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James L. Bischoff

Publications and source records attributed to James L. Bischoff.

At least 37 records · Page 2Linked to original sources

Responses of sediment geochemistry to climate change in Owens Lake sediment: An 800-k.y. record of saline/fresh cycles in core OL-92

Geochemical parameters of sediments from drill hole OL-92 indicate that Owens Lake was saline, alkaline, and highly productive during interglacial periods, and was hydrologically open and relatively unproductive during glacial periods. Abundance of CaCO 3 , organic carbon, and cation-exchange capacity of the clay fraction show cyclic variation down the core. Six minima in these components during the past 500 k.y. are interpreted as caused by intensive overflow that occurred during Sierran glacial advances. Maxima in these components indicate closed-lake conditions, reflecting warmer and more arid interglacial climates. The pattern of CaCO 3 abundance suggests that closed lake conditions predominated over the past 500 k.y. The absence of gaylussite and gypsum in the sediments, however, indicates lake salinity never exceeded about 15 wt %, a limit which requires flushing of accumulated salts every 10 k.y. Oscillations of CaCO 3 generally indicate a 100-k.y. dominant cycle, a characteristic of the marine δ 18 O record. Four of the last five marine isotope terminations are clearly shown in the Owens Lake record. The last interglacial at Owens Lake appears to have occurred between 120 ka and 50 ka. The roughly 10-k.y. offset between this interval and marine oxygen-isotope stage 5 reflects either error in the age-depth model, or alternatively, a time lag between changes in Northern Hemisphere ice volumes and the manifestation of local climate change in lake geochemistry and sedimentology.

California

A time-depth scale for Owens Lake sediments of core OL-92; radiocarbon dates and constant mass-accumulation rate

Results of radiocarbon analyses of carbonates and humates from the upper 31 m of OL-92 indicate coherent and linear progression of dates with depth down to about 24 m and 30 ka. Scatter of results below this depth indicates that the practical limit of radiocarbon dating in this core is about 30 ka. The average mass-accumulation rate (MAR) for the top 24 m is 52.4 g/cm 2 /k.y. calculated from radiocarbon dates and bulk density reconstruction. A similar calculation for the entire core down to the Bishop ash bed (304 m, 759 ka) gives a MAR of 51.4 g/cm 2 /k.y., suggesting a constant MAR throughout the past 760 k.y. A time-depth curve for the entire core was then constructed from this constant value and using pore-water content to correct for sediment compaction. The resulting curve is remarkably coincident with a similar plot independently derived from 10 within-Brunhes paleomagnetic events identified by Glen et al. (this volume). That MAR remained relatively constant through the glacial/interglacial cycles may imply that the increased sediment supply during the high runoff of glacial times was balanced by increased size of the depositional area and vice-versa during interglacials. Surface area of the lake is approximately proportional to river discharge, but only up to the spill point of the lake. The constant MAR suggests, therefore, that spilling of Owens Lake was relatively infrequent during the past 800 k.y., as independently inferred from the sediment geochemistry (Bischoff et al., this volume, chapter 4).

California

Dating of the Basal Aurignacian Sandwich at Abric Romanı́ (Catalunya, Spain) by Radiocarbon and Uranium-Series

Abric Romaní, a rock shelter located near Barcelona, Spain, contains a charcoal-bearing basal Aurignacian occupation level sandwiched between beds of moss-generated carbonate. The Aurignacian culture is the oldest artefact industry in Europe with which anatomically modern human remains have been associated. Radiocarbon analysis of charcoal fragments by accelerator mass spectrometry (AMS) dates the basal Aurignacian to about 37 ± 2 ka bp. U-series analyses by alpha spectrometry (AS) and mass spectrometry (MS) date the enclosing carbonate to 43 ± 1 ka bp. These results confirm the great antiquity of the Aurignacian in northern Spain and support the similar AMS dates from El Castillo and l'Arbreda caves. They also show that radiocarbon dates are significantly younger than U-series at 40 ka bp, as predicted by theory.

Catalunya

Interstadial climatic cycles: A link between western North America and Greenland?

During the interval 33.6 to 26.1 ka, Searles Lake in southeastern California went through six major cycles of expansion and contraction. A comparison of U/Th ages for these events with the chronologies for quasi-cyclic interstadial episodes in the ice core from Summit, Greenland, suggests that the episodes of low water at Searles Lake are synchronous with the interstadial episodes at Summit. The two phenomena may be linked by variations in the strength of the global hydrological cycle, driven by oscillations in the Atlantic Ocean thermohaline circulation.

California

The Solubility and Stabilization of Ikaite (CaCO3·6H2O) from 0° to 25°C: Environmental and Paleoclimatic Implications for Thinolite Tufa

We determined the solubility of ikaite from 0° to 25°C to model its saturation state in natural waters and test the hypothesis that it is the precursor of the calcite pseudomorphs in thinolite tufa of Quaternary Lake Lahontan. Reversible solubility at buffered $P_{CO_{2}}$ yields the following expression for the dissolution constant of ikaite: $log K_{ikaite} = 0.15981 - 2011.1/T$. Where $T = ^{\circ}K$, and $0^{\circ}C \leq t \leq 25^{\circ}C$. Derived standard state properties are $\Delta G_{ikaite}^{\circ} = -2541.9 kJmol^{-1} \pm 0.66; \Delta H_{ikaite}^{\circ} = -2973.4 kJmol^{-1} \pm 1.02; S_{ikaite}^{\circ} = 306.6 JT^{-1}mol^{-1} \pm 1.2$. Modeling shows that ikaite is undersaturated at all temperatures in seawater and in alkaline lakes, but that it rapidly approaches saturation near 0°C. Its precipitation in near-freezing marine sediments requires large additions of $HCO_{3}$ to pore fluids from the diagenetic decomposition of organic matter. Its crystallization in tufas of alkaline lakes, however, requires only small additions of Ca from springs. Simple kinetic experiments show that ikaite is stabilized in natural environments by orthophosphate, which prevents the crystallization of the more stable anhydrous forms of $CaCO_{3}$ but does not interact with the ikaite. Therefore, the presence of ikaite or its pseudomorphs is an indicator of near-freezing conditions in environments with high concentrations of orthophosphate. If ikaite is the precursor of thinolite tufa, then the thinolite likely grew below the sediment-water interface at the site of sublacustrine springs during prolonged cold periods.

Journal of Geology

Core OL-92 from Owens Lake, southeast California

The drilling project at Owens Lake commenced in April, 1991. This Open-File Report represents an effort to make available to other researchers our preliminary data collected during the first year of study following completion of the core-drilling phase. Nineteen data collections and preliminary interpretations are presented in the following sections. They are the work of fifteen first-authors and their numerous co-authors. Broadly, their topics include a field log of the core (1 contribution), sedimentological analyses (1), clay- mineral identification (1), geochemical analyses (5), dating and age estimates of the cored sediments (4), and identifications of fossil materials (7).

California

Quartz solubility in hydrothermal seawater: An experimental study and equation describing quartz solubility for up to 0.5 M NaCl solutions

Experimental investigations confirm an increase of quartz solubility in sea-water relative to distilled water. Combination of the experimental data with published data, most of which related to distilled water, permitted construction of a database for calculating an equation that fits all the data. Application of the equation indicates a shallower depth of circulation for sea- floor hydrothermal waters than has previously been calculated. Use of the equation as a quartz geothermometer-geobarometer has applications not only for hydrothermal sea-water systems, but also for other geothermal and geological systems.

American Journal of Science

Abrupt Mousterian/Aurignacian boundary at c. 40 ka bp: Accelerator 14C dates from l'Arbreda Cave (Catalunya, Spain)

The cultural transition from Mousterian to Aurignacian is abrupt at l'Arbreda Cave and occurs within a homogeneous sedimentary unit with no visible lithologic changes. Fragments of milligram-size charcoal were collected immediately above and below the cultural boundary for radiocarbon dating by accelerator. Four charcoal fragments from the lowest basal Aurignacian level yielded dates of 37·7 ± 1·0, 37·7 ± 1·0, 39·9 ± 1·2, and 38·7 ± 1·2 ka bp (average 38·5 ± 1·0 ka bp). These ages are similar to three dates from the same cultural horizon at El Castillo Cave in Cantabria and both sets of dates are significantly older than the earliest reported for the Aurignacian in the Aquitaine and in other parts of Central and Western Europe. The dates are in accord with similarly early dates for Aurignacian in Bulgaria and suggest that appearance of Aurignacian peoples is synchronous across Europe. Three fragments from the uppermost Mousterian level yielded dates of 39·4 ± 1·4, 34·1 ± 0·75, and 41·4 ± 1·6 ka bp. Discounting the spurious 34·1 ka bp result, these dates are slightly older (average 40·4 ± 1·4 ka bp) but overlap with counting error the basal Aurignacian dates. The data show that the transition from Mousterian to Aurignacian was chronologically abrupt at this location. These results strongly support the replacement hypothesis.

l'Arbreda Cave

Salinity variations in submarine hydrothermal systems by layered double-diffusive convection

Various mechanisms have been proposed to explain the salinity variations in vent fluids of seafloor geothermal systems. New experiments reacting diabase and evolved seawater were carried out to reproduce earlier published observations of Cl depletions attributed to formation of an ephemeral Cl-bearing mineral. The absence of any Cl depletions in the present study suggests that the formation of Cl-bearing minerals is not sufficiently widespread to account for the observed salinity variations in the vent fluids. A re-evaluation of both field and laboratory evidence has led to a new model for subseafloor circulation that accounts for salinity variations as well as other chemical and mineralogic observations. In place of a simple single-pass convection system, we propose that the seafloor systems consist of two vertically nested convection cells in which a brine layer at depth heats and drives an overlying seawater cell. Such layering of salinities, a process known in fluid mechanics as double-diffusive convection, is an expected result when convection is induced in saline fluids. The process provides for stable high-temperature heat transfer upward from the cracking front adjacent to the magma, and for limited chemical exchange of the brine with the overlying seawater to explain salinity variations and high metal contents in the vent fluids. The brine also provides an effective medium to produce the secondary mineral assemblages observed in rocks from the mid-ocean ridges and ophiolites unsuccessfully produced in laboratory studies using seawater. The brine originates from the two-phase separation of seawater during magmatic/tectonic events and accumulates and remains relatively stable in the region immediately above the magma chamber.

Journal of Geology

Liquid-vapor relations in the critical region of the system NaCl-H 2 O from 380 to 415°C: A refined determination of the critical point and two-phase boundary of seawater

Pressure-temperature-composition ( P - T - x ) relations for coexisting vapor and liquid phases in the system NaCl-H 2 O were determined experimentally in the critical region from 380 to 415°C. The results provide much improved control on the P - T - x critical line in this region. The critical point of seawater (3.2 wt% NaCl solution), which is bracketed in the present study, is at 407°C and 298.5 bar. In addition, the P - T two-phase boundary of seawater was re-determined. These results provide increased precision and accuracy for theoretical models of critical phenomena in this important two-component system and of the limiting P - T conditions of seawater in seafloor geothermal systems.

Geochimica et Cosmochimica Acta

The laboratory albitization of mid-ocean ridge basalt

Complete alteration of fresh mid-ocean ridge basalt to albite + actinolite + smectite took place in the presence of quartz and 3.4m NaCl at 350°C and 400 bars. Significant Na-metasomatism occurred in exchange for Ca + Fe + Mn. In contrast, alteration of the basalt/quartz mixture with a synthetically prepared "natural brine," and basalt with 3.4m NaCl or "natural brine" did not produce significant albitization. Based on these and previous experiments that reacted basalt with a variety of fluids, it is concluded that excess silica, a high Na/Ca ratio, and an absence of strong acidity (dissolved Mg) in the altering fluid are important for the albitization of basalt.

Journal of Geology

Critical behavior of dilute NaCl in H2O

The compositions of the saturated vapor and liquid phases are measured for the system NaCl-H 2 O at 380°C, which is close to the critical point of pure water. The shape of the phase equilibrium curve is classical, which confirms a conclusion reached earlier on the basis of less accurate data. This implies that the long-range forces introduced by the NaCl suppress the non-classical effects present in pure H 2 O. An empirical equation of a classical type fits these data.

Chemical Physics Letters

Pressure-composition relations for coexisting gases and liquids and the critical points in the system NaCl-H 2 O at 450, 475, and 500°C

Pressure-temperature-composition ( P , T , x ) relations for the co-existing vapor and liquid phases in the system NaCl-H 2 O were determined experimentally at 450, 475, and 500°C. Data for each isotherm include P - x relations near the critical point and extend to the three-phase assemblage vapor-liquid-halite on the vapor side. On the liquid side the P - x data range from the critical point to the room-temperature halite saturation point (~25 wt.% NaCl). Critical pressures were calculated from measured pressures and compositions and classical theory. The results generally support the few data points of Urusova (1974, 1975) and Ölander and Liander (1950) but differ markedly from the extensive data of Sourirajan and Kennedy (1962).

Geochimica et Cosmochimica Acta

Phase separation in seafloor geothermal systems: An experimental study of the effects on metal transport

Experimental investigations were carried out by reacting natural and evolved sea-water with crystalline basalt from the Juan de Fuca Ridge in order to study the effects of vapour-liquid phase separation on metal mobilization in sea-floor geothermal systems in which phase separation occurs between the top of a magma chamber (300-500 bar) and the sea-floor (230-250 bar). The geochemical processes produced by a combination of closed-system phase separation and adiabatic expansion under the conditions characterizing the sea-floor geothermal systems resulted in a significant increase in the acidity and concentration of heavy metals in the liquid phase and strikingly high concentrations of metals in the vapour.

American Journal of Science