California: 1. Geochemical assessment

A study was undertaken to quantitatively evaluate the hydrologic processes affecting the chemical and isotopic composition of drain lateral water in a drained agricultural field in the western San Joaquin Valley, California. The results elucidate the process of mixing of deep and shallow groundwater (below and within 6 m from land surface) entering the drain laterals. The deep groundwater was subject to evapoconcentration prior to drainage system installation and has been displaced downward (to depths greater than 6 m) in the groundwater system. The proportions of deep and shallow groundwater entering the drain laterals was calculated from the end-member oxygen 18 compositions determined in groundwater samples. The percentage of total drain lateral flow which is deep groundwater flow is about 30% for the shallow drain lateral (1.8 m below land surface) (drain lateral 1)) and 60% for the deep drain lateral (2.7 m below land surface (drain lateral 2)). During irrigation, the percentages of deep groundwater flow decrease to 0 and 30% for the shallow and deep drain laterals, respectively. Selenium concentrations in drain lateral waters decrease during irrigation but selenium loads increase. Total estimated annual loads were 1.1 and 5.4 kg of selenium for drain laterals 1 and 2, respectively. Substantial percentages of the annual load occurred during 8 days of irrigation, 23 and 9% for drain laterals 1 and 2, respectively.

California

Groundwater flow and solute movement to drain laterals, western San Joaquin Valley, California: 2. Quantitative hydrologic assessment

Groundwater flow modeling was used to quantitatively assess the hydrologic processes affecting ground water and solute movement to drain laterals. Modeling results were used to calculate the depth distribution of groundwater flowing into drain laterals at 1.8 m (drain lateral 1) and 2.7 m (drain lateral 2) below land surface. The simulations indicated that under nonirrigated conditions about 89% of the flow in drain lateral 2 was from groundwater originating from depths greater than 6 m below land surface. The deep groundwater has higher selenium concentrations than shallow groundwater. Simulation of irrigated conditions indicates that as recharge (deep percolation) increases, the proportional contribution of deep groundwater to drain lateral flow decreases. Groundwater flow paths and travel times estimated from the simulation results indicate that groundwater containing high concentrations of selenium (greater than 780 μg L −1 ) probably will continue to enter drain lateral 2 for decades.

California

Ground-water development and the effects on ground-water levels and water quality in the town of Atherton, San Mateo County, California

The installation of at least 100 residential wells in the town of Atherton, California, during the 198792 drought has raised concerns about the increased potential for land subsidence and salt water intrusion. Data were collected and monitor ing networks were established to assess current processes and to monitor future conditions affect ing these processes. Data include recorded pump age, recorded operation time, and measured pumpage rates from 38 wells; water levels from 49 wells; water chemistry samples from 20 wells, and land-surface elevation data from 22 survey sites, including one National Geodetic Survey estab lished bench mark. Geologic, lithologic, climato logic, well construction, well location, and historical information obtained from available reports and local, state, and Federal agencies were used in this assessment. Estimates of annual residential pumpage from 269 assumed active residential wells in the study area indicate that the average annual total pumping rate is between 395 and 570 acre-feet per year. The nine assumed active institutional wells are estimated to pump a total of about 200 acre- feet per year, or 35 to 50 percent of the total resi dential pumpage. Assuming that 510 acre-feet per year is the best estimate of annual residential pumpage, total pumpage of 710 acre-feet per year would represent about 19 percent of the study area's total water supply, as estimated. Depth-to-water-level measurements in wells during April 1993 through September 1995 typically ranged from less than 20 feet below land surface nearest to San Francisco Bay to more than 70 feet below land surface in upslope areas near exposed bedrock, depending on the season. This range, which is relatively high historically, is attributed to above normal rainfall between 1993 and 1995. Water levels expressed as hydraulic heads indicate the presence of three different hydrologic subareas on the basis of hydraulic-head contour configurations and flow direction. That all measured hydraulic heads in the study area from April 1993 through September 1995 were above sea level indicates that saltwater intrusion was unlikely during this period. The chemistry of 20 well-water samples is characterized as a calcium magnesium carbonate bicarbonate type water. There is no evidence of saltwater intrusion from San Francisco Bay; how ever, water samples from wells nearest the bay and bedrock assemblages indicate a greater concentra tion of dissolved constituents and salinity. Dissolved-solids concentrations of water samples from wells in these areas exceeded 1,000 milli grams per liter, and several samples contained a substantial fraction of sodium and chloride. Water hardness for the 20 wells sampled averaged 471 milligrams per liter as calcium carbonate, which is classified as very hard. One well sample exceeded the primary maximum contaminant level for drinking water in nitrate, several wells exceeded the secondary maximum contaminant level for chloride and sulfate, and all wells sampled exceeded the secondary maximum contaminant level for total dissolved solids. Land-subsidence and the resultant damage because of excessive ground-water pumping, in combination with periodic drought, have a well- documented history in the south San Francisco Bay area. Land-elevation surveying data from 1934 to 1967 indicate that subsidence ranged from 0.1 to approximately 0.5 foot in the vicinity of the study area. It could not be determined from land- surface elevation surveying data from 1993 whether subsidence is currently occurring in the study area.

Water-Resources Investigations Report

Evaluation of a monitoring program for assessing the effects of management practices on the quantity and quality of drainwater from the Panoche Water District, western San Joaquin Valley, California

An evaluation was made of an existing monitoring program in the Panoche Water District for 1986-93. The Panoche Water District is an agricultural area located in the western San Joaquin Valley of California. Because irrigation drainage from this area has high concentrations of dissolved solids and selenium, management strategies have been developed to improve the quality of drainwater discharge. The purpose of the Panoche Water District's monitoring program is to assess the effects of water- and land-use practices on local ground water and drain flow from the district. Drainflow from the district consists of the discharge from 50 separate on-farm underground tile-drainage systems. The Panoche Water District maintains information on water deliveries, planned and actual crop types, and planned and actual acreages planted each year. In addition, the water district monitors ground-water and drainage-system discharges using a variety of data-collection methods. A total of 62 observation well sites are used to monitor ground-water level and quality. A total of 42 sites were monitored for drainflow quantity, and drain flow quality samples were collected from the outlets of each of the 50 drainage systems. However, these data were collected inconsistently and (or) intermittently during the period studied. All data obtained from the water district were compiled and stored in a geographic information system database. Water delivered for irrigation by the Panoche Water District is a mix of imported water and local ground water pumped directly into delivery canals. Although delivered water is a mix, information on the proportion of water from the two sources is not reported. Also, individual growers pump directly to their crops unknown quantities of ground water, the total of which could be greater than 60 percent of total applications during years when water district deliveries are greatly reduced (for example, the years during and following a drought). To evaluate the effects of irrigation on ground-water and drainflow quality, data on the combined chemical characteristics and the volume of water applied to crops are needed as part of the district's monitoring program. For example, without these data, this study could estimate only the effects of irrigation on ground-water recharge for 1986 (60.4 106 m3/y), 1987 (74.2 106 m3/y), and 1988 (56.0 106 m3/y) in the Panoche Water District water years when the amount of ground water pumped by individual growers was probably small. Water-level data show a significant decline of the water table in the upslope, undrained parts of the study area, and little or no significant change in the down slope, drained parts of the study area. Pumping from productions wells, most of which are located in the upslope part of the study area, may have contributed to the decline of the water table in the upslope area. The quantities of drainflow, dissolved solids, and selenium discharged from the study area decreased during the study period. However, drainflow, dissolved solids, and selenium discharged from individual on-farm drainage systems did not decrease. These data also illustrate the need for consistent and regular monitoring of the factors that affect drainage in the western San Joaquin Valley.

Open-File Report

Calculation of a water budget and delineation of contributing sources to drainflows in the western San Joaquin Valley, California

Geohydrologic data and a ground-water flow model were used to calculate a water budget and evaluate the contribution of regional groundwater flow to on-farm drainflow in a part of the western San Joaquin Valley, California. Regional ground-water flow is affected by the distribution of unconsolidated coarse- and fine-grained sediment. Predominantly coarse-grained sediment in the upslope areas results in a water table greater than 3 meters below land surface, but the low-lying areas are underlain by predominantly fine-grained sediments and have a water table within 3 meters of land surface. The vertical component of flow is downward in the upslope areas, but can be upward at some locations in the low-lying areas. Results of model simulations indicate that about 18.5x10 6 cubic meters per year of drainflow originates as recharge within the fields that overlay the drainage systems (89 percent), and 2.3x10 6 cubic meters per year of drainflow is lateral-flowing ground water and upward-moving deep percolation originating as recharge within fields upslope of the drainage systems (11 percent). The drainage systems that intercept this upslope recharge overlay predominantly coarse-grained sediment associated with old stream channels. This ground water can move upward from depths greater than 29 meters below land surface and distances as great as 3.6 kilometers, requiring from 10 to more than 90 years to reach the drainage systems.

California

Effects of ground-water chemistry and flow on quality of drainflow in the western San Joaquin Valley, California

Chemical and geohydrologic data were used to assess the effects of regional ground-water flow on the quality of on-farm drainflows in a part of the western San Joaquin Valley, California. Shallow ground water beneath farm fields has been enriched in stable isotopes and salts by partial evaporation from the shallow water table and is being displaced by irrigation, drainage, and regional ground-water flow. Ground-water flow is primarily downward in the study area but can flow upward in some down- slope areas. Transitional areas exist between the downward and upward flow zones, where ground water can move substantial horizontal distances (0.3 to 3.6 kilometers) and can require 10 to 90 years to reach the downslope drainage systems. Simulation of ground-water flow to drainage systems indicates that regional ground water contributes to about 11 percent of annual drainflow. Selenium concentrations in ground water and drainwater are affected by geologic source materials, partial evaporation from a shallow water table, drainage-system, and regional ground-water flow. Temporal variability in drainflow quality is affected in part by the distribution of chemical constituents in ground water and the flow paths to the drainage systems. The mass flux of selenium in drainflows, or load, generally is proportional to flow, and reductions in drainflow quantity should reduce selenium loads over the short-term. Uncertain changes in the distribution of ground-water quality make future changes in drainflow quality difficult to quantify.

Open-File Report

Selenium mobility and distribution in irrigated and nonirrigated alluvial soils

Dissolution and leaching of soil salts by irrigation water is a primary source of Se to shallow groundwater in the western San Joaquin Valley, California. In this study, the mobility and distribution of selenite and selenate in soils with different irrigation and drainage histories was evaluated using sorption experiments and an advection-dispersion model. The sorption studies showed that selenate (15–12400 µg Se L −1 ) is not adsorbed to soil, whereas selenite (10–5000 µg Se L −1 ) is rapidly adsorbed. The time lag between adsorption and desorption of selenite is considerable, indicating a dependence of reaction rate on reaction direction (hysteresis). Selenite adsorption and desorption isotherms were different, and both were described with the Freundlich equation. Model results and chemical analyses of extracts from the soil samples showed that selenite is resistant to leaching and therefore can represent a potential long-term source of Se to groundwater. In contrast, selenate behaves as a conservative constituent under alkaline and oxidized conditions and is easily leached from soil.

Soil Science Society of America Journal

Selenium speciation methods and application to soil saturation extracts from San Joaquin Valley, California

Methods to determine soluble concentrations of selenite, selenate, and organic Se were evaluated on saturation extracts of soil samples collected from three sites on the Panoche Creek alluvial fan in the western San Joaquin Valley, California. The methods were used in combination with hydride-generation atomic-absorption spectrometry for detection of Se, and included a selective chemical-digestion method and three chromatographic methods using XAD-8 resin, Sep-Pak C 18 cartridge, and a combination of XAD-8 resin and activated charcoal. The chromatography methods isolate dissolved organic matter that can inhibit Se detection by hydride-generation atomic-absorption spectrometry. Isolation of hydrophobic organic matter with XAD-8 did not affect concentrations of selenite and selenate, and the isolated organic matter represents a minimal estimation of organic Se. Ninety-eight percent of the Se in the extracts was selenate and about 100% of the isolated organic Se was associated with the humic acid fraction of dissolved organic matter. The depth distribution of Se species in the soil saturation extracts support a hypothesis that the distribution of soluble Se and salinity in these soils is the result of evaporation from a shallow water table and leaching by irrigation water low in Se and salinity.

California