Geology Reports⌕ Search

Geology topics

James L. Bischoff

Publications and source records attributed to James L. Bischoff.

At least 37 records · Page 2Linked to original sources

Responses of sediment geochemistry to climate change in Owens Lake sediment: An 800-k.y. record of saline/fresh cycles in core OL-92

Geochemical parameters of sediments from drill hole OL-92 indicate that Owens Lake was saline, alkaline, and highly productive during interglacial periods, and was hydrologically open and relatively unproductive during glacial periods. Abundance of CaCO 3 , organic carbon, and cation-exchange capacity of the clay fraction show cyclic variation down the core. Six minima in these components during the past 500 k.y. are interpreted as caused by intensive overflow that occurred during Sierran glacial advances. Maxima in these components indicate closed-lake conditions, reflecting warmer and more arid interglacial climates. The pattern of CaCO 3 abundance suggests that closed lake conditions predominated over the past 500 k.y. The absence of gaylussite and gypsum in the sediments, however, indicates lake salinity never exceeded about 15 wt %, a limit which requires flushing of accumulated salts every 10 k.y. Oscillations of CaCO 3 generally indicate a 100-k.y. dominant cycle, a characteristic of the marine δ 18 O record. Four of the last five marine isotope terminations are clearly shown in the Owens Lake record. The last interglacial at Owens Lake appears to have occurred between 120 ka and 50 ka. The roughly 10-k.y. offset between this interval and marine oxygen-isotope stage 5 reflects either error in the age-depth model, or alternatively, a time lag between changes in Northern Hemisphere ice volumes and the manifestation of local climate change in lake geochemistry and sedimentology.

California↗

A time-depth scale for Owens Lake sediments of core OL-92; radiocarbon dates and constant mass-accumulation rate

Results of radiocarbon analyses of carbonates and humates from the upper 31 m of OL-92 indicate coherent and linear progression of dates with depth down to about 24 m and 30 ka. Scatter of results below this depth indicates that the practical limit of radiocarbon dating in this core is about 30 ka. The average mass-accumulation rate (MAR) for the top 24 m is 52.4 g/cm 2 /k.y. calculated from radiocarbon dates and bulk density reconstruction. A similar calculation for the entire core down to the Bishop ash bed (304 m, 759 ka) gives a MAR of 51.4 g/cm 2 /k.y., suggesting a constant MAR throughout the past 760 k.y. A time-depth curve for the entire core was then constructed from this constant value and using pore-water content to correct for sediment compaction. The resulting curve is remarkably coincident with a similar plot independently derived from 10 within-Brunhes paleomagnetic events identified by Glen et al. (this volume). That MAR remained relatively constant through the glacial/interglacial cycles may imply that the increased sediment supply during the high runoff of glacial times was balanced by increased size of the depositional area and vice-versa during interglacials. Surface area of the lake is approximately proportional to river discharge, but only up to the spill point of the lake. The constant MAR suggests, therefore, that spilling of Owens Lake was relatively infrequent during the past 800 k.y., as independently inferred from the sediment geochemistry (Bischoff et al., this volume, chapter 4).

California↗

The generation of HCl in the system CaCl 2 -H 2 O: Vapor-liquid relations from 380-500°C

We determined vapor-liquid relations (P-T-x) and derived critical parameters for the system CaCl2-H2O from 380-500??C. Results show that the two-phase region of this system is extremely large and occupies a significant portion of the P-T space to which circulation of fluids in the Earth's crust is constrained. Results also show the system generates significant amounts of HCl (as much as 0.1 mol/kg) in the vapor phase buffered by the liquid at surprisingly high pressures (???230 bars at 380??C, <580 bars at 500??C), presumably by hydrolysis of CaCl2: CaCl2 + 2H2O = Ca(OH)2 + 2HCl. We interpret the abundance of HCl in the vapor as due to its preference for the vapor phase, and by the preference of Ca(OH)2 for either the liquid phase or solid. The recent recognition of the abundance of CaCl2 in deep brines of the Earth's crust and their hydrothermal mobilization makes the hydrolysis of CaCl2 geologically important. The boiling of Ca-rich brines produces abundant HCl buffered by the presence of the liquid at moderate pressures. The resultant Ca(OH)2 generated by this process reacts with silicates to form a variety of alteration products, such as epidote, whereas the vapor produces acid-alteration of rocks through which it ascends.

Geochimica et Cosmochimica Acta↗

The alteration of rhyolite in CO 2 charged water at 200 and 350°C: The unreactivity of CO 2 at higher temperature

Geochemical and hydrologic modeling indicates that geothermal waters in the T > 270&deg;C reservoirs beneath Yellowstone National Park have HCO 3 ≪ Cl and contrast with waters in reservoirs at lower temperatures which attain HCO 3 about equal to Cl. Experiments reacting rhyolite with 0.5 molal solutions of CO 2 at 200&deg; and 350&deg;C were carried out to test the hypothesis of 3 and 4 to explain the chemistry of these springs: that CO 2 is relatively unreactive with volcanic rocks at temperatures >270&deg;C. The experimental results strongly support this hypothesis. Extent of alteration is twenty-seven times greater at 200&deg;C than at 350&deg;C. The dominant process in the experiments appears to be the alteration of the albitic component of the rhyolite by dissolved CO 2 to form a kaolinite-like alteration product plus quartz: 2NaAlSi3O8+2CO2+3H2O=2Na++2HCO3-+Al2Si2O5(OH)4+4SiO2. Turn MathJax on CO 2 reacts with water to form H 2 CO 3 which dissociates to H + and HCO 3 &minus; , more so at lower temperatures. Kinetic and thermodynamic considerations suggest that the reactivity of H 2 CO 3 with wallrocks is at its maximum between 150&deg; and 200&deg;C, consuming most of the H + and liberating equivalent amounts of cations and bicarbonate. Wallrocks in higher temperature reservoirs are relatively unreactive to dissolved CO 2 which is eventually lost from the system by boiling. These observations also offer a possible explanation for the change in chemical sediments from chloride-dominated to bicarbonate-dominated salts found in the stratigraphic section at Searles Lake, California, the terminus of the Owens River which derives its dissolved load from hot springs of the Long Valley caldera.

Geochimica et Cosmochimica Acta↗

Dating of the Basal Aurignacian Sandwich at Abric Romanı́ (Catalunya, Spain) by Radiocarbon and Uranium-Series

Abric Romaní, a rock shelter located near Barcelona, Spain, contains a charcoal-bearing basal Aurignacian occupation level sandwiched between beds of moss-generated carbonate. The Aurignacian culture is the oldest artefact industry in Europe with which anatomically modern human remains have been associated. Radiocarbon analysis of charcoal fragments by accelerator mass spectrometry (AMS) dates the basal Aurignacian to about 37 ± 2 ka bp. U-series analyses by alpha spectrometry (AS) and mass spectrometry (MS) date the enclosing carbonate to 43 ± 1 ka bp. These results confirm the great antiquity of the Aurignacian in northern Spain and support the similar AMS dates from El Castillo and l'Arbreda caves. They also show that radiocarbon dates are significantly younger than U-series at 40 ka bp, as predicted by theory.

Catalunya↗

Interstadial climatic cycles: A link between western North America and Greenland?

During the interval 33.6 to 26.1 ka, Searles Lake in southeastern California went through six major cycles of expansion and contraction. A comparison of U/Th ages for these events with the chronologies for quasi-cyclic interstadial episodes in the ice core from Summit, Greenland, suggests that the episodes of low water at Searles Lake are synchronous with the interstadial episodes at Summit. The two phenomena may be linked by variations in the strength of the global hydrological cycle, driven by oscillations in the Atlantic Ocean thermohaline circulation.

California↗

The Solubility and Stabilization of Ikaite (CaCO3·6H2O) from 0° to 25°C: Environmental and Paleoclimatic Implications for Thinolite Tufa

We determined the solubility of ikaite from 0° to 25°C to model its saturation state in natural waters and test the hypothesis that it is the precursor of the calcite pseudomorphs in thinolite tufa of Quaternary Lake Lahontan. Reversible solubility at buffered $P_{CO_{2}}$ yields the following expression for the dissolution constant of ikaite: $log K_{ikaite} = 0.15981 - 2011.1/T$. Where $T = ^{\circ}K$, and $0^{\circ}C \leq t \leq 25^{\circ}C$. Derived standard state properties are $\Delta G_{ikaite}^{\circ} = -2541.9 kJmol^{-1} \pm 0.66; \Delta H_{ikaite}^{\circ} = -2973.4 kJmol^{-1} \pm 1.02; S_{ikaite}^{\circ} = 306.6 JT^{-1}mol^{-1} \pm 1.2$. Modeling shows that ikaite is undersaturated at all temperatures in seawater and in alkaline lakes, but that it rapidly approaches saturation near 0°C. Its precipitation in near-freezing marine sediments requires large additions of $HCO_{3}$ to pore fluids from the diagenetic decomposition of organic matter. Its crystallization in tufas of alkaline lakes, however, requires only small additions of Ca from springs. Simple kinetic experiments show that ikaite is stabilized in natural environments by orthophosphate, which prevents the crystallization of the more stable anhydrous forms of $CaCO_{3}$ but does not interact with the ikaite. Therefore, the presence of ikaite or its pseudomorphs is an indicator of near-freezing conditions in environments with high concentrations of orthophosphate. If ikaite is the precursor of thinolite tufa, then the thinolite likely grew below the sediment-water interface at the site of sublacustrine springs during prolonged cold periods.

Journal of Geology↗

Core OL-92 from Owens Lake, southeast California

The drilling project at Owens Lake commenced in April, 1991. This Open-File Report represents an effort to make available to other researchers our preliminary data collected during the first year of study following completion of the core-drilling phase. Nineteen data collections and preliminary interpretations are presented in the following sections. They are the work of fifteen first-authors and their numerous co-authors. Broadly, their topics include a field log of the core (1 contribution), sedimentological analyses (1), clay- mineral identification (1), geochemical analyses (5), dating and age estimates of the cored sediments (4), and identifications of fossil materials (7).

California↗

U-Series dates for stalagmitic flowstone E (Riss/Würm interglaciation) at Grotte du Lazaret, Nice, France

Several samples of stalagmitic flowstone (Ensemble E) at Grotte du Lazaret (Nice, France) were dated by U-series isotopes. The results show that this speleothem began to grow about 130,000 yr B.P. and continued to about 70,000 yr B.P., coinciding almost exactly with the last interglaciation (isotope stage 5). Even though Ensemble E is not in direct stratigraphic relation with the cave deposits, this study shows that the Acheulian artifacts industry and fauna within Lazaret are older than the Riss/Wurm interglaciation.

Quaternary Research↗

Quartz solubility in hydrothermal seawater: An experimental study and equation describing quartz solubility for up to 0.5 M NaCl solutions

Experimental investigations confirm an increase of quartz solubility in sea-water relative to distilled water. Combination of the experimental data with published data, most of which related to distilled water, permitted construction of a database for calculating an equation that fits all the data. Application of the equation indicates a shallower depth of circulation for sea- floor hydrothermal waters than has previously been calculated. Use of the equation as a quartz geothermometer-geobarometer has applications not only for hydrothermal sea-water systems, but also for other geothermal and geological systems.

American Journal of Science↗

Densities of liquids and vapors in boiling NaCl-H2O solutions: a PVTx summary from 300° to 500°C

Experimental data for densities of liquids and vapors on the two-phase surface of the system NaCl-H 2 O were compiled and evaluated to provide a complete summary between 300 &deg; and 500 &deg; C. The results are added to a previously published PTx summary compiled in the same manner to provide a PVTx summary of the present state of knowledge. Results are in table form of use to the understanding of two-phase behaviour in boiling hydrothermal systems and to theoretical modeling of this important system.

American Journal of Science↗

Abrupt Mousterian/Aurignacian boundary at c. 40 ka bp: Accelerator 14C dates from l'Arbreda Cave (Catalunya, Spain)

The cultural transition from Mousterian to Aurignacian is abrupt at l'Arbreda Cave and occurs within a homogeneous sedimentary unit with no visible lithologic changes. Fragments of milligram-size charcoal were collected immediately above and below the cultural boundary for radiocarbon dating by accelerator. Four charcoal fragments from the lowest basal Aurignacian level yielded dates of 37·7 ± 1·0, 37·7 ± 1·0, 39·9 ± 1·2, and 38·7 ± 1·2 ka bp (average 38·5 ± 1·0 ka bp). These ages are similar to three dates from the same cultural horizon at El Castillo Cave in Cantabria and both sets of dates are significantly older than the earliest reported for the Aurignacian in the Aquitaine and in other parts of Central and Western Europe. The dates are in accord with similarly early dates for Aurignacian in Bulgaria and suggest that appearance of Aurignacian peoples is synchronous across Europe. Three fragments from the uppermost Mousterian level yielded dates of 39·4 ± 1·4, 34·1 ± 0·75, and 41·4 ± 1·6 ka bp. Discounting the spurious 34·1 ka bp result, these dates are slightly older (average 40·4 ± 1·4 ka bp) but overlap with counting error the basal Aurignacian dates. The data show that the transition from Mousterian to Aurignacian was chronologically abrupt at this location. These results strongly support the replacement hypothesis.

l'Arbreda Cave↗

Salinity variations in submarine hydrothermal systems by layered double-diffusive convection

Various mechanisms have been proposed to explain the salinity variations in vent fluids of seafloor geothermal systems. New experiments reacting diabase and evolved seawater were carried out to reproduce earlier published observations of Cl depletions attributed to formation of an ephemeral Cl-bearing mineral. The absence of any Cl depletions in the present study suggests that the formation of Cl-bearing minerals is not sufficiently widespread to account for the observed salinity variations in the vent fluids. A re-evaluation of both field and laboratory evidence has led to a new model for subseafloor circulation that accounts for salinity variations as well as other chemical and mineralogic observations. In place of a simple single-pass convection system, we propose that the seafloor systems consist of two vertically nested convection cells in which a brine layer at depth heats and drives an overlying seawater cell. Such layering of salinities, a process known in fluid mechanics as double-diffusive convection, is an expected result when convection is induced in saline fluids. The process provides for stable high-temperature heat transfer upward from the cracking front adjacent to the magma, and for limited chemical exchange of the brine with the overlying seawater to explain salinity variations and high metal contents in the vent fluids. The brine also provides an effective medium to produce the secondary mineral assemblages observed in rocks from the mid-ocean ridges and ophiolites unsuccessfully produced in laboratory studies using seawater. The brine originates from the two-phase separation of seawater during magmatic/tectonic events and accumulates and remains relatively stable in the region immediately above the magma chamber.

Journal of Geology↗

Liquid-vapor relations for the system NaCl-H2O: Summary of the P-T- x surface from 300° to 500°C

Experimental data on the vapor-liquid equilibrium relations for the system NaCl-H 2 O were compiled and compared in order to provide an improved estimate of the P-T-x surface between 300 &deg; to 500 &deg; C, a range for which the system changes from subcritical to critical behavior. Data for the three-phase curve (halite + liquid + vapor) and the NaCl-H 2 O critical curve were evaluated, and the best fits for these extrema then were used to guide selection of best fit for isothermal plots for the vapor-liquid region in-between. Smoothing was carried out in an iterative procedure by replotting the best-fit data as isobars and then as isopleths, until an internally consistent set of data was obtained. The results are presented in table form that will have application to theoretical modelling and to the understanding of two-phase behavior in saline geothermal systems.

American Journal of Science↗