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J.N. Rosholt

Publications and source records attributed to J.N. Rosholt.

At least 19 recordsLinked to original sources
USGS2006

Genesis of marine terrace soils, Barbados, West Indies: evidence from mineralogy and geochemistry

Well-developed, clay-rich soils dominated by interstratified kaolinite-smectite are found on the uplifted coral reef terraces on the island of Barbados. The reef limestone is unlikely to have been the soil parent material however, because it is 98% CaCO 3 and geomorphic evidence argues against the 20 m of reef solution required to produce the soils by this process. The mineralogy of the sand, silt, and clay fractions of the soils, and trace element geochemistry, suggest that aeolian materials carried on the trade winds from Africa, volcanic ash from the island of St. Vincent, and quartz from Tertiary bedrock on the island itself are the parent materials for the soils. -Authors

Earth Surface Processes and Landforms↗
USGS1989

Uranium-series nuclides in the Golden fault, Colorado, U.S.A.: Dating latest fault displacement and measuring recent uptake of radionuclides by fault-zone materials

Concentrations and isotopic ratios of U, Th and Ra were measured in a fault zone near Golden, Colorado where major displacement occurred between about 190 and 615 ka. Faulting created new surfaces for leaching and provided the pathways for U-rich ground water. Uranium and 230 Th, the latter produced by the decay of dissolved 234 U, are adsorbed by fault gouge, hematite-stained sand and brecciated sand- and claystones. The observed U enrichment is as much as six times baseline value and the simultaneous enrichment of 230 Th is estimated at about ninefold relative to 238 U. The adsorption of radionuclides chemically analogous to Th, such as Pu (IV) and Np, and 237 Np decay products, on fault-zone materials would contribute to the immobilization of high-level radioactive waste in the vicinity of a repository in the event of leakage from engineered barriers into fractured rock-mass.

Colorado↗
USGS1989

The Uranium-trend dating method: Principles and application for southern California marine terrace deposits

Uranium-trend dating is an open-system method for age estimation of Quaternary sediments, using disequilibrium in the 238U234U230Th decay series. The technique has been applied to alluvium, colluvium, loess, till, and marine sediments. In this study we tested the U-trend dating method on calcareous marine terrace deposits from the Palos Verdes Hills and San Nicolas Island, California. Independent age estimates indicate that terraces in these areas range from ???80 ka to greater than 1.0 Ma. Two low terraces on San Nicolas Island yielded U-trend plots that have a clustered array of points and the ages of these deposits are indeterminate or highly suspect. Middle Pleistocene terraces and one early Pleistocene terrace on San Nicolas Island and all terraces on the Palos Verdes Hills gave reasonably linear U-trend plots and estimated ages that are stratigraphically consistent and in agreement with independent age estimates. We conclude that many marine terrace deposits are suitable for U-trend dating, but U-trend plots must be carefully evaluated and U-trend ages should be consistent with independent geologic control. ?? 1989.

Quaternary International↗
USGS1986

Uranium series disequilibrium in a young surficial uranium deposit, northeastern Washington, U.S.A.

A recently discovered ore-grade accumulation of U in organic-rich sediments of late Quaternary age provides an opportunity for studying the early association of U, U-daughters, and organic matter in a natural setting. The U occurs in valley-fill sediments of peat, peaty clay, silt, and sand along the north fork of Flodelle Creek, Stevens County, Washington. Radiometric techniques (delayed neutron, high-resolution gamma-ray spectrometry, thin-source alpha spectrometry) were employed to determine the abundance and distribution of U-series nuclides, the extent of secular equilibrium within the U decay series, and the apparent U-series ages of U incorporation. Sixteen lithologically distinct intervals were sampled from a 292 cm core. Uranium contents range from 140 to 2790 ppm and are positively correlated with organic contents. Measured alpha activity ratios of 234 U/ 238 U (1.31–1.38) are very similar to those reported in coexisting waters, suggesting a rather constant isotopic composition of introduced U. Much lower Th contents of <10–40 ppm are controlled by the type and abundance of silicate detritus. The youth of the host sediments (<15 000 a) and the paucity of associated radioactivity suggested large excesses of U relative to radioactive daughters and such excesses were observed, particularly in the shallowest intervals. Apparent ages of U emplacement determined by the (alpha) activity ratio of 230 Th daughter to 234 U parent show a general increase with depth and fair agreement with estimated depositional ages. This observation suggests dominantly syndepositional or early post depositional emplacement of U followed by decay-generated buildup of 230 Th daughter with time. However, interval by interval comparisons of the relative abundances of other daughters, particularly 226 Ra and 210 Pb, indicate variability caused by processes other than closed-system growth and decay, probably because chemically diverse daughters that are decay-generated in situ have differing mobilities and because upwelling ground water continuously adds more U and minor amounts of daughters. If 230 Th is considered the least susceptible to these modifications, the data suggest some addition of 234 U in the deepest intervals and some loss of 226 Ra and/or gain of 222 Rn throughout the studied core.

Washington↗
USGS1984

Radioactive disequilibria in mineralised fracture samples from two uranium occurrences in northern Sweden

Mineralised fractures from two uranium occurrences in northern Sweden were examined mineralogically and isotopically to establish the presence or absence of radioactive equilibrium that may indicate recent rock-water interaction processes based on the natural mobility of uranium (i.e.; during the last 0.5 Ma). The results show evidence of radioactive disequilibrium in six of the nine samples investigated. Disequilibria are attributable to solution to solid 234U recoil gain (weakly mineralised zones adjacent to the main mineralisation) and solid to solution 234U recoil loss (moderate to highly mineralised zones). The absence of significant 238U loss in the samples emphasises the reducing conditions at the sampled depths. ?? 1984.

LITHOS↗
USGS1984

Radioisotope dilution analyses of geological samples using 236U and 229Th

The use of 236U and 229Th in alpha spectrometric measurements has some advantages over the use of other tracers and measurement techniques in isotope dilution analyses of most geological samples. The advantages are: (1) these isotopes do not occur in terrestrial rocks, (2) they have negligible decay losses because of their long half lives, (3) they cause minimal recoil contamination to surface-barrier detectors, (4) they allow for simultaneous determination of the concentration and isotopic composition of uranium and thorium in a variety of sample types, and (5) they allow for simple and constant corrections for spectral inferences, 0.5% of the 238U activity is subtracted for the contribution of 235U in the 236U peak and 1% of the 229Th activity is subtracted from the 230Th activity. Disadvantages in using 236U and 229Th are: (1) individual separates of uranium and thorium must be prepared as very thin sources for alpha spectrometry, (2) good resolution in the spectrometer system is required for thorium isotopic measurements where measurement times may extend to 300 h, and (3) separate calibrations of the 236U and 229Th spike solution with both uranium and thorium standards are required. The use of these tracers in applications of uranium-series disequilibrium studies has simplified the measurements required for the determination of the isotopic composition of uranium and thorium because of the minimal corrections needed for alpha spectral interferences. ?? 1984.

Nuclear Instruments and Methods In Physics Researc↗
USGS1982

The chemical and isotopic record of rock-water interaction in the Sherman Granite, Wyoming and Colorado

Chemical, isotopic, radiographic, and rock-leaching data are combined to describe the effects of rock-water interactions in core samples of petrographically fresh, 1.43 b.y.-old Sherman Granite. The data serve to identify sensitive indicators of incipient alteration and to estimate the degree, pathways, and timing of element mobilization. Unfractured core samples of Sherman Granite are remarkably fresh by most chemical or isotopic criteria, but incipient alteration is indicated by the abundance and distribution of uranium and the degree of radioactive equilibration of uranium with its decay products. Uranium abundances which are out of equilibrium with lead decay products indicate remobilization of a portion (3 to 60 percent) of original uranium in late Phanerozoic time. Association of uranium with minor but pervasive secondary alteration products also indicates some remobilization. The amount of apparent uranium mobility in unfractured Sherman Granite (3 to 60 percent) is small compared to the results of similar studies of Archean granites from nearby localities. Chemical and isotopic data evaluated as a function of core-sample depth suggest a uranium migrational pathway involving near-surface leaching and reconcentration at depth. Movement of solutions through the upper 200 ft (60 m) of Sherman Granite is fracture controlled, and brecciated granite shows more obvious petrographic, chemical, and isotopic evidence of alteration and multi-element redistribution. Laboratory experiments using freshly crushed Sherman Granite confirm that uranium is leached in preference to elements such as Si, Mg, Ca, and K, and that leachable uranium is situated close to the solid-liquid interface; perhaps as uranium along grain boundaries, in crystal defects, or on cleavage traces of minerals that exclude uranium from their structure. ?? 1981 Springer-Verlag.

Contributions to Mineralogy and Petrology↗
USGS1982

Accumulation rates of Th-230, Pa-231, and some transition metals on the Bermuda Rise

Measurements of 238 U, 234 U, 230 Th, 232 Th, 231 Pa, Mn, Fe, Co, Ni, Cu, and Zn were made on 23 samples from core GPC-5, a 29-m giant piston core from a water depth of 4583 m on the northeastern Bermuda Rise (33°41.2′N, 57°36.9′W). This area is characterized by rapid deposition of sediment transported by abyssal currents. Unsupported 230 Th and 231 Pa are present throughout the core but, because of large variations in the sedimentation rate, show marked departures from exponential decay with depth. The trend with depth of the 231 Pa ex 230 Th ex "> 231 Pa ex 230 Th ex ratio is consistent with the average accumulation rate of 36 cm/1000 y reported earlier on the basis of radiocarbon dating and CaCO 3 stratigraphy. When expressed on a carbonate-free basis, concentrations of Mn, Co, Ni, Cu, Zn, 230 Th ex , and 231 Pa ex all show cyclic variations positively correlated with those of CaCO 3 . The correlations can be explained by a model in which all of these constituents, including CaCO 3 , are supplied to the sediments from the water column at a constant rate. Concentration variations are controlled mainly by varying inputs of terrigenous detritus, with low inputs occurring during interglacials and high inputs during glacials. Relationships between the metal and 230 Th ex concentrations permit estimates of the rates at which the metals are removed to the sediment by scavenging from the water column. The results, in μg/cm 2 -1000 y, are: 4300 ± 1100 for Mn, 46 ± 16 for Ni and 76 ± 26 for Cu. These rates are somewhat larger than ocean-wide averages estimated by other methods, and the absolute rate of 230 Th accumulation in GPC-5 averages about nine times higher than production in the overlying water column. This part of the Bermuda Rise and similar bottom-current deposits may act as important accumulators of elements scavenged from seawater.

Geochimica et Cosmochimica Acta↗
USGS1980

The distribution and mobility of uranium in glassy and zeolitized tuff, Keg Mountain area, Utah, U.S.A.

The distribution and mobility of uranium in a diagenetically altered, 8 Ma old tuff in the Keg Mountain area, Utah, are modelled in this study. The modelling represents an improvement over similar earlier studies in that it: (1) considers a large number of samples (76) collected with good geologic control and exhibiting a wide range of alteration; (2) includes radiometric data for Th, K and RaeU (radium equivalent uranium) as well as U; (3) considers mineralogic and trace-element data for the same samples; and (4) analyzes the mineral and chemical covariation by multivariate statistical methods. The variation of U in the tuff is controlled mainly by its primary abundance in glass and by the relative abundance of non-uraniferous detritus and uraniferous accessory minerals. Alteration of glass to zeolite, even though extensive, caused no large or systematic change in the bulk concentration of U in the tuff. Some redistribution of U during diagenesis is indicated by association of U with minor alteration products such as opal and hydrous Fe-Mn oxide minerals. Isotopic studies indicate that the zeolitized tuff has been open to migration of U decay products during the last 0.8 Ma. The tuff of Keg Mountain has not lost a statistically detectable fraction of its original U, even though it has a high (??? 9 ppm) trace U content and has been extensively altered to zeolite. Similar studies in a variety of geological environments are required in order to identify the particular combination of conditions most favorable for liberation and migration of U from tuffs. ?? 1980.

Chemical Geology↗
USGS1970

Age of the moon: An isotopic study of uranium-thorium-lead systematics of lunar samples

Concentrations of U, Th, and Pb in Apollo 11 samples studied are low (U. 0.16 to 0.87; Th, 0.53 to 3.4; Pb, 0.29 to 1.7, in ppm) but the extremely radiogenic lead in samples allows radiometric dating. The fine dust and the breccia have a concordant age of 4.66 billion years on the basis of 207 Pb/ 206 Pb, 206 Pb/ 238 U, 207 Pb/ 235 U, and 208 Pb/ 232 Th ratios. This age is comparable with the age of meteorites and with the age generally accepted for the earth. Six crystalline and vesicular samples are distinctly younger than the dust and breccia. The 238 U/ 235 U ratio is the same as that in earth rocks, and 234 U is in radioactive equilibrium with parent 238 U.

Science↗
USGS1969

Uranium, thorium, and lead systematics in Granite Mountains, Wyoming

Uranium, thorium and lead concentrations and isotopic compositions were determined on total rocks and a feldspar sample from widely separated parts of the Granite Mountains in central Wyoming. Linear relations defined by 206 Pb/ 204 Pb − 207 Pb/ 204 Pb and 208 Pb/ 204 Pb − 232 Th/ 204 Pb for the total rock samples define 2.8 billion-year isochrons. In contrast, 238 U/ 206 Pb ages are anomalously old by a factor of at least four. The low 238 U/ 204 Pb values, coupled with the radiogenic 206 Pb/ 204 Pb and radiogenic 207 Pb/ 204 Pb ratios, indicate that contents of uranium in near-surface rocks would have had to have been considerably greater than those presently observed to have generated the radiogenic lead. It is possible that more than 10 11 kg of uranium has been removed from the Granite Mountains, and the most feasible interpretation is that most of this uranium was leached from near-surface rocks at some time during the Cenozoic, thus providing a major source for the uranium deposits in the central Wyoming basins.

Wyoming↗
USGS1969

Loss of uranium from crystallized silicic volcanic rocks

Dense primarily crystallized silicic groundmass material from two welded ash-flow units and one lava flow of Tertiary age from the Western United States contain only 20 to 60 percent of the uranium present in nonhydrated glass from the rock units. These differences reflect loss of uranium from the crystallized specimens, probably as a result of groundwater leaching. It appears likely that most crystallized silicic volcanic rocks have lost comparable amounts of uranium.

Earth and Planetary Science Letters↗
USGS1966

Disequilibrium of the 238U series in basalt

Radioisotope analyses of basalt samples from Hawaii, Japan, and Iwo Jima show that: (1) 234 U and 238 U are virtually in radioactive equilibrium, (2) 230 Th exceeds equilibrium values in all these samples, (3) 210 Pb concentrations range from 10–200% of the equilibrium values and average 30% deficient, and (4) 226 Ra is probably not in equilibrium with 234 U. The source regions of the basalts or magma forming processes are open systems, chemically. The enrichment of some of the uranium-daughter nuclides is insufficient to account for the excess 206 Pb in volcanic rocks. The isotopic composition of lead and specific activity of 210 Pb in sublimates from Showa-shinzan, Japan are also reported.

Hawaii↗