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J.A. Commeau

Publications and source records attributed to J.A. Commeau.

16 recordsLinked to original sources
USGS2024

Effect of chlorine in clay-mineral specimens prepared on silver metal-membrane mounts for X-ray powder diffraction analysis

Silver metal-membrane filters are commonly used as substrates in the preparation of oriented clay-mineral specimens for X-ray powder diffraction (XRD). They are relatively unaffected by organic solvent treatments and specimens can be prepared rapidly. The filter mounts are adaptable to automatic sample changers, have few discrete reflections at higher 20 angles, and, because of the high atomic number of silver, produce a relatively low overall background compared with other membrane filters, such as cellulose (Poppe and Hathaway, 1979). The silver metal-membrane filters, however, present some problems after heat treatment if either the filters or the samples contain significant amounts of chlorine. At elevated temperature, the chloride ions react with the silver substrate to form crystalline compounds. These compounds change the mass-absorption coefficient of the sample, reducing peak intensities and areas and, therefore, complicating the semiquantitative estimation of clay minerals. A simple procedure that eliminates most of the chloride from a sample and the silver metal-membrane substrate is presented here.

Clays and Clay Minerals↗
USGS1996

Silt heavy-mineral distributions off the Southeastern United States

Until recently heavy-mineral studies of marine sediments were largely restricted to sand fractions. New techniques permitting analysis of decalcified silt fractions have been applied to sediments off the southeastern United States. Our data, which confirm predictions from the basic relationship among grain size, specific gravity, and equivalent hydraulic transport behavior, show that concentrations and average diameters of the silt heavy minerals progressively decrease seaward. Heavy minerals always constitute a substantially greater weight percent of the silt than of the sand fraction. Despite corroded surface textures suggestive of extensive weathering and dissolution, spatial trends in the detrital heavy-mineral populations are predominantly controlled by source and hydraulic factors.

Geo-Marine Letters↗
USGS1995

Silt fraction heavy-mineral distributions in a lateritic environment: The rivers and insular shelf of north-central Puerto Rico

This fraction, which is enriched in heavy minerals relative to the sand fraction, is mainly detrital but contains a strong authigenic component. The authigenic silt heavy-mineral fraction is largely a product of the lateritic weathering and dominated by iron oxides and alterites. Grains of bladed rutile and leached ilmenite are common. Spatial variability in silt-fraction mineralogy is considerable. Within the Rio Cibuco system variability is related to compositional differences in rapidly eroding source rocks. On the shelf, silt heavy-mineral abundances are greatest at the river mouths and decrease seaward. Variability in the shelf samples is controlled primarily by source rivers and shelf sorting processes.

Puerto Rico↗
USGS1995

Paleocene to Middle Miocene planktic foraminifera of the southwestern Salisbury Embayment, Virginia and Maryland: biostratigraphy, allostratigraphy, and sequence stratigraphy

The Paleocene to Middle Miocene sedimentary fill of the southwestern Salisbury Embayment contains a fragmental depositional record, interrupted by numerous local diastems and regional unconformities. Using planktic foraminiferal biostratigraphy, 15 unconformity-bounded depositional units have been identified, assigned to six formations and seven alloformations previously recognized in the embayment. The units correlate with second- and third-order sequences of the Exxon sequence stratigraphy model, and include transgressive and highstand systems tracts. Alloformation, formation, and sequence boundaries are marked by abrupt, scoured, burrowed, erosional surfaces, which display lag deposits, biostratigraphic gaps, and intense reworking of microfossils above and below the boundaries. Paleocene deposits represent the upper parts of upper Pleocene Biochronozones P4 and P5, and rest uncomformably on Cretaceous sedimentary beds of various ages (Maastrichtian to Albian). Lower Eocene deposits represent parts of Biochronozones P6 and P9. Middle Eocene strata represent mainly parts of Biochronozones P11, P12, and P14. Upper Eocene sediments include parts of Biochronozones P15, P16, and P17. Oligocene deposits encompass parts of Biochronozones. N4b to N7 undifferentiated, P21a, and, perhaps, N4a. Lower Miocene deposits encompass parts of Biochronozones N4b to N7 undifferentiated. Middle Miocene strata represent mainly parts of Biochronorones N8, N9, and N10. Nine plates of scanning electron micrographs illustrate the principal planktic foraminifera used to establish the biostratigraphic framework. Two new informal formine of Praeterenuitella praegemma Li, 1987, are introduced.

Journal of Foraminiferal Research↗
USGS1992

Mineralogy of the silt fraction in surficial sediments from the United States mid-Atlantic shelf, slope and rise

An analysis of the abundances and distributions of silt-sized heavy minerals from the U.S. mid-Atlantic outer continental shelf, slope, and rise shows that heavy minerals constitute a substantially greater weight percent of the silt fraction than that of the sand fraction regardless of environment and sediment texture. Concentrations of silt-sized heavy minerals progressively decrease from the shelf where they average 6.94%, to the slope and rise where they average 4.45% and 3.45%, respectively. A mixed amphibole-garnet+staurolite-epidote-pyroxene association dominates the silt-sized heavy mineral assemblage on the slope and rise; an ilmenite-amphibole-epidote association predominates on the shelf. Downslope trends in detrital nonmicaceous silt-sized heavy mineral abundances are related to hydraulic sorting rather than to chemical weathering. Elevated concentrations of the authigenic pyrite, siderite, dolomite+ankerite, and, possibly, phosphorite in the surficial slope sediment suggests that formation of silt-sized heavy minerals by diagenetic processes is relatively more important there than on the continental shelf or rise.

Marine Geology↗
USGS1991

Mineralogy of the silt fraction in surficial sediments from the outer continental shelf off southeastern New England

The silt-sized heavy mineral assemblage, which is predominantly detrital, has been concentrated in this fraction by hydraulic factors and ranges between 11.8 wt. % of the silt fraction in the sandy sediments near Georges Bank to 3.4% in the clayey silt deposit south of Martha's Vineyard. By contrast, the sand fraction averages only 1.5% heavy minerals. Lateral variability within the silt-sized heavy mineral assemblage is considerable. Zircon and ilmenite abundances progressively decrease from east to west on the continental shelf off southeastern New England. Conversely, abundances within the amphibole and the epidote groups increase from east to west.

Journal of Sedimentary Petrology↗
USGS1990

Fine-grained rutile in the Gulf of Maine: Diagenetic origin, source rocks, and sedimentary environment of deposition

The Gulf of Maine, an embayment of the New England margin, is floored by shallow, glacially scoured basins that are partly filled with late Pleistocene and Holocene silt and clay containing 0.7 to 1.0 wt percent TiO 2 , chiefly in the form of silt-size rutile. Eleven basins in the gulf are estimated to contain 479 X 10 6 metric tons of TiO 2 (to a depth of 10 m) in the U.S. exclusive economic zone and 168 X 10 6 in Canada, based on analyses of surface sediment and of cores 10 to 20 m long. The U.S. annually consumes approximately 1 X 10 6 metric tons of TiO 2 , of which 73 percent is imported. The inferred amount of fine-grained TiO 2 in the basins is large, and we interpret it to be predominantly rutile; but no attempt has been made yet to mine and beneficiate the fine-grained ore.Sedimentary rocks of Nova Scotia, New Brunswick, and northern Maine contain fine-grained rutile crystals and have been the major source of the fine-grained sediment in the Gulf of Maine basins during and after the Wisconsinan glaciation. We conclude that much of the rutile in the Gulf of Maine mud formed diagenetically in poorly cemented Carboniferous and Triassic coarse-grained sedimentary rocks of Nova Scotia and New Brunswick after the dissolution of titanium-rich detrital minerals (ilmenite, ilmenomagnetite). Another major source of rutile is the generally finer grained Paleozoic sedimentary rocks of northern Maine (and possibly northwestern New Brunswick) which contain recycled diagenetic rutile that most likely originated in sandstones. Additional Wisconsinan sources of fine-grained, diagenetic TiO 2 probably include sedimentary rocks of inferred Triassic age that underlie the Gulf of Maine.The diagenesis of rutlie in coarse sedimentary rocks (especially arkose and graywacke) followed by erosion, segregation, and deposition (and including recycling of fine-grained rutile from shales) can serve as a model for predicting and prospecting for unconsolidated deposits of fine-grained TiO 2 .Gulf of Maine mud is comparable in TiO 2 content to typical shale. A determination of whether the fine-grained TiO 2 in shales primarily occurs as detrital titanium minerals from metamorphic and igneous sources or as recycled, diagenetic titanium oxides from sedimentary sources may assist in interpreting shale provenance and environment of deposition.

Economic Geology↗
USGS1987

Chemistry and mineralogy of pyrite-enriched sediments at a passive margin sulfide brine seep: Abyssal Gulf of Mexico

Pyrite is rapidly accumulating at the contact between the Cretaceous limestones of the Florida Platform and the hemipelagic sediments of the abyssal Gulf of Mexico. Sediments sampled with the submersible “Alvin” in 3266 m of water are associated with a dense community of organisms that depend on chemosynthetic primary production as a food source. Analysis of the chemistry, mineralogy, and textural composition of these sediments indicate that iron sulfide mineralization is occurring at the seafloor within an anoxic micro-habitat sustained by the advection of hydrogen sulfide-charged saline brines from the adjacent platform. The chemosynthetic bacteria that directly overlie the sediments oxidize hydrogen sulfide for energy and provide elemental sulfur that reacts with iron monosulfide to form some of the pyrite. The sediments are mixtures of pyrite (∼ 30 wt.%), Ba Sr sulfates (∼ 4 wt.%), clays, and locally derived biogenic carbonates and are progressively being cemented by iron sulfides. Oxidation of hydrogen sulfide produces locally acidic conditions that corrode the adjacent limestones. Potential sources of S, H 2 S, Fe, Ba, and Sr are discussed.

Earth and Planetary Science Letters↗
USGS1984

Ferromanganese micronodules from the surficial sediments of Georges Bank

Ferromanganese micronodules have been found on Georges Bank, off the U.S. northeast coast, distributed throughout the surficial sediments within an area about 125 km long and at least 12 km wide. These coarse, sand-sized concretions have precipitated from metal-rich interstitial waters and contain many of the textural and structural features common to other neritic nodules. Most of the nodules have accreted around detrital grains, and X-ray powder diffraction analyses indicate the presence of geothite and vernadite (  -MnO 2 ) in the ferromanganese layers. Chemical analyses of the micronodules, when compared with similar data on deep-sea manganese nodules, reveal lower Mn/Fe ratios, significantly higher concentrations of V and As, comparable values of Mo, and an order of magnitude less of Co, Ni, Ce and most other metals.

Georges Bank↗
USGS1984

Geologic reconnaissance and geochemical analysis of ferromanganese crusts of the Ratak Chain, Marshall Islands

The U.S. Geological Survey R/V S.P. LEE (cruise L9-84-CP) left Majuro, Ratak chain of the Marshall Islands, on July 28, 1984 and reached Hawaii on August 15, 1984. The main objective of this cruise was to study the distribution and composition of ferromanganese-oxide crusts in the Marshall Islands area (Fig. 1). A total of 5410 km of 12-kHz and 3.5-kHz seismic-reflection data, and 730 km of 80-in 3 to 148-in 3 airgun seismic-reflection data were collected. A description of these data and the ship-tracklines are presented in Schwab and Bailey (1984). This open-file report describes the types of samples collected and tabulates the results of our preliminary geochemical analyses of the ferromanganese-oxide crusts.

Open-File Report↗
USGS1977

Clay-mineral variability in the suspended sediments of the San Francisco Bay system, California

Semiquantitative determinations of the clay-mineral composition have been made on nearly synoptic samples of surface suspended sediments collected seasonally throughout the San Francisco Bay system. The relative amounts of chlorite + kaolinite are generally highest in the northern reach of the system, whereas illite is dominant in the southern reach. The proportion of montmorillonite is low throughout the bay. Time-series and replicate samples collected at individual stations show that the difference in clay-mineral content between reaches is real and reflects a change in the source of clay-mineral particles within the bay. The Sacramento-San Joaquin river system supplies the northern reach, whereas most clay-mineral particles come from resuspension by waves and tidal currents in the southern reach. Analyses of bottom sediments and the spatial variability in the northern reach suggest that the relationship between the abundance and sources of clay minerals may, in turn, be a function of particle size. This study demonstrates the utility of suspended clay minerals in the interpretation of sediment-dispersal patterns in estuaries.

California↗