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J. G. Brown

Publications and source records attributed to J. G. Brown.

5 recordsLinked to original sources
USGS2008

Hydrologic data from the study of acidic contamination in the Miami Wash— Pinal Creek Area, Arizona, water years 1997–2004

Since 1984, hydrologic data have been collected as part of a U.S. Geological Survey study of the occurrence and movement of acidic contamination in the aquifer and streams of the Pinal Creek drainage basin near Globe, Arizona. Ground-water data from that study are presented for water years 1997 through 2004 and include location, construction information, site plans, water levels, chemical and physical field measurements, and selected chemical analyses of water samples for 31 project wells. Hydrographs of depth to ground water are also included. Surface-water data for four sites are also presented and include selected chemical analyses of water samples. Monthly precipitation data and long-term precipitation statistics are presented for two sites. Chemical analyses of samples collected from the stream and shallow ground water in the perennial reach of Pinal Creek are also included.

Arizona↗
USGS2003

Kinetic dissolution of carbonates and Mn oxides in acidic water: Measurement of in situ field rates and reactive transport modeling

The kinetics of carbonate and Mn oxide dissolution under acidic conditions were examined through the in situ exposure of pure phase samples to acidic ground water in Pinal Creek Basin, Arizona. The average long-term calculated in situ dissolution rates for calcite and dolomite were 1.65??10-7 and 3.64??10-10 mmol/(cm2 s), respectively, which were about 3 orders of magnitude slower than rates derived in laboratory experiments by other investigators. Application of both in situ and lab-derived calcite and dolomite dissolution rates to equilibrium reactive transport simulations of a column experiment did not improve the fit to measured outflow chemistry: at the spatial and temporal scales of the column experiment, the use of an equilibrium model adequately simulated carbonate dissolution in the column. Pyrolusite (MnO2) exposed to acidic ground water for 595 days increased slightly in weight despite thermodynamic conditions that favored dissolution. This result might be related to a recent finding by another investigator that the reductive dissolution of pyrolusite is accompanied by the precipitation of a mixed Mn-Fe oxide species. In PHREEQC reactive transport simulations, the incorporation of Mn kinetics improved the fit between observed and simulated behavior at the column and field scales, although the column-fitted rate for Mn-oxide dissolution was about 4 orders of magnitude greater than the field-fitted rate. Remaining differences between observed and simulated contaminant transport trends at the Pinal Creek site were likely related to factors other than the Mn oxide dissolution rate, such as the concentration of Fe oxide surface sites available for adsorption, the effects of competition among dissolved species for available surface sites, or reactions not included in the model.

Applied Geochemistry↗
USGS2000

Reactive transport of metal contaminants in alluvium: Model comparison and column simulation

A comparative assessment of two reactive-transport models, PHREEQC and HYDROGEOCHEM (HGC), was done to determine the suitability of each for simulating the movement of acidic contamination in alluvium. For simulations that accounted for aqueous complexation, precipitation and dissolution, the breakthrough and rinseout curves generated by each model were similar. The differences in simulated equilibrium concentrations between models were minor and were related to (1) different units in model output, (2) different activity coefficients, and (3) ionic-strength calculations. When adsorption processes were added to the models, the rinseout pH simulated by PHREEQC using the diffuse double-layer adsorption model rose to a pH of 6 after pore volume 15, about 1 pore volume later than the pH simulated by HGC using the constant-capacitance model. In PHREEQC simulation of a laboratory column experiment, the inability of the model to match measured outflow concentrations of selected constituents was related to the evident lack of local geochemical equilibrium in the column. The difference in timing and size of measured and simulated breakthrough of selected constituents indicated that the redox and adsorption reactions in the column occurred slowly when compared with the modeled reactions. MINTEQA2 and PHREEQC simulations of the column experiment indicated that the number of surface sites that took part in adsorption reactions was less than that estimated from the measured concentration of Fe hydroxide in the alluvium.

Applied Geochemistry↗
USGS1994

Hydrogeology and hydrologic system of Pinal Creek Basin, Gila County, Arizona

Acidic water that contains elevated concentrations of metals has contaminated a stream and alluvial aquifer in a mining district near Globe, Arizona. The contaminated aquifer is a narrow layer of unconsolidated alluvium along Miami Wash and Pinal Creek. The alluvium overlies basin fill, which extends throughout most of the Pinal Creek basin. The alluvium and basin fill compose the primary aquifer in the basin. Horizontal hydraulic con- ductivities were estimated at about 200 meters per day in the alluvium, and average linear ground- water flow velocities are about 5 meters per day. Water levels in the aquifer respond rapidly to periods of extended runoff in the basin and variable rates of ground-water pumping. Fluctuations of as much as 2.5 meters in 6 months have been measured. Ground-water levels were near record highs during spring 1985 and declined as much as 13 meters by spring 1989. Measured hydraulic gradients indicate that flow is generally upward from the basin fill to the alluvium. From 1980 to 1984, seepage of 155 liters per second from Webster Lake and 279 liters per second streamflow infiltration were estimated to be the two largest sources of inflow to the regional aquifer. Major outflows from the aquifer were 166 liters per second of pumpage and 240 liters per second of natural ground-water discharge to Pinal Creek.

Arizona↗