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J. R. Clark

Publications and source records attributed to J. R. Clark.

22 records · Page 2Linked to original sources
USGS1964

Crystal chemistry and structure refinement of five hydrated calcium borates

The crystal structures of the five known members of the series Ca 2 B 6 O 11 ·xH 2 O (x = 1, 5, 5, 7, 9, and 13) have been refined by full-matrix least-squares techniques, yielding bond distances and angles with standard errors of less than 0·01 Å and 0·5°, respectively. The results illustrate the crystal chemical principles that govern the structures of hydrated borate compounds. The importance of hydrogen bonding in the ferroelectric transition of colemanite is confirmed by more accurate proton assignments.

Journal of Inorganic and Nuclear Chemistry↗
USGS1963

Boron-oxygen polyanion in the crystal structure of tunellite

The crystal structure of tunellite, SrO·3B 2 O 3 ·4H 2 O, with infinite sheets of composition n[B 6 O 9 (OH) 2 ] 2- , has cations and water molecules in the spaces within the sheets. Adjacent sheets are held together by hydrogen bonding through the water molecules. The boron-oxygen polyanions provide the first example in hydrated borate crystals of one oxygen linked to three borons.

Science↗
USGS1960

Crystal structure refinement of reedmergnerite, the boron analog of albite

Ordering of boron in a feldspar crystallographic site T 1 (0) has been found in reedmergnerite, which has silicon-oxygen and sodium-oxygen distances comparable to those in isostructural low albite. If a simple ionic model is assumed, calculated bond strengths yield a considerable charge imbalance in reedmergnerite, an indication of the inadequacy of the model with respect to these complex structures and of the speculative nature of conclusions based on such a model.

Science↗