Geology topics
Publications and source records attributed to J.D. Knight.
At the fossil-pollen-defined Cretaceous-Tertiary boundary in the Raton Basin of New Mexico and Colorado, an iridium abundance anomaly and excess scandium, titanium, and chromium are associated with a thin ash or dust fallout bed (now kaolinitic clay) that was preserved in freshwater coal swamps. ?? 1984 Nature Publishing Group.
Indium concentrations are anomalously high at the palynological Cretaceous-Tertiary boundary in fluvial sedimentary rocks of the lower part of the Raton Formation at several localities in the Raton Basin of New Mexico and Colorado. The iridium anomaly is associated with a thin bed of kaolinitic claystone in a discontinuous carbonaceous shale and coal sequence.
The palynologically defined Cretaceous-Tertiary boundary in the western interior of North America occurs at the top of an iridium-rich clay layer. The boundary is characterized by the abrupt disappearance of certain pollen species, immediately followed by a pronounced, geologically brief change in the ratio of fern spores to angiosperm pollen. The occurrence of these changes at two widely separated sites implies continentwide disruption of the terrestrial ecosystem, probably caused by a major catastrophic event at the end of the period.
During the past year we have been measuring trace element abundances and searching for anomalously high iridium (Ir) concentrations in continental sedimentary rocks that span the Cretaceous-Tertiary boundary in the Raton and San Juan Basins of northern New Mexico and southern Colorado. Using neutron activation and radiochemical separations, we have identified anomalous concentrations of Ir in samples from two sites in the Raton Basin: in a drill core at York Canyon, about 50 km west of Raton, New Mexico, and in a road cut near the city of Raton. In both cases the anomaly occurs essentially at the base of thin coal beds, across a thickness span of only a few cm and at the same level at which several species of Cretaceous pollen become extinct and the ratio of angiosperm pollen to fern spores drops sharply. The Ir surface density ranges from 8 to 40 × 10 −9 g cm −2 . In the York Canyon core the Ir concentration reaches a value of 5.6 × 10 −9 g/g of rock over a local background of about 10 −11 g/g; the Pt abundance distribution is similar to that for Ir, while Au reaches its maximum concentration about 10 cm below the Ir peak. Se, V, Cr, Mn, Co, and Zn are about two-fold more abundant at the anomaly zone than in adjacent zones, and mass spectrometric 244 Pu analysis showed the 244 Pu/Ir atom ratio ⩽ 1 × 10 7 . In the San Juan Basin we have located a small Ir spike (55 × 10 −12 g/g over a local background of 8 × 10 −12 g/g) that is accompanied by high concentrations of Co and Mn. It is thought to be due to geochemical enrichment processes.
An iridium abundance anomaly, with concentrations up to 5000 parts per trillion over a background level of 4 to 20 parts per trillion, has been located in sedimentary rocks laid down under freshwater swamp conditions in the Raton Basin of northeastern New Mexico. The anomaly occurs at the base of a coal bed, at the same stratigraphic position at which several well-known species of Cretaceous-age pollen became extinct.