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J. E. Elliott

Publications and source records attributed to J. E. Elliott.

At least 19 recordsLinked to original sources

History of wildlife toxicology and the interpretation of contaminant concentrations in tissues

The detection and interpretation of contaminants in tissues of wildlife belongs to the field of toxicology, a scientific discipline with a long, intriguing, and illustrious history. Concern over poisoning of wildlife began in the late nineteenth century, and initially focused more on identifying environmental problems than determining contaminant concentrations in tissues. Endpoint measurements were characterized for sensitivity, specificity, variability, clarity of interpretation, validity, and applicability to field sampling. The use of stable isotopes to identify the environmental source of a metal is a recent development in the field of wildlife toxicology. The chemical forms of Mercury may be changed within some organs (e.g., demethylation by liver), further complicating interpretation of wildlife tissue concentrations. The field of wildlife toxicology has been shaped by chemical use and misuse, ecological mishaps, and research in the allied field of human toxicology. The development and use of new chemicals, and unexpected and unpredicted contamination problems continue to drive this discipline.

Book chapter↗

Satellite telemetry and prey sampling reveal contaminant sources to pacific northwest ospreys

Migratory behavior can be an important factor in determining contaminant exposure in avian populations. Accumulation of organochlorine (OC) pesticides while birds are wintering in tropical regions has been cited often as the reason for high concentrations in migrant populations. To explore this issue, we satellite tracked 16 Ospreys (Pandion haliaetus) over the period 1996-2003 from breeding sites in British Columbia, Canada, and integrated the results into a database on 15 Ospreys that were satellite tracked over the period 1995-1999, from breeding locations in Washington and Oregon, USA. Data on wintering sites of 31 Ospreys in Mexico and Central America were used for spatially targeted sampling of prey fish. Concentrations of the main organochlorine contaminant, p,p???-dichloro-diphenyl-dichloroethylene (DDE), in fish composites from Mexico ranged from 0.005 to 0.115 ??g/g wet mass. Significant differences existed among fish families in p,p???-DDE, total dichloro- diphenyltrichloroethane (??DDT), ??chlordanes, and total polychlorinated biphenyls (??PCBs). Catfish (family Ariidae) generally had significantly higher levels of DDT metabolites and other organochlorine contaminants compared to other fish families collected. Differences in prey contaminant levels were detected among the collection sites around coastal Mexico, with fish from Veracruz State generally having higher levels of DDT metabolites, ??chlordanes, ??PCBs, and hexachlorobenzene. Eggs collected from 16 nests throughout the Pacific Northwest (nine from British Columbia, seven from Oregon and Washington) where Ospreys had been satellite tagged, showed marked variation in levels of DDT metabolites (p,p???-DDE; range 0.02-10.14 ??g/g). Wintering site had no significant effect on contaminant concentrations in sample eggs from those specific Ospreys; rather concentrations of p,p???-DDE, were predicted by breeding sites with highest levels in eggs of Ospreys breeding in the lower Columbia River, consistent with published reports of continued high concentrations of DDT and related compounds in that system. ?? 2007 by the Ecological Society of America.

Ecological Applications↗

Assessment of biological effects of chlorinated hydrocarbons in osprey chicks

Osprey ( Pandion haliaetus ) eggs were collected during 1995 and 1996 at seven sites along the Fraser and Columbia River systems of British Columbia, Canada, and Washington and Oregon, USA. Fifty-four eggs were placed into a laboratory incubator. Thirty-eight of the hatched chicks were sacrificed within 24 h. Hatching success did not differ among sites and therefore between treatment and reference areas. Residual yolk sacs of eggs collected downstream of the large bleached-kraft pulp mill at Castlegar contained greater mean concentrations of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD, 2,930 ng/kg lipid) compared with reference sites such as the Nechako River, an upper tributary of the Fraser system (33.7 ng/kg). Total polychlorinated biphenyls (PCBs) in yolk sacs were also higher at Castlegar and in samples from the Columbia River downstream of Portland, Oregon, compared with those from the Nechako River. Concentrations of measured chemicals, including TCDD toxic equivalents (TEQs), total PCBs, p , p ′-dichlorodiphenylethylene ( p , p ′-DDE), and other organochlorines were not different in eggs that failed to hatch compared with calculated whole-egg values for hatched eggs. There were significant biochemical responses; a hepatic cytochrome P4501A (CYP1A) cross-reactive protein was detected in all samples tested and correlated positively with ethoxyresorufin o -deethylase (EROD) activity and yolk sac concentrations of TEQs and total PCBs. Tissue concentrations of vitamin A compounds varied among sites and correlated positively with yolk sac concentrations of TEQs and PCBs. Morphological, histological, and other physiological parameters, including chick growth, edema, deformities, and hepatic and renal porphyrin concentrations, neither varied among sites nor showed concentration-related effects.

British Columbia, Oregon, Washington↗

Contaminants in ospreys from the Pacific Northwest: II. Organochlorine pesticides, polychlorinated biphenyls and mercury, 1991-1997

Eggs of ospreys ( Pandion haliaetus ) were collected over the period 1991 to 1997 at 111 nests in the Fraser and Columbia River drainage systems of British Columbia, Washington, and Oregon. Contents were analyzed for organochlorine (OC) pesticides, polychlorinated biphenyls (PCBs), and total mercury. Blood samples were taken from nestling ospreys at two time points during the 1992 breeding season on the Thompson River and analyzed for non-ortho PCBs. Concentrations of DDE and related compounds showed high variability among individual eggs within study areas and no significant differences in mean concentrations among study areas. Some eggs contained high concentrations of DDE, up to 20 mg/kg (wet weight), for which there were no evident local sources, suggesting that exposure occurred outside of the breeding grounds. Most other OC pesticides measured in osprey eggs showed a similar distribution, although mean concentrations of chlordane-related compounds were generally, and in some cases significantly, higher in samples collected from the Columbia River sites compared to elsewhere. Significantly greater concentrations of PCBs were found in eggs from the Columbia River basin compared to the Fraser. This was attributed to extensive development of hydroelectric generation and related industries on the Columbia system. Significant differences among sites were also found in the pattern of PCB congeners, e.g., eggs from the lower Columbia River site had proportionally greater concentrations of less chlorinated, Aroclor 1242–type PCBs compared to other sites. In contrast, eggs from upper reaches of the Columbia River had relatively greater amounts of Aroclor 1254 and 1260 congeners. Mercury concentrations in osprey eggs tended to be uniform among sites and comparable to those reported in the literature for ospreys nesting on naturally formed lakes and rivers. There were no significant temporal changes in mean concentrations of any of the measured compounds at sites monitored from 1991 to 1997.

Archives of Environmental Contamination and Toxico↗

Chlorinated hydrocarbons in livers of American mink (Mustela vison) and river otter (Lutra canadensis) from the Columbia and Fraser River Basins, 1990-1992

We investigated chlorinated hydrocarbon contaminants in aquatic mustelid species on the Fraser and Columbia Rivers of northwestern North America. Carcasses of river otter (Lutra canadensis) (N=24) and mink (Mustela vison) (N=34) were obtained from commercial trappers during the winters of 1990–91 and 1991–92. Pooled liver samples were analyzed for organochlorine pesticides, polychlorinated biphenyls (PCBs), including non-ortho congeners, polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs). Most samples contained detectable concentrations of DDE, PCBs, although there was substantial variability in patterns and trends among neighboring samples. Concentrations of DDE were in some mink and several otter samples from the lower Columbia River elevated (to 4700 μg/kg wet weight); excluding one mink sample from the Wenatchee area, mean DDE levels generally decreased between 1978–79 and 1990–92. PCBs were present in all samples. PCB concentrations in otter livers collected from the lower Columbia were ten-fold lower than measured a decade previously; nevertheless, a sample taken near Portland had a mean concentration of 1500 μg/kg, within a range of concentrations associated with reproductive effects in captive mink. Concentrations of 2,3,7,8-TCDD and TCDF were generally below detection limits, except for one otter collected near a pulp mill at Castlegar, on the upper Columbia, with 11 ng TCDD/kg in liver. Elevated concentrations of higher chlorinated PCDD/Fs, probably resulting from use of chlorophenolic wood preservatives, were found in both species; one otter sample from the lower Columbia had 2200 ng OCDD/kg. International TCDD toxic equivalent levels in mink (31 ng/kg) and otter (93 ng/kg) from the lower Columbia River approached toxicity thresholds for effects on reproduction in ranch mink.

British Columbia, Oregon, Washington↗

Poisoning of raptors with organophosphorus and carbamate pesticides with emphasis on Canada, U.S. and U.K.

We reviewed cases of raptor mortality resulting from cholinesterase-inhibiting pesticides. We compiled records from the U.S., U.K. and Canada for the period 1985-95 (520 incidents) and surveyed the relevant literature to identify the main routes of exposure and those products that led to the greatest number of poisoning cases. A high proportion of cases in the U.K. resulted from abusive uses of pesticides (willful poisoning). The proportion was smaller in North America where problems with labeled uses of pesticides were as frequent as abuse cases. Poisoning resulting from labeled use was possible with a large number of granular pesticides and some seed treatments through secondary poisoning or through the ingestion of contaminated invertebrates, notably earthworms. With the more toxic products, residue levels in freshly-sprayed insects were high enough to cause mortality. The use of organophosphorus products as avicides and for the topical treatment of livestock appeared to be common routes of intoxication. The use of insecticides in dormant oils also gave rise to exposure that can be lethal or which can debilitate birds and increase their vulnerability. A few pesticides of high toxicity were responsible for the bulk of poisoning cases. Based on limited information, raptors appeared to be more sensitive than other bird species to organophosphorus and carbamate pesticides. Some of the more significant risk factors that resulted in raptor poisonings were: insectivory and vermivory; opportunistic taking of debilitated prey; scavenging, especially if the gastrointestinal tracts are consumed; presence in agricultural areas; perceived status as pest species; and flocking or other gregarious behavior at some part of their life cycle. Lethal or sublethal poisoning should always be considered in the diagnosis of dead or debilitated raptors even when another diagnosis (e.g., electrocution, car or building strike) is apparent. Many cases of poisoning are not currently diagnosed as such and, even when diagnosed, the information is often not made available to regulatory authorities. The importance of pesticide intoxications relative to other sources of mortality is highly variable in time and place; on a regional level, the increased mortality of raptors resulting from cholinesterase-inhibiting pesticides can be significant, especially in the case of rare species.

Journal of Raptor Research↗

Contaminants in ospreys from the Pacific Northwest: I. Trends and patterns in polychlorinated dibenzo-p-dioxins and -dibenzofurans in eggs and plasma

Osprey ( Pandion haliaetus ) eggs were collected from 1991 to 1997 at nests (n = 121) upstream and downstream of bleached kraft pulp mills and at reference sites in the Fraser and Columbia River drainage systems of British Columbia, Washington, and Oregon. Blood samples were collected from nestling ospreys during the 1992 breeding season on the Thompson River. Samples were analyzed for polychlorinated dibenzo- p -dioxins (PCDDs) and -dibenzofurans (PCDFs). Mean concentrations of 2,3,7,8-TCDD were significantly higher in eggs collected in 1991 at downstream compared to upstream nests near pulp mills at Kamloops and Castlegar, British Columbia. There were no significant temporal trends in 2,3,7,8-TCDD, -TCDF or other measured compounds at a sample of nests monitored between 1991 and 1994 downstream of the Castlegar pulp mill, despite changes in bleaching technology (CIO 2 substitution). However, by 1997 concentrations of 2,3,7,8-TCDD and -TCDF were significantly lower than previous years in nests sampled downstream at both Castlegar and Kamloops. An unusual pattern of higher chlorinated PCDDs and PCDFs was found in many of the osprey eggs collected in this study, and considerable individual variation in the pattern existed among eggs from the same site. For example, eggs from four different nests at one study area (Quesnel) on the Fraser River had concentrations of 1,2,3,4,6,7,8-HpCDD ranging from <1 to 1,100 ng/kg and OCDD from <1 to 7,000 ng/kg wet weight. Higher mean concentrations of HpCDD and OCDD were found in eggs from the Thompson River, a tributary of the Fraser, compared to the Columbia River, and concentrations were generally higher at nests upstream of pulp mills. In plasma samples, 1,2,3,4,6,7,8-HpCDD and OCDD were the main compounds detected, with no significant differences measured between samples upstream versus downstream or earlier versus later in the breeding season. Use of chlorophenolic wood preservatives by lumber processors was considered the main source of higher chlorinated PCDD/Fs throughout the systems, based on patterns of trace PCDFs in eggs and significant correlations between egg concentrations of pentachlorophenol and both HpCDD (r = 0.891, p < 0.01) and OCDD (r = 0.870, p < 0.01).

British Columbia, Oregon, Washington↗

Reconnaissance geologic map of the Sliderock Mountain area, Sweet Grass and Stillwater counties, Montana

The remains of a deeply eroded Late Cretaceous stratovolcano centered near Sliderock Mountain dominate the map area. The volcano consists mostly of lahars, although basaltic andesite lava flows are also present. An extensively eroded, weakly mineralized hypabyssal intrusive complex, inferred to represent the volcano's solidified magma chamber, intrudes previously erupted lava flows and associated lahars. Cretaceous sandstone and shale and Paleozoic sedimentary rocks, principally limestone of the Madison Group, host the stratovolcano; remnants of these rocks are preserved as large xenoliths and roof pendants.

Montana↗

Geology and genesis of the Baid Al Jimalah tungsten deposit, Kingdom of Saudi Arabia

The Baid al Jimalah tungsten deposit in Saudi Arabia (lat 25 degrees 09'N, long 42 degrees 41'E) consists predominantly of swarms of steeply dipping, subparallel, tungsten-bearing quartz veins and of less abundant, smaller stockwork veins. It is spatially, temporally, and genetically associated with a 569 Ma, highly differentiated, porphyritic, two-feldspar granite that intrudes Late Proterozoic immature sandstones.Paragenetic data from crosscutting veins demonstrate unambiguously a single cycle of magma intrusion and hydrothermal mineralization. Hypogene mineralization can be divided into three periods: (1) early quartz-molybdenite stockwork veining, (2) wolframite- and scheelite-bearing, greisen-bordered veining, and (3) late, quartz-carbonate-fluorite veining. The first two of these three periods can be further divided into several stages that are transitional to each other. The greisen-bordered veins, in particular, show replacement of earlier mineral assemblages by later ones. Precious and base metal veins at Baid al Jimalah East, approximately 1.5 km east of the Baid al Jimalah tungsten deposit, are genetically related to the tungsten deposit and probably formed contemporaneously with the greisenized tungsten-bearing veins.Fluid inclusion and oxygen isotope data indicate that the Baid al Jimalah deposit formed over a temperature range of 120 degrees to 550 degrees C, from low salinity magmatic and metamorphic fluids, and at a depth of about 4.2 km. Early stockwork veins (period 1) formed at low magmatic temperatures (ca. 550 degrees C) from magma-derived (delta 18 O = 9.6-9.7ppm), low-salinity (1-2 wt % NaCl equiv) fluid. This hydrothermal fluid was generally low density and CO 2 rich. All other veins were formed from regionally derived fluid in equilibrium with metamorphic rocks (delta 18 O = 7.9 + or - 1.0ppm at the site of deposition). This fluid probably scavenged most of the period 2 ore-mineral components from a postulated granite batholith whose existence is indicated by a 6-mGal gravity low centered on the deposit. The greisen-bordered tungsten veins (period 2) formed from fluids in the liquid state at temperatures mostly between 380 degrees and 440 degrees C with salinities between 4.5 and 10.9 wt percent NaCl equiv. Late, barren veins (period 3) formed from liquids with salinities between 0.0 and 3.5 wt percent NaCl equiv at temperatures as low as 120 degrees C. The veins at Baid al Jimalah East formed from liquids with salinities between 0 and 4.2 wt percent NaCl equiv at temperatures mostly between about 340 degrees and 390 degrees C. Important volatile constituents in some hydrothermal fluids were CO 2 and CH 4 , in addition to H 2 O and HF. The delta 18 O data on mineral separates of fresh and altered Bald al Jimalah granite, and whole-rock delta 18 O data on country-rock samples as far as 16 km from the deposit, indicate that the rocks in the Bald al Jimalah area were pervasively infiltrated by a fluid with relatively high delta 18 O values. Interaction and exchange of the country rocks with this delta 18 O fluid led to an increase in the delta 18 O values of volcanic rocks of the Jurdhawiyah Group but to a decrease in the delta 18 O values of the high value delta 18 O Murdama Group sandstones, resulting in a hydrothermal anomaly exceeding 100 km 2 in area. This fluid had an estimated delta 18 O value of about 6 to 8 per mil, essentially identical to that of the metamorphic water calculated from the vein quartz, thus strongly supporting the conclusion that all of the mineral deposits at Baid al Jimalah (except for the early-stage quartz-molybdenite veins), as well as the 12-km 2 geochemical anomaly surrounding the deposit, were from the same metamorphic fluid.Bald al Jimalah is similar in character and origin to Phanerozoic tungsten-tin greisen deposits throughout the world, especially the Hemerdon deposit in Devon, England. It is also analogous to Climax-type molybdenum deposits, which contain virtually identical mineral assemblages, but with the relative proportions of molybdenum and tungsten mineralization reversed, primarily owing to differences in oxygen fugacity. This similarity in mineralization styles and fluid histories indicates that metallogenic processes in granite-related deposits in the late Precambrian were similar to those seen in the Phanerozoic.

Economic Geology↗

Maps showing mineral resource assessment for porphyry and stockwork deposits of copper, molybdenum, and tungsten and for stockwork and disseminated deposits of gold and silver in the Butte 1° x 2° quadrangle, Montana

This report documents the assessment for potential occurrences of undiscovered porphyry and stockwork deposits of copper, molybdenum, and tungsten (porphyry Cu-Mo-W) and stockwork and disseminated deposits of gold and silver (disseminated Au-Ag) in the Butte 1 °X2° quadrangle. The Butte quadrangle, in west-central Montana, is one of the best known mineral producing regions in the U.S. Mining districts in the quadrangle, including the world famous Butte or Summit Valley district, have produced a variety of metallic and nonmetallic mineral commodities valued at more than $6.4 billion (at the time of production). Because of its importance as a mineral producing region, the Butte quadrangle was selected for study by the U.S. Geological Survey under the Conterminous United States Mineral Assessment Program (CUSMAP). Under this program, new data on geology, geochemistry, geophysics, geochronology, mineral resources, and remote sensing were collected and synthesized. The field and laboratory studies were supported, in part, by funding from the Geologic Framework and Synthesis Program and the Wilderness Program. The methods used in this resource assessment for porphyry Cu-Mo-W and disseminated Au-Ag deposits in the quadrangle include a compilation of all data, the development of descriptive occurrence models, and the analysis of data using techniques provided by a Geographic Information System (GIS). This map is one of several maps on the Butte 1 °X2° quadrangle. Other deposit types have been assessed for the Butte quadrangle, and maps (U.S. Geological Survey (USGS) Miscellaneous Investigation Series Maps) for each of the following have been prepared: Vein and replacement deposits of gold, silver, copper, lead, zinc, manganese, and tungsten (Elliott, Wallace, and others, 1992a) and skarn deposits of gold, silver, copper, tungsten, and iron (Elliott and others, 1992b ). Other publications resulting from this study include linear features map (Rowan and others, 1991 ); limonite and hydrothermal alteration map (Rowan and Segal, 1989); mineral occurrence maps (Elliott and others, 1986; Elliott, Loen, and others, 1992); and geologic maps (Wallace, 1987; Wallace and others, 1987).

Montana↗

Map showing mineral resource assessment for vein and replacement deposits of gold, silver, copper, lead, zinc, manganese, and tungsten in the Butte 1° x 2° quadrangle, Montana

The purpose of this report is to assess the potential for undiscovered vein and replacement deposits of gold, silver, copper, lead, zinc, manganese, and tungsten in the Butte 1° x 2° quadrangle. This quadrangle, in west-central Montana, is one of the most mineralized and productive regions in the United States. Its mining districts, including the world famous Butte or Summit Valley district, have produced a variety of metallic and nonmetallic mineral commodities valued at more than $6.4 billion. Because of its importance as a mineral producing region, the Butte quadrangle was selected for study by the U.S. Geological Survey under the Conterminous United States Mineral Assessment Program (CUSMAP). Under this program, new data on geology, geochemistry, geophysics, geochronology, mineral resources, and remote sensing were collected and synthesized. The field and laboratory studies were also supported by funding from the Geologic Framework and Synthesis Program and the Wilderness Program. The methods used in resource assessment include a compilation of all data into data sets, the development of a descriptive model for vein and replacement deposits in the quadrangle, and the analysis of data using techniques provided by the Geographic Information System (GIS). This map is one of a number of reports and maps on the Butte 1 °X2° quadrangle. Other publications resulting from this study include U.S. Geological Survey Miscellaneous Investigations Series Maps 1-2050-A (Rowan and Segal, in press) and I-2050-B (Purdy and Rowan, in press); Miscellaneous Field Studies Map MF-1925 (Wallace, 1987); and Open-File Reports 86-292 (Wallace and others, 1986) and 86--0632 (Elliott and others, 1986). Reports on mineral resource assessment for several other types of deposits in the Butte quadrangle are in preparation.

Montana↗