Geology ReportsSearch

Geology topics

J.L. Stoddard

Publications and source records attributed to J.L. Stoddard.

4 recordsLinked to original sources

Empirical critical loads of atmospheric nitrogen deposition for nutrient enrichment and acidification of sensitive US lakes

The ecological effects of elevated atmospheric nitrogen (N) deposition on high-elevation lakes of the western and northeastern United States include nutrient enrichment and acidification. The nutrient enrichment critical load for western lakes ranged from 1.0 to 3.0 kilograms (kg) of N per hectare (ha) per year, reflecting the nearly nonexistent watershed vegetation in complex, snowmelt-dominated terrain. The nutrient enrichment critical load for northeastern lakes ranged from 3.5 to 6.0 kg N per ha per year. The N acidification critical loads associated with episodic N pulses in waters with low values of acid neutralizing capacity were 4.0 kg N per ha per year (western) and 8.0 kg N per ha per year (northeastern). The empirical critical loads for N-caused acidification were difficult to determine because of a lack of observations in the West, and high sulfur deposition in the East. For both nutrient enrichment and acidification, the N critical load was a function of how atmospheric N deposition was determined.

BioScience

Effects of nitrogen deposition and empirical nitrogen critical loads for ecoregions of the United States

Human activity in the last century has led to a significant increase in nitrogen (N) emissions and atmospheric deposition. This N deposition has reached a level that has caused or is likely to cause alterations to the structure and function of many ecosystems across the United States. One approach for quantifying the deposition of pollution that would be harmful to ecosystems is the determination of critical loads. A critical load is defined as the input of a pollutant below which no detrimental ecological effects occur over the long-term according to present knowledge. The objectives of this project were to synthesize current research relating atmospheric N deposition to effects on terrestrial and freshwater ecosystems in the United States, and to estimate associated empirical N critical loads. The receptors considered included freshwater diatoms, mycorrhizal fungi, lichens, bryophytes, herbaceous plants, shrubs, and trees. Ecosystem impacts included: (1) biogeochemical responses and (2) individual species, population, and community responses. Biogeochemical responses included increased N mineralization and nitrification (and N availability for plant and microbial uptake), increased gaseous N losses (ammonia volatilization, nitric and nitrous oxide from nitrification and denitrification), and increased N leaching. Individual species, population, and community responses included increased tissue N, physiological and nutrient imbalances, increased growth, altered root : shoot ratios, increased susceptibility to secondary stresses, altered fire regime, shifts in competitive interactions and community composition, changes in species richness and other measures of biodiversity, and increases in invasive species. The range of critical loads for nutrient N reported for U.S. ecoregions, inland surface waters, and freshwater wetlands is 1-39 kg N.ha -1.yr -1, spanning the range of N deposition observed over most of the country. The empirical critical loads for N tend to increase in the following sequence for different life forms: diatoms, lichens and bryophytes, mycorrhizal fungi, herbaceous plants and shrubs, and trees. The critical load approach is an ecosystem assessment tool with great potential to simplify complex scientific information and communicate effectively with the policy community and the public. This synthesis represents the first comprehensive assessment of empirical critical loads of N for major ecoregions across the United States. ?? 2011 by the Ecological Society of America.

Ecological Applications

Regional trends in aquatic recovery from acidification in North America and Europe

Rates of acidic deposition from the atmosphere ('acid rain') have decreased throughout the 1980s and 1990s across large portions of North America and Europe. Many recent studies have attributed observed reversals in surface-water acidification at national and regional scales to the declining deposition. To test whether emissions regulations have led to widespread recovery in surface-water chemistry, we analysed regional trends between 1980 and 1995 in indicators of acidification (sulphate, nitrate and base-cation concentrations, and measured (Gran) alkalinity) for 205 lakes and streams in eight regions of North America and Europe. Dramatic differences in trend direction and strength for the two decades are apparent. In concordance with general temporal trends in acidic deposition, lake and stream sulphate concentrations decreased in all regions with the exception of Great Britain all but one of these regions exhibited stronger downward trends in the 1990s than in the 1980s. In contrast, regional declines in lake and stream nitrate concentrations were rare and, when detected, were very small. Recovery in alkalinity, expected wherever strong regional declines in sulphate concentrations have occurred, was observed in all regions of Europe, especially in the 1990s, but in only one region (of five) in North America. We attribute the lack of recovery in three regions (south/central Ontario, the Adirondack/Catskill mountains and midwestern North America) to strong regional declines in base-cation concentrations that exceed the decreases in sulphate concentrations.

Nature

Chemical characteristics and temporal trends in eight streams of the Catskill Mountains, New York

Discharge to concentration relationships for eight streams studied by the U.S. Geological Survey (USGS) as part of the U.S. Environmental Protection Agency's (U.S. EPA) Long-Term Monitoring Project (1983-89) indicate acidification of some streams by H2SO4 and HNO3 in atmospheric deposition and by organic acids in soils. Concentrations of major ions in precipitation were similar to those reported at other sites in the northeastern United States. Average concentrations of SO42- and NO3- were similar among streams, but base cation concentrations differed widely, and these differences paralleled the differences in acid neutralizing capacity (ANC). Baseflow ANC is not a reliable predictor of stream acidity at high flow; some streams with high baseflow ANC (> 150 ??eq L-1) declined to near zero ANC at high flow, and one stream with low baseflow ANC (< 50 ??eq L-1) did not approach zero ANC as flow increased. Episodic decreases in ANC and pH during peak flows were associated with increased concentrations of NO3- and dissolved organic carbon (DOC). Aluminum concentrations exceeding 300 ??g L-1 were observed during peak flows in headwater streams of the Neversink River and Rondout Creek. Seasonal Kendall Tau tests for temporal trends indicate that SO42- concentrations in streamwater generally decreased and NO3- concentrations increased during the period 1983-1989. Combined acid anion concentrations (SO42- + NO3-) were generally unchanged throughout the period of record, indicating both that the status of these streams with respect to acidic deposition is unchanged, and that NO3- is gradually replacing SO42- as the dominant acid anion in the Catskill streams.Discharge to concentration relationships for eight streams studied by the US Geological Survey (USGS) as part of the Environmental Protection Agency's (US EPA) Long-term monitoring project (19831-89) indicate acidification of some streams by H2SO4 and HNO3 in atmospheric deposition and by organic acids in soils. Concentrations of major ions in precipitations were similar to those reported at other sites in the northeastern United States. Average concentrations of SO42- and No3- were similar among streams, but base cation concentrations differed widely, and these differences parallelel the differences in acid neutralizing capacity (ANC).

Water, Air, & Soil Pollution