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James A. Kingsbury

Publications and source records attributed to James A. Kingsbury.

44 records · Page 3Linked to original sources

Water quality in the lower Tennessee River Basin, Tennessee, Alabama, Kentucky, Mississippi, and Georgia, 1999-2001

This report contains the major findings of a 1999?2001 assessment of water quality in the Lower Tennessee River Basin. It is one of a series of reports by the National Water-Quality Assessment (NAWQA) Program that present major findings in 51 major river basins and aquifer systems across the Nation. In these reports, water quality is discussed in terms of local, State, and regional issues. Conditions in a particular basin or aquifer system are compared to conditions found elsewhere and to selected national benchmarks, such as those for drinking-water quality and the protection of aquatic organisms. This report is intended for individuals working with water-resource issues in Federal, State, or local agencies, universities, public interest groups, or in the private sector. The information will be useful in addressing a number of current issues, such as the effects of agricultural and urban land use on water quality, human health, drinking water, source-water protection, hypoxia and excessive growth of algae and plants, pesticide registration, and monitoring and sampling strategies. This report is also for individuals who wish to know more about the quality of streams and ground water in areas where they live, and how that water quality compares to the quality of water in other areas across the Nation. The water-quality conditions in the Lower Tennessee River Basin summarized in this report are discussed in detail in other reports that can be accessed from the Lower Tennessee River Basin Web site (http://tn.water.usgs.gov/lten/lten.html). Detailed technical information, data and analyses, collection and analytical methodology, models, graphs, and maps that support the findings presented in this report in addition to reports in this series from other basins can be accessed from the national NAWQA Web site (http://water.usgs.gov/nawqa).

Alabama, Georgia, Kentucky, Mississippi, Tennessee↗

Shallow Ground-Water Quality in Agricultural Areas of Northern Alabama and Middle Tennessee, 2000-2001

As part of the U.S. Geological Survey National Water-Quality Assessment Program, 32 monitoring wells were installed near cropland in parts of northern Alabama and Middle Tennessee to characterize the effect of row-crop agriculture on shallow ground-water quality. The wells were completed in regolith overlying carbonate bedrock. These geologic units are part of the Mississippian carbonate aquifer, a source of drinking water for domestic and municipal supply in the area. The majority of these wells were sampled in the spring of 2000 for inorganic constituents, nutrients, pesticides, and selected pesticide degradates. Land use and soil characteristics were delineated for a 1,640-foot radius buffer area around each well to relate water quality to environmental factors. A strong association among soil characteristics, land use, and hydrogeology limited the analysis of the effect of these factors on nitrate and pesticide occurrence. Nitrate and pesticide concentrations generally were low, and no samples exceeded established drinking-water maximum contaminant levels. The maximum concentration of nitrate was about 8 milligrams per liter as nitrogen, and the median concentration was 1 milligram per liter. Nitrate concentrations were strongly correlated to dissolved-oxygen concentrations, and ratios of chloride to nitrate indicate nitrate concentrations were affected by denitrification in about a third of the samples. A pesticide or pesticide degradate was detected at concentrations greater than 0.01 microgram per liter in 91 percent of the samples. Pesticides with the highest use typically were detected most frequently and at the highest concentrations; however, glyphosate had the highest estimated use but was not detected in any samples. Fluometuron and atrazine, two high-use pesticides, were detected in 83 and 70 percent, respectively, of the samples from wells where the pesticide was applied in the buffer area. Maximum concentrations of fluometuron and atrazine were 2.13 and 1.83 micrograms per liter, respectively. Detection rates of pesticide degradates were similar to parent pesticides, and concentrations of degradates generally were comparable to or greater than the parent pesticide. Pesticide detections were correlated to dissolved-oxygen concentrations, suggesting that pesticides are most likely to be detected at high concentrations where ground-water residence time is short and the rate of recharge is fast. Nitrate and pesticide data collected in this study were compared to data collected from similar agricultural land-use studies conducted by the National Water-Quality Assessment Program throughout the Nation. Nitrate concentrations generally were lower in this study than in samples from other agricultural areas; however, pesticides were detected more frequently in samples from wells in this study. For example, atrazine and its degradate, deethylatrazine, were detected in 62 and 47 percent, respectively, of water samples in this study but were detected in about 25 percent of the 851 wells sampled for agricultural land-use studies nationwide. In national study areas where atrazine use is greater than in the lower Tennessee River Basin, atrazine was detected in 30 percent of the water samples. Pesticides used on cotton were detected much more frequently in this study, but many of the study areas nationwide have smaller amounts of cotton acreage than the lower Tennessee River Basin. Similarities in nitrate concentrations and the pesticides detected frequently in this agricultural land-use study and a network of drinking-water wells in the same area completed in bedrock in the Mississippian carbonate aquifer (sampled in a previous study) indicate the aquifer is susceptible to contamination from nonpoint sources. Nitrate concentrations were not statistically different for the two well networks and were correlated to total pesticide concentrations in both networks. Although detection frequencies and maximum concentrations

Water-Resources Investigations Report↗

Water quality of the Mississippian carbonate aquifer in parts of middle Tennessee and northern Alabama, 1999

Water-quality data for nitrate, fecal-indicator bacteria, pesticides, and volatile organic compounds collected in parts of Middle Tennessee and northern Alabama indicate that the Mississippian carbonate aquifer in these areas is susceptible to contamination from point and nonpoint sources. Thirty randomly located wells (predominantly domestic), two springs, and two additional public-supply wells were sampled in the summer of 1999 as part of the U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Program. These wells and springs were sampled to characterize the occurrence and distribution of the above constituents in this karst aquifer of Mississippian age and to determine the principal environmental factors related to their occurrence. Nitrate and fecal indicator bacteria were frequently detected at the sampled sites. Nitrate exceeded the drinking-water maximum contaminant level of 10 milligrams per liter in two samples; the median concentration for all samples was about 1.5 milligrams per liter. Correlation of nitrate concentrations to the amount of cropland near a site and to pesticide detections indicates that fertilizer application is the predominant source of nitrogen to the aquifer. Fecal-indicator bacteria were present in samples from about 40 percent of the sites. The presence of fecal-indicator bacteria is weakly correlated to the depth to ground water but is not correlated to a specific land use near the sites. Pesticides and pesticide breakdown products (metabolites) were detected at 74 percent of the sites sampled. Concentrations generally were less than 1 microgram per liter and no pesticide detections exceeded drinking-water maximum contaminant levels. The maximum total pesticide concentration measured was about 4 micrograms per liter. Intensity of pesticide use, proximity of sites to areas of pesticide application, and soil hydrologic group were the primary factors affecting the occurrence of pesticides. Volatile organic compounds were detected at generally low concentrations at about 81 percent of the sites sampled. Concentrations of trichloroethylene, tetrachloroethylene, and 1,2-dichloropropane at three sites equalled or exceeded drinking-water maximum contaminant levels. The maximum concentration measured was 7.5 micrograms per liter of trichloroethylene. The presence of volatile organic compounds in the Mississippian carbonate aquifer was not related to hydrogeology, soil properties, or land use near the sites; although higher total volatile organic compound concentrations and greater numbers of compounds in samples generally were associated with a higher percentage of urban land use near a site. Chloroform was the most frequently detected compound, and correlation of low-level detections to the amount of wetlands near sites having these detections may indicate biogenic formation of chloroform. The relation between land use and water quality was stronger for constituents that are contributed to the environment systematically (fertilizer and pesticide applications), than those contributed inadvertently (leaking septic tanks or chemical spills or leaks). Land use and soils characterized in circular buffer areas near sites sampled in this karst aquifer explained some of the variation in nitrate concentration and presence of pesticides. Use of land use and soil data with greater detail than the large scale data used in this analysis and buffer areas based on well capacities and ground-water withdrawals might strengthen this type of analysis.

Alabama, Tennessee↗

Environmental setting and water-quality issues in the lower Tennessee River basin

The goals of the National Water-Quality Assessment Program are to describe current water-quality conditions for a large part of the Nation's water resources, identify water-quality changes over time, and identify the primary natural and human factors that affect water quality. The lower Tennessee River Basin is one of 59 river basins selected for study. The water-quality assessment of the lower Tennessee River Basin study unit began in 1997. The lower Tennessee River Basin study unit encompasses an area of about 19,500 square miles and extends from Chattanooga, Tennessee, to Paducah, Kentucky. The study unit had a population of about 1.5 million people in 1995. The study unit was subdivided into subunits with relatively homogeneous geology and physiography. Subdivision of the study unit creates a framework to assess the effects of natural and cultural settings on water quality. Nine subunits were delineated in the study unit; their boundaries generally coincide with level III and level IV ecoregion boundaries. The nine subunits are the Coastal Plain, Transition, Western Highland Rim, Outer Nashville Basin, Inner Nashville Basin, Eastern Highland Rim, Plateau Escarpment and Valleys, Cumberland Plateau, and Valley and Ridge.The lower Tennessee River Basin consists of predominantly forest (51 percent) and agricultural land (40 percent). Activities related to agricultural land use, therefore, are the primary cultural factors likely to have a widespread effect on surface- and ground-water quality in the study unit. Inputs of total nitrogen and phosphorus from agricultural activities in 1992 were about 161,000 and 37,900 tons, respectively. About 3.7 million pounds (active ingredient) of pesticides was applied to crops in the lower Tennessee River Basin in 1992. State water-quality agencies identified nutrient enrichment and pathogens as water-quality issues affecting both surface and ground water in the lower Tennessee River Basin. Water-quality data collected by State and Federal agencies between 1980 and 1996 were summarized to characterize surface- and ground-water quality of the subunits with respect to these issues. Median concentrations of nitrogen species generally were less than 1 milligram per liter in surface and ground water in all subunits, and were highest throughout the subunits that had the largest percentages of agricultural land use. Median phosphorus concentrations also were less than 1 milligram per liter in all subunits. Phosphatic limestones present in two subunits had a larger effect on phosphorus concentrations in surface and ground water than did the amount of agricultural land use in these subunits. Median counts of fecal coliform were higher in surface water than in ground water in all subunits. The highest median counts in surface water were in the Valley and Ridge (7,500 colonies per 100 milliliters) and the Outer Nashville Basin subunits (5,000 colonies per 100 milliliters). Highest median counts in ground water were in the Inner and Outer Nashville Basin subunit. Natural setting likely has an important effect with respect to fecal contamination of surface and ground water in the lower Tennessee River Basin.

Alabama, Georgia, Kentucky, Mississippi, Tennessee↗

Hydrogeology, ground-water quality, and source of ground water causing water-quality changes in the Davis well field at Memphis, Tennessee

An investigation was conducted by the U.S. Geological Survey from 1992 to 1994 to collect and interpret hydrogeologic and water-quality data to determine the source of ground water causing water-quality changes in water from wells screened in the Memphis aquifer in the Davis well field at Memphis, Tennessee. Water-quality changes in aquifers used for water supply are of concern because these changes can indicate a potential for contamination of the aquifers by downward leakage from near-surface sources. The water-quality changes at the Davis well field were detected by Memphis Light, Gas and Water Division, which has periodically sampled and analyzed water from many of the 14 production wells since the well field began operation in 1971. Memphis Light, Gas and Water Division analyzed the water samples primarily for hardness, alkalinity, chloride, ulfate, and iron. Results of the e analy es and results of more recent (1992) analyse of water samples by the U.S. Geological Survey indicate that the quality of water from eight of the production wells has changed since the well field began operation. For example, from 1972 to 1991, hardness of water from one well has increased from 90 to 292 milligrams per liter (224 percent). The confining unit, which separates the fluvial deposits aquifer from the Memphis aquifer in the area of the well field, is relatively thick and contains many clay layers. However, a test hole drilled for one of five shallow wells installed in the alluvial aquifer in the Mississippi Alluvial Plain just west of the well field indicated that the confining unit separating the alluvial aquifer from the Memphis aquifer locally is absent. Differences in hydrauLic head between the alluvial and fluvial deposits aquifers and the Memphis aquifer favor downward leakage of ground water. Thus, the absence of the confining unit beneath the Mississippi Alluvial Plain just west of the well field provides a direct pathway for water in the alluvial aquifer to enter the Memphis aquifer. Comparison of selected water-quality properties and major inorganic and trace element constituent concentrations in samples from the alluvial, fluvial deposits, and Memphis aquifers indicates that the source of ground water causing waterquality changes at the Davis well field is the alluvial aquifer west of the well field . The presence of tritium and chlorofluorocarbons in water from wells screened in the Memphis aquifer in the western part of the well field indicates that relatively young (post-1940) water from the alluvial aquifer has entered the Memphis aquifer. NETPATH geochemical model code was used to mix waters from the alluvial aquifer with water from the Memphis aquifer using chloride as a conservative tracer. The resulting models indicated that a mixture containing 3 percent alluvial aquifer water mixed with 97 percent unaffected Memphis aquifer water would produce the chloride concentration measured in water from the Memphis aquifer well most affected by water-quality changes. NETPATH also was used to calculate mixing percentages of alluvial and Memphis aquifer Abstract waters based on changes in the concentrations of selected dissolved major inorganic and trace element constituents that define the dominant reactions that occur during mixing. These models indicated that a mixture containing 18 percent alluvial aquifer water and 82 percent unaffected Memphis aquifer water would produce the major constituent and trace element concentrations measured in water from the Memphis aquifer well most affected by water-quality changes. However, these model simulations predicted higher dissolved methane concentrations than were measured in water samples from the Memphis aquifer wells.

Tennessee↗