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J. Dougherty

Publications and source records attributed to J. Dougherty.

2 recordsLinked to original sources

Understanding shallow gas occurrences in the Gulf of Lions

New coring data have been acquired along the western Gulf of Lions showing anomalous concentrations of methane (up to 95,700 ppm) off the Rhône prodelta and the head of the southern canyons Lacaze-Duthiers and Cap de Creus. Sediment cores were acquired with box and kasten cores during 2004–2005 on several EuroSTRATAFORM cruises. Anomalous methane concentrations are discussed and integrated with organic carbon data. Sampled sites include locations where previous surveys identified acoustic anomalies in high-resolution seismic profiles, which may be related to the presence of gas. Interpretation of the collected data has enabled us to discuss the nature of shallow gas along the Gulf of Lions, and its association with recent sedimentary dynamics. The Rhône prodelta flood deposits deliver significant amounts of terrigenous organic matter that can be rapidly buried, effectively removing this organic matter from aerobic oxidation and biological uptake, and leading to the potential for methanogenesis with burial. Away from the flood-related sediments off the Rhône delta, the organic matter is being reworked and remineralized on its way along the western coast of the Gulf of Lions, with the result that the recent deposits in the canyon contain little reactive carbon. In the southernmost canyons, Lacaze-Duthiers and Cap de Creus, the gas analyses show relatively little shallow gas in the core samples. Samples with anomalous gas (up to 5,000 ppm methane) are limited to local areas where the samples also show higher amounts of organic matter. The anomalous samples at the head of the southern canyons may be related to methanogenesis of recent drape or of older sidewall canyon infills.

Gulf of Lions

Geochemical constraints on the distribution of gas hydrates in the Gulf of Mexico

Gas hydrates are common within near-seafloor sediments immediately surrounding fluid and gas venting sites on the continental slope of the northern Gulf of Mexico. However, the distribution of gas hydrates within sediments away from the vents is poorly documented, yet critical for gas hydrate assessments. Porewater chloride and sulfate concentrations, hydrocarbon gas compositions, and geothermal gradients obtained during a porewater geochemical survey of the northern Gulf of Mexico suggest that the lack of bottom simulating reflectors in gas-rich areas of the gulf may be the consequence of elevated porewater salinity, geothermal gradients, and microbial gas compositions in sediments away from fault conduits.

Geo-Marine Letters