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Holly J. Stein

Publications and source records attributed to Holly J. Stein.

8 recordsLinked to original sources

Ages and trace element fertility of porphyry-related mineralization in the Philipsburg polymetallic district, Montana, with a comparison to Butte

The Philipsburg mining district is a Mo-Cu porphyry system with associated Cordilleran polymetallic veins. Geochronology was employed to date the porphyry (~66 Ma, U/Pb in zircon) and molybdenite mineralization from the veins (~76 Ma, Re-Os). Age results suggest that the two-mineralization events model proposed by Lund et al. (2018) for the Butte district can be applied to the Philipsburg deposit. Furthermore, common fertility indicators from zircon trace elements were analyzed with variable success to characterize the existing Mo-Cu mineralization of the Philipsburg porphyry. This raises concerns about the benefits of this method and/or the importance of sampling, which could impact exploration for similar porphyry deposits.

Montana↗

Constraints on the genesis of Au veins in interior Alaska: Evidence from geochronology and vein textures

The origin of Au-bearing, low sulfide quartz veins in the Pogo and Tibbs Creek regions of interior Alaska remain enigmatic. Intrusion-related Au and mesozonal orogenic vein models have both been proposed (Thompson and Newberry, 2000; Rhys et al., 2003; Goldfarb et al., 2022; Dilworth et al., 2007). To date, studies of igneous geochronology and metamorphic timing have shown that gold veins formed between intervals of magmatism and post-date regional metamorphic fabrics. Relatively little description of detailed mineralogy, vein textures, and absolute timing of mineralization exist – resulting in new questions about the deposit origin. This study attempts to relate these parameters through investigation of new U-Pb crystallization and Re-Os mineralization ages combined with detailed descriptions of vein textures to constrain the origin of the veins.

Alaska↗

Timing and genesis of ore formation in the Qarachilar Cu-Mo-Au deposit, Ahar-Arasbaran metallogenic zone, NW Iran: Evidence from geology, fluid inclusions, O–S isotopes and Re–Os geochronology

In the Qarachilar Cu-Mo-Au deposit of the Ahar–Arasbaran metallogenic zone (AAMZ), northwest Iran, mineralization occurs as three quartz-sulfide veins that cut granodiorite-quartz monzodiorite rocks of the Qaradagh batholith (QDB). Ore formation can be divided into three stages, with chalcopyrite, molybdenite, and gold-bearing pyrite appearing mainly in the first two stages. The main wall-rock alteration is silicification, and intermediate argillic, carbonate, and propylitic alteration. Fluid inclusion microthermometry indicates trapping of medium- to high-salinity (9.2–55 wt% NaCl equiv.) fluids at Qarachilar. Fluid inclusion trapping conditions are estimated to be 190 °C–530 °C and 0.1–3 kbar. The variable phase ratios as well as spatial coexisting of liquid- and vapor-rich two-phase and halite-bearing multiphase fluid inclusions homogenizing over the same temperatures are consistent with fluid boiling during ore formation. Obtained δ 18 O H2O values of quartz from ore-stage veins are +5.7‰ to +9.7‰, signifying that the ore–fluid system was predominantly magmatic water. The average calculated δ 34 S H2S values are 1 ± 1‰ for pyrite, chalcopyrite and molybdenite, consistent with a magmatic source for sulfur. Combined, the fluid inclusion and stable isotope data indicate that the ore-forming fluids at Qarachilar were magmatic in origin and were subsequently cooled and diluted by meteoric water. Fluid boiling and mixing facilitated hydrothermal alteration and mineralization. Molybdenite Re–Os dating shows that mineralization occurred at 42.35 ± 0.16 Ma, coincident with formation of porphyry Cu-Mo mineralization at Agarak deposit, and Hanqasar, Aygedzor and Dastakert prospects in the Lesser Caucasus. However, Qarachilar is older than all porphyry Cu-Mo mineralization in the AAMZ and Urumieh-Dokhtar magmatic arc (UDMA), which suggests that collision between Arabia and Eurasia were oblique and thus diachronous. Our data suggest that mineralization at Qarachilar is related to collisional Eocene magmatic–hydrothermal activity related to Neo-Tethys subduction, and shares a number of similarities with the vein-type Cu-Mo-Au mineralization related to Cu-Mo porphyries.

Ore Geology Reviews↗

Radiometric dating of marine-influenced coal using Re–Os geochronology

Coal deposits are integral to understanding the structural evolution and thermal history of sedimentary basins and correlating contemporeous estuarine and fluvial delatic strata with marine sections. While marine shales may readily lend themselves to Re&ndash;Os dating due to the dominance of hydrogenous Re and Os, the lack of a chronometer for near-shore sedimentary environments hampers basinwide correlations in absolute time. Here, we employ the Re&ndash;Os geochronometer, along with total organic carbon (TOC) and Rock&ndash;Eval data, to determine the timing and conditions of a marine incursion at the top of the Matewan coal bed, Kanawha Formation, Pottsville Group, West Virginia, USA. The observed range for hydrogen index (HI: 267&ndash;290 mg hydrocarbon/gram total organic carbon) for these coal samples suggests dominance of aliphatic hydrocarbons with low carbon (<C 19 ) chain length. Average Re ( 107.6&plusmn;16.4 ng/g ) and Os ( 0.52&plusmn;0.09 ng/g ) concentrations of the marine-influenced Matewan coal are higher by few orders of magnitude than published data for terrestrial coal. A Re&ndash;Os isochron for the Matewan coal provides an age of 325&plusmn;14 Ma (Model 3; MSWD = 12; n=19 ; 2 &sigma; ). This is the first Re&ndash;Os age derived from coal samples; the age overlaps a new composite Re&ndash;Os age of 317&plusmn;2 Ma for the immediately overlying Betsie Shale Member. External precision for replicate Os analyses carried out for several Matewan coal samples shows a positive correlation with their HI. The HI, which is low in terrestrial organic matter, reflects the degree of marine influence. Thus, samples with the most profound marine influence also have the best analytical reproducibility. Equilibration of Os isotopes with seawater under marine conditions overwhelms variability inherited from terrestrial plant debris, decreasing scatter on the isochron. The 187 Re/ 188 Os ratios of the Matewan coal (&sim;3300&ndash;5135) are higher than most of those previously published for Phanerozoic black shale (mostly <2000). Mass balance calculations based on Re/TOC and Os/TOC ratios for the Matewan coal indicate that both Re and Os are primarily marine in origin, and their high 187 Re/ 188 Os ratios confirm efficient removal of both elements from a sulfidic water column into the coal. We show that Re&ndash;Os geochronology of marine-influenced coal can be a viable tool for constraining depositional ages.

West Virginia↗

Ad Duwayhi, Saudi Arabia: Geology and geochronology of a neoproterozoic intrusion-related gold system in the Arabian shield

The Ad Duwayhi gold deposit, located in the east-central part of the Arabian shield, is the newest gold discovery in Saudi Arabia. Exploration to date has identified a gold resource of greater than 1 million ounces (oz) with significant potential for expansion. Gold mineralization was closely associated, in time and space, with emplacement of a late- to postorogenic, intracrustal, northwest-oriented granite body (659 &plusmn; 7 Ma) and comagmatic square quartz porphyry (646 &plusmn; 11 Ma), a hypabyssal and perhaps younger phase of the granite. Mineralization was largely confined to northeast-striking, southeast-dipping fault zones. Hydrothermal alteration consisted of early biotitic alteration overprinted by sericitic alteration. Sericitic alteration was coincident with gold mineralization and produced a quartz-sericite-carbonate-pyrite-rutile mineral assemblage, found both as vein fill and wall-rock alteration products. Mineralization styles, in the following general paragenetic sequence, include (1) quartz-molybdenite veins in and near the granite stock, (2) low-grade gold-bearing quartz vein breccia in and along the margins of the granite stock, (3) gold-bearing stockwork and sheeted quartz veins, and (4) massive to banded gold-rich tabular quartz veins. The gold-bearing stockwork, sheeted, and tabular veins are generally spatially associated with square quartz porphyry dikes and more distal to the granite stock. Mineralized zones at Ad Duwayhi are characterized by low sulfide and base metal content and gold/silver ratios of approximately 6/1. Gold shows no significant correlation with other metals, except lead, and moderate correlation with silver. Re-Os dating of molybdenite from a quartz-molybdenite vein and a tabular quartz vein with cogenetic gold produced robust ages of 655.6 &plusmn; 2.7 and 649.9 &plusmn; 2.3 Ma, respectively, documenting that gold mineralization and crystallization of granite and square quartz porphyry were, within uncertainty, coeval events. This age correlation combined with granite textural features, the presence of unidirectional solidification textures in granite and square quartz porphyry, and the nature and time-space distribution of mineralization styles, all indicate that mineralization evolved in and near the interface between a crystallizing magma and the surrounding rocks and, thus, is consistent with an intrusion-related genesis. In light of our findings at Ad Duwayhi, a reassessment of similar intrusion-hosted deposits in the Arabian shield is warranted, and areas of late- to postorogenic plutonism, particularly in the Afif composite terrane, should be considered prospective for intrusion-related gold systems.

Economic Geology↗

Tectonic evolution of the Proterozoic Colorado Province, Southern Rocky Mountains: A summary and appraisal

The Colorado province is a major component of a >1000-km-wide belt of Paleoproterozoic ocean-arc rocks that occupies the southwestern United States. Known as the Transcontinental Proterozoic provinces, this belt of largely juvenile rocks was added to the southern margin of the North American craton during the interval 1.8-1.70 Ga by convergent tectonism along the Cheyenne belt. A growing body of data suggests that these rocks were deposited, at least locally, on older rocks of earliest Proterozoic and Archean ages, probably correlative with the Trans-Hudson and Penokean orogens. The volcano-plutonic and associated sedimentary rocks of the Colorado province record two major, regional orogenies: (1) an older, protracted thermotectonic episode (1.78-1.70 Ga), named the Colorado orogeny, which involved mainly amphibolite-facies metamorphism during piecemeal assembly of various ocean-arc terranes; and (2) a younger, Mesoproterozoic intra-continental orogeny, named the Berthoud orogeny, which involved associated regional heating and A-type plutonism chiefly during the interval 1.45-1.40 Ga. The term "Colorado orogeny" is proposed for the regional Paleoproterozoic dynamothermal deformation. To distinguish differences in the geodynamics and ages of deformation and facilitate comparisons from place to place, type localities are proposed for separate phases or events of the Colorado orogeny. The central Front Range is suggested as a type area for the Berthoud orogeny, because the character and orientation of structures there are readily distinguished from those of the older Colorado orogeny.

Colorado↗

Geochemistry, geochronology, mineralogy, and geology suggest sources of and controls on mineral systems in the southern Toquima Range, Nye County, Nevada

Geochemistry maps showing the distribution and abundance of 18 elements in about 1,400 rock samples, both mineralized and unmineralized, from the southern Toquima Range, Nev., indicate major structural and lithologic controls on mineralization, and suggest sources of the elements. Radiometric age data, lead mineralogy and paragenesis data, and lead-isotope data supplement the geochemical and geologic data, providing further insight into timing, sources, and controls on mineralization. Major zones of mineralization are centered on structural margins of calderas and principal northwest-striking fault zones, as at Round Mountain, Manhattan, and Jefferson mining districts, and on intersections of low-angle and steep structures, as at Belmont mining district. Paleozoic sedimentary rocks, mostly limestones (at Manhattan, Jefferson, and Belmont districts), and porous Oligocene ash-flow tuffs (at Round Mountain district) host the major deposits, although all rock types have been mineralized as evidenced by numerous prospects throughout the area. Principal mineral systems are gold-silver at Round Mountain where about 7 million ounces of gold and more than 4 million ounces of silver has been produced; gold at Gold Hill in the west part of the Manhattan district where about a half million ounces of gold has been produced; gold-mercury-arsenic-antimony in the east (White Caps) part of the Manhattan district where a few hundred thousand ounces of gold has been produced; and silver-lead-antimony at Belmont where more than 150,000 ounces of silver has been produced. Lesser amounts of gold and silver have been produced from the Jefferson district and from scattered mines elsewhere in the southern Toquima Range. A small amount of tungsten was produced from mines in the granite of the Round Mountain pluton exposed east of Round Mountain, and small amounts of arsenic, antimony, and mercury have been produced elsewhere in the southern Toquima Range. All elements show unique distribution patterns that suggest specific sources and lithologic influences on deposition, as well as multiple episodes of mineralization. Principal episodes of mineralization are Late Cretaceous (molybdenum and tungsten in and near granite; silver at Belmont and Silver Point mines), early Oligocene [tourmaline and base- and precious-metals around the granodiorite of Dry Canyon stock as well as at Manhattan(?)], late Oligocene (gold at Round Mountain and Jefferson), and Miocene (gold at Manhattan). Most likely principal sources of molybdenum, tungsten, silver, and bismuth are Cretaceous granites; of antimony, arsenic, and mercury are intermediate-composition early Oligocene intrusives; and of gold are early and late Oligocene and early Miocene magmas of the volcanic cycle. Lead may have been derived principally from Cretaceous granitic magma and Paleozoic sedimentary rocks. Several areas prospective for undiscovered mineral deposits are suggested by spatial patterns of element distributions related to geologic features. The Manhattan district in the vicinity of the White Caps mine may be underlain by a copper-molybdenum porphyry system related to a buried stock; peripheral high-grade gold veins and skarn deposits may be present below deposits previously mined. The Jefferson district also may be underlain by a copper-molybdenum porphyry system related to a buried stock, it too with peripheral high-grade gold deposits. The Bald Mountain Canyon belt of small gold veins has potential for deeper deposits in buried porous ash-flow tuff similar to the huge Round Mountain low-grade gold-silver deposit. Several other areas have potential for a variety of mineral deposits. Altogether the geochemical, geochronologic, mineralogic, and geologic evidence suggests recurring mineralizing episodes of varied character, from Late Cretaceous to late Tertiary time, related to a long-lived hot spot deep in the crust or in the upper mantle. Granite plutons of Late Cretaceous age were minerali

Nevada↗