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Harland L. Goldstein

Publications and source records attributed to Harland L. Goldstein.

At least 19 recordsLinked to original sources

The influence of surface crust dynamics and sediment availability on aeolian dust emission from ephemeral lake beds: Evidence from Etosha Pan, Namibia

Ephemeral lake beds (playas) are major global sources of atmospheric mineral dust, yet controls governing sediment availability and emission potential at fine spatial scales remain poorly constrained. This study presents the first in situ measurements of surface erodibility and potential PM 10 emission fluxes from Etosha Pan, Namibia. Threshold shear velocities and PM 10 emission fluxes were quantified using a Portable In-Situ Wind ERosion Laboratory (PI-SWERL) across five surface types spanning highly emissive hotspots to non-emissive consolidated salt crusts. Threshold shear velocities ranged from 0.38 m s −1 on deflated clay-rich surfaces to >1.14 m s −1 on recently inundated or cemented salt crusts, and PM 10 fluxes at u ⁎ = 0.56 m s −1 varied by more than three orders of magnitude. Emissions were highest where degraded efflorescent crusts exposed fine sediment, whereas halite-rich crusts exhibited greater mechanical strength and resisted wind erosion despite low surface moisture. X-ray diffraction analyses confirmed spatial variability in evaporite and silicate mineral assemblages, with halite abundance inversely related to dust emission potential. Antecedent hydrological conditions regulated sediment availability. Moderate wetting–drying cycles promoted weak, emissive crusts, whilst persistently wet or dry conditions were associated with continuous, resistant crusts and reduced emissions. Distinct emission regimes arose from differences in crust failure and saltation feedbacks, highlighting sub-landform-scale variability in dust sources. Crust dynamism, driven by spatial variability in surface conditions and antecedent hydrological regime, is identified as a key, under-represented control on dust emission. The relationships quantified here provide new empirical constraints for improving the representation of sediment availability in global dust modelling.

Etosha Pan↗

Light absorbing particles deposited to snow cover across the Upper Colorado River Basin, Colorado Rocky Mountains, 2013-16: Interannual variations from multiple natural and anthropogenic sources

Atmospheric particulate matter (PM) as light-absorbing particles (LAPs) deposited to snow cover can result in early onset and rapid snow melting, challenging management of downstream water resources. We identified LAPs in 38 snow samples (water years 2013–2016) from the mountainous Upper Colorado River basin by comparing among laboratory-measured spectral reflectance, chemical, physical, and magnetic properties. Dust sample reflectance, averaged over the wavelength range of 0.35–2.50 μm, varied by a factor of 1.9 (range, 0.2300–0.4444) and was suppressed mainly by three components: (a) carbonaceous matter measured as total organic carbon (1.6–22.5 wt. %) including inferred black carbon, natural organic matter, and carbon-based synthetic, black road-tire-wear particles, (b) dark rock and mineral particles, indicated by amounts of magnetite (0.11–0.37 wt. %) as their proxy, and (c) ferric oxide minerals identified by reflectance spectroscopy and magnetic properties. Fundamental compositional differences were associated with different iron oxide groups defined by dominant hematite, goethite, or magnetite. These differences in iron oxide mineralogy are attributed to temporally varying source-area contributions implying strong interannual changes in regional source behavior, dust-storm frequency, and (or) transport tracks. Observations of dust-storm activity in the western U.S. and particle-size averages for all samples (median, 25 μm) indicated that regional dust from deserts dominated mineral-dust masses. Fugitive contaminants, nevertheless, contributed important amounts of LAPs from many types of anthropogenic sources.

Colorado↗

Microplastic and associated black particles from road-tire wear: Implications for radiative effects across the cryosphere and in the atmosphere

The environmental effects of airborne micro- and nano-size plastic particles are poorly understood. Microscopy and chemical analyses of atmospherically deposited particles on snow surfaces at high elevation (2,865–3,690 m) in the Upper Colorado River basin (UCRB; Colorado Rocky Mountains) revealed the presence of black substances intimately associated with microplastic fibers, particles interpreted to have originated as tire matter. Identical and similar particles occur in shredded tires and road-surface samples. The substance responsible for the black color of all tires is carbon black, a graphitic light-absorbing tire additive produced by hydrocarbon combustion that homogeneously permeates the mixture of tire polymers and other additives. Such black tire matter may thus exert radiative effects closely similar to those of black carbon. The presence in snow of many organic compound types common to tires, measured by two-dimensional gas chromatography, suggests that atmospherically deposited black road-tire-wear matter is among the light-absorbing particulates that advance the onset and rate of snow melt in the UCRB. The mass of road-tire-wear particles shed from vehicles may be estimated by multiplying measured amounts of eroded tire-per-distance traveled by vehicular distances. Under a combination of measurements and assumptions about the amounts and radiative properties of atmospheric tire-wear particles, the radiative effects of these particles might add about 10%–30% to those effects from black carbon, an estimate ripe for revision. On regional and global scales, the amounts and effects of emitted and deposited tire-wear matter likely vary by factors of geographic source, transport pathway, and depositional setting.

JGR - Atmospheres↗

Microplastic particles in dust-on-snow, Upper Colorado River Basin, Colorado Rocky Mountains, 2013–16

Atmospheric dust deposited to snow cover (dust-on-snow) diminishes snow-surface albedo (SSA) to result in early onset and accelerated rate of melting, effects that challenge management of downstream water resources. During ongoing investigations to identify the light-energy absorbing dust particles most responsible for diminished SSA in the Upper Colorado River Basin of the Colorado Rocky Mountains, we found microplastic particles, which are defined as those less than 5 millimeters in any dimension. In each of the 38 samples that represented the last remaining dust layer during melt seasons of 2013–16, microplastics were identified by size, shape, and color, and their relative amounts were visually estimated using stereomicroscopy. Considering the remote, high-elevation settings of the sample sites, the microplastic particles must have been deposited from the atmosphere. The possible role of microplastics for diminishing SSA of snow cover in the Upper Colorado River Basin may be linked to the solar-energy absorptive properties of polymers and is the subject of ongoing investigation.

Colorado↗

Aeolian sediments in paleowetland deposits of the Las Vegas Formation

The Las Vegas Formation (LVF) is a well-characterized sequence of groundwater discharge (GWD) deposits exposed in and around the Las Vegas Valley in southern Nevada. Nearly monolithologic bedrock surrounds the valley, which provides an excellent opportunity to test the hypothesis that GWD deposits include an aeolian component. Mineralogical data indicate that the LVF sediments are dominated by carbonate minerals, similar to the local bedrock, but silicate minerals are also present. The median particle size is ~35 μm, consistent with modern dust in the region, and magnetic properties contrast strongly with local bedrock, implying an extralocal origin. By combining geochemical data from the LVF sediments and modern dust, we found that an average of ~25% of the LVF deposits were introduced by aeolian processes. The remainder consists primarily of authigenic groundwater carbonate as well as minor amounts of alluvial material and soil carbonate. Our data also show that the aeolian sediments accumulated in spring ecosystems in the Las Vegas Valley in a manner that was independent of both time and the specific hydrologic environment. These results have broad implications for investigations of GWD deposits located elsewhere in the southwestern U.S. and worldwide.

Nevada↗

Atmospheric processing of iron-bearing mineral dust aerosol and its effect on growth of a marine diatom, Cyclotella meneghiniana

Iron (Fe) is a growth-limiting micronutrient for phytoplankton in major areas of oceans and deposited wind-blown desert dust is a primary Fe source to these regions. Simulated atmospheric processing of four mineral dust proxies and two natural dust samples followed by subsequent growth studies of the marine planktic diatom Cyclotella meneghiniana in artificial sea-water (ASW) demonstrated higher growth response to ilmenite (FeTiO 3 ) and hematite (α-Fe 2 O 3 ) mixed with TiO 2 than hematite alone. The processed dust treatment enhanced diatom growth owing to dissolved Fe (DFe) content. The fresh dust-treated cultures demonstrated growth enhancements without adding such dissolved Fe. These significant growth enhancements and dissolved Fe measurements indicated that diatoms acquire Fe from solid particles. When diatoms were physically separated from mineral dust particles, the growth responses become smaller. The post-mineralogy analysis of mineral dust proxies added to ASW showed a diatom-induced increased formation of goethite, where the amount of goethite formed correlated with observed enhanced growth. The current work suggests that ocean primary productivity may not only depend on dissolved Fe but also on suspended solid Fe particles and their mineralogy. Further, the diatom C. meneghiniana benefits more from mineral dust particles in direct contact with cells than from physically impeded particles, suggesting the possibility for alternate Fe-acquisition mechanism/s.

Environmental Science & Technology↗

Dust deposited on snow cover in the San Juan Mountains, Colorado, 2011-2016: Compositional variability bearing on snow-melt effects

Light-absorbing particles in atmospheric dust deposited on snow cover (dust-on-snow, DOS) diminish albedo and accelerate the timing and rate of snow melt. Identification of these particles and their effects are relevant to snow-radiation modeling and thus water-resource management. Laboratory-measured reflectance of DOS samples from the San Juan Mountains (USA) were compared with DOS mass loading, particle sizes, iron mineralogy, carbonaceous matter type and content, and chemical compositions. Samples were collected each spring for water years 2011-2016, when individual dust layers had merged into one (all layers merged) at the snow surface. Average reflectance values of the six samples were 0.2153 (sd, 0.0331) across the visible wavelength region (0.4-0.7 µm) and 0.3570 (sd, 0.0498) over the full-measurement range (0.4-2.50 µm). Reflectance values correlated inversely to concentrations of ferric oxide, organic carbon (1.4-10 wt. %), magnetite (0.05-0.13 wt. %), and silt (PM63-3.9; median grain sizes averaged 21.4 µm) but lacked correspondence to total iron and PM10 contents. Measurements of reflectance and Mössbauer spectra and magnetic properties indicated that microcrystalline hematite and nano-size goethite were primarily responsible for diminished visible reflectance. Positive correlations between organic carbon and metals attributed to fossil-fuel combustion, with observations from electron microscopy, indicated that some carbonaceous matter occurred as black carbon. Magnetite was a surrogate for related light-absorbing minerals, dark rock particles, and contaminants. Similar analyses of DOS from other areas would help evaluate the influences of varied dust sources, wind-storm patterns, and anthropogenic inputs on snow melt and water resources in and beyond the Colorado River basin.

Colorado↗

'Dust in the wind’ from source-to-sink: Analysis of the 14-15 April 2015 storm in Utah

On 14–15 April 2015, an intense intermountain cyclone in the western USA caused high winds and a dust storm that degraded air quality in the eastern Great Basin, and deposited dust-on-snow (DOS) in the Wasatch Range near Salt Lake City, Utah. We analyzed the storm and documented its “source-to-sink” development to relate the frontal passage with dust mobilization, air quality changes, and dust deposition on montane snowpack near Alta, Utah. This case study is first to track a dust storm and measure the elemental composition and radiative properties of the resulting DOS as a single specific event layer in Wasatch montane snowpack; prior studies have assessed seasonally aggregated DOS deposits. Dust plumes on MODIS imagery indicate mobilization from known regional “hotspots” for aeolian activity, including clay- and silt-rich alluvium, modern playas, and disturbed areas within the Pleistocene Paleolake Bonneville Basin. This 2015 single event dust layer was 1–3 cm thick with a median dust size of 10.81–12.55 µm; its measured radiative properties are similar to aggregated dusts previously assessed in Wasatch snowpack. Dust from the 2015 DOS event is enriched in the elements As, Cd, Cu, and Mo by a 10× factor relative to average elemental concentrations in the upper continental crust; its heavy metals (Cu, Pb, As, Cd, Mo, Zn) are probably derived from regional mine operations. Tracking elemental fluxes from source-to-sink is important for resolving environmental impacts, and informing future analysis of single storm dust loading, ecosystem impacts, and quantity and quality of meltwater-fed drinking water.

Utah↗

Bioavailable iron production in airborne mineral dust: Controls by chemical composition and solar flux

A large part of oceanic biological production is limited by the scarcity of dissolved iron. Mineral dust aerosol , processed under acidic atmospheric conditions , is the primary natural source of bioavailable iron to oceanic life. However, synergistic and antagonistic effects of non-Fe-containing minerals on atmospheric processing of Fe-containing minerals and Fe solubilization are poorly understood. The current study focuses on mineralogical influences of non-Fe-bearing semiconductor minerals, such as titanium dioxide (TiO 2 ), on the dissolution of iron in selected natural mineral dust aerosols under atmospherically relevant conditions. Further, the role of elevated Ti concentrations in dust is evaluated using magnetite , a proxy for Fe(II) containing minerals, under both dark and light conditions. Our results highlight that relatively higher Ti:Fe ratios, regardless of their total Fe content, enhances the total iron dissolution in mineral dust aerosols as well as in magnetite. Moreover, elevated Ti percentages also yield high Fe(II) fractions in mineral dust systems under dark conditions. Upon irradiation however, dissolved Fe(II) is suppressed by high Ti levels due to the involvement of photochemical redox cycling reactions with hydroxyl radicals ( • OH). These synergistic and antagonistic effects of Ti are further evaluated by altering the chemical composition of natural dusts with artificially added anatase (TiO 2 ) and synthetic amorphous titania . The current study reveals important mineralogical controls by non-Fe-bearing minerals on dust iron dissolution to better understand global iron mobilization.

Atmospheric Environment↗

Phosphorus speciation and solubility in aeolian dust deposited in the interior American West

Aeolian dust is a significant source of phosphorus (P) to alpine oligotrophic lakes, but P speciation in dust and source sediments and its release kinetics to lake water remain unknown. Phosphorus K-edge XANES spectroscopy shows that calcium-bound P (Ca−P) is dominant in 10 of 12 dust samples (41−74%) deposited on snow in the central Rocky Mountains and all 42 source sediment samples (the fine fraction) (68−80%), with a lower proportion in dust probably because acidic snowmelt dissolves some Ca−P in dust before collection. Iron-bound P (Fe−P, ∼54%) dominates in the remaining two dust samples. Chemical extractions (SEDEX) on these samples provide inaccurate results because of unselective extraction of targeted species and artifacts introduced by the extractions. Dust releases increasingly more P in synthetic lake water within 6−72 h thanks to dissolution of Ca−P, but dust release of P declines afterward due to back adsorption of P onto Fe oxides present in the dust. The back sorption is stronger for the dust with a lower degree of P saturation determined by oxalate extraction. This work suggests that P speciation, poorly crystalline minerals in the dust, and lake acidification all affect the availability and fate of dust-borne P in lakes.

Arizona, Colorado, New Mexico, Utah↗

Iron dissolution and speciation in atmospheric mineral dust: Metal-metal synergistic and antagonistic effects

Under acidic atmospheric conditions, iron leached from atmospheric mineral dust may influence the distribution of bioavailable iron at a global scale. However, the effects of non-Fe-containing minerals on iron dissolution remain unknown. This work describes metal-metal synergistic and antagonistic effects on iron dissolution that go beyond aggregation and ionic strength effects in mineral dust mixtures. In this study, we investigated iron mobilization by proton-promoted dissolution in natural mineral dust samples from the Kalahari Desert (SZ1) and Australian Red Dawn event (RO), along with one iron oxide proxy, hematite. The total iron dissolution in natural dust samples highly corresponds with the respective amount of Ti, rather than their particle sizes or Fe contents. The dust sample with high Ti content, SZ1, also showed a higher fraction of dissolved Fe(II), under dark conditions. These observations are in good agreement with the dissolution data for hematite artificially mixed with metal oxides. Total iron dissolution in hematite, mixed with TiO 2 , is 1.5- and 2-fold higher compared to that of just hematite under dark and light conditions, respectively. However, dissolution of hematite is suppressed when mixed with Al 2 O 3 and CaO. Under dark conditions, furthermore, dissolved Fe(II) fraction is enhanced for hematite when mixed with TiO 2 compared to that of other mixtures or hematite alone. Yet, dissolved Fe(II) is lower in hematite mixed with TiO 2 under light conditions compared to that of hematite alone, suggesting photo-oxidation of Fe(II) by reactive oxygen species, such as OH radicals.

Atmospheric Environment↗

Late Quaternary loess and soils on uplands in the Canyonlands and Mesa Verde areas, Utah and Colorado

Thin loess deposits on the uplands of the southeastern Colorado Plateau have previously not been well studied. We sampled deposits and soils from trenches on Hatch Point (HP) mesa near Canyonlands National Park, Utah, and from two outcrops in Mesa Verde National Park, Colorado. At HP, the oldest buried unit yielded 2 optically stimulated luminescence (OSL) ages of 10,370 and 7555 yr; the middle unit yielded 10 OSL ages from 6220 to 1385 yr; and the youngest unit had a single age of 1740 yr. At Mesa Verde (MV), three loess units are preserved in the two outcrops we examined; 6 OSL ages range from 51 to 17 ka. At least one buried soil is present between two units with ages of about 50 and 40 ka. The ages of the loess units in both study areas correspond well with OSL-dated dune sands in Canyonlands National Park and with dune sands on Black Mesa, Arizona. Particle-size distribution combined with chemical and magnetic data indicate that HP loess was derived mostly from nearby sandstone sources with a small component of far-traveled atmospheric dust, whereas MV loess was sourced both from the nearby sandstone and the San Juan River and its tributaries.

Colorado, Utah↗

Controls on the chemical composition of saline surface crusts and emitted dust from a wet playa in the Mojave Desert (USA)

Saline-surface crusts and their compositions at ephemeral, dry, and drying lakes are important products of arid-land processes. Detailed understanding is lacking, however, about interactions among locally variable hydrogeologic conditions, compositional control of groundwater on vadose zone and surface salts, and dust composition. Chemical and physical data from groundwater, sediments, and salts reveal compositional controls on saline-surface crusts across a wet playa, Mojave Desert, with bearing on similar settings elsewhere. The compositions of chemically and isotopically distinctive shallow (<3 m) water masses are recorded in the composition of associated salts. In areas with deeper and more saline groundwater, however, not all ions are transported through the vadose zone. Retention of arsenic and other elements in the vadose zone diminishes the concentrations of potentially toxic elements in surface salts, but creates a reservoir of these elements that may be brought to the surface during wetter conditions or by human disturbance. Selective wind-erosion loss of sulfate salts was identified by the compositional contrast between surface salt crusts and underlying groundwater. At the sub-basin scale, compositional links exist among groundwater, salt crusts, and dust from wet playas. Across the study basin, however, lateral variations in groundwater and solid-salt compositions are produced by hydrogeologic heterogeneity.

Journal of Arid Environments↗

Iron oxide minerals in dust-source sediments from the Bodélé Depression, Chad: Implications for radiative properties and Fe bioavailability of dust plumes from the Sahara

Atmospheric mineral dust can influence climate and biogeochemical cycles. An important component of mineral dust is ferric oxide minerals (hematite and goethite) which have been shown to influence strongly the optical properties of dust plumes and thus affect the radiative forcing of global dust. Here we report on the iron mineralogy of dust-source samples from the Bodélé Depression (Chad, north-central Africa), which is estimated to be Earth’s most prolific dust producer and may be a key contributor to the global radiative budget of the atmosphere as well as to long-range nutrient transport to the Amazon Basin. By using a combination of magnetic property measurements, Mössbauer spectroscopy, reflectance spectroscopy, chemical analysis, and scanning electron microscopy, we document the abundance and relative amounts of goethite, hematite, and magnetite in dust-source samples from the Bodélé Depression. The partition between hematite and goethite is important to know to improve models for the radiative effects of ferric oxide minerals in mineral dust aerosols. The combination of methods shows (1) the dominance of goethite over hematite in the source sediments, (2) the abundance and occurrences of their nanosize components, and (3) the ubiquity of magnetite, albeit in small amounts. Dominant goethite and subordinate hematite together compose about 2% of yellow-reddish dust-source sediments from the Bodélé Depression and contribute strongly to diminution of reflectance in bulk samples. These observations imply that dust plumes from the Bodélé Depression that are derived from goethite-dominated sediments strongly absorb solar radiation. The presence of ubiquitous magnetite (0.002–0.57 wt%) is also noteworthy for its potentially higher solubility relative to ferric oxide and for its small sizes, including PM < 0.1 μm. For all examined samples, the average iron apportionment is estimated at about 33% in ferric oxide minerals, 1.4% in magnetite, and 65% in ferric silicates. Structural iron in clay minerals may account for much of the iron in the ferric silicates. We estimate that the mean ferric oxides flux exported from the Bodélé Depression is 0.9 Tg/yr with greater than 50% exported as ferric oxide nanoparticles (<0.1 μm). The high surface-to-volume ratios of ferric oxide nanoparticles once entrained into dust plumes may facilitate increased atmospheric chemical and physical processing and affect iron solubility and bioavailability to marine and terrestrial ecosystems.

Aeolian Research↗

Concentrations of mineral aerosol from desert to plains across the central Rocky Mountains, western United States

Mineral dusts can have profound effects on climate, clouds, ecosystem processes, and human health. Because regional dust emission and deposition in western North America are not well understood, measurements of total suspended particulate (TSP) from 2011 to 2013 were made along a 500-km transect of five remote sites in Utah and Colorado, USA. The TSP concentrations in μg m −3 adjusted to a 24-h period were relatively high at the two westernmost, dryland sites at Canyonlands National Park (mean = 135) and at Mesa Verde National Park (mean = 99), as well as at the easternmost site on the Great Plains (mean = 143). The TSP concentrations at the two intervening montane sites were less, with more loading on the western slope of the Rocky Mountains (Telluride, mean = 68) closest to the desert sites compared with the site on the eastern slope (Niwot Ridge, mean = 58). Dust concentrations were commonly highest during late winter-late spring, when Pacific frontal storms are the dominant causes of regional wind. Low concentrations (<7 wt%) of organic matter indicated that rock-derived mineral particles composed most TSP. Most TSP mass was carried by particle sizes larger than 10 μm (PM >10 ), as revealed by relatively low average daily concentrations of fine (<5 μg m −3 ; PM 2.5 ) and coarse (<10 μg m −3 ; PM 2.5–10 ) fractions monitored at or near four sites. Standard air-quality measurements for PM 2.5 and PM 10 apparently do not capture the large majority of mineral-particulate pollution in the remote western interior U.S.

Aeolian Research↗

Regional variability in dust-on-snow processes and impacts in the Upper Colorado River Basin

Dust deposition onto mountain snow cover in the Upper Colorado River Basin frequently occurs in the spring when wind speeds and dust emission peaks on the nearby Colorado Plateau. Dust loading has increased since the intensive settlement in the western USA in the mid 1880s. The effects of dust-on-snow have been well studied at Senator Beck Basin Study Area (SBBSA) in the San Juan Mountains, CO, the first high-altitude area of contact for predominantly southwesterly winds transporting dust from the southern Colorado Plateau. To capture variability in dust transport from the broader Colorado Plateau and dust deposition across a larger area of the Colorado River water sources, an additional study plot was established in 2009 on Grand Mesa, 150&thinsp;km to the north of SBBSA in west central, CO. Here, we compare the 4-year (2010&ndash;2013) dust source, deposition, and radiative forcing records at Grand Mesa Study Plot (GMSP) and Swamp Angel Study Plot (SASP), SBBSA's subalpine study plot. The study plots have similar site elevations/environments and differ mainly in the amount of dust deposited and ensuing impacts. At SASP, end of year dust concentrations ranged from 0.83&thinsp;mg&thinsp;g &minus;1 to 4.80&thinsp;mg&thinsp;g &minus;1 , and daily mean spring dust radiative forcing ranged from 50&ndash;65&thinsp;W&thinsp;m &minus;2 , advancing melt by 24&ndash;49&thinsp;days. At GMSP, which received 1.0&thinsp;mg&thinsp;g &minus;1 less dust per season on average, spring radiative forcings of 32&ndash;50&thinsp;W&thinsp;m &minus;2 advanced melt by 15&ndash;30&thinsp;days. Remote sensing imagery showed that observed dust events were frequently associated with dust emission from the southern Colorado Plateau. Dust from these sources generally passed south of GMSP, and back trajectory footprints modelled for observed dust events were commonly more westerly and northerly for GMSP relative to SASP. These factors suggest that although the southern Colorado Plateau contains important dust sources, dust contributions from other dust sources contribute to dust loading in this region, and likely account for the majority of dust loading at GMSP.

Hydrological Processes↗

Aeolian responses to climate variability during the past century on Mesquite Lake Playa, Mojave Desert

The erosion and deposition of sediments by wind from 1901 to 2013 have created large changes in surface features of Mesquite Lake playa in the Mojave Desert. The decadal scale recurrence of sand-sheet development, migration, and merging with older dunes appears related to decadal climatic changes of drought and wetness as recorded in the precipitation history of the Mojave Desert, complemented by modeled soil-moisture index values. Historical aerial photographs, repeat land photographs, and satellite images document the presence and northward migration of a mid-20th century sand sheet that formed during a severe regional drought that coincided with a multi-decadal cool phase of the Pacific Decadal Oscillation (PDO). The sand sheet slowly eroded during the wetter conditions of the subsequent PDO warm phase (1977–1998) due to a lack of added sediment. Sand cohesion gradually increased in the sand sheet by seasonal additions of salt and clay and by re-precipitation of gypsum, which resulted in the wind-carving of yardangs in the receding sand sheet. Smaller yardangs were aerodynamically shaped from coppice dunes with salt-clay crusts, and larger yardangs were carved along the walls and floor of trough blowouts. Evidence of a 19th century cycle of sand-sheet formation and erosion is indicated by remnants of yardangs, photographed in 1901 and 1916, that were found buried in the mid-20th century sand sheet. Three years of erosion measurements on the playa, yardangs, and sand sheets document relatively rapid wind erosion. The playa has lowered 20 to 40 cm since the mid-20th century and a shallow deflation basin has developed since 1999. Annually, 5–10 cm of surface sediment was removed from yardang flanks by a combination of wind abrasion, deflation, and mass movement. The most effective erosional processes are wind stripping of thin crusts that form on the yardang surfaces after rain events and the slumping of sediment blocks from yardang flanks. These wind-eroded landforms persist several decades to a century before eroding away or being buried by younger sands. On Mesquite Lake playa the climatic history of alternating PDO phases of multi-decadal drought and wetness is recorded twice by the presence of yardangs formed nearly a century apart.

Mesquite Lake, Mojave Desert↗

Effect of sulfate and carbonate minerals on particle-size distributions in arid soils

Arid soils pose unique problems during measurement and interpretation of particle-size distributions (PSDs) because they often contain high concentrations of water-soluble salts. This study investigates the effects of sulfate and carbonate minerals on grain-size analysis by comparing analyses in water, in which the minerals dissolve, and isopropanol (IPA), in which they do not. The presence of gypsum, in particular, substantially affects particle-size analysis once the concentration of gypsum in the sample exceeds the mineral’s solubility threshold. For smaller concentrations particle-size results are unaffected. This is because at concentrations above the solubility threshold fine particles cement together or bind to coarser particles or aggregates already present in the sample, or soluble mineral coatings enlarge grains. Formation of discrete crystallites exacerbates the problem. When soluble minerals are dissolved the original, insoluble grains will become partly or entirely liberated. Thus, removing soluble minerals will result in an increase in measured fine particles. Distortion of particle-size analysis is larger for sulfate minerals than for carbonate minerals because of the much higher solubility in water of the former. When possible, arid soils should be analyzed using a liquid in which the mineral grains do not dissolve, such as IPA, because the results will more accurately reflect the PSD under most arid soil field conditions. This is especially important when interpreting soil and environmental processes affected by particle size.

Soil Science Society of America Journal↗