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J.D. Gordon

Publications and source records attributed to J.D. Gordon.

At least 19 recordsLinked to original sources

Spatial and temporal variability of the overall error of National Atmospheric Deposition Program measurements determined by the USGS collocated-sampler program, water years 1989-2001

Data from the U.S. Geological Survey (USGS) collocated-sampler program for the National Atmospheric Deposition Program/National Trends Network (NADP/NTN) are used to estimate the overall error of NADP/NTN measurements. Absolute errors are estimated by comparison of paired measurements from collocated instruments. Spatial and temporal differences in absolute error were identified and are consistent with longitudinal distributions of NADP/NTN measurements and spatial differences in precipitation characteristics. The magnitude of error for calcium, magnesium, ammonium, nitrate, and sulfate concentrations, specific conductance, and sample volume is of minor environmental significance to data users. Data collected after a 1994 sample-handling protocol change are prone to less absolute error than data collected prior to 1994. Absolute errors are smaller during non-winter months than during winter months for selected constituents at sites where frozen precipitation is common. Minimum resolvable differences are estimated for different regions of the USA to aid spatial and temporal watershed analyses.

Conference Paper↗

Sediment laboratory quality-assurance project: studies of methods and materials

In August 1996 the U.S. Geological Survey initiated the Sediment Laboratory Quality-Assurance project. The Sediment Laboratory Quality Assurance project is part of the National Sediment Laboratory Quality-Assurance program. This paper addresses the fmdings of the sand/fme separation analysis completed for the single-blind reference sediment-sample project and differences in reported results between two different analytical procedures. From the results it is evident that an incomplete separation of fme- and sand-size material commonly occurs resulting in the classification of some of the fme-size material as sand-size material. Electron microscopy analysis supported the hypothesis that the negative bias for fme-size material and the positive bias for sand-size material is largely due to aggregation of some of the fine-size material into sand-size particles and adherence of fine-size material to the sand-size grains. Electron microscopy analysis showed that preserved river water, which was low in dissolved solids, specific conductance, and neutral pH, showed less aggregation and adhesion than preserved river water that was higher in dissolved solids and specific conductance with a basic pH. Bacteria were also found growing in the matrix, which may enhance fme-size material aggregation through their adhesive properties. Differences between sediment-analysis methods were also investigated as pan of this study. Suspended-sediment concentration results obtained from one participating laboratory that used a total-suspended solids (TSS) method had greater variability and larger negative biases than results obtained when this laboratory used a suspended-sediment concentration method. When TSS methods were used to analyze the reference samples, the median suspended sediment concentration percent difference was -18.04 percent. When the laboratory used a suspended-sediment concentration method, the median suspended-sediment concentration percent difference was -2.74 percent. The percent difference was calculated as follows: Percent difference = (( reported mass - known mass)/known mass ) X 100.

Conference Paper↗

The stability of hydrogen ion and specific conductance in filtered wet-deposition samples stored at ambient temperatures

Separate experiments by the U.S. Geological Survey (USGS) and the Illinois State Water Survey Central Analytical Laboratory (CAL) independently assessed the stability of hydrogen ion and specific conductance in filtered wet-deposition samples stored at ambient temperatures. The USGS experiment represented a test of sample stability under a diverse range of conditions, whereas the CAL experiment was a controlled test of sample stability. In the experiment by the USGS, a statistically significant (?? = 0.05) relation between [H+] and time was found for the composited filtered, natural, wet-deposition solution when all reported values are included in the analysis. However, if two outlying pH values most likely representing measurement error are excluded from the analysis, the change in [H+] over time was not statistically significant. In the experiment by the CAL, randomly selected samples were reanalyzed between July 1984 and February 1991. The original analysis and reanalysis pairs revealed that [H+] differences, although very small, were statistically different from zero, whereas specific-conductance differences were not. Nevertheless, the results of the CAL reanalysis project indicate there appears to be no consistent, chemically significant degradation in sample integrity with regard to [H+] and specific conductance while samples are stored at room temperature at the CAL. Based on the results of the CAL and USGS studies, short-term (45-60 day) stability of [H+] and specific conductance in natural filtered wet-deposition samples that are shipped and stored unchilled at ambient temperatures was satisfactory.

Water, Air, & Soil Pollution↗

External quality-assurance results for the National Atmospheric Deposition Program/National Trends Network during 1991

The U.S. Geological Survey used four programs in 1991 to provide external quality assurance for the National Atmospheric Deposition Program/National Trends Network (NADP/NTN). An intersite-comparison program was used to evaluate onsite pH and specific-conductance determinations. The effects of routine sample handling, processing, and shipping of wet-deposition samples on analyte determinations and an estimated precision of analyte values and concentrations were evaluated in the blind-audit program. Differences between analytical results and an estimate of the analytical precision of four laboratories routinely measuring wet deposition were determined by an interlaboratory-comparison program. Overall precision estimates for the precipitation-monitoring system were determined for selected sites by a collocated-sampler program. Results of the intersite-comparison program indicated that 93 and 86 percent of the site operators met the NADP/NTN accuracy goal for pH determinations during the two intersite-comparison studies completed during 1991. The results also indicated that 96 and 97 percent of the site operators met the NADP/NTN accuracy goal for specific-conductance determinations during the two 1991 studies. The effects of routine sample handling, processing, and shipping, determined in the blind-audit program indicated significant positive bias (a=.O 1) for calcium, magnesium, sodium, potassium, chloride, nitrate, and sulfate. Significant negative bias (or=.01) was determined for hydrogen ion and specific conductance. Only ammonium determinations were not biased. A Kruskal-Wallis test indicated that there were no significant (*3t=.01) differences in analytical results from the four laboratories participating in the interlaboratory-comparison program. Results from the collocated-sampler program indicated the median relative error for cation concentration and deposition exceeded eight percent at most sites, whereas the median relative error for sample volume, sulfate, and nitrate concentration at all sites was less than four percent. The median relative error for hydrogen ion concentration and deposition ranged from 4.6 to 18.3 percent at the four sites and as indicated in previous years of the study, was inversely proportional to the acidity of the precipitation at a given site. Overall, collocated-sampling error typically was five times that of laboratory error estimates for most analytes.

Water-Resources Investigations Report↗

The precision of wet atmospheric deposition data from national atmospheric deposition program/national trends network sites determined with collocated samplers

A collocated, wet-deposition sampler program has been operated since October 1988 by the U.S. Geological Survey to estimate the overall sampling precision of wet atmospheric deposition data collected at selected sites in the National Atmospheric Deposition Program and National Trends Network (NADP/NTN). A duplicate set of wet-deposition sampling instruments was installed adjacent to existing sampling instruments at four different NADP/NTN sites for each year of the study. Wet-deposition samples from collocated sites were collected and analysed using standard NADP/NTN procedures. Laboratory analyses included determinations of pH, specific conductance, and concentrations of major cations and anions. The estimates of precision included all variability in the data-collection system, from the point of sample collection through storage in the NADP/NTN database. Sampling precision was determined from the absolute value of differences in the analytical results for the paired samples in terms of median relative and absolute difference. The median relative difference for Mg2+, Na+, K+ and NH4+ concentration and deposition was quite variable between sites and exceeded 10% at most sites. Relative error for analytes whose concentrations typically approached laboratory method detection limits were greater than for analytes that did not typically approach detection limits. The median relative difference for SO42- and NO3- concentration, specific conductance, and sample volume at all sites was less than 7%. Precision for H+ concentration and deposition ranged from less than 10% at sites with typically high levels of H+ concentration to greater than 30% at sites with low H+ concentration. Median difference for analyte concentration and deposition was typically 1.5-2-times greater for samples collected during the winter than during other seasons at two northern sites. Likewise, the median relative difference in sample volume for winter samples was more than double the annual median relative difference at the two northern sites. Bias accounted for less than 25% of the collocated variability in analyte concentration and deposition from weekly collocated precipitation samples at most sites.A collocated, wet-deposition sampler program has been operated since OCtober 1988 by the U.S Geological Survey to estimate the overall sampling precision of wet atmospheric deposition data collected at selected sites in the National Atmospheric Deposition Program and National Trends Network (NADP/NTN). A duplicate set of wet-deposition sampling instruments was installed adjacent to existing sampling instruments four different NADP/NTN sites for each year of the study. Wet-deposition samples from collocated sites were collected and analysed using standard NADP/NTN procedures. Laboratory analyses included determinations of pH, specific conductance, and concentrations of major cations and anions. The estimates of precision included all variability in the data-collection system, from the point of sample collection through storage in the NADP/NTN database.

Atmospheric Environment↗

Hydrologic data for urban studies in the Austin metropolitan area, Texas, 1986

The Geological Survey, in cooperation with the Texas Department of Water resources, began hydrologic studies in the Austin urban area in 1954. In cooperation with the city of Austin, the program was expanded in 1975 to include additional streamflow and rainfall-gaging stations, and the collection of surface water-quality data. In 1978, the program was expanded to include a ground-water resources study of the South Austin metropolitan area in the Balcones fault zone. The objectives of the Austin urban hydrology study are as follows: To determine, on the basis of historical data and hydrologic analyses, the magnitude and frequency of flood peaks and flood volume. To determine the effect of urban development on flood peaks and volume. To determine the variations in water quality during different seasons and flow conditions in representative watersheds with various types of urban development. To quantitatively appraise the ground-water resources of the Edwards aquifer in hydraulic circulation with Barton Springs, the effect of urbanization on the quality and quantity of recharge and discharge, and the extent of contamination in the aquifer. This report presents the basic hydrologic data collected in the Austin urban area for the 1986 water year (Oct. 1, 1985 to Sept. 30, 1986). Additional explanations of terms related to streamflow, water quality, and other hydrologic data used in this report are defined in the U.S. Geological Survey annual report Water Resources Data for Texas, TX-85-3, 1986. Analyses of "Hydrologic data for urban studies in the Austin, Texas, metropolitan area" from 1975 to 1982 are presented in a report by Veenhuis and Gannett (1986). Two analyses were made to determine the effects of urbanization on flood peaks in streams in the Austin metropolitan area. The first analysis compares flood recurrence intervals of urban drainage basins to rural drainage basins. In the second analysis, data from one drainage basin in which considerable urban development occurred during the study period, were used. The data were analyzed for changes in rainfall-runoff and flood frequency relations due to urbanization.

Open-File Report↗

Hydrologic data for urban studies in the Austin metropolitan area, Texas, 1985

Hydrologic investigations of urban watersheds in Texas were begun by the U.S. Geological Survey in 1954. Studies are now in progress in Austin, and Houston. Studies have been completed in the Dallas, Fort Worth, and San Antonio areas. The Geological Survey, in cooperation with the Texas Department of Water Reources, began hydrologic studies in the Austin urban area in 1954. In cooperation with the city of Austin, the program was expanded in 1975 to include additional streamflow and rainfall gaging stations, and the collection of surface water-quality data. In 1978, the program was expanded to include a ground-water resources study of the South Austin metropolitan area in the Balcones Fault Zone. The objectives of the Austin urban hydrology study are as follows: To determine, on the basis of historical data and hydrologic analyses, the magnitude and frequency of flood peaks and flood volume. To determine the effect of urban development on flood peaks and volume. To determine the variations in water quality during different seasons and flow conditions in representative watersheds with various types of urban development. To quantitatively appraise the ground-water resources of the Edwards aquifer in hydraulic circulation with Barton Springs, the effect of urbanization on the quality and quantity of recharge and discharge, and the extent of contamination in the aquifer. This report presents the basic hydrologic data collected in the Austin urban area for the 1985 water year (Oct. 1, 1984 to Sept. 30, 1985). Additional explanations of terms related to streamflow, water quality, and other hydrologic data used in this report are defined in the U.S. Geological Survey annual report Water Resources Data for Texas, TX-85-3, 1985.

Texas↗

Hydrologic data for urban studies in the Austin metropolitan area, Texas, 1984

Hydrologic investigations of urban watersheds in Texas were begun by the U.S. Geological Survey in 1954. Studies are now in progress in Austin, and Houston. Studies have been completed in the Dallas, Fort Worth, and San Antonio areas. The Geological Survey, in cooperation with the Texas Department of Water Reources, began hydrologic studies in the Austin urban area in 1954. In cooperation with the city of Austin, the program was expanded in 1975 to include additional streamflow and rainfall gaging stations, and the collection of surface water-quality data. In 1978, the program was expanded to include a ground-water resources study of the South Austin metropolitan area in the Balcones Fault Zone. The objectives of the Austin urban hydrology study are as follows: To determine, on the basis of historical data and hydrologic analyses, the magnitude and frequency of flood peaks and flood volume. To determine the effect of urban development on flood peaks and volume. To determine the variations in water quality during different seasons and flow conditions in representative watersheds with various types of urban development. To quantitatively appraise the ground-water resources of the Edwards aquifer in hydraulic circulation with Barton Springs, the effect of urbanization on the quality and quantity of recharge and discharge, and the extent of contamination in the aquifer. This report presents the basic hydrologic data collected in the Austin urban area for the 1984 water year (Oct. 1, 1983 to Sept. 30, 1984). Additional explanations of terms related to streamflow, water quality, and other hydrologic data used in this report are defined in the U.S. Geological Survey annual report Water Resources Data for Texas, TX-84-3, 1984.

Texas↗

Hydrologic data for urban studies in the Austin, Texas, metropolitan area, 1983

Hydrologic investigations of urban watersheds in Texas were begun by the U.S. Geological Survey in 1954. Studies are now in progress in Austin, and Houston. Studies have been completed in the Dallas, Fort Worth, and San Antonio areas. The Geological Survey, in cooperation with the Texas Department of Water Reources, began hydrologic studies in the Austin urban area in 1954. In cooperation with the city of Austin, the program was expanded in 1975 to include additional streamflow and rainfall gaging stations, and the collection of surface water-quality data. In 1978, the program was expanded to include a ground-water resources study of the South Austin metropolitan area in the Balcones Fault Zone. The objectives of the Austin urban hydrology study are as follows: To determine, on the basis of historical data and hydrologic analyses, the magnitude and frequency of flood peaks and flood volume. To determine the effect of urban development on flood peaks and volume. To determine the variations in water quality during different seasons and flow conditions in representative watersheds under various types of urban development. To quantitatively appraise the ground-water resources along the Balcones Fault Zone, the effect of urbanization on the quality and quantity of recharge and discharge, and the extent of contamination in the Edwards aquifer that is in hydrologic circulation with Barton Springs. This report presents the basic hydrologic data collected in the Austin urban area for the 1983 water year (Oct. 1, 1982 to Sept. 30, 1983). Additional explanations of terms related to streamflow, water quality, and other hydrologic data used in this report are defined in the U.S. Geological Survey annual report Water Resources Data for Texas, TX-83-3, 1983.

Texas↗

Hydrologic data for urban studies in the Austin, Texas, metropolitan area, 1980

Hydrologic investigations of urban watersheds in Texas were begun by the U.S. Geological Survey in 1954. Studies are now in progress in Austin, Houston, and San Antonio. Studies have been completed in the Dallas and Fort Worth areas. The Geological Survey, in cooperation with the Texas Department of Water Resources, began hydrologic studies in the Austin urban area in 1954. In cooperation with the city of Austin, the program was expanded in 1975 to include additional streamflow and rainfall gaging stations, and the collection of surface water-quality data. In 1978, the program was expanded to include a ground-water resources study of the South Austin metropolitan area in the Balcones fault zone. The objectives of the Austin urban hydrology study are as follows: To determine, on the basis of historical data and hydrologic analyses, the magnitude and frequency of flood peaks and flood volume. To determine the effect of urban development on flood peaks and volume. To determine the variations in water quality during different seasons and flow conditions in representatives watersheds under various types of urban development. To quantitatively appraise the ground-water resources along the Balcones fault zone, the effect of urbanization on the quality and quantity of recharge and discharge, and the extent of contamination in the Edwards aquifer that is is hydrologic circulation with Barton Springs. This report presents the basic hydrologic data collected in the Austin urban area for the 1980 water year (Oct. 1, 1979 to Sept. 30, 1980). Additional explanations of terms related to streamflow, water quality, and other hydrologic data used in this report are defined in the U.S. Geological Survey annual report Water Resources Data for Texas, TX-80-3, 1980.

Texas↗