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James L. Robinson

Publications and source records attributed to James L. Robinson.

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Water quality in the Mobile River Basin, Alabama, Georgia, Mississippi, and Tennessee, 1999-2001

This report contains the major findings of a 1999?2001 assessment of water quality in the Mobile River Basin. It is one of a series of reports by the National Water-Quality Assessment (NAWQA) Program that present major findings in 51 major river basins and aquifer systems across the Nation. In these reports, water quality is discussed in terms of local, State, and regional issues. Conditions in a particular basin or aquifer system are compared to conditions found elsewhere and to selected national benchmarks, such as those for drinking-water quality and the protection of aquatic organisms. This report is intended for individuals working with water-resource issues in Federal, State, or local agencies, universities, public interest groups, or in the private sector. The information will be useful in addressing a number of current issues, such as the effects of agricultural and urban land use on water quality, human health, drinking water, source-water protection, hypoxia and excessive growth of algae and plants, pesticide registration, and monitoring and sampling strategies. This report is also for individuals who wish to know more about the quality of streams and ground water in areas near where they live, and how that water quality compares to the quality of water in other areas across the Nation. The water-quality conditions in the Mobile River Basin summarized in this report are discussed in detail in other reports that can be accessed from the Mobile River Basin Web site (http://al.water.usgs.gov/pubs/mobl/mobl.html). Detailed technical information, data and analyses, collection and analytical methodology, models, graphs, and maps that support the findings presented in this report in addition to reports in this series from other basins can be accessed from the national NAWQA Web site (http://water.usgs.gov/nawqa).

Alabama, Georgia, Mississippi, Tennessee

Summary of hydrogeology and simulation of ground-water flow and land-surface subsidence in the northern part of the Gulf Coast aquifer system, Texas

The northern part of the Gulf Coast aquifer system in Texas, which includes the Chicot, Evangeline, and Jasper aquifers, supplies most of the water used for industrial, municipal, agricultural, and commercial purposes for an approximately 25,000- square-mile (mi 2 ) area that includes the Beaumont and Houston metropolitan areas. The area has an abundant amount of potable ground water, but withdrawals of large quantities of ground water have resulted in potentiometric-surface declines in the Chicot, Evangeline, and Jasper aquifers and land-surface subsidence from depressurization and compaction of clay layers interbedded in the aquifer sediments. This fact sheet summarizes a study done in cooperation with the Texas Water Development Board (TWDB) and the Harris-Galveston Coastal Subsidence District (HGCSD) as a part of the TWDB Ground-Water Availability Modeling (or Model) (GAM) program. The study was designed to develop and test a ground-water-flow model of the northern part of the Gulf Coast aquifer system in the GAM area (fig. 1) that waterresource managers can use as a tool to address future groundwater- availability issues.

Texas

Hydrogeology and simulation of ground-water flow and land-surface subsidence in the northern part of the Gulf Coast aquifer system, Texas

As a part of the Texas Water Development Board Ground- Water Availability Modeling program, the U.S. Geological Survey developed and tested a numerical finite-difference (MODFLOW) model to simulate ground-water flow and land-surface subsidence in the northern part of the Gulf Coast aquifer system in Texas from predevelopment (before 1891) through 2000. The model is intended to be a tool that water-resource managers can use to address future ground-water-availability issues. From land surface downward, the Chicot aquifer, the Evangeline aquifer, the Burkeville confining unit, the Jasper aquifer, and the Catahoula confining unit are the hydrogeologic units of the Gulf Coast aquifer system. Withdrawals of large quantities of ground water have resulted in potentiometric surface (head) declines in the Chicot, Evangeline, and Jasper aquifers and land-surface subsidence (primarily in the Houston area) from depressurization and compaction of clay layers interbedded in the aquifer sediments. In a generalized conceptual model of the aquifer system, water enters the ground-waterflow system in topographically high outcrops of the hydrogeologic units in the northwestern part of the approximately 25,000-square-mile model area. Water that does not discharge to streams flows to intermediate and deep zones of the system southeastward of the outcrop areas where it is discharged by wells and by upward leakage in topographically low areas near the coast. The uppermost parts of the aquifer system, which include outcrop areas, are under water-table conditions. As depth increases in the aquifer system and as interbedded sand and clay accumulate, water-table conditions evolve into confined conditions. The model comprises four layers, one for each of the hydrogeologic units of the aquifer system except the Catahoula confining unit, the assumed no-flow base of the system. Each layer consists of 137 rows and 245 columns of uniformly spaced grid blocks, each block representing 1 square mile. Lateral no-flow boundaries were located on the basis of outcrop extent (northwestern), major streams (southwestern, northeastern), and downdip limit of freshwater (southeastern). The MODFLOW general-head boundary package was used to simulate recharge and discharge in the outcrops of the hydrogeologic units. Simulation of land-surface subsidence (actually, compaction of clays) and release of water from storage in the clays of the Chicot and Evangeline aquifers was accomplished using the Interbed-Storage Package designed for use with the MODFLOW model. The model was calibrated by trial-anderror adjustment of selected model input data in a series of transient simulations until the model output (potentiometric surfaces, land-surface subsidence, and selected water-budget components) reasonably reproduced field measured (or estimated) aquifer responses. Model calibration comprised four elements: The first was qualitative comparison of simulated and measured heads in the aquifers for 1977 and 2000; and quantitative comparison by computation and areal distribution of the root-mean-square error between simulated and measured heads. The second calibration element was comparison of simulated and measured hydrographs from wells in the aquifers in a number of counties throughout the modeled area. The third calibration element was comparison of simulated water-budget componentsprimarily recharge and dischargeto estimates of physically reasonable ranges of actual water-budget components. The fourth calibration element was comparison of simulated land-surface subsidence from predevelopment to 2000 to measured land surface subsidence from 1906 through 1995.

Texas

Age and source of water in springs associated with the Jacksonville Thrust Fault Complex, Calhoun County, Alabama

Water from wells and springs accounts for more than 90 percent of the public water supply in Calhoun County, Alabama. Springs associated with the Jacksonville Thrust Fault Complex are used for public water supply for the cities of Anniston and Jacksonville. The largest ground-water supply is Coldwater Spring, the primary source of water for Anniston, Alabama. The average discharge of Coldwater Spring is about 32 million gallons per day, and the variability of discharge is about 75 percent. Water-quality samples were collected from 6 springs and 15 wells in Calhoun County from November 2001 to January 2003. The pH of the ground water typically was greater than 6.0, and specific conductance was less than 300 microsiemens per centimeter. The water chemistry was dominated by calcium, carbonate, and bicarbonate ions. The hydrogen and oxygen isotopic composition of the water samples indicates the occurrence of a low-temperature, water-rock weathering reaction known as silicate hydrolysis. The residence time of the ground water, or ground-water age, was estimated by using analysis of chlorofluorocarbon, sulfur hexafluoride, and regression modeling. Estimated ground-water ages ranged from less than 10 to approximately 40 years, with a median age of about 18 years. The Spearman rho test was used to identify statistically significant covariance among selected physical properties and constituents in the ground water. The alkalinity, specific conductance, and dissolved solids increased as age increased; these correlations reflect common changes in ground-water quality that occur with increasing residence time and support the accuracy of the age estimates. The concentration of sodium and chloride increased as age increased; the correlation of these constituents is interpreted to indicate natural sources for chloride and sodium. The concentration of silica increased as the concentration of potassium increased; this correlation, in addition to the isotopic data, is evidence that silicate hydrolysis of clay minerals occurred. The geochemical modeling program NETPATH was used to investigate possible mixing scenarios that could yield the chemical composition of water collected from springs associated with the Jacksonville Thrust Fault Complex. The results of NETPATH modeling suggest that the primary source of water in Coldwater Spring is a deep aquifer, and only small amounts of rainwater from nearby sources are discharged from the spring. Starting with Piedmont Sports Spring and moving southwest along a conceptual ground-water flow path that parallels the Jacksonville Thrust Fault Complex, NETPATH simulated the observed water quality of each spring, in succession, by mixing rainwater and water from the spring just to the northeast of the spring being modeled. The percentage of rainwater and ground water needed to simulate the quality of water flowing from the springs ranged from 1 to 25 percent rainwater and 75 to 99 percent ground water.

Scientific Investigations Report

Ground-water quality beneath an urban residential and commercial area, Montgomery, Alabama, 1999-2000

The Black Warrior River aquifer, which is composed of the Coker, Gordo, and Eutaw Formations, supplies more than 50 percent of the ground water used for public water supply in the Mobile River Basin. The city of Montgomery, Alabama, is partially built upon a recharge area for the Black Warrior River aquifer, and is one of many major population centers that depend on the Black Warrior River aquifer for public water supply. To represent the baseline ground-water quality in the Black Warrior River aquifer, water samples were collected from 30 wells located in a low-density residential or rural setting; 9 wells were completed in the Coker Formation, 9 wells in the Gordo Formation, and 12 wells in the Eutaw Formation. To describe the ground-water quality beneath Montgomery, Alabama, water samples also were collected from 30 wells located in residential and commercial areas of Montgomery, Alabama; 16 wells were completed in the Eutaw Formation, 8 wells in alluvial deposits, and 6 wells in terrace deposits. The alluvial and terrace deposits directly overlie the Eutaw Formation with little or no hydraulic separation. Ground-water samples collected from both the rural and urban wells were analyzed for physical properties, major ions, nutrients, metals, volatile organic compounds, and pesticides. Samples from the urban wells also were analyzed for bacteria, chlorofluorocarbons, dissolved gases, and sulfur hexafluoride. Ground-water quality beneath the urban area was compared to baseline water quality in the Black Warrior River aquifer.Compared to the rural wells, ground-water samples from urban wells contained greater concentrations or more frequent detections of chloride and nitrate, and the trace metals aluminium, chromium, cobalt, copper, nickel, and zinc. Pesticides and volatile organic compounds were detected more frequently and in greater concentrations in ground-water samples collected from urban wells than in ground-water samples from rural wells.The Spearman rho test was used to check for statistically significant covariance among urban ground-water quality and land-use type. The number of pesticides and volatile organic compounds detected and concentrations of nickel increased as the percentage of residential land use increased. Greater nickel concentrations also were associated with a greater number of volatile organic compounds detected. As the percentage of commercial land use increased, the numbers of pesticides and volatile organic compounds detected decreased. The number of pesticides detected in the urban ground-water samples increased as concentrations of nitrite plus nitrate increased; the number of pesticides detected and the concentrations of nitrite plus nitrate decreased as the age of the ground water increased. These correlations may indicate that, with time, pesticides and nitrate are removed from the ground-water system by physical, chemical, or biological processes.The effects of surficial geology on the occurrence of pesticides and volatile organic compounds was investigated by calculating frequencies of detection. The detection frequency for pesticides was greater for urban samples collected from wells where the surficial geology is sand than for urban samples collected from wells where the surficial geology is clay. The frequency of detection of volatile organic compounds did not show this relation.

Water-Resources Investigations Report

Hydrogeologic framework and simulation of ground-water flow and travel time in the shallow aquifer system in the area of Naval Support Activity Memphis, Millington, Tennessee

Naval Support Activity (NSA) Memphis is a Department of the Navy facility located at the City of Millington, Tennessee, about 5 miles north of Memphis. Contaminants have been detected in surface-water, sediment, and ground-water samples collected at the facility. As part of the Installation Restoration Program, the Navy is considering remedial-action options to prevent or lessen the effect of ground-water contamination at the facility and to control the movement and discharge of contaminants. A numerical model of the ground-water-flow system in the area of NSA Memphis was constructed and calibrated so that quantifiable estimates could be made of ground-water-flow rates, direction, and time-of-travel. The sediments beneath NSA Memphis, to a depth of about 200 feet, form a shallow aquifer system. From youngest to oldest, the stratigraphic units that form the shallow aquifer system are alluvium, loess, fluvial deposits, and the Cockfield and Cook Mountain Formations. The shallow aquifer system is organized into five hydrogeologic units: (1) a confining unit composed of the relatively low permeability sediments of the upper alluvium and the loess; (2) the A1 aquifer comprising sand and gravel of the lower alluvium and the fluvial deposits, and sand lenses in the upper part of the preserved section of the Cockfield Formation; (3) a confining unit composed of clay and silt within the upper part of the Cockfield Formation; (4) the Cockfield aquifer comprising sand lenses within the lower part of the preserved section of the Cockfield Formation; and (5) a confining unit formed by low permeability sediments of the Cook Mountain Formation that composes the upper confining unit for the Memphis aquifer. Thicknesses of individual units vary considerably across the facility. Structural and depositional features that affect the occurrence of ground water in the shallow aquifer system include faulting, an erosional scarp, and 'windows' in the confining units. Underlying the shallow aquifer system is the Memphis aquifer, the primary source of water for NSA Memphis and the City of Memphis, Tennessee. Analyses of sediment cores, aquifer and well specific-capacity tests, and numerical modeling were used to estimate the hydraulic characteristics of units of the shallow aquifer system. The vertical hydraulic conductivity of core samples of the alluvium-loess confining unit ranged from about 8.5 x 10-5 to 1.6 x 10-2 feet per day, and the total porosity of the samples ranged from about 35 to 48 percent. The results of the aquifer test were used to estimate a horizontal hydraulic conductivity of about 5 feet per day for the alluvial-fluvial deposits aquifer. The total porosity of core samples of the alluvial-fluvial deposits aquifer ranged from about 22 to 39 percent. The vertical hydraulic conductivity of core samples of the Cockfield confining unit ranged from about 4.5 x 10-5 to 2.5 x 10-3 feet per day, and the total porosity ranged from about 41 to 55 percent. Well specific-capacity tests indicate that the horizontal hydraulic conductivity of sand units that compose the Cockfield aquifer range from about 0.5 to 3 feet per day. The vertical hydraulic conductivity of core samples of the Cook Mountain confining unit ranged from about 5.0 x 10-6 to 9.9 x 10-4 feet per day. Total porosity of core samples of the Cook Mountain confining unit ranged from about 30 to 42 percent. Ground-water flow and time-of-travel in the shallow aquifer system were simulated using the MODFLOW finite-difference model and the -particle-tracking program MODPATH. A three-layer, steady-state model of the shallow aquifer system was constructed and calibrated to the potentiometric surface of the A1 aquifer. Results of numerical modeling support the proposed conceptual hydrogeologic model of the shallow aquifer system. Ground-water time-of-travel in the A1 aquifer was simulated using an assumed effective porosity of 25 percent. Typical ground-water-flow velocities were on the order of 15 to 25 feet per year in the layer representing the Al aquifer in the model. The average residence time of particles seeded in this layer was about 800 years. Ground-water travel times were simulated at three sites within the Al aquifer: (1) the former N-6 hangar location, (2) the "grassy" area near Solid Waste Management Unit 7, and (3) at Solid Waste Management Unit 2. Results indicate close agreement between the particle-tracking simulations and the measured extent of contaminant plumes at the former N-6 hangar area and the grassy area near Solid Waste Management Unit 7. Based on the results of particle-tracking analyses of ground-water flow and the estimated locations of contaminant plumes at these two sites, the potential for contaminants to reach the Memphis aquifer in the next 100 years is negligible. However, particle-tracking analysis of ground-water flow at Solid Waste Management Unit 2 suggests that the time-of-travel of contaminants to Big Creek Drainage Canal could be less than 30 years.

Tennessee

Ground-water resources data for Baldwin County, Alabama

Geologic and hydrologic data for 237 wells were collected, and water-levels in 223 wells in Baldwin and Escambia Counties were measured. Long-term water water-level data, available for many wells, indicate that ground-water levels in most of Baldwin County show no significant trends for the period of record. However, ground-water levels have declined in the general vicinity of Spanish Fort and Daphne, and ground-water levels in the Gulf Shores and Orange Beach areas are less than 5 feet above sea level in places. The quality of ground water generally is good, but problems with iron, sulfur, turbidity, and color occur. The water from most private wells in Baldwin County is used without treatment or filtration. Alabama public- health law requires that water from public-supply wells be chlorinated. Beyond that, the most common treatment of ground water by public-water suppliers in Baldwin County consists of pH adjustment, iron removal, and aeration. The transmissivity of the Miocene-Pliocene aquifer was determined at 10 locations in Baldwin County. Estimates of transmissivity ranged from 700 to 5,400 feet squared per day. In general, aquifer transmissivity was greatest in the southeastern part of the county, and least in the western part of the county near Mobile Bay. A storage coefficient of 1.5 x 10-3 was determined for the Miocene-Pliocene aquifer near Loxley.

Open-File Report

Potentiometric surface of the Miocene-Pliocene aquifer system of Baldwin County, Alabama, 1995

Baldwin County, the fastest growing county in Alabama in 1995, is 100-percent dependent on ground water for public water supply. Ground-water withdrawals in Baldwin County were estimated to be about 7 million gallons per day in 1996, 12 million gallons per day in 1980, and 30 gallons per day in 1990. The effects of future increases in ground-water withdrawals, to supply the needs of the growing county population, cannot be assessed without defining baseline conditions. To address the future of ground-water development, the Baldwin County Commission requested the USGS to perform a study of the ground-water resources of Baldwin County.

Alabama

Descriptions of anisotropy and heterogeneity and their effect on ground-water flow and areas of contribution to public supply wells in a karst carbonate aquifer system

Delineation of areas of contribution to wells tapping a karst carbonate aquifer system can be extremely difficult using conventional approaches designed for isotropic and homogeneous aquifers, because ground-water flow tends to be through solution-enhanced conduits. Nonradial flow along preferential zones can result in inaccurate estimates of flow paths and traveltimes. Because of the large variability in factors affecting contributing areas and an imperfect understanding of how these factors can vary, the estimation of contributing areas is an approximation at best. To better understand the effects of aquifer anisotropy and heterogeneity on areas of contribution, an exploratory modeling approach was used. MODFLOW, a numerical flow model, and MODPATH, a particle tracking program, were used to generate time-related areas of contribution for six hypothetical carbonate aquifer system types. The six types were conceptualized to approximate different types of aquifer anisotropy and heterogeneity. These include: (1) an isotropic and homogeneous single-layer system; (2) an anisotropic in a horizontal plane single layer system; (3) a discrete vertically fractured single-layer system; (4) a multilayered system; (5) a doubly porous single-layer system; and (6) a vertically and horizontally interconnected heterogeneous system. The simulated aquifer anisotropy was 5:1 (Kxx/Kyy) determined from TENSOR2D results. The simulated discrete vertical fracture network represents locations inferred from mapped photolineaments. The simulated enhanced flow zones were determined from borehole video and geophysical logs. Areas of contribution were simulated for two prototype regions. The two prototypes were selected to be representative of the hydrologic diversity within the study area and were designated the Central Swamp and Lake Terrace regions. Localized conditions in pumping, production well distribution, and aquifer transmissivity affect the size, shape, and orientation of areas of contribution to public supply wells. The simulated areas of contribution are 60 percent larger in the Central Swamp region where pumpage is more than double and transmissivity is about half that of the Lake Terrace region. Although these factors are important, this study focused on the effects from hydrogeologic factors common to karst carbonate aquifer systems. This study indicates that the distribution and type of aquifer anisotropy and heterogeneity will affect the size, shape, and orientation of areas of contribution in a karst carbonate aquifer system. The size of the 50-year time-related areas of contribution ranged from 8.2 to 39.1 square miles in the Central Swamp region and from 4.0 to 18.3 square miles in the Lake Terrace region. Simulations showed that the size of areas of contribution is primarily affected by simulated withdrawal rates, effective porosity of the carbonate rock, and transmissivity. The shape and orientation of the simulated areas of contribution primarily result from aquifer anisotropy, well distribution, flow along solution-enhanced zones, and short-circuiting of flow through fracture networks. Comparisons also were made between protection zones delineated using analytical models and areas of contribution delineated using numerical models. The size of the 5-year time-related protection zone in the Central Swamp region using an analytical model was almost twice as large as the numerically simulated area of contribution, and more than eight times larger than the numerically simulated area of contribution in the Lake Terrace region. The differences in size are primarily the result of how the flow field is approximated. The analytical method assumes only lateral flow to wells but numerical methods allow particles to move laterally and vertically. Additionally, multiple-well-interference effects resulting from the close proximity of several pumping wells cause individual capture zones to converge or diverge, depending on the difference in pumping rates and orientation among the wells. Such an interpretation is not available from analytical methods. The simulated distributions of aquifer anisotropy and heterogeneity, in this study, were highly conceptualized, but were based on plausible occurrences of anisotropy and heterogeneity inherent in carbonate aquifer systems.

Florida