James J. Thordsen — Page 2

USGS1999

Geochemistry and hydromechanical interactions of fluids associated with the San Andreas fault system, California

18 O values establish that waters are predominantly of meteoric origin. The chemical compositions of water and gases are controlled mainly by the ambient rock types, and chemical geothermometry gives reservoir temperatures of 80-150 degrees C indicating shallow to moderate circulation depths of up to 6 km. However, compositions and isotope abundances of noble gases and delta 13 C values of HCO 3 indicate a significant (up to 50%) mantle component for the volatiles. The relatively high fluxes of CO 2 (C/ 3 He nearly equal 10 10 ) and other volatiles of mantle origin support a deep continuous flow model, especially at depths >6 km. Numerical simulations indicate that these high fluxes of CO 2 of mantle and deep crustal origin are sufficient to generate lithostatic fluid pressures, and thus a weakened fault, in time scales comparable to those of earthquake cycles.

California↗

USGS1997

Deep well injection of brine from Paradox Valley, Colorado: Potential major precipitation problems remediated by nanofiltration

Groundwater brine seepage into the Dolores River in Paradox Valley, Colorado, increases the dissolved solids load of the Colorado River annually by ∼2.0 × 10 8 kg. To abate this natural contamination, the Bureau of Reclamation plans to pump ∼3540 m 3 /d of brine from 12 shallow wells located along the Dolores River. The brine, with a salinity of 250,000 mg/L, will be piped to the deepest (4.9 km) disposal well in the world and injected mainly into the Mississippian Leadville Limestone. Geochemical modeling indicates, and water-rock experiments confirm, that a huge mass of anhydrite (∼1.0 × 10 4 kg/d) likely will precipitate from the injected brine at downhole conditions of 120°C and 500 bars. Anhydrite precipitation could increase by up to 3 times if the injected brine is allowed to mix with the highly incompatible formation water of the Leadville Limestone and if the Mg in this brine dolomitizes the calcite of the aquifer. Laboratory experiments demonstrate that nanofiltration membranes, which are selective to divalent anions, provide a new technology that remediates the precipitation problem by removing ∼98% of dissolved SO 4 from the hypersaline brine. The fluid pressure used (50 bars) is much lower than would be required for traditional reverse osmosis membranes because nanofiltration membranes have a low rejection efficiency (5–10%) for monovalent anions. Our results indicate that the proportion of treatable brine increases from ∼60% to >85% with the addition of trace concentrations of a precipitation inhibitor and by blending the raw brine with the effluent stream.

Water Resources Research↗