Soil organic carbon content in rice soils of Arkansas and Louisiana and a comparison to non-agricultural soils; including a bibliography for agricultural soil carbon
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Open-File Report↗
Geology topics
J.S. Leventhal
Publications and source records attributed to J.S. Leventhal.
Relationship between inferred redox potential of the depositional environment and geochemistry of the Upper Pennsylvanian (Missourian) Stark Shale Member of the Dennis Limestone, Wabaunsee County, Kansas, U.S.A.
Analyses of 21 samples collected from a core of the 52.8-cm-thick Stark Shale Member of the Dennis Limestone in Wabaunsee County, Kansas, demonstrate four cycles with two-orders-of-magnitude variations in contents of Cd, Mo, P, V and Zn, and order-of-magnitude variations in contents of organic carbon, Cr, Ni, Se and U. The observed variability in amounts and/or ratios of many metals and amounts and compositions of the organic matter appear related to the cause and degree of water-column stratification and the resulting absence/presence of dissolved O2 or H2S. High Cd, Mo, U, V, Zn and S contents, a high degree of pyritization (DOP) (0.75-0.88), and high high V (V + Ni) (0.84-0.89) indicate the presence of H2S in a strongly stratified water column. Intermediate contents of metals and S, intermediate DOP (0.67-0.75) and intermediate V (V + Ni) (054-0.82) indicate a less strongly stratified anoxic water column. Whereas, low metal contents and low V (V + Ni) (0.46-0.60) indicate a weakly stratified, dysoxic water column. High P contents at the top of the organic-matter-rich intervals within the Stark Shale Member indicate that phosphate precipitation was enhanced near the boundary between anoxic and dysoxic water compositions. Relatively abundant terrestrial organic matter in intervals deposited from the more strongly stratified H2S-bearing water column indicates a combined halocline-thermocline with the fresher near-surface water the transport mode for the terrestrial organic matter. The predominance of algal organic matter in intervals deposited from a less strongly stratified water column indicates the absence of the halocline and the presence of the more generally established thermocline. Relatively low amounts of degraded, hydrogen-poor organic matter characterize intervals deposited in a weakly stratified, dysoxic water column. The inferred variability in chemistry of the depositional environments may be related to climate variations and/or minor changes in sea level during the general phase of deeper water deposition responsible for this widespread shale member. ?? 1992.
Chemical Geology↗
Organic matter and containment of uranium and fissiogenic isotopes at the Oklo natural reactors
Some of the Precambrian natural fission reactors at Oklo in Gabon contain abundant organic matter 1,2 , part of which was liquefied at the time of criticality and subsequently converted to a graphitic solid 3,4 . The liquid organic matter helps to reduce U(VI) to U(IV) from aqueous solutions, resulting in the precipitation of uraninite 5 . It is known that in the prevailing reactor environments, precipitated uraninite grains incorporated fission products. We report here observations which show that these uraninite crystals were held immobile within the resolidified, graphitic bitumen. Unlike water-soluble (humic) organic matter, the graphitic bituminous organics at Oklo thus enhanced radionuclide containment. Uraninite encased in solid graphitic matter in the organic-rich reactor zones lost virtually no fissiogenic lanthanide isotopes. The first major episode of uranium and lead migration was caused by the intrusion of a swarm of adjacent dolerite dykes about 1,100 Myr after the reactors went critical. Our results from Oklo imply that the use of organic, hydrophobic solids such as graphitic bitumen as a means of immobilizing radionuclides in pretreated nuclear waste warrants further investigation.
Nature↗
Organic matter and thermochemical sulfate reduction in the Viburnum Trend, southeast Missouri
The role of organic matter in Mississippi Valley-type Pb-Zn deposits has been studied by systematically sampling and characterizing various types of organic matter in the Upper Cambrian Bonneterre formation in lead-zinc mines from the Viburnum Trend and from rocks as far as 20 km away from the Trend. Organic matter that is several kilometers from ore consists of insoluble disseminated kerogen in carbonates. Kerogen from brown dolostones yields mainly n-alkane pyrolysis products up to approximately n-C 20 H 42 , whereas gray and white carbonates that are poorer in organic carbon give much smaller quantities of pyrolysis products. Within meters to centimeters of ore in the Milliken mine, at the south end of the Viburnum Trend, organic matter occurs as solid, partly soluble tacky bitumen and insoluble hard blebs of millimeter to centimeter size. These hydrocarbon materials also yield n-alkane pyrolysis products up to C 20 . In contrast, the solid insoluble organic matter in intimate contact (intergrown) with ore (galena and chalcopyrite) is friable and brittle. Products from pyrolysis-gas chromatography-mass spectrometry of this material are quite different from the kerogen in rocks or the hydrocarbon blebs; they are substituted aromatic molecules such as toluene and methyl naphthalene, rather than n-alkanes.The sulfur content of solid organic matter from the Milliken mine varies and is lowest for tacky material away from ore, intermediate for blebs near ore, and highest for friable material in intimate contact with ore.Pyrolysis-gas chromatography of this sample suite documents the progression of kerogen (far from ore) through solid petroleumlike material (near ore) to degraded organic matter (in contact with ore). The change in the organic matter from n-alkane to a hydrogen poorer aromatic character with a higher sulfur content when associated with sulfide ores, suggests that chemical reactions such as nonbiological (thermochemical) sulfate reduction, which consume hydrogen and produce reactive sulfur, were responsible for organic degradation.
Economic Geology↗
An interpretation of carbon and sulfur relationships in Black Sea sediments as indicators of environments of deposition
Syngenetic iron sulfides in sediments are formed from dissolved sulfide resulting from sulfate reduction and catabolism of organic matter by anaerobic bacteria. It has been shown that in recent marine sediments deposited below oxygenated waters there is a constant relationship between reduced sulfur and organic carbon which is generally independent of the environment of deposition. Reexamination of data from recent sediments from euxinic marine environments ( e.g. , the Black Sea) also shows a linear relationship between carbon and sulfur, but the slope is variable and the line intercepts the S axis at a value between 1 and 2 percent S. It is proposed that the positive S intercept is due to watercolumn microbial reduction of sulfate using metabolizable small organic molecules and the sulfide formed is precipitated and accumulates at the sediment-water interface. The variation in slope and intercept of the C to S plots for several cores and for different stratigraphic zones for the Black Sea can be interpreted in relation to thickness of the aqueous sulfide layer or thinness of the oxygen containing layer and to deposition rate, but also may be influenced by availability of iron, and perhaps the type of organic matter (Leventhal, 1979).
Geochimica et Cosmochimica Acta↗
Geochemistry of the Chattanooga shale, Dekalb County, central Tennessee.
This Upper Devonian shale is of interest because of its unusual enrichment in trace elements, especially U; a new chemical analysis for major, minor and trace elements is presented. Stable isotopes of carbon (organic) show delta 13C approx -29per mille and for total sulphur show -21 to -27per mille delta 34S. The organic matter was found to range from dominantly marine (Dowelltown member) to dominantly terrestrial (Gassaway member) by extraction-column chromatography-GS and also by pyrolysis-GS of kerogen. Trace elements U, Mo, Co, Zn, Cu, Ni, V, As and Hg are enriched in the organic- and sulphide-rich units. This enrichment can be related to a euxinic depositional environment, to a very slow sedimentation rate (approx 2 mm/1000 years), to the type of organic matter that varied from mainly marine to terrestrial, and to the source of the metals, which shows abundance variations that originated, at least in part, from volcanic ash layers.-R.S.M.
Southeastern Geology↗
Chemical and mineralogical analysis of devonian black-shale samples from Martin County, Kentucky; Carroll and Washington counties, Ohio; Wise County, Virginia; and Overton County, Tennessee, U.S.A.
Core samples of Devonian shales from five localities in the Appalachian basin have been analyzed chemically and mineralogically. The amounts of major elements are similar; however, the minor constituents, organic C, S, phosphate and carbonate show ten-fold variations in amounts. Trace elements Mo, Ni, Cu, V, Co, U, Zn, Hg, As and Mn show variations in amounts that can be related to the minor constituents. All samples contain major amounts of quartz, illite, two types of mixed-layer clays, and chlorite in differing quantities. Pyrite, calcite, feldspar and kaolinite are also present in many samples in minor amounts. Dolomite, apatite, gypsum, barite, biotite and marcasite are present in a few samples in trace amounts. Trace elements listed above are strongly controlled by organic C with the exception of Mn which is associated with carbonate minerals. Amounts of organic C generally range from 3 to 6%, and S is in the range of 2-5%. Amounts of trace elements show the following general ranges in ppm (parts per million): Co, 20-40; Cu, 40-70; U, 10-40; As, 20-40; V, 150-300; Ni, 80-150; high values are as much as twice these values. The organic C was probably the concentrating agent, and the organic C and sulfide S together created an environment that immobilized and preserved these trace elements. Closely spaced samples showing an abrupt transition in color also show changes in organic C, S and trace-element contents. Several associations exist between mineral and chemical content. Pyrite and marcasite are the only minerals found to contain sulfide-S. In general, the illite-chlorite mixed-layer clay mineral shows covariation with organic C if calcite is not present. The enriched trace elements are not related to the clay types, although the clay and organic matter are intimately associated as the bulk fabric of the rock. ?? 1982.
Chemical Geology↗
Pyrolysis gas chromatography-mass spectrometry to characterize organic matter and its relationship to uranium content of Appalachian Devonian black shales
Gas Chromatographic analysis of volatile products formed by stepwise pyrolysis of black shales can be used to characterize the kerogen by relating it to separated, identified precursors such as land-derived vitrinite and marine-source Tasmanites . Analysis of a Tasmanites sample shows exclusively n- alkane "> n-alkane and -alkene pyrolysis products, whereas a vitrinite sample shows a predominance of one- and two-ring substituted aromatics. For core samples from northern Tennessee and for a suite of outcrop samples from eastern Kentucky, the organic matter type and the U content (<10−120ppm) show variations that are related to precursor organic materials. The samples that show a high vitrinite component in their pyrolysis products are also those samples with high contents of U.
Geochimica et Cosmochimica Acta↗