Reply to the discussion by F. Lagroix and S.K. Banerjee of "Geochemical evidence for the origin of late Quaternary loess in central Alaska"
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Alaska↗
Geology topics
James R. Budahn
Publications and source records attributed to James R. Budahn.
Geochemical Analyses of Geologic Materials from Areas of Critical Environmental Concern, Clark and Nye Counties, Nevada
INTRODUCTION An assessment of known and undiscovered mineral resources of selected areas administered by the Bureau of Land Management (BLM) in Clark and Nye Counties, Nevada was conducted by the U.S. Geological Survey (USGS), Nevada Bureau of Mines and Geology (NBMG), and University of Nevada, Las Vegas (UNLV). The purpose of this work was to provide the BLM with information for use in their long-term planning process in southern Nevada so that they can make better-informed decisions. The results of the assessment are in Ludington (2006). Existing information about the areas, including geology, geophysics, geochemistry, and mineral-deposit information was compiled, and field examinations of selected areas and mineral occurrences was conducted. This information was used to determine the geologic setting, metallogenic characteristics, and mineral potential of the areas. Twenty-five Areas of Critical Environmental Concern (ACECs) were identified by BLM as the object of this study. They range from tiny (less than one km2) to large (more than 1,000 km2). The location of the study areas is shown on Figure 1. This report includes geochemical data for rock samples collected by staff of the USGS and NBMG in these ACECs and nearby areas. Samples have been analyzed from the Big Dune, Ash Meadows, Arden, Desert Tortoise Conservation Center, Coyote Springs Valley, Mormon Mesa, Virgin Mountains, Gold Butte A and B, Whitney Pockets, Rainbow Gardens, River Mountains, and Piute-Eldorado Valley ACECs.
Open-File Report↗
Tephra layers of Blind Spring Valley and related upper Pliocene and Pleistocene tephra layers, California, Nevada, and Utah: Isotopic ages, correlation, and magnetostratigraphy
Numerical ages have been determined for a stratigraphic sequence of silicic tephra layers exposed at the Cowan Pumice Mine in Blind Spring Valley, near Benton Hot Springs, east-central California, as well as at Chalk Cliffs, north of Bishop, Calif. The tephra layers at these sites were deposited after eruptions from nearby sources, most of them from near Glass Mountain, and some from unknown sources. The ages were determined primarily by the laser-fusion 40 Ar/ 39 Ar method, mostly on sanidine feldspar; two were determined by conventional K-Ar analysis on obsidian clasts.
California, Nevada, Utah↗
Weathering of the meade peak phosphatic shale member, phosphoria formation: Observations based on uranium and its decay products
Variably weathered outcrop samples of the Meade Peak Phosphatic Shale Member of the Phosphoria Formation have 5-10% of the contained uranium (U) in a form readily extractable by 0.1 M sodium bicarbonate. Fission track radiography of outcrop samples and other less-weathered channel and core samples indicate that this mobile fraction of U is likely hosted by organic matter, secondary iron oxides and clay minerals, trace uraninite, and very fine-grained apatite cement. During weathering, this extractable U fraction is especially susceptible to redistribution, which produces small but measurable departures (1-15%) from radioactive (secular) equilibrium in the 238 U decay-series. The most weath- ered samples show the strongest isotopic evidence for redistribution of U during the last 350 ka, but sequestration of U by alteration products limits open-system losses of U at the whole-rock scale. In less-weathered samples, isotopic evidence for minor U loss (or gain) over longer time periods (1 Ma) is consistent with relatively non-aggressive attack of phosphatic rock during weathering. Comparative extractability of selenium (Se) suggests that a larger fraction of Se (19%) is readily available for mobilization during the earliest stages of weathering.
Book chapter↗
Trace element and Nd, Sr, Pb isotope geochemistry of Kilauea Volcano, Hawai'i, near-vent eruptive products: 1983-2001
This open-file report serves as a repository for geochemical data referred to in U.S. Geological Survey Professional Paper 1676 (Heliker, Swanson, and Takahashi, eds., 2003), which includes multidisciplinary research papers pertaining to the first twenty years of Puu Oo Kupaianaha eruption activity. Details of eruption characteristics and nomenclature are provided in the introductory chapter of that volume (Heliker and Mattox, 2003). Geochemical relations of this data are depicted and interpreted by Thornber (2003), Thornber and others (2003a) and Thornber (2001). This report supplements Thornber and others (2003b) in which whole-rock and glass major-element data on ~1000 near-vent lava samples collected during the 1983 to 2001 eruptive interval of Kilauea Volcano, Hawai'i, are presented. Herein, we present whole-rock trace element compositions of 85 representative samples collected from January 1983 to May 2001; glass trace-element compositions of 39 Pele’s Tear (tephra) samples collected from September 1995 to September 1996, and whole-rock Nd, Sr and Pb isotopic analyses of 10 representative samples collected from September 1983 to September 1993. Thornber and others (2003b) provide a specific record of sample characteristics, location, etc., for each of the samples reported here. Spreadsheets of both reports may be integrated and sorted based upon time of formation or sample numbers. General information pertaining to the selectivity and petrologic significance of this sample suite is presented by Thornber and others (2003b). As justified in that report, this select suite of time-constrained geochemical data is suitable for constructing petrologic models of pre-eruptive magmatic processes associated with prolonged rift zone eruption of Hawaiian shield volcanoes.
Hawai'i↗
Dinosaurs that did not die: Evidence for Paleocene dinosaurs in the Ojo Alamo Sandstone, San Juan Basin, New Mexico
Palynologic and paleomagnetic data confirm a Paleocene age for the Ojo Alamo Sandstone (and its contained dinosaurs) throughout the San Juan Basin of New Mexico. The recently reported discovery of 34 skeletal elements from a single hadrosaur in the Ojo Alamo provides unequivocal evidence that these bones were not reworked from underlying Cretaceous strata. Geochemical studies of samples from several single-dinosaur-bone specimens from the Paleocene Ojo Alamo Sandstone and the underlying Late Cretaceous (Campanian) Kirtland Formation show that mineralized bones from these two rock units contain distinctly different abundances of uranium and rare-earth elements and demonstrate that Cretaceous and Paleocene bones were mineralized at different times when mineralizing fluids had distinctly different chemical compositions. These findings indicate that the dinosaur bone from the Paleocene Ojo Alamo is indigenous and not reworked. These data show that a relatively diverse assemblage of dinosaurs survived the end-Cretaceous asteroid-impact extinction event of 65.5 Ma. The San Juan Basin’s Paleocene dinosaur fauna is herein named the Alamoan fauna. Magnetic-polarity chronology shows that these survivors lived for about one million years into the Paleocene and then became extinct around 64.5 Ma. We suggest that a plausible survival mechanism for this Lazarus fauna may have been the large numbers of buried dinosaur eggs, laid just before the asteroid impact occurred. These buried eggs would have provided a safe haven for developing dinosaur embryos for the first one to two years after the impact, thereby making it possible for them to survive the worst of the impact’s early devastation.
Colorado, New Mexico↗
Eagle collapse center: Interpretation of evidence for late Cenozoic evaporite-related deformation in the Eagle River basin, Colorado
Evaporite tectonism resulted in deformation and collapse over an area of ~2500 km2 that is referred to as the Eagle collapse center. The collapse center includes much of the Eagle and Colorado River drainage basins between Vail, Dotsero, and McCoy, Colorado. The volume loss of evaporitic rocks by dissolution in the collapse center is estimated to be nearly 1700 km3 3 . Before ca. 10 Ma, Miocene basaltic flows partly covered an extensive, nearly horizontal, low-relief surface. Parts of this surface collapsed 1.3 km near the present-day Eagle and Colorado Rivers. Remnants of this surface outside the area of collapse, such as highlands of the White River uplift, the flank of the Gore Range, and Basalt Mountain, stand at elevations of 2.9–3.6 km. The high-standing Castle Peak basaltic cap, situated near the center of the Eagle collapse center, may not have collapsed, or collapsed little. The areas of collapse lie within or nearby known and inferred limits of the Pennsylvanian Eagle Valley Evaporite (mostly halite, gypsum, and anhydrite) that was deposited in the Central Colorado trough. Our geologic mapping and research in the Eagle collapse center delineate synclinal sags in the basaltic flows with amplitudes of 0.5–1 km, sinuous and discontinuous high-angle faults that cut basaltic flows, elongate grabens, evaporite-cored anticlines, and an ellipsoidal fault system that drops a 30 km X 10 km mountain block of younger strata into evaporite. Collapse as far as 20 km from the Colorado and Eagle Rivers suggests that the greater load on evaporite beneath surrounding highlands causes lateral flow of evaporite toward anticlinal crests in river valleys. Thus, gravity-driven evaporite flow and removal of evaporite by dissolution in groundwater and by subsequent discharge to surface waters combine to produce large-scale collapse. Although most evaporite tectonism post dates the basaltic flow capped surface, local angular unconformities under this surface record earlier, possibly Laramide evaporite tectonism, and overthickened post-evaporite red beds record some late Paleozoic evaporite deformation
Colorado↗
Correlation of late Cenozoic basaltic lava flows in the Carbondale and Eagle collapse centers in west-central Colorado based on geochemical, isotopic, age, and petrographic data
Major-, minor-, and trace-element abundance data on 220, late Cenozoic, basaltic rocks in and around the Carbondale and Eagle collapse centers in west-central Colorado are combined with isotopic, age, and petrographic data to correlate lava flows and establish the timing and minimum areal extent of collapse events associated with removal of Pennsylvanian evaporite. On the basis of these data, 46 distinct compositional groups of volcanic rocks were identified. The rocks within each group, which are represented by at least two samples, have compositions and ages that are indistinguishable from each other and are either (1) undifferentiated samples from the same eruption and possibly from outcrops of the same flow, (2) differentiated from the same magma batch erupted at different times or (3) related to each other by very small differences in the degree of partial melting. The areal extent of chemically correlated and dated volcanic flows in the region was established and these results were used to recognize and understand many of the collapse events as described in companion papers in this volume. Compositional data are also used to infer the petrogenetic processes that generated the parental magmas. Subtle but significant differences among rocks that are broadly similar in geochemical and isotopic composition and were erupted over a small time interval (<0.5 m.y.) suggests that the mantle source region of these magmas is quite heterogeneous. Over the past 11 m.y., the lavas became less mafic and more enriched in incompatible trace elements. This heterogeneity is attributed to variable contributions of subducted material in the lithosphere during the melting processes. To account for its isotopic features, the source material must be at least mid-Proterozoic in age. A melt contribution from underlying asthenospheric mantle can not be ruled out but none of the volcanic rocks have clear characteristics of oceanic-island basalts or mid-oceanic-ridge basalts. The trace-element compositions of rocks that were sampled from multiple stacked flows are indistinguishable from one another.This suggests that lower and/or upper crustal assimilation had a minor effect on their overall chemistry. However, Pb isotopic data suggest that crustal contamination of at least some samples did occur.
Colorado↗
40Ar/39Ar ages of late Cenozoic volcanic rocks within and around the Carbondale and Eagle collapse centers, Colorado: Constraints on the timing of evaporite-related collapse and incision of the Colorado River
40 Ar/ 39 Ar dating results of 133 samples from 84 late Cenozoic volcanic rocks provide emplacement ages that constrain the timing of evaporite collapse and the incision rates of the Colorado River. Our samples are from areas in west-central Colorado, both within and outside of the Carbondale and Eagle collapse centers. Significant pulses of volcanic activity occurred in the intervals from 24 to 22, 16 to 13, 11 to 9, and 8 to 7 Ma. In addition, small flows, widely spaced in time and space were emplaced during the last 4 m.y. Although individual basaltic flows appear to be chemically and isotopically homogeneous, there are significant geochemical and isotopic differences between flows, even between some flows that apparently have the same age within the limits of analytical precision. A low-relief early to middle Miocene erosional surface has been postulated in west-central Colorado. Our studies are consistent with the existence of a low-relief paleotopographic surface that is now at a minimum elevation range of ~2.9–3.4 km outside areas of collapse. Elevation departures from this range suggest that 1000 m of subsidence due to evaporite removal has locally occurred in the Carbondale and Eagle collapse centers. 40 Ar/ 39 Ar ages from downdropped and disrupted basaltic flows in the Carbondale center constrain initial collapse to >13 Ma, the timing of much of the evaporite-related collapse to the past 10–8 m.y., and an increase in the rate of collapse during the last 3 m.y. Ages and elevations of basaltic rocks above the Colorado River in Glenwood Canyon are used to calculate average apparent incision rates for the Colorado River in Glenwood Canyon of 24 mm/k.y. from 7.8 to 3.0 Ma. The average apparent incision rate increased by an order of magnitude to 242 mm/k.y. during the last 3 m.y
Colorado↗
Evaporite tectonism in the lower Roaring Fork River valley, west-central Colorado
Evaporite tectonism in the lower Roaring Fork River valley in west-central Colorado has caused regional subsidence of a differentially downdropped area in the southern part of the Carbondale collapse center during the late Cenozoic. A prominent topographic depression coincides with this collapse area, and drainage patterns within the collapse area contrast sharply with those outside of it. Miocene volcanic rocks are downdropped as much as 1220 m in the collapse area. Much of the structural lowering occurred along the margins of the collapse area. Major Laramide-age structures bound the east and west sides of the collapse area, but movement on these structures during late Cenozoic collapse was in an opposite direction to their Laramide movement. Within the interior part of the collapse area faults and folds have as much as 300 m of structural relief. Large blocks of rock may be rafting into the Roaring Fork River valley as underlying evaporite flows toward the valley. Sinkholes are common in the collapse area, as are closed, or nearly closed, structurally controlled topographic depressions that are formed in both surficial deposits and bedrock. Upper Cenozoic deltaic and lacustrine deposits preserved on ridgelines and mesas document the positions of former structural depressions that were initially filled with sediments and later breached by erosion. At least 450 m of syn-collapse sediments accumulated in a collapse depression on the north side of Mount Sopris. Complexly deformed and brecciated deposits in the interior parts of the collapse center are interpreted as collapse debris. Evaporite flow is an important element in the collapse process, and during early stages of collapse it was perhaps the primary means of deformation. Flow by itself, does not remove evaporite from the collapse area. Dissolution and accompanying transport of dissolved constituents by groundwater and surface water are the ultimate means by which evaporite exits the collapse area. Collapse continues today, as evidenced by historic sinkholes and modern high-salinity loads in rivers and thermal springs. Thick evaporite deposits still underlie much of the collapse area, so collapse will likely continue in the future.
Colorado↗
Radionuclides in fly ash and bottom ash: Improved characterization based on radiography and low energy gamma-ray spectrometry
Two radiation-based techniques for determining the distribution and relative abundance of radionuclides are described, and applied to a suite of fly ash and bottom ash samples from a Kentucky power plant. The technique of fission-track radiography provides new observations of the variety of uranium hosts and of uranium distribution in individual particles of fly ash, and thus aids prediction of the leachability of uranium during long-term disposal or utilization of fly ash. Uranium is largely dispersed within glassy components of fly ash particles and shows little evidence for obvious surface enrichment that could be attributed to secondary adsorption. The technique of low energy gamma-ray spectrometry provides simultaneous, non-destructive determination of the relative abundance of 238 U, 226 Ra, 228 Ra and 210 Pb in representative 150–250 g samples. The measurements provide a means for screening samples to determine if the combustion process causes significant preferential redistribution of radionuclides that could affect their subsequent mobility. Results indicate that radium isotopes are not significantly (within 10–15%) fractionated from parent 238 U and 232 Th during coal combustion. In contrast, 210 Pb appears to be preferentially enriched in some samples of fly ash, and depleted in bottom ash relative to 238 U and 226 Ra. In this application 210 Pb acts as a tracer for elemental lead, and confirms the expected greater volatility of Pb compared to more refractory elements during coal combustion.
Fuel↗
An empirical equation for modeling rare earth element mineral-mineral partitioning; an application to mantle metasomatism
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Open-File Report↗