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J. Southon

Publications and source records attributed to J. Southon.

4 recordsLinked to original sources

Elevated levels of radiocarbon in methane dissolved in seawater reveal likely local contamination from nuclear powered vessels

Measurements of the natural radiocarbon content of methane ( 14 C-CH 4 ) dissolved in seawater and freshwater have been used to investigate sources and dynamics of methane. However, during investigations along the Atlantic, Pacific, and Arctic Ocean Margins of the United States, as well as in the North American Great Lakes, some samples revealed highly elevated 14 C-CH 4 values, as much as 4–5 times above contemporary atmospheric 14 C-CH 4 levels. Natural production of the 14 CH 4 isotopologue is too low to cause these observations nor can it explain the variations in location and depth. Numerous lab and field validation tests and blanks, as well as the relatively small number of samples that display these elevated values, all suggest that these signals are not derived from an unknown procedural issue. Here we suggest that the byproducts of nuclear power generation include localized discharges of the 14 CH 4 isotopologue into marine and aquatic environments, severely altering the measured 14 C-CH 4 isotopic signals. Since several of our sample sites are distant from on-land nuclear powerplants, we conduct further calculations concluding that the most elevated anomalies in 14 C-CH 4 likely originate with discharge from nuclear-powered vessels.

Maryland, North Carolina, Oregon, Virginia, Washin

Dating North America's oldest petroglyphs, Winnemucca Lake subbasin, Nevada

On the west side of the Winnemucca Lake subbasin, Nevada, distinctive deeply carved meter-scale petroglyphs are closely spaced, forming panels on boulder-sized surfaces of a partially collapsed tufa mound. The large, complex motifs at this side are formed by deeply carved lines and cupules. A carbonate crust deposited between 10 200 and 9800 calibrated years B.P. (ka) coats petroglyphs at the base of the mound between elevations of 1202 and 1206 m. Petroglyphs above the carbonate crust are carved into a branching form of carbonate that dates to 14.8 ka. Radiocarbon dates on a multiple-layered algal tufa on the east side of the basin, which formed at an elevation of 1205 m, as well as a sediment-core-based total inorganic carbon record for the period 17.0–9.5 ka indicate that water level in the Winnemucca Lake subbasin was constrained by spill over the Emerson Pass Sill (1207 m) for most of the time between 12.9 ± 0.3 and ≥9.2 ka. These and other data indicate that the lake in the Winnemucca Lake subbasin fell beneath its spill point between 14.8 and 13.2 ka and also between 11.3 and 10.5 ka (or between 11.5 and 11.1 ka), exposing the base of the collapsed tufa mound to petroglyph carving. The tufa-based 14C record supports decreased lake levels between 14.8–13.2 ka and 11.3–10.5 ka. Native American artifacts found in the Lahontan Basin date to the latter time interval. This does not rule out the possibility that petroglyph carving occurred between 14.8 and 13.2 ka when Pyramid Lake was relatively shallow and Winnemucca Lake had desiccated.

Nevada

Ocean science: Radiocarbon variability in the western North Atlantic during the last deglaciation

We present a detailed history of glacial to Holocene radiocarbon in the deep western North Atlantic from deep-sea corals and paired benthic-planktonic foraminifera. The deglaciation is marked by switches between radiocarbon-enriched and -depleted waters, leading to large radiocarbon gradients in the water column. These changes played an important role in modulating atmospheric radiocarbon. The deep-ocean record supports the notion of a bipolar seesaw with increased Northern-source deep-water formation linked to Northern Hemisphere warming and the reverse. In contrast, the more frequent radiocarbon variations in the intermediate/deep ocean are associated with roughly synchronous changes at the poles.

Science

Weathering controls on mechanisms of carbon storage in grassland soils

On a sequence of soils developed under similar vegetation, temperature, and precipitation conditions, but with variations in mineralogical properties, we use organic carbon and 14C inventories to examine mineral protection of soil organic carbon. In these soils, 14C data indicate that the creation of slow-cycling carbon can be modeled as occurring through reaction of organic ligands with Al3+ and Fe3+ cations in the upper horizons, followed by sorption to amorphous inorganic Al compounds at depth. Only one of these processes, the chelation Al3+ and Fe3+ by organic ligands, is linked to large carbon stocks. Organic ligands stabilized by this process traverse the soil column as dissolved organic carbon (both from surface horizons and root exudates). At our moist grassland site, this chelation and transport process is very strongly correlated with the storage and long-term stabilization of soil organic carbon. Our 14C results show that the mechanisms of organic carbon transport and storage at this site follow a classic model previously believed to only be significant in a single soil order (Spodosols), and closely related to the presence of forests. The presence of this process in the grassland Alfisol, Inceptisol, and Mollisol soils of this chronosequence suggests that this process is a more significant control on organic carbon storage than previously thought. Copyright 2004 by the American Geophysical Union.

Global Biogeochemical Cycles