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Jeffrey J. McDonnell

Publications and source records attributed to Jeffrey J. McDonnell.

7 recordsLinked to original sources

Insights into plant water uptake from xylem-water isotope measurements in two tropical catchments with contrasting moisture conditions

Water transpired by trees has long been assumed to be sourced from the same subsurface water stocks that contribute to groundwater recharge and streamflow. However, recent investigations using dual water stable isotopes have shown an apparent ecohydrological separation between tree-transpired water and stream water. Here we present evidence for such ecohydrological separation in two tropical environments in Puerto Rico where precipitation seasonality is relatively low and where precipitation is positively correlated with primary productivity. We determined the stable isotope signature of xylem water of 30 mahogany ( Swietenia spp.) trees sampled during two periods with contrasting moisture status. Our results suggest that the separation between transpiration water and groundwater recharge/streamflow water might be related less to the temporal phasing of hydrologic inputs and primary productivity, and more to the fundamental processes that drive evaporative isotopic enrichment of residual soil water within the soil matrix. The lack of an evaporative signature of both groundwater and streams in the study area suggests that these water balance components have a water source that is transported quickly to deeper subsurface storage compared to waters that trees use. A Bayesian mixing model used to partition source water proportions of xylem water showed that groundwater contribution was greater for valley-bottom, riparian trees than for ridge-top trees. Groundwater contribution was also greater at the xeric site than at the mesic–hydric site. These model results (1) underline the utility of a simple linear mixing model, implemented in a Bayesian inference framework, in quantifying source water contributions at sites with contrasting physiographic characteristics, and (2) highlight the informed judgement that should be made in interpreting mixing model results, of import particularly in surveying groundwater use patterns by vegetation from regional to global scales.

Hydrological Processes↗

Water's Way at Sleepers River watershed – revisiting flow generation in a post-glacial landscape, Vermont USA

The Sleepers River Research Watershed (SRRW) in Vermont, USA, has been the site of active hydrologic research since 1959 and was the setting where Dunne and Black demonstrated the importance and controls of saturation-excess overland flow (SOF) on streamflow generation. Here, we review the early studies from the SRRW and show how they guided our conceptual approach to hydrologic research at the SRRW during the most recent 25 years. In so doing, we chronicle a shift in the field from early studies that relied exclusively on hydrometric measurements to today's studies that include chemical and isotopic approaches to further elucidate streamflow generation mechanisms. Highlights of this evolution in hydrologic understanding include the following: (i) confirmation of the importance of SOF to streamflow generation, and at larger scales than first imagined; (ii) stored catchment water dominates stream response, except under unusual conditions such as deep frozen ground; (iii) hydrometric, chemical and isotopic approaches to hydrograph separation yield consistent and complementary results; (iv) nitrate and sulfate isotopic compositions specific to atmospheric inputs constrain new water contributions to streamflow; and (v) convergent areas, or ‘hillslope hollows’, contribute disproportionately to event hydrographs. We conclude by summarizing some remaining challenges that lead us to a vision for the future of research at the SRRW to address fundamental questions in the catchment sciences.

Vermont↗

The geochemical evolution of riparian ground water in a forested piedmont catchment

The principal weathering reactions and their rates in riparian ground water were determined at the Panola Mountain Research Watershed (PMRW) near Atlanta, Georgia. Concentrations of major solutes were measured in ground water samples from 19 shallow wells completed in the riparian (saprolite) aquifer and in one borehole completed in granite, and the apparent age of each sample was calculated from chloroflourocarbons and tritium/helium-3 data. Concentrations of SiO 2 , Na + , and Ca 2+ generally increased downvalley and were highest in the borehole near the watershed outlet. Strong positive correlations were found between the concentrations of these solutes and the apparent age of ground water that was modern (zero to one year) in the headwaters, six to seven years midway down the valley, and 26 to 27 years in the borehole, located ∼500 m downstream from the headwaters. Mass-balance modeling of chemical evolution showed that the downstream changes in ground water chemistry could be largely explained by weathering of plagioclase to kaolinite, with possible contributions from weathering of K-feldspar, biotite, hornblende, and calcite. The in situ rates of weathering reactions were estimated by combining the ground water age dates with geochemical mass-balance modeling results. The weathering rate was highest for plagioclase (∼6.4 μmol/L/year), but could not be easily compared with most other published results for feldspar weathering at PMRW and elsewhere because the mineral-surface area to which ground water was exposed during geochemical evolution could not be estimated. However, a preliminary estimate of the mineral-surface area that would have contacted the ground water to provide the observed solute concentrations suggests that the plagioclase weathering rate calculated in this study is similar to the rate calculated in a previous study at PMRW, and three to four orders of magnitude slower than those published in previous laboratory studies of feldspar weathering. An accurate model of the geochemical evolution of riparian ground water is necessary to accurately model the geochemical evolution of stream water at PMRW.

Groundwater↗

Shallow water table fluctuations in relation to soil penetration resistance

Hydrologic modeling of catchments is frequently hampered by lack of information on subsurface stratigraphy and zones of preferred flow. We evaluated the usefulness of soil penetration resistance, easily measured by a dynamic cone penetrometer, together with measurements of ground water level fluctuations, as a cost-effective means to infer subsurface flow patterns. At our field site at Sleepers River, Vermont, penetration resistance was lowest in the surficial 10 to 30 cm, then typically increased to a local maximum at 60 to 80 cm, which we interpreted as the soil/till interface. Below this depth usually lies a zone of decreased resistance in the till, giving way to either a gradual or abrupt increase in resistance toward the bedrock surface at 1 to 4.5 m depth. Penetration resistance had a weak but significant negative correlation with saturated hydraulic conductivity determined by bail tests (r 2 = 0.25, p < 0.05). At many wells, monthly ground water levels tended to cluster at or just above the resistant zone near the soil/till interface. Chemical and isotopic dynamics in nested wells finished above and below the resistant zone suggest that the zone may temporarily isolate the deeper ground water reservoir from meltwater inputs, which were clearly identified by low δ 18 O values. In ground water discharge zones, δ 18 O values tended to converge throughout the profile. In contrast, dissolved organic carbon (DOC) maintained a gradient of increasing concentration toward land surface, even in otherwise well-mixed waters, reflecting its rapid release from organic horizons. Understanding the effect of soil penetration resistance on ground water behavior may be useful in future catchment modeling efforts.

Vermont↗

Tracer and hydrometric study of preferential flow in large undisturbed soil cores from the Georgia Piedmont, USA

We studied the temporal patterns of tracer throughput in the outflow of large (30 cm diameter by 38 cm long) undisturbed cores from the Panola Mountain Research Watershed, Georgia. Tracer breakthrough was affected by soil structure and rainfall intensity. Two rainfall intensities (20 and 40 mm hr -1 ) for separate Cl - and Br - amended solutions were applied to two cores (one extracted from a hillslope soil and one extracted from a residual clay soil on the ridge). For both low and high rainfall intensity experiments, preferential flow occurred in the clay core, but not in the hillslope core. The preferential flow is attributed to well-developed interpedal macrochannels that are commonly found in structured clay soils, characteristic of the ridge site. However, each rainfall intensity exceeded the matrix infiltration capacity at the top of the hillslope core, but did not exceed the matrix infiltration capacity at the middle and bottom of the hillslope core and at all levels in the clay core. Localized zones of saturation created when rainfall intensity exceeds the matrix infiltration capacity may cause water and tracer to overflow from the matrix into macrochannels, where preferential flow occurs to depth in otherwise unsaturated soil. Copyright © 1999 John Wiley & Sons, Ltd.

Hydrological Processes↗

Base cation concentrations in subsurface flow from a forested hillslope: The role of flushing frequency

A 20-m-wide trench was excavated to bedrock on a hillslope at the Panola Mountain Research Watershed in the Piedmont region of Georgia to determine the effect of upslope drainage area from the soil and bedrock surfaces on the geochemical evolution of base cation concentrations in subsurface flow. Samples were collected from ten 2-m sections and five natural soil pipes during three winter rainstorms in 1996. Base cation concentrations in hillslope subsurface flow were generally highest early and late in the storm response when flow rates were low, but during peak flow, concentrations varied little. Base cation concentrations in matrix flow from the 10 trench sections were unrelated to the soil surface drainage area and weakly inversely related to the bedrock surface drainage area. Base cation concentrations in pipe flow were lower than those in matrix flow and were also consistent with the inverse relation to bedrock surface drainage area found in matrix flow. The left side of the trench, which has the highest bedrock surface drainage area, had consistently lower mean base cation concentrations than the right side of the trench, which has the lowest bedrock surface drainage area. During moderate size rain events of about 20–40 mm, subsurface flow occurred only on the left side of the trench. The greater volume of water that has flowed through the left side of the trench appears to have resulted in greater leaching of base cations from soils and therefore lower base cation concentrations in subsurface flow than in flow from the right side of the trench. Alternatively, a greater proportion of flow that bypasses the soil matrix may have occurred through the hillslope on the left side of the trench than on the right side. Flushing frequency links spatial hillslope water flux with the evolution of groundwater and soil chemistry.

Georgia↗