Geology topics

Heather A. Lowers

Publications and source records attributed to Heather A. Lowers.

At least 55 records · Page 3Linked to original sources

USGS2022

Demonstration of a novel quantitative microscopy technique for automated characterization of in situ particulate matter in coal miners with progressive massive fibrosis

Rationale: Increasing exposure to respirable crystalline silica (RCS) linked to changes in mining production processes has been implicated in the resurgence of severe lung disease in U.S. coal miners. Lung mineralogy can provide insight into particle pathogenesis. However, standard approaches to characterizing in situ particulate matter (PM) by pulmonary pathologists have poor inter-rater comparability, and consensus agreement is time consuming. Scanning electron microscopy/energy-dispersive spectroscopy (SEM/EDX) is technically complex and labor intensive. We developed a method for quantitative in situ PM characterization using conventional polarized light microscopy (PLM) and explored PM features in lung tissue of coal miners with progressive massive fibrosis (PMF). Methods: With institutional review board approval, PLM images were obtained from 30 miners with PMF, classified by pathologists consensus based on PM profusion; 10 from each profusion group (mild/moderate/severe) were selected. Automated PM counting and characterization (including dimensions and grayscale intensity of PM > 0.3 m diameter) was performed on image samples using PLM with modified cell-counting software (BZ-X800 light microscope, Keyence Corporation, Osaka, Japan) (Figure 1). Quantitative PM density loge(PM count)/mm3 tissue was calculated for each sample and compared to pathologist PM profusion groups. PMF lesion type using consensus pathologist classification (13 coal-type, 9 mixed-type, and 8 silicotic-type) was compared to automated PM birefringence level (% particles with mean grayscale intensity <65, range 0-255). RCS particles are expected to be weakly birefringent (lower intensity) relative to other common minerals (e.g., silicates) contained in coal mine dust. PM features were analyzed in R 4.0.3 using one-way ANOVA for between-group comparisons. Results: Measured PM log-density increased significantly with higher qualitative profusion group (mild=10.480.98/mm3, moderate=11.460.81/mm3, severe=12.520.86/mm3, p<0.0001). Prevalence of weakly birefringent particles was significantly higher among silicotic-type PMF samples (31.57.9%) compared to either coal-type (21.510.1%, p=0.022) or mixed-type lesions (21.510.5%, p=0.025). Conclusion: This pilot study demonstrates the feasibility of a novel quantitative microscopy technique for counting and characterizing in situ lung PM in coal miners with PMF. Quantitative PM burden was comparable to pulmonary pathologists consensus profusion classification, but this method was substantially less time consuming and labor intensive and provided additional information about relevant PM features. The higher prevalence of weakly birefringent particles seen in silicotic-type PMF lesions may help inform mineralogic pathogenesis of RCS. Future efforts will expand the number of PMF cases analyzed, further validate our mineralogic findings using data from SEM/EDX and lung tissue digestate methods, and compare findings in historical versus contemporary coal miners with PMF.

Conference Paper↗

USGS2022

Petrogenesis and rare earth element mineralization of the Elk Creek carbonatite, Nebraska, USA

Although carbonatites are the primary source of the world’s rare earth elements (REEs), the processes responsible for ore-grade REE enrichment in carbonatites are still poorly understood. In this study, we present a petrologic, geochemical, and isotopic evaluation of the Elk Creek carbonatite in southeast Nebraska to constrain the origin of REE mineralization. The Elk Creek carbonatite is a multilithologic carbonatite comprised of an early apatite-dolomite carbonatite, a middle/heavy REE-enriched magnetite-dolomite carbonatite, and a late-stage light REE-enriched, barite-dolomite carbonatite, as well as a suite of breccias. Neodymium, strontium, and carbon isotopic data from the early apatite-dolomite carbonatite, ε Nd (T) = 2.3 to 3.4, 87 Sr/ 86 Sr (i) = 0.702704 to 0.702857, and δ 13 C = −3.3 to −3.4, indicate that the parental magma and REEs were derived from the mantle, and textural and chemical data suggest that hydrothermal processes played an important role in reaching ore-grade enrichment. Higher initial 87 Sr/ 86 Sr values (∼0.7041) of REE-mineralized lithologies are evidence that these fluids were derived, in part, from meteoric water that interacted with the country rock. Modeling of the C-O isotopic data reveals that some of the isotopic variation results from closed-system Rayleigh fractionation of an evolving carbonatitic magma between 300 and 500 °C, but an excursion to heavier δ 18 O is likely the result of interaction with H 2 O-CO 2 -fluids at temperatures from 400 to 100 °C. Hydrothermal dolomite has higher 87 Sr/ 86 Sr values than early-formed magmatic dolomite, consistent with metasomatism by fluids derived, in part, from a more radiogenic source such as the Precambrian-age wall rock. Rare earth element mineralization occurs primarily in fine-grained, cavity filling minerals including monazite, bastnäsite, parisite, and synchysite along with barite, dolomite, quartz, and iron oxides. We interpret the LREE enrichment at Elk Creek to be the product of hydrothermal fluids derived from the evolving carbonatite magma and fluids from the wall rock. The REEs likely became enriched in late-stage fluids from the evolving magma as well as being remobilization by the dissolution of earlier formed minerals. Middle/heavy REE-enrichment in the magnetite-dolomite carbonatite is hosted in hydrothermal dolomite and is attributed to variations in the composition of hydrothermal fluids.

Nebraska↗

USGS2022

Indicator mineral analyses of stream-sediment samples using automated mineralogy and mineral chemistry: Applicability to exploration in covered terranes in eastern Alaska, USA

In the past two decades, significant research efforts have been devoted to porphyry copper indicator mineral (PCIM) identification and mineral chemistry to assist exploration. Such studies are important in the Yukon-Tanana upland region of eastern Alaska because well-established geochemical exploration techniques, such as the geochemistry of stream-sediment samples, are less effective in the search for mineral resources owing to cover materials that subdue geochemical signatures. The unglaciated Yukon-Tanana upland region is well-endowed with mineral resources, including porphyry Cu-Mo-Au deposits at Taurus, Bluff, Dennison, and Oreo. Using automated scanning electron microscope (SEM) techniques, numerous PCIMs have been identified in rocks and stream-sediment samples that would likely not have been observed using visual binocular microscope methods. Sulfide minerals such as chalcopyrite, chalcocite, covellite, bornite, molybdenite, and pyrrhotite were identified in rock samples, and more than half of the stream-sediment samples from drainages containing known porphyry mineral occurrences contain chalcopyrite with or without bornite. Many drainages without known occurrences also contain these minerals, which suggests potential for additional occurrences. Svanbergite, an aluminum phosphate sulfate (APS) mineral [SrAl 3 (PO 4 )(SO 4 )(OH) 6 ], was identified in some of the altered or mineralized rock samples from Taurus, and in stream drainages containing porphyry occurrences and may represent the best indicator mineral for Taurus-like porphyry deposits. Apatite chemistry has great potential as a tool for assessing the presence of porphyry mineralization. Grains from rock and stream-sediment samples that contain high Cl (>∼0.4 wt%), Fe (>0.4 wt%), and Mn (>2000 ppm) clearly distinguish apatite from other sources (metamorphic, unmineralized igneous rocks). This study is one of the first to document new streamlined indicator mineral sample collection and processing methods and to combine automated SEM techniques and chemistry of minerals derived from both bedrock and surficial (stream) sediments as they apply to porphyry exploration.

Alaska↗

USGS2021

Approach for quantifying rare Earth elements at low keV

The challenges of analyzing bastnaesite (REECO3F) and hydroxylbastnaesite (REECO3OH) include beam sensitivity, quantification of light elements in a heavy element matrix, the presence of elements that cannot be analyzed with EPMA (H), and the use of x-ray lines whose physical constants are not well known. To overcome some of these challenges, Ca, La, Ce, Pr, Nd, and Sm were analyzed at 15 keV accelerating voltage and the light elements (C, O, F) were analyzed at 7 keV accelerating voltage. This approach is ideal for samples that are homogeneous within the volume analyzed. However, for the bastnaesite of interest, this solution is unsatisfactory as backscattered electron imaging reveals chemical variations at scales of less than 1 m (fig. 1). Monte Carlo simulations and wavescans of the REE M family of x-rays were evaluated to determine the best analytical approach. Monte Carlo simulations using Casino v2.42 were ran on a substrate of CeCO3F with a density of 5.00 g/cm3 at 15 keV and 7 kCV accelerating voltage. Depth distribution curves, φ(ρz), reveal x-ray generation at 15 keV for the Ce L shell x-rays approaches 1.0 m whereas the depth of Ce M shell x-ray generation at 7 keV is less than 0.4 m. Similarly, the K shell x-ray generation depth for C, O, and F at 7 keV is also less than 0.4 m. These simulations demonstrate an accelerating voltage of 7 keV or less and use of the REE M x-rays is necessary to acquire chemical information from the same volume of material for the light and heavy elements. Bastnaesite contains all REE and therefore one must consider the energy of the highest x-ray line of interest, namely the Lu M at 1.83 kV, to achieve an overvoltage (Eo/Ec) of over 2. Bastnaesite is also an insulator and requires a conductive coating, therefore 7 keV was used to avoid contributions of the coating material to the analysis given the above constraints. The USNM REE phosphate standards, Edinburgh REE glasses, CeO2, LaB6, and the metals of Sm, Dy, Gd, Er, and Yb were selected to evaluate the peak overlaps of the M family x-ray lines. The materials were coated with ~ 5nm iridium with a Leica ACE600 prior to analysis. Full spectrometer wavescans were collected at 7 keV accelerating voltage, 50 nA beam current, and 20 um beam diameter on a JEOL 8530F Plus using TAP and TAPL crystals. The step size was 0.109 mm along the length of the spectrometer with a dwell of 3 seconds at each step. M and M lines are broad and not individually resolved for the light REE but become more separated and sharper with increasing atomic number. M and M lines for each REE are also present across the spectrometer range further complicating peak interference corrections. The peak positions and overall shape for the Ce M and M lines vary with the coordination of the element. Significant shifts in position and shape were not observed when comparing the Ce M peaks of CeO2 and CePO4. Similar results were seen when comparing the available REE metal to the phosphate (Sm, Dy, Gd, Er, Yb). These wavescans suggest the use of the M or M lines if matrix matched standards are not available.

Microscopy and Microanalysis↗

USGS2021

Pathology and mineralogy demonstrate respirable crystalline silica is a major cause of severe pneumoconiosis in US coal miners

Rationale: The reasons for resurgent coal workers’ pneumoconiosis and its most severe forms, rapidly progressive pneumoconiosis and progressive massive fibrosis (PMF), in the United States (US) are not yet fully understood. Objective: To compare the pathologic and mineralogic features of contemporary coal miners suffering severe pneumoconiosis to their historical counterparts. Methods: Lung pathology specimens from 85 coal miners with PMF were included for evaluation and analysis. We compared the proportion of cases with pathologic and mineralogic findings in miners born between 1910 and 1930 (historical) to those born in or after 1930 (contemporary). Results: We found a significantly higher proportion of silica-type PMF (57% vs. 18%, p<0.001) among contemporary miners compared to their historical counterparts. Mineral dust alveolar proteinosis (MDAP) was also more common in contemporary miners compared to their historical counterparts (70% vs. 37%, p<0.01). In situ mineralogic analysis showed the percentage (26.1% vs. 17.8%, p<0.01) and concentration (47.3 x 108 vs. 25.8 X 108 particles/cm3, p=0.036) of silica particles was significantly greater in specimens from contemporary miners compared to their historical counterparts. The concentration of silica particles was significantly greater when silica-type PMF, MDAP, silicotic nodules, or immature silicotic nodules were present (p<0.05). Conclusions: Exposure to respirable crystalline silica appears causal in the unexpected surge in severe disease in contemporary miners. Our findings underscore the importance of controlling workplace silica exposure in order to prevent the disabling and untreatable adverse health effects afflicting US coal miners. Primary Source of Funding: Alpha Foundation for the Improvement of Mine Safety and Health, Inc.

Annals of the American Thoracic Society↗

USGS2019

Pyritization history in the middle to upper Cambrian Alum Shale, Scania Sweden: Evidence for ongoing diagenetic processes

Detailed diagenetic studies of the late Cambrian Alum Shale in southern Sweden were undertaken across an interval that includes the peak Steptoean Positive Carbon Isotope Excursion (SPICE) event to evaluate the pyrite mineralization history in the formation. Samples were collected from the Andrarum-3 core (Scania, Sweden); here the Alum was deposited in the distal, siliciclastic mudstone-rich end of a shelf system. Abundant cryptobioturbation is observed in the Alum, which points to oxic–dysoxic conditions prevailing during deposition. Petrographic examination of polished thin sections ( n = 65) reveals the presence of numerous texturally distinct types of pyrite, including matrix framboids, two different types of framboid concretions (those with rims of iron-dolomite and those lacking rims), disseminated euhedral pyrite crystals, concretions of euhedral pyrite crystals, overgrowths of pyrite on these different pyrite generations, anhedral pyrite intergrown with bedding parallel mineralized fractures (i.e., “beef”), and massive vertical/subvertical accumulations of pyrite. Paragenetic relationships outline the relative timing of formation of the texturally distinct pyrite. Framboids and framboid concretions formed prior to precipitation of any euhedral pyrite crystals, and these pyrite generations precipitated prior to the pyrite overgrowths on them. As Alum Shale sediments are all distorted by these texturally different pyrite generations, they are likely to have formed early in the postdepositional history of the formation. In contrast, pyrite associated with “beef” is likely temporally related to the onset of hydrocarbon generation, which in this part of Sweden is thought to have been many tens of millions of years after deposition. Because vertical/subvertical massive pyrite features distort “beef,” they clearly postdate it. Of all these pyrite textures, only framboid concretions appear to be restricted to the SPICE interval. The texturally distinct nature of the pyrite generations, along with evidence of their formation at different times in the postdepositional history of the Alum Shale, is the key outcome of this petrographic study. Because the petrographic data presented herein point to a postdeposition origin for all generations of pyrite, diagenetic processes—not those processes associated with deposition—were responsible for the complex pyritization history observed in the Alum, in the Andrarum-3 core.

Scania↗

USGS2019

Geochemistry of hematite veins in IOA-IOCG deposits of SE Missouri, USA: Relation to felsic magmatism and caldera lakes

The paragenesis, textures, and chemical compositions of secondary hematite in regional potassic altered rhyolites, four IOA deposits, the sedimentary iron deposit at Pilot Knob and the Boss IOCG deposit in SE Missouri were determined and compared to primary magnetite from the IOA and IOCG deposits. Magnetite is composed of elements characteristics of mafic to intermediate intrusions whereas hematite is enriched in elements characteristic of felsic igneous rocks. These results suggest that magnetite formed from fluids discharged from mafic to intermediate composition intrusions. Hematite precipitated from fluids discharged from felsic intrusions or fluids that evolved in caldera lakes. Hematite in the sedimentary iron deposit at Pilot Knob formed in an evaporative caldera lake with fluid inputs from felsic intrusions.

Missouri↗

USGS2019

Absence of magnetite microlites, geochemistry of magnetite veins and replacements in IOA deposits, SE Missouri, USA: Relations to intermediate intrusions

The paragenesis, textures, and chemical compositions of magnetite in two mafic to intermediate intrusions and four IOA deposits in SE Missouri were studied to discriminate between igneous and hydrothermal sources. In this study, we found that replacement magnetite with mineral inclusion-rich cores yields erroneously high Ti, Al, Si, Mg, and Mn contents as determined by EMP and LA-ICP-MS due to rutile and silicate inclusions. Thus, identification of high-Ti microlites on the basis of inclusion-rich cores with high Ti contents is an analytical artefact. Since the high-Ti magnetite microlite flotation model is critically dependent on this type of analysis, it may be invalid. The presence of coarse-grained high-Ti vein magnetite with ilmenite lamellae enveloped by replacement magnetite with inclusion-rich cores in ore zones suggests that the veins were high-temperature conduits for low-temperature replacement ores. The trace element compositions of vein and replacement magnetite suggest that iron was sourced from mafic to intermediate intrusions. These results support a magmatic-hydrothermal origin for IOA systems in SE Missouri.

Missouri↗

USGS2018

The complexity of mudstone diagenesis - some insight from the Tøyen Formation, Lower to Middle Ordovician, southern Sweden

The Lower to Middle Ordovician Tøyen Shale in southern Sweden, a biostratigraphically well-dated siliciclastic mudstone unit, shows 18 distinct authigenic cements that include sulfides, carbonates, silicates, clays, and phosphates. Marcasite, sphalerite, galena, and six texturally distinct types of pyrite characterize the sulfides whereas only one type of dolomite and three different generations of calcite are observed in this unit. Quartz, phosphate, and organic matter occur as only one generation each. Authigenic clay minerals are represented by chlorite and kaolinite. The paragenetic sequence of cements is subdivided into the two pre-burial carbonates, succeeded by ten relatively early burial cements, and six late burial cements, the kaolinite being the latest of them all and potentially being of Cretaceous age. Based on textural relationships, the paragenetic sequence of alterations started with dolomite precipitation followed by calcite, and then five different generations of pyrite. All eleven other phases post-date these initial seven cements in the Tøyen Shale.

GFF↗

USGS2018

Method to characterize inorganic particulates in lung tissue biopsies using field emission scanning electron microscopy

Humans accumulate large numbers of inorganic particles in their lungs over a lifetime. Whether this causes or contributes to debilitating disease over a normal lifespan depends on the type and concentration of the particles. We developed and tested a protocol for in situ characterization of the types and distribution of inorganic particles in biopsied lung tissue from three human groups using field emission scanning electron microscopy (FE-SEM) combined with energy dispersive spectroscopy (EDS). Many distinct particle types were recognized among the 13 000 particles analyzed. Silica, feldspars, clays, titanium dioxides, iron oxides and phosphates were the most common constituents in all samples. Particles were classified into three general groups: endogenous , which form naturally in the body; exogenic particles, natural earth materials; and anthropogenic particles, attributed to industrial sources. These in situ results were compared with those using conventional sodium hypochlorite tissue digestion and particle filtration. With the exception of clays and phosphates, the relative abundances of most common particle types were similar in both approaches. Nonetheless, the digestion/filtration method was determined to alter the texture and relative abundances of some particle types. SEM/EDS analysis of digestion filters could be automated in contrast to the more time intensive in situ analyses.

Toxicology Mechanisms and Methods↗

USGS2018

Characterizing the source of potentially asbestos-bearing commercial vermiculite insulation using in situ IR spectroscopy

Commercially produced vermiculite insulation from Libby, Montana, contains trace levels of asbestiform amphibole, which is known to cause asbestos-related diseases. When vermiculite insulation is found in a building, evaluation for its potential asbestos content traditionally involves collecting a sample from an attic or wall and submitting it for time-consuming analyses at an off-site laboratory. The goal of this study was to determine if in situ near-infrared reflectance measurements could be used to reliably identify the source of vermiculite ore and therefore its potential to contain asbestos. Spectra of 52 expanded ore samples, including attic insulation, commercial packing materials, and horticultural products from Libby, Montana; Louisa, Virginia; Enoree, South Carolina; Palabora, South Africa; and Jiangsu, China, were measured with a portable spectrometer. The mine sources for these vermiculite ores were identified based on collection location, when known, and on differences in elemental composition as measured by electron probe microanalysis. Reflectance spectra of the insulation samples show vibrational overtone and combination absorptions that vary in wavelength position and relative intensity depending on elemental composition and proportions of their constituent micas (i.e., vermiculite ore usually consists of a mixture of hydrobiotite and vermiculite mineral flakes). Band depth ratios of the 1.38/2.32, 1.40/1.42, and 2.24/2.38 μm absorptions allow determination of a vermiculite insulation's source and detection of its potential to contain amphibole, talc, and/or serpentine impurities. Spectroscopy cannot distinguish asbestiform vs. non-asbestiform amphiboles. However, if the spectrally determined mica composition and mineralogy of an insulation sample is consistent with ore from Libby, then it is likely that some portion of the sodic-calcic amphibole it contains is asbestiform, given that all of the nearly two dozen Libby vermiculite insulation samples examined with scanning electron microscopy in this study contain amphiboles. One sample of expanded vermiculite ore from multiple sources was recognized as a limitation of the spectral method, therefore an additional test (i.e., 2.24 μm absorption position vs. 2.24/2.38 μm band depth ratio) was incorporated into the spectral method to eliminate misclassification caused by such mixtures. With portable field spectrometers, the methodology developed can be used to determine vermiculite insulation's source and estimate its potential amphibole content, thereby providing low-cost analysis with onsite reporting to property owners.

American Mineralogist↗

USGS2017

USGS Spectral Library Version 7

We have assembled a library of spectra measured with laboratory, field, and airborne spectrometers. The instruments used cover wavelengths from the ultraviolet to the far infrared (0.2 to 200 microns [μm]). Laboratory samples of specific minerals, plants, chemical compounds, and manmade materials were measured. In many cases, samples were purified, so that unique spectral features of a material can be related to its chemical structure. These spectro-chemical links are important for interpreting remotely sensed data collected in the field or from an aircraft or spacecraft. This library also contains physically constructed as well as mathematically computed mixtures. Four different spectrometer types were used to measure spectra in the library: (1) Beckman™ 5270 covering the spectral range 0.2 to 3 µm, (2) standard, high resolution (hi-res), and high-resolution Next Generation (hi-resNG) models of Analytical Spectral Devices (ASD) field portable spectrometers covering the range from 0.35 to 2.5 µm, (3) Nicolet™ Fourier Transform Infra-Red (FTIR) interferometer spectrometers covering the range from about 1.12 to 216 µm, and (4) the NASA Airborne Visible/Infra-Red Imaging Spectrometer AVIRIS, covering the range 0.37 to 2.5 µm. Measurements of rocks, soils, and natural mixtures of minerals were made in laboratory and field settings. Spectra of plant components and vegetation plots, comprising many plant types and species with varying backgrounds, are also in this library. Measurements by airborne spectrometers are included for forested vegetation plots, in which the trees are too tall for measurement by a field spectrometer. This report describes the instruments used, the organization of materials into chapters, metadata descriptions of spectra and samples, and possible artifacts in the spectral measurements. To facilitate greater application of the spectra, the library has also been convolved to selected spectrometer and imaging spectrometers sampling and bandpasses, and resampled to selected broadband multispectral sensors. The native file format of the library is the SPECtrum Processing Routines (SPECPR) data format. This report describes how to access freely available software to read the SPECPR format. To facilitate broader access to the library, we produced generic formats of the spectra and metadata in text files. The library is provided on digital media and online at https://speclab.cr.usgs.gov/spectral-lib.html . A long-term archive of these data are stored on the USGS ScienceBase data server ( https://dx.doi.org/10.5066/F7RR1WDJ ).

Data Series↗

USGS2017

Organic petrology and micro-spectroscopy of Tasmanites microfossils: Applications to kerogen transformations in the early oil window

The transformation of kerogen to hydrocarbons in the early stages of oil generation is critical for understanding the resource potential of liquid-rich shale plays. Organic petrology commonly is used for visual evaluation of type, quality, and thermal maturity of organic matter, but the relationship of visual petrographic changes to chemical transformations is not well characterized. To improve understanding of these processes, organic-walled microfossils of the unicellular green alga Tasmanites (composed of algaenan) in Upper Devonian Ohio Shale (Huron Member, Appalachian Basin) were analyzed by micro-spectroscopy techniques including micro-Fourier transform infrared (micro-FTIR), X-ray photoelectron (XPS), electron probe microanalysis (EPMA), and fluorescence. Immature to mid-oil window maturation sequences of core and outcrop samples with solid bitumen reflectance (BR) and vitrinite reflectance (VR) values ranging from 0.45 to 0.80 %Ro were used. Hydrous pyrolysis was applied to low-maturity (BR: 0.25–0.39 %Ro) Huron and time-correlative New Albany shale samples to create similar artificial maturation sequences for comparison. Micro-FTIR spectroscopy revealed a decrease in the CH 2 /CH 3 ratio with increasing maturity, indicating Tasmanites aliphatic chains become shorter and more branched. Oxygenated functional groups decreased relative to aliphatic stretching bands and increased aromaticity was noted at the highest maturities. In samples that were pyrolyzed for 72 h at temperatures of 300–320 °C (BR: 0.56–0.68 %Ro), Tasmanites showed similar trends, whereas at pyrolysis temperatures of 340 °C and higher (BR > 1.0 %Ro), Tasmanites was pseudomorphed by accumulations of solid bitumen, carbonate and sulfide. Replacement of Tasmanites by these phases in hydrous pyrolysis experiments ≥340 °C and its absence at higher maturities (peak oil, VR and BR ≥ 0.9 %Ro) in naturally matured samples, as documented in a previous study, implies that a large fraction of the algaenan component of original organic carbon is converted to petroleum during thermal maturation. XPS analysis indicated the molar proportion of aliphatic carbon increases with increasing thermal maturity, accompanied by decreases in oxygenated functional groups and olefinic carbon. EPMA of Tasmanites showed highest concentrations of S, with concentrations of redox-sensitive trace elements U, Mo, Ni and V generally at or below detection limits. Decrease in organic S with increasing thermal maturity may be related to cleavage of Tasmanites at C S linkages; however, this relationship was inconsistent and presence of adjacent or entrained nanoscale silicate or sulfide phases may impact measured trace element concentrations. Fluorescence microscopy and spectroscopy showed a red shift in spectral maxima and decreased emission intensities with increasing maturity, interpreted as due to non-radiative energy loss possibly because of increased aromaticity. Collectively, these results provide new insights into the in situ chemical transformations that accompany petrographic changes as oil-prone kerogen converts to petroleum with thermal advance from immature conditions into the mid-oil window.

Organic Geochemistry↗

USGS2017

Geochemistry and mineralogy of the Dotson Zone HREE deposit in the Bokan Mountain peralkaline igneous complex, southeastern Alaska, USA

The Bokan Mountain igneous complex (BMIC) is a typical example of a peralkaline intrusive system that has evolved to the point of developing late stage HFSE- and REE-rich silicic pegmatites and dikes. The Dotson Zone comprises a series of felsic dikes that extend from the southeast margin of the composite pluton and may represent an important resource of critical HREEs. Petrographically, the primary igneous mineral assemblage is altered by late-igneous and hydrothermal fluids resulting in redistribution and enrichment of REEs. An area of flexure in the southeastern end of the Dotson Zone was the primary locus of enrichment as shown by the pervasive alteration and consistently high REE+Y values. We favor a model in which the dikes were emplaced concurrently with the marginal intrusions, and then altered during emplacement of the inner, main intrusion in a relatively rapid series of overlapping intrusive and late magmatic fluid-high temperature hydrothermal events as the complex cooled. A much later sodic intrusive event focused on the BMIC may have resulted in additional silica-Na-Zr-rich alteration in proximity to the pluton.

Conference Paper↗

USGS2016

Mineral thermometry and fluid inclusion studies of the Pea Ridge iron oxide-apatite–rare earth element deposit, Mesoproterozoic St. Francois Mountains Terrane, southeast Missouri, USA

Mineral thermometry and fluid inclusion studies were conducted on variably altered and mineralized samples from the Mesoproterozoic Pea Ridge iron oxide-apatite (IOA)-rare earth element (REE) deposit in order to constrain P-T conditions, fluid chemistry, and the source of salt and volatiles during early magnetite and later REE mineralization. Scanning electron microscopy (SEM)-cathodoluminescence and SEM-backscatter electron images show that quartz and rutile precipitated before, during, and after magnetite and REE mineral growth. Ti-in-quartz and Zr-in-rutile equilibration temperatures range from ≤350° to 750°C in the amphibole, magnetite, hematite, and silicified zones where T increased during magnetite and quartz growth and dropped precipitously after fracturing and brecciation. Late drusy quartz cements within a REE-rich breccia pipe record the lowest T (≤315°–400°C). Liquid-, vapor-rich, and hypersaline (±hematite, calcite) fluid inclusions are common and liquid CO 2 is present locally. Salinities define three populations: saline (10–27 wt % NaCl equiv), hypersaline (34–>60 wt % NaCl equiv), and dilute (0–10 wt % NaCl equiv ). The wide range of eutectic melting temperatures (−67° to −19°C) suggests that saline inclusions trapped variable proportions of a CaCl-MgCl-FeCl-bearing fluid end member and an NaCl-KCl fluid end member. Homogenization temperatures and pressures of these saline inclusions suggest they were trapped when fluids unmixed into brine and vapor at T <350°C, P <15 MPa, and a depth of ~1.5 km. Hypersaline inclusions were trapped at low T and P (~200°C and ~1 MPa) along the V + L + H curve when the system vented to the paleosurface. Data for dilute inclusions in late drusy quartz from the REE-rich breccia pipe are indicative of a boiling epithermal environment. The Na/Cl, Na/K, and Cl/Br ratios of fluid inclusion extracts provide evidence for mixtures of magmatic hydrothermal fluids and evaporated seawater. Extracts from magnetite, hematite, and pyrite plot in the magmatic-hydrothermal field, indicating that Fe was derived from a magmatic source. Their enrichments in Mg and Ca are consistent with a mafic magmatic source. The positive correlation between Na/Mg and Na/Ca ratios may be due to halite saturation or albitization of igneous rocks. Extracts from barite in the REE-rich breccia pipes are enriched in Na and Br and plot near the seawater evaporation trend. He is highly enriched relative to Ne and Ar in fluid inclusion extracts, which precludes air as a source of He. Although the He is mostly of crustal origin, pyrite with a 3 He/ 4 He (R/R A ) of 0.1 contains up to 12% mantle He. Many extracts have low 20 Ne/ 22 Ne ratios due to nucleogenic production of 22 Ne in high F/O minerals such as fluorapatite or F biotite. The arrays of data for 3 He/ 4 He (R/R A ) and 22 Ne/ 20 Ne suggest that volatiles were derived from two sources, a moderate F mafic magma containing mantle He and a high F silicic magma with crustal He. Together with other evidence cited in this report, these data (1) support a magmatic hydrothermal origin for the Mesoproterozoic magnetite-apatite deposit with ore fluids derived from a concealed mafic to intermediate-composition intrusion, (2) suggest that the REE minerals in breccia pipes were either derived from apatite or precipitated in response to decompression and cooling during breccia pipe formation, (3) provide evidence for the influx of basinal brine, magmatic fluids from granitic intrusions, and meteoric water after breccia pipe formation, and (4) show that Pea Ridge was relatively unaffected by the late Paleozoic Mississippi Valley-type (MVT) Pb-Zn system in overlying Cambrian sedimentary rocks.

Missouri↗

USGS2016

The distribution and composition of REE-bearing minerals in placers of the Atlantic and Gulf coastal plains, USA

Rare earth element (REE) resources are currently of great interest because of their importance as raw materials for high-technology manufacturing. The REE-phosphates monazite (light REE enriched) and xenotime (heavy REE enriched) resist weathering and can accumulate in placer deposits as part of the heavy mineral assemblage. The Atlantic and Gulf coastal plains of the southeastern United States are known to host heavy mineral deposits with economic concentrations of zircon, ilmenite and rutile. This study provides a perspective on the distribution and composition of REE phosphate minerals in the region. The elemental chemistry and mineralogy of sands and associated heavy-mineral assemblages from new and archived sediment samples across the coastal plains are examined, along with phase-specific compositions of monazite, xenotime and zircon. Both monazite and xenotime are present across the coastal plains. The phase-specific compositions allow monazite content to be estimated using La as a geochemical proxy. Similarly, both Y and Yb are geochemical proxies for xenotime, but their additional presence in zircon and monazite require a correction to prevent overestimation of xenotime content. Applying this correction, maps of monazite and xenotime content across the coastal plains were generated using sample coverage from the National Geochemical Database (NGS) and National Uranium Resource Evaluation (NURE). The NGS and NURE approach of sampling stream sediments in small watersheds links samples to nearby lithologies. The results show an approximately 40 km-wide band of primarily Cretaceous, marine sediments bordering the Piedmont province from North Carolina to Alabama in which monazite and xenotime content are relatively high (up to 4.4 wt. % in < 150 μm bulk sediment). Strong correlations between concentrations of the two phases were found, with estimated monazite:xenotime ratios ranging approximately 6:1 to 12:1 depending upon the dataset analyzed. From a resource perspective, xenotime correlation with monazite indicates a heavy REE potential in coastal plain placers, and exploration may be warranted within the identified coastal plain band along the boundary of the Piedmont region.

Journal of Geochemical Exploration↗

USGS2016

Ore mineralogy and textural zonation in the world-class epithermal Waihi Vein System, Hauraki Goldfield

The Waihi district in the Hauraki Goldfield of New Zealand contains adularia-sericite epithermal gold-silver veins that have produced more than 7.7 Moz gold. The outermost veins of the district (Martha, Favona, Moonlight, and Cowshed) contain abundant colloform, cherty, and black quartz fill textures, with minor crustiform and massive quartz. The central veins (Amaranth, Trio, and Union) contain predominantly massive and crustiform textures, and these veins are also commonly coarser grained than outermost veins. Pyrite, sphalerite, galena, chalcopyrite, electrum, and acanthite occur in both outermost and central veins; base metal sulfide minerals typically increase in abundance in deeper samples. Antimony-, arsenic-, and selenium-bearing minerals are most abundant in the Favona and Moonlight veins, whereas base metal sulfide minerals are more abundant in the central veins at Correnso. Throughout the Waihi vein system, electrum is by far the most widespread, abundant, and significant gold-bearing mineral, but LA-ICP-MS analyses show that arsenian pyrite also contains some gold. Mineralogical and textural data are consistent with the central veins forming at a deeper structural level, or from hydrothermal fluids with different chemistry, or both.

Book chapter↗

USGS2015

Sedimentology of SPICE (Steptoean positive carbon isotope excursion): A high-resolution trace fossil and microfabric analysis of the middle to late Cambrian Alum Shale Formation, southern Sweden

The Cambrian Alum Shale Formation in the Andrarum-3 core from Scania, southern Sweden, consists of black siliciclastic mudstone with minor carbonate intercalations. Four facies comprise three siliciclastic mudstones and one fine-grained carbonate. The facies reflect deposition along a transect from deep ramp to basin on a Cambrian shelf. The three mudstone facies contain abundant clay clasts and laterally variable siltstone laminae. Bed-load transport processes seem to have dominated deposition on this deep shelf. These sedimentary rocks record mainly event deposition, and only relatively few, thin laminae probably resulted from suspension settling. The Alum Shale Formation deep shelf did not show a bioturbation gradient, but fecal strings are common and Planolites burrows are rare in all mudstone facies. Evidence for biotic colonization indicates that this mudstone environment was not persistently anoxic, but rather was most likely intermittently dysoxic. The Alum Shale Formation in the Andrarum-3 core shows an overall decrease of grain size, preserved energy indicators, and carbonate content upsection interpreted to reflect a deepening upward. The succession can also be divided into four small-scale fining-upward cycles that represent deepening, and four overlying coarsening-upward cycles that represent upward shallowing.

Book chapter↗