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J. G. Brown

Publications and source records attributed to J. G. Brown.

9 recordsLinked to original sources
USGS2008

Hydrologic data from the study of acidic contamination in the Miami Wash— Pinal Creek Area, Arizona, water years 1997–2004

Since 1984, hydrologic data have been collected as part of a U.S. Geological Survey study of the occurrence and movement of acidic contamination in the aquifer and streams of the Pinal Creek drainage basin near Globe, Arizona. Ground-water data from that study are presented for water years 1997 through 2004 and include location, construction information, site plans, water levels, chemical and physical field measurements, and selected chemical analyses of water samples for 31 project wells. Hydrographs of depth to ground water are also included. Surface-water data for four sites are also presented and include selected chemical analyses of water samples. Monthly precipitation data and long-term precipitation statistics are presented for two sites. Chemical analyses of samples collected from the stream and shallow ground water in the perennial reach of Pinal Creek are also included.

Arizona↗
USGS2003

Kinetic dissolution of carbonates and Mn oxides in acidic water: Measurement of in situ field rates and reactive transport modeling

The kinetics of carbonate and Mn oxide dissolution under acidic conditions were examined through the in situ exposure of pure phase samples to acidic ground water in Pinal Creek Basin, Arizona. The average long-term calculated in situ dissolution rates for calcite and dolomite were 1.65??10-7 and 3.64??10-10 mmol/(cm2 s), respectively, which were about 3 orders of magnitude slower than rates derived in laboratory experiments by other investigators. Application of both in situ and lab-derived calcite and dolomite dissolution rates to equilibrium reactive transport simulations of a column experiment did not improve the fit to measured outflow chemistry: at the spatial and temporal scales of the column experiment, the use of an equilibrium model adequately simulated carbonate dissolution in the column. Pyrolusite (MnO2) exposed to acidic ground water for 595 days increased slightly in weight despite thermodynamic conditions that favored dissolution. This result might be related to a recent finding by another investigator that the reductive dissolution of pyrolusite is accompanied by the precipitation of a mixed Mn-Fe oxide species. In PHREEQC reactive transport simulations, the incorporation of Mn kinetics improved the fit between observed and simulated behavior at the column and field scales, although the column-fitted rate for Mn-oxide dissolution was about 4 orders of magnitude greater than the field-fitted rate. Remaining differences between observed and simulated contaminant transport trends at the Pinal Creek site were likely related to factors other than the Mn oxide dissolution rate, such as the concentration of Fe oxide surface sites available for adsorption, the effects of competition among dissolved species for available surface sites, or reactions not included in the model.

Applied Geochemistry↗
USGS2000

Reactive transport of metal contaminants in alluvium: Model comparison and column simulation

A comparative assessment of two reactive-transport models, PHREEQC and HYDROGEOCHEM (HGC), was done to determine the suitability of each for simulating the movement of acidic contamination in alluvium. For simulations that accounted for aqueous complexation, precipitation and dissolution, the breakthrough and rinseout curves generated by each model were similar. The differences in simulated equilibrium concentrations between models were minor and were related to (1) different units in model output, (2) different activity coefficients, and (3) ionic-strength calculations. When adsorption processes were added to the models, the rinseout pH simulated by PHREEQC using the diffuse double-layer adsorption model rose to a pH of 6 after pore volume 15, about 1 pore volume later than the pH simulated by HGC using the constant-capacitance model. In PHREEQC simulation of a laboratory column experiment, the inability of the model to match measured outflow concentrations of selected constituents was related to the evident lack of local geochemical equilibrium in the column. The difference in timing and size of measured and simulated breakthrough of selected constituents indicated that the redox and adsorption reactions in the column occurred slowly when compared with the modeled reactions. MINTEQA2 and PHREEQC simulations of the column experiment indicated that the number of surface sites that took part in adsorption reactions was less than that estimated from the measured concentration of Fe hydroxide in the alluvium.

Applied Geochemistry↗
USGS1994

Hydrogeology and hydrologic system of Pinal Creek Basin, Gila County, Arizona

Acidic water that contains elevated concentrations of metals has contaminated a stream and alluvial aquifer in a mining district near Globe, Arizona. The contaminated aquifer is a narrow layer of unconsolidated alluvium along Miami Wash and Pinal Creek. The alluvium overlies basin fill, which extends throughout most of the Pinal Creek basin. The alluvium and basin fill compose the primary aquifer in the basin. Horizontal hydraulic con- ductivities were estimated at about 200 meters per day in the alluvium, and average linear ground- water flow velocities are about 5 meters per day. Water levels in the aquifer respond rapidly to periods of extended runoff in the basin and variable rates of ground-water pumping. Fluctuations of as much as 2.5 meters in 6 months have been measured. Ground-water levels were near record highs during spring 1985 and declined as much as 13 meters by spring 1989. Measured hydraulic gradients indicate that flow is generally upward from the basin fill to the alluvium. From 1980 to 1984, seepage of 155 liters per second from Webster Lake and 279 liters per second streamflow infiltration were estimated to be the two largest sources of inflow to the regional aquifer. Major outflows from the aquifer were 166 liters per second of pumpage and 240 liters per second of natural ground-water discharge to Pinal Creek.

Arizona↗
USGS1989

Chemical, geologic, and hydrologic data from the study of acidic contamination in the Miami Wash-Pinal Creek area, Arizona, water years 1984-87

Occurrence and movement of acidic contamination in the aquifer and streams of the Pinal Creek basin near Globe, Arizona, is the focus of an ongoing study by the U.S. Geological Survey. Groundwater data from that study for water years 1984 to 1987 include location, construction information, and site plans for six groups of monitoring wells, mineralogic and particle-size analyses of drill cuttings, water level measurements, and chemical analyses of water samples from 39 wells. Surface water data for 13 sites in this study include discharge measurements and chemical analysis of water and streambed sediment samples. Monthly discharge data are presented for one site. Monthly precipitation amounts and statistics of long-term precipitation are presented for two sites. (USGS)

Open-File Report↗
USGS1989

Geology and ground-water resources of the San Carlos Indian Reservation, Gila, Graham, and Pinal counties, Arizona

The San Carlos Indian Reservation includes about 2,900 sq mi in east- central Arizona. Relatively impermeable pre-Tertiary rocks are exposed in about 23% of the reservation and underlie water-bearing Tertiary and quaternary basin fill and Quaternary stream alluvium in much of the southern part of the reservation. About 9,000 members of the San Carlos Apache Tribe live on the reservation and rely on groundwater to meet public supply, irrigation, and other needs. Basin fill is widespread in the valley of the San Carlos and Gila Rivers and consists of fine sand, silt, limestone, clay, and pyroclastic volcanics that may attain a total maximum thickness of more than 3,200 ft in the reservation. Quaternary stream alluvium overlies the basin fill along many streams and washes. Stream alluvium consists of poorly sorted, unconsolidated, gravelly, muddy, sand; and sandy gravel and reaches a maximum thickness of 100 ft along the San Carlos and Gila Rivers. The volume of recoverable water stored in the basin fill to a depth of 1,200 ft is estimated to be about 20 million acre-ft. The volume of recoverable water stored in the stream alluvium on the reservation is estimated to be more than 100,000 acre-ft. The stream alluvium along the San Carlos River supplies most of the water used for drinking. Water throughout much of the reservation is suitable for most uses except for that in the alluvium along the Gila River, which contains large concentrations of dissolved solids. (USGS)

Water-Resources Investigations Report↗
USGS1988

Simulation of five ground-water withdrawal projections for the Black Mesa area, Navajo and Hopi Indian Reservations, Arizona

The N Aquifer is the main source of water in the 5,400 sq mi Black Mesa area in the Navajo and Hopi Indian Reservations in northeastern Arizona. Water in the aquifer is under confined conditions in the central 3,300 sq mi of the area. Maximum saturated thickness is about 1,050 ft. Annual groundwater withdrawals from 1972 through 1986 averaged 5,480 acre-ft and included 3,820 acre-ft used to operate a coal mine on Black Mesa. As a result, water levels have declined in a large part of the aquifer. The coal company has applied for a permanent permit under the Surface Mining Control and Reclamation Act of 1977. An existing mathematical model of the aquifer in the Black Mesa area was converted to a newer model program and recalibrated by using revised estimates of selected aquifer parameters and a finer spatial grid. The model was used to simulate four groundwater withdrawal alternatives that combined the existing and proposed mining plans with projected constant or increasing pumpage for nearby communities. A fifth alternative combined increasing community pumpage with no mine withdrawals and was used as a basis for comparison. Simulated water levels for the year 2031 in the coal-lease area are projected to be 60 ft lower than in 1985 for the proposed mining plan combined with growing community pumpage and > 100 ft lower than predevelopment water levels over an area of 1,660 sq mi. Groundwater would rise to within 100 ft of predevelopment levels < 10 yr after mine withdrawals cease. Withdrawals at the mine were a minor factor in determining simulated water levels at most communities in the study area. Water levels at Tuba City were not affected by mine pumpage in any projection. (Author 's abstract)

Water-Resources Investigations Report↗