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Henrieta Dulaiova

Publications and source records attributed to Henrieta Dulaiova.

5 recordsLinked to original sources
USGS2016

Isotopic constraints on the genesis and evolution of basanitic lavas at Haleakala, Island of Maui, Hawaii

To understand the dynamics of solid mantle upwelling and melting in the Hawaiian plume, we present new major and trace element data, Nd, Sr, Hf, and Pb isotopic compositions, and 238 U– 230 Th– 226 Ra and 235 U– 231 Pa– 227 Ac activities for 13 Haleakala Crater nepheline normative basanites with ages ranging from ∼900 to 4100 yr B.P. These basanites of the Hana Volcanics exhibit an enrichment in incompatible trace elements and a more depleted isotopic signature than similarly aged Hawaiian shield lavas from Kilauea and Mauna Loa. Here we posit that as the Pacific lithosphere beneath the active shield volcanoes moves away from the center of the Hawaiian plume, increased incorporation of an intrinsic depleted component with relatively low 206 Pb/ 204 Pb produces the source of the basanites of the Hana Volcanics. Haleakala Crater basanites have average ( 230 Th/ 238 U) of 1.23 ( n = 13), average age-corrected ( 226 Ra/ 230 Th) of 1.25 ( n = 13), and average ( 231 Pa/ 235 U) of 1.67 ( n = 4), significantly higher than Kilauea and Mauna Loa tholeiites. U-series modeling shows that solid mantle upwelling velocity for Haleakala Crater basanites ranges from ∼0.7 to 1.0 cm/yr, compared to ∼10 to 20 cm/yr for tholeiites and ∼1 to 2 cm/yr for alkali basalts. These modeling results indicate that solid mantle upwelling rates and porosity of the melting zone are lower for Hana Volcanics basanites than for shield-stage tholeiites from Kilauea and Mauna Loa and alkali basalts from Hualalai. The melting rate, which is directly proportional to both the solid mantle upwelling rate and the degree of melting, is therefore greatest in the center of the Hawaiian plume and lower on its periphery. Our results indicate that solid mantle upwelling velocity is at least 10 times higher at the center of the plume than at its periphery under Haleakala.

Hawaii↗
USGS2014

Mercury dynamics in a coastal aquifer: Maunalua Bay, Oʻahu, Hawaiʻi

We evaluated the influence of groundwater–seawater interaction on mercury dynamics in Maunalua Bay, a coral reef ecosystem located on the south shore of Oʻahu, Hawaiʻi, by combining geochemical data with submarine groundwater discharge (SGD) rates. During a rising tide, unfiltered total mercury (U-HgT) concentrations in seawater increased from ∼6 to 20 pM at Black Point (west Bay) and from ∼2.5 to 8 pM at Niu (central Bay). We attribute this change to an increase in suspended particulate matter at high tide. Approximately 90% of mercury in groundwater at Niu was in the filtered (<0.45 μm) fraction, with a concentration of ∼4 pM. Groundwater discharge during a period of amplified SGD at Niu appeared to contribute to an increase in total mercury concentrations in filtered seawater (F-HgT; 1.2 to 2.4 pM) and in unfiltered seawater (U-HgT; 2.5 to 3.2 pM). The larger magnitude of change in F-HgT relative to U-HgT suggests mercury complexation and/or solubility dynamics in seawater were altered by the addition of groundwater. We used site specific 222 Rn derived SGD flux estimates and groundwater F-HgT concentrations to calculate mercury loadings at Black Point (∼3 nmol m −2 d −1 ) and at Niu (∼1 nmol m −2 d −1 ). We calculated a weighted average Maunalua Bay groundwater mercury flux of 0.68 ± 0.67 mol yr −1 by combining the proportional flux of F-HgT from three distinct SGD zones, and place these results into a broader context by comparing and contrasting flux estimates from locations around the world. Results from existing SGD studies should be evaluated to develop future sampling strategies that address more targeted questions about mercury biogeochemical cycling at the groundwater–seawater interface.

Hawai'i↗
USGS2012

Utilizing multichannel electrical resistivity methods to examine the dynamics of the fresh water–seawater interface in two Hawaiian groundwater systems

Multichannel electrical resistivity (ER) measurements were conducted at two contrasting coastal sites in Hawaii to obtain new information on the spatial scales and dynamics of the fresh water&ndash;seawater interface and rates of coastal groundwater exchange. At Kiholo Bay (located on the dry, Kona side of the Big Island) and at a site in Maunalua Bay (Oahu), there is an evidence for abundant submarine groundwater discharge (SGD). However, the hydrologic and geologic controls on coastal groundwater discharge are likely to be different at these two sites. While at Kiholo Bay SGD is predominantly through lava tubes, at the Maunalua Bay site exchange occurs mostly through nearshore submarine springs. In order to calculate SGD fluxes, it is important to understand the spatial and temporal scales of coastal groundwater exchange. From ER time series data, subsurface salinity distributions were calculated using site-specific formation factors. A salinity mass balance box model was then used to calculate rates of point source (i.e., spatially discreet) and total fresh water discharge. From these data, mean SGD rates were calculated for Kiholo Bay (&sim;9,200 m 3 /d) and for the Maunalua Bay site (&sim;5,900 m 3 /d). While such results are on the same order of magnitude to geochemical tracer-derived SGD rates, the ER SGD rates provide enhanced details of coastal groundwater exchange that can enable a more cohesive whole watershed perspective.

Hawai'i↗
USGS2004

Novel geophysical and geochemical techniques used to study submarine groundwater discharge in Biscayne Bay, Florida

Introduction Submarine groundwater discharge (SGD) is a problem of major proportions on a world-wide scale. The ubiquitous nature of SGD along varied coastlines and its importance to coastal water and geochemical budgets have recently been thrust into the global spotlight . For example, the discharge of nutrient-enriched groundwater into coastal waters may cause nutrient imbalances that can lead to eutrophication or near-shore micro-organism blooms . Similarly, SGD can also directly affect threatened coastal freshwater resources and impact fragile coastal ecosystems, such as coral reefs. Recently, much effort has been devoted to developing and adapting new tracer techniques and methods for the identification and quantification of SGD. As the discharge of coastal groundwater most often occurs as diffuse seepage rather than through a single vent feature, assessing SGD has remained difficult for both oceanographers and hydrologists alike. Burnett and colleagues have developed a systematic approach to investigate SGD by using a combination of both physical seepage measurements and a suite of naturally occurring isotopic tracers in the U/Th decay chain – 222 Rn and 223,224,226,228 Ra. Manheim et al. further extended SGD investigations by adapting geophysical resistivity techniques to examine fine-scale change in conductivity fields within coastal sediments. Such streaming resistivity profiling has been successfully applied to identify sites of SGD, as well as the dynamic position of the fresh water/saltwater interface.

Florida↗