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J. F. Sutter

Publications and source records attributed to J. F. Sutter.

18 recordsLinked to original sources

Contrasting P‐T‐t paths: Thermochronologic evidence for a Late Paleozoic final assembly of the Avalon Composite Terrane in the New England Appalachians

Strongly contrasting pressure‐temperature‐time paths for the Avalon composite terrane and the structurally overlying Putnam‐Nashoba zone in eastern New England obtained from thermochronologic and thermobarometric data are best explained by a late Paleozoic underthrusting of cover rocks by the Avalon composite terrane. We present new Ar and U‐Pb thermochronologic data that show that in the southern Hope Valley zone, Permian (280 Ma) anatectic metamorphic conditions of 700°C and 6 kbar were quenched by relatively rapid cooling (12°C/m.y.) and exhumation (0.5 km/m.y.) for ∼40 m.y. In contrast, peak metamorphic conditions in the Putnam‐Nashoba zone predate Silurian intrusions, and slower cooling (3.5°C/m.y.) began at about 400 Ma. One‐dimensional thermal modeling suggests that these two belts were not in thermal equilibrium during the Permian metamorphism of the Avalon composite terrane. Because of the absence of high‐grade Alleghanian metamorphism in rocks overlying the Avalon terrane, we conclude that high‐grade Alleghanian metamorphism in the Avalon terrane occurred east of rocks now overlying it and that significant motion between Avalon and this cover occurred after peak Alleghanian metamorphism. Similarly contrasting metamorphic histories between Avalon inliers (Willimantic window, Massabesic complex gneiss, Pelham dome) and their cover rocks reveals the regional significance of this boundary. The core rocks all show Permian cooling, but the cover rocks show post‐Acadian cooling ages decreasing from east to west to the Pelham area, where hornblende ages in Avalon and cover differ by only 35 rather than 80 m.y. Model calculations show that thermal equilibrium between instantaneously thrusted blocks of rocks is generally obtained in tens of millions of years. Consequently, underthrusting of Avalon is constrained to be middle Mississippian or younger. Because the leading edge of the underthrusting block would have been heated the longest and would have most closely approached thermal equilibrium with its cover, core rocks of the Pelham dome must have been relatively close to this leading edge. Thus Carboniferous to Permian underplating from a generally eastward direction best explains these thermochronologic relationships.

Connecticut, Maine, Massachusetts, New Hampshire, ↗

Geochemistry and argon thermochronology of the Variscan Sila Batholith, southern Italy: source rocks and magma evolution

The Sila batholith is the largest granitic massif in the Calabria-Peloritan Arc of southern Italy, consisting of syn to post-tectonic, calc-alkaline and metaluminous tonalite to granodiorite, and post-tectonic, peraluminous and strongly peraluminous, two-mica??cordierite??Al silicate granodiorite to leucomonzogranite. Mineral 40Ar/39Ar thermochronologic analyses document Variscan emplacement and cooling of the intrusives (293-289 Ma). SiO2 content in the granitic rocks ranges from ???57 to 77 wt%; cumulate gabbro enclaves have SiO2 as low as 42%. Variations in absolute abundances and ratios involving Hf, Ta, Th, Rb, and the REE, among others, identify genetically linked groups of granitic rocks in the batholith: (1) syn-tectonic biotite??amphibole-bearing tonalites to granodiorites, (2) post-tectonic two-mica??Al-silicate-bearing granodiorites to leucomonzogranites, and (3) post-tectonic biotite??hornblende tonalites to granodiorites. Chondrite-normalized REE patterns display variable values of Ce/Yb (up to ???300) and generally small negative Eu anomalies. Degree of REE fractionation depends on whether the intrusives are syn- or post-tectonic, and on their mineralogy. High and variable values of Rb/Y (0.40-4.5), Th/Sm (0.1-3.6), Th/Ta (0-70), Ba/Nb (1-150), and Ba/Ta (???50-2100), as well as low values of Nb/U (???2-28) and La/Th (???1-10) are consistent with a predominant and heterogeneous crustal contribution to the batholith. Whole rock ??18O ranges from ???+8.2 to +11.7???; the mafic cumulate enclaves have the lowest ??18O values and the two-mica granites have the highest values. ??18O values for biotite??honblende tonalitic and granodioritic rocks (9.1 to 10.8???) overlap the values of the mafic enclaves and two-mica granodiorites and leucogranites (10.7 to 11.7???). The initial Pb isotopic range of the granitic rocks (206Pb/204Pb ???18.17-18.45, 207Pb/204Pb ???15.58-15.77, 208Pb/204Pb ???38.20-38.76) also indicates the predominance of a crustal source. Although the granitic groups cannot be uniquely distinguished on the basis of their Pb isotope compositions most of the post-tectonic tonalites to granodiorites as well as two-mica granites are somewhat less radiogenic than the syn-tetonic tonalites and granodiorites. Only a few of the mafic enclaves overlap the Pb isotope field of the granitic rocks and are consistent with a cogenetic origin. The Sila batholith was generated by mixing of material derived from at least two sources, mantle-derived and crustal, during the closing stages of plate collision and post-collision. The batholith ultimately owes its origin to the evolution of earlier, more mafic parental magmas, and to complex intractions of the fractionating mafic magmas with the crust. Hybrid rocks produced by mixing evolved primarily by crystal fractionation although a simple fractionation model cannot link all the granitic rocks, or explain the entire spectrum of compositions within each group of granites. Petrographic and geochemical features characterizing the Sila batholith have direct counterparts in all other granitic massifs in the Calabrian-Peloritan Arc. This implies that magmatic events in the Calabrian-Peloritan Arc produced a similar spectrum of granitic compositions and resulted in a distinctive type of granite magmatism consisting of coeval, mixed, strongly peraluminous and metaluminous granitic magmas. ?? 1994 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

Early Paleozoic alkalic and calc-alkalic plutonism and associated contact metamorphism, central Virginia Piedmont

Early Paleozoic plutonism in the central Virginia Piedmont consists of the igneous Lahore Complex and Ellisville Pluton. The Lahore Complex consists of a small altered mafic pluton intruded by the shoshonitic, alkalic monzonites of the Lahore Pluton (-450 Ma) that, in turn, is intruded by the calc-alkaline, granodioritic Ellisville Pluton (-440 Ma). These plutons were emplaced at about 760aC at a depth of 12 to 18 km within greenschist-facies rocks and are enclosed by contact-metamorphosed rocks.

Virginia↗

Differential unroofing within the central metasedimentary Belt of the Grenville Orogen: constraints from 40Ar/39Ar thermochronology

An 40Ar/39Ar thermochronological investigation of upper greenschist to granulite facies gneiss, amphibolite and marble was conducted in the Central Metasedimentary Belt (CMB), Ontario, to constrain its cooling history. Incremental 40Ar/39Ar release spectra indicate that substantial differential unroofing occurred in the CMB between ??? 1000 and ??? 600 Ma. A consistent pattern of significantly older hornblende and phlogopite 40Ar/3Ar cooling ages on the southeast sides of major northeast striking shear zones is interpreted to reflect late displacement due to extensional deformation. Variations in hornblende 40Ar/39Ar age plateaus exceeding 200 Ma occur over distances less than 50 km with major age discontinuities occurring across the Robertson Lake shear zone and the Sharbot Lake mylonite zone which separate the Sharbot Lake terrane from the Elzevir and Frontenac terranes. Extensional displacements of up to 14 km are inferred between the Frontenac and Elzevir terranes of the CMB. No evidence for significant post argon-closure vertical displacement is indicated in the vicinity of the Perth Road mylonite within the Frontenac terrane. Variations of nearly 100 Ma in phlogopite 40Ar/39Ar plateau ages occur in undeformed marble on either side of the Bancroft Shear Zone. Phlogopites from sheared and mylonitized marble within the shear zone yield 40Ar/39Ar diffusional loss profiles, but have older geologically meaningless ages thought to reflect incorporation of excess argon. By ??? 900 Ma, southeast directed extension was occurring throughout the CMB, possibly initiated along previous zones of compressional shearing. An easterly migration of active zones of extension is inferred, possibly related to an earlier, overall easterly migration of active zones of regional thrusting and easterly migration of an ancient subduction zone. The duration of extensional shearing is not well constrained, but must have ceased before ??? 600 Ma as required by the deposition of overlying undeformed Cambrian and/or Ordovician sedimentary rocks. ?? 1992 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

High-precision 40Ar/39Ar sanidine geochronology of ignimbrites in the Mogollon-Datil volcanic field, southwestern New Mexico

40Ar/39Ar age spectra have been obtained from 85 sanidine separates from 36 ignimbrites and one rhyolitic lava in the latest Eocene-Oligocene Mogollon-Datil volcanic field of southwestern New Mexico. Of the 97 measured age spectra, 94 yield weighted-mean plateau ages each giving single-spectrum 1?? precision of??0.25%-0.4% (??0.07-0.14 Ma). Replicate plateau age determinations for eight different samples show within-sample 1?? precisions averaging ??0.25%. Plateau ages from multiple (n=3-8) samples of individual ignimbrites show 1?? within-unit precision of ??0.1%-0.4% (??0.04-0.13 Ma). This within-unit precision represents a several-fold improvement over published K-Ar data for the same ignimbrites, and is similar to the range of precisions reported from single-crystal laser fusion studies. A further indication of the high precision of unit-mean 40Ar/30Ar ages is their close agreement with independently established stratigraphic order. Two samples failed to meet plateau criteria, apparently due to geologic contamination by older feldspars. Effects of minor contamination are shown by six other samples, which yielded slightly anomalous plateau ages. 40Ar/39Ar plateau ages permit resolution of units differing in age by 0.5% (0.15 Ma) or less. This high resolution, combined with paleomagnetic studies, has helped to correlate ignimbrites among isolated ranges and has allowed development of an integrated timestratigraphic framework for the volcanic field. Mogollon-Datil ignimbrites range in age from 36.2 to 24.3 Ma. Ignimbrite activity was strongly episodic, being confined to four brief (<2.6 m.y.) eruptive episodes separated by 1-3 m.y. gaps. Ignimbrite activity generally tended to migrate from the southeast toward the north and west. ?? 1990 Springer-Verlag.

Bulletin of Volcanology↗

40Ar-39Ar dating of the Manson impact structure: A Cretaceous-Tertiary boundary crater candidate

The mineralogy of shocked mineral and lithic grains in the Cretaceous-Tertiary (K-T) boundary claystone worldwide is most consistent with a bolide impact on a continent. Both the concentrations and sizes of these shocked grains are greatest in the western interior of North America. These data suggest that the Manson impact structure in north-central Iowa is a viable candidate for the K-T boundary impact event. Argon-40–argon-39 age spectrum dating of shocked microcline from the crystalline central uplift of the Manson impact structure indicates that there was severe argon-40 loss at 65.7 ± 1.0 million years ago, an age that is indistinguishable from that of the K-T boundary, within the limits of analytical precision.

Science↗

Thermochronology of economic mineral deposits: Dating the stages of mineralization at Panasqueira, Portugal, by high-precision 40Ar/ 39Ar age spectrum techniques on muscovite

40 Ar/ 39 Ar age spectrum dates for 13 muscovites have been used to reconstruct the thermal history (thermochronology) of the Panasqueira, Portugal, tin-tungsten deposit, a deposit spatially associated with a belt of Hercynian plutons. Muscovite samples with an age difference as small as 2.2 m.y. (0.7% of the age) are statistically distinct. Statistics are even better for comparison of multiple samples from separate events; that is, a difference of 0.9 m.y. (0.3%) can be resolved in this approximately 300-m.y.-old deposit. The major tin and tungsten ore-forming stages, which are the oxide-silicate stage, the main sulfide stage, and greisenization, occurred between 296.3 + or - 0.8 (1 Sigma ) and 291.6 + or - 0.8 m.y. (1 Sigma ). The first substage of the oxide-silicate stage was a short-lived thermal pulse at 296.3 + or - 0.6 m.y.; the fluids responsible may have emanated from the known granite cupola. The main sulfide stage was active at 294.5 + or - 0.9 m.y. as a slightly longer lived pulse with oldest evidence for this stage (295.8 + or - 0.6 m.y.) coming from areas farthest away from the known cupola and youngest evidence (293.5 + or - 0.8 m.y.) closest to the cupola. A second substage of the oxide-silicate stage occurred as a short-lived thermal pulse at 292.9 + or - 0.7 m.y., synchronous with greisenization of the cupola and alteration of the silica cap at 292.1 + or - 0.4 m.y. The duration of activity of the oxide-silicate stage, the main sulfide stage, greisenization, and alteration of the silica cap based on the ages of all 13 muscovites was greater than 4.2 + or - 0.5 m.y. (1 Sigma ). Minor argon loss from all dated muscovites occurred during later reheating, probably during the longer lived pyrrhotite alteration stage. A single center, the known cupola, had a prolonged role and was the source for main sulfide stage, oxide-silicate stage II, greisenization, and alteration of the silica cap and possibly oxide-silicate stage I and the pyrrhotite alteration stage; however, a separate source for these latter two stages cannot be ruled out.This study is an example of a new and powerful application of 40 Ar/ 39 Ar age spectrum dating of muscovite. Because of the high precision demonstrated in this study, it is now possible to establish time constraints necessary for solving some of the long-standing problems in economic geology. Beyond this, the unique geologic situation of Panasqueira has allowed us to quantify the thermal characteristics of muscovite. Published fluid inclusion data have been used to estimate a muscovite argon closure temperature of approximately 325 degrees C during rapid cooling or short reheating and a temperature of approximately 270 degrees C during slow cooling or extended reheating. Argon-loss patterns displayed by all dated muscovites resulted from reheating after original closure; the mechanism for this argon loss appears to have been argon transport by volume diffusion. Thus, 40 Ar/ 39 Ar age spectrum dating of muscovite can be used to evaluate thermal conditions controlling argon diffusion as well as age, duration, and number of episodes of mineralization.

Economic Geology↗

Evidence for Late-Paleozoic brine migration in Cambrian carbonate rocks of the central and southern Appalachians: Implications for Mississippi Valley-type sulfide mineralization

Many Lower Paleozoic limestones and dolostones in the Valley and Ridge province of the central and southern Appalachians contain 10 to 25 weight percent authigenic potassium feldspar. This was considered to be a product of early diagenesis, however, 40 Ar 39 Ar "> 40 Ar 39 Ar analyses of overgrowths on detrital K-feldspar in Cambrian carbonate rocks from Pennsylvania, Maryland, Virginia, and Tennessee yield Late Carboniferous-Early Permian ages (278–322 Ma). Simple mass balance calculations suggest that the feldspar could not have formed isochemically, but required the flux of multiple pore volumes of fluid through the rocks, reflecting regional fluid migration events during the Late-Paleozoic Alleghanian orogeny. Microthermometric measurements of fluid inclusions in overgrowths on detrital K-feldspar and quartz grains from unmineralized rocks throughout the study area indicate homogenization temperatures from 100° to 200°C and freezing point depressions of −14° to −18.5°C (18–21 wt.% NaCl equiv). The apparent similarity of these fluids to fluid inclusions in ore and gangue minerals of nearby Mississippi Valley-type (MVT) deposits suggests that the regional occurrences of authigenic K-feldspar and MVT mineralization may be genetically related. This hypothesis is supported by the discovery of authigenic K-feldspar intergrown with sphalerite in several mines of the Mascot-Jefferson City District, E. Tennessee. Regional potassic alteration in unmineralized carbonate rocks and localized occurrences of MVT mineralization are both explainable by a gravity-driven flow model, in which deep brines migrate towards the basin margin under a hydraulic gradient established during the Alleghanian orogeny. The authigenic K-feldspar may reflect the loss of K during disequilibrium cooling of the ascending brines. MVT deposits are probably localized manifestations of the same migrating fluids, occurring where the necessary physical and chemical traps are present.

Geochimica et Cosmochimica Acta↗

Alleghanian deformation, metamorphism, and granite emplacement in the central Piedmont of the southern Appalachians

Evidence of late Paleozoic (Alleghanian) penetrative deformation, amphilbolite-facies, metamorphism, and syntectonic granite emplacement has been found in an area of the central Piedmont in the southern Appalachians. The High Shoals Granite batholith in the Kings Mountain belt of south-central North Carolina consists of coarse-grained, megacrystic biotite granite with a strong, nearly vertical, gneissoid, foliation, defined by parallel feldspar megacrysts and biotite. U-Ph isotopic data on zircons from the granite yield a concordant age of 317 Ma (Pennsylvanian). This pervasively deformed late Paleozoic granite in the central Piedmont is far west of those known in the Kiokee and Raleigh belts. Field relationships indicate that the High Shoals Granite was emplaced during the late stages of regional F2 folding, close in time to the thermal peak of amphibolite-facies metamorphism. Mineral assemblages typical of Barrovian metamorphism are found in zones of decreasing grade away from the High Shoals contact. These zones, delimited by a kyanite(out)-sillimanite (in) isograd which completely surrounds the batholith and by part of a regional chloritoid (out)-staurolite (in) isograd west and southwest of it, conform to the shape of the batholith and cut across F2 folds. Furthermore, hornblendes from epidoteamphibolite facies to upper amphibolite facies metamorphic rocks in the Kings Mountain belt of North Carolina and South Carolina yield 40Ar/39Ar plateau ages of 318 to 323 Ma. These dates are analytically the same as the crystallization age of High Shoals Granite as established of zireon using the U-Ph method and demonstrate the synchroneity of intrusion of the High Shoals with the dominant regional metamorphism in this part of the Kings Mountain belt.

Southern Appalachians↗

40Ar/39Ar and K-Ar data bearing on the metamorphic and tectonic history of western New England

40 Ar/ 39 Ar ages of coexisting biotite and hornblende from Proterozoic Y gneisses of the Berkshire and Green Mountain massifs, as well as 40 Ar/ 39 Ar and K-Ar mineral and whole-rock ages from Paleozoic metamorphic rocks, suggest that the thermal peak for the dominant metamorphic recrystallization in western New England occurred 465 ± 5 m.y. ago (Taconian). Although textural data indicate a complex metamorphic-tectonic history for Paleozoic rocks, no evidence in rocks at least as high as kyanite grade dictates an Acadian age for the Barrovian metamorphism. Available 40 Ar/ 39 Ar and K-Ar data suggest that the low-grade metamorphism and cleavage formation in Taconic allochthons and the higher-grade metamorphism and emplacement of the Berkshire massif allochthon are Taconian. 40 Ar/ 39 Ar age data from a poorly defined terrane beginning near the east margin of the Green Mountain massif and extending along the eastern one-third of the Berkshire massif as far south as Otis, Massachusetts, suggest that the area has been retrograded during a metamorphism that peaked at least 376 ± 5 m.y. ago (Acadian). Available age and petrologic data from western New England indicate the presence of at least three separate metamorphic-structural domains of Taconian age: (1) a small area of relict high-pressure and low-temperature metamorphism in northern Vermont (T-1 domain), (2) a broad area in Vermont and eastern New York of normal Barrovian metamorphism from chlorite to garnet grade and characterized by a gentle metamorphic gradient (T-2 domain), and (3) a rather narrow belt of steep-gradient, Barrovian series metamorphic rocks extending from near the Cortlandt Complex northeastward through Dutchess County, New York, to the Berkshire massif in western Massachusetts (T-3 domain). Areas of maximum metamorphic intensity within the T-3 domain coincide with areas of maximum crustal thickening resulting from imbricate thrusting (Berkshire massif) or from recumbent folding (Manhattan Prong) of remobilized North American continental crust in the later stages of the Taconic orogeny.

Geological Society of America Bulletin↗

U-Th-Pb, Rb-Sr, and Ar-Ar mineral and whole-rock isotopic systematics in a metamorphosed granitic terrane, southeastern California

Mesozoic structural domes are developed in an older Proterozoic crystalline basement of granitic to granodioritic foliate metaplutonic rocks in the Halloran Hills, southeastern California. Isotopic analyses of whole rocks and mineral separates from these rocks by U-Th-Pb, Rb-Sr, and Ar-Ar techniques yield a complex pattern of discordance that is the result of a fairly simple geologic history. Individual mineral isotopic systems have variably equilibrated with each other in response to Mesozoic regional metamorphism and locally to later heating during Mesozoic batholith emplacement. Discordant U-Th-Pb zircon data indicate that the granitic core rocks are 1,710 Ma and that one dioritic phase may be slightly older. Rb-Sr whole-rock model dates scatter about 1,700 Ma Rb-Sr amphibole–whole-rock and U-Th-Pb amphibole dates are also Proterozoic. Potassium feldspars retain a 207 Pb/ 206 Pb signature of their Proterozoic age. Ar-Ar amphibole spectra from the flank of the main dome reveal disturbed dates of 1,450 Ma to 1,100 Ma, and the dates become younger toward the structurally deeper core of the dome. All remaining isotopic determinations yield Mesozoic or younger dates for mineral–whole-rock systems. Rb-Sr whole-rock–apatite–feldspar–biotite analyses show nonequilibration of strontium isotopes, with resultant mineral pair dates from 4 foliate plutonic rocks ranging from 200 to 50 Ma. No single metamorphic age is indicated by the Rb-Sr data. Rb-Sr whole-rock–biotite dates are consistently younger than any other determinations and may be reduced by weathering or gain of nonradiogenic strontium from ground water. U-Pb sphene and apatite analyses from rocks that yield 1,710-Ma zircon dates are nearly concordant at 140 Ma. An amphibole from the structurally deepest rocks of the main dome that yield 140- to 150-Ma U-Pb sphene dates has an Ar-Ar plateau date of 144 Ma. The U-Pb sphene and Ar-Ar amphibole analyses are believed to be the best age estimate for the end of the highest-temperature phase of regional metamorphism. Th-Pb sphene and apatite dates and Ar-Ar biotite dates cluster at 90 ± 5 Ma as a consequence of regional cooling during Late Cretaceous time following extensive Mesozoic plutonism in the region at 97 to 90 Ma. We interpret the discordant mineral date patterns to have resulted from metamorphism of ∼1,700-Ma plutonic rocks during the Jurassic (≥ 140–50 Ma) and subsequent uplift and cooling to ∼200 °C at about 90 Ma. On the basis of this study, the isotope dating systems ranked in decreasing order of resistance to resetting are: U-Th-Pb zircon (concordia intercept) ≥ Rb-Sr whole rock ∼Rb-Sr amphibole ∼U-Th-Pb amphibole ∼Pb-Pb whole rock > Ar-Ar amphibole ≥ Rb-Sr sphene ≥ U-Pb sphene and apatite > Rb-Sr plagioclase-potassium feldspar-apatite > Th-Pb sphene and apatite ∼Ar-Ar biotite ∼U-Pb feldspars > Rb-Sr biotite.

California↗

LASER MICROPROBE **4**0Ar/**3**9Ar DATING OF MINERAL GRAINS IN SITU.

A laser-microprobe attached to a mass spectrometer for **4**0Ar/**3**9Ar age determination of single mineral grains in geological materials has been made operational at the US Geological Survey, Reston, VA. This microanalytical technique involves focusing a pulsed laser beam onto a sample contained in an ultra-high vacuum chamber attached to a rare-gas mass spectrometer. Argon in the neutron-irradiated sample is released by heating with the laser pulse and its isotopic composition is measured to yield an **4**0Ar/**3**9Ar age. Laser probe **4**0Ar/**3**9Ar ages of single mineral grains measured in situ can aid greatly in understanding the chronology of many geological situations where datable minerals are present but are not physically separable in quantities needed for conventional age dating.

Scanning Electron Microscopy↗

Interpretation of discordant 40Ar/39Ar age-spectra of mesozoic tholeiites from Antarctica

Conventional K-Ar ages of tholeiitic basalts of the Ferrar Group in the central Transantarctic Mountains indicate significant loss of radiogenic 40 Ar from this unit over much of its outcrop area. Argon loss varies inversely with amount of devitrified matrix in the basalts, which have not been thermally or tectonically disturbed since extrusion. 40 Ar/ 19 Ar age-spectra of these tholeiites are generally discordant and indicate significant inhomogeneity in the distribution of radiogenic 40 Ar with respect to 39 Ar, but are distinctly different from release patterns of thermally disturbed samples. Amounts of argon redistribution vary directly with amounts of devitrification and are reflected in progressive modification of the age spectra. A model of redistribution of radiogenic 40 Ar by devitrification of originally glassy matrix is suggested that is consistent with disturbance of the conventional K-Ar systematics as well as the 40 Ar/ 39 Ar age-spectra. Samples with substantial redistribution but minor loss of radiogenic argon yield age spectra whose apparent ages decrease from low-temperature to high-temperature steps, similar to those reported for some lunar basalts, breccias, and soils. Modification of all the age spectra is attributed to redistribution of radiogenic 40 Ar during progressive devitrification, although 39 Ar-recoil effects suggested by Turner and Cadogan (1974) may be a factor in some cases. Where devitrification involves most potassium sites within the basalt, 40 Ar/ 39 Ar age-plateaux may be formed that have no geologic significance.

Geochimica et Cosmochimica Acta↗