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Gregory J. Walsh

Publications and source records attributed to Gregory J. Walsh.

At least 37 records · Page 2Linked to original sources
USGS2021

Integrated geophysical imaging of rare-earth-element-bearing iron oxide-apatite deposits in the eastern Adirondack Highlands, New York

The eastern Adirondack Highlands of northern New York host dozens of iron oxide-apatite (IOA) deposits containing magnetite and rare earth element (REE)-bearing apatite. We use new aeromagnetic, aeroradiometric, ground gravity, and sample petrophysical and geochemical data to image and understand these deposits and their geologic framework. Aeromagnetic total field data reflect highly magnetic leucogranite host rock and major structures that likely served as fluid conduits for the hydrothermal system. Bandpass filtering of the aeromagnetic data reveals individual deposits that were verified in the field or from historical records. A three-dimensional inversion for magnetic susceptibility images these deposits at depth, allowing inference of plunge directions and relative size. Radiometric data highlight variations in the surface geology and several large tailings piles that contain REE-bearing apatite. Within the host rock, eTh (equivalent Th), K and the eTh/K ratio are variable with high eTh/K near several of the IOA deposits. Areas with elevated K or low eTh/K representing potassic alteration appear to be rare; instead elevated eTh/K ratios likely reflect widespread sodic alteration overprinting potassic alteration. Bouguer gravity anomalies show limited correspondence to the surface geology, radiometric data, or magnetic data, but do exhibit ~10-km wide highs in areas where deposits are observed. Two-dimensional forward models of the gravity and magnetic data show that deeper dense material beneath the leucogranite is quantitatively feasible. If these dense rocks represent intrusions that were emplaced or still cooling at the time of mineralization, they may have served as a heat source that helped to drive the hydrothermal system. Combining datasets, we find that deposits occur towards the distal ends of major structures within the host leucogranite and mostly above gravity highs. The geophysical modeling thus suggests that IOA deposits formed in structural, thermal, and chemical traps near the distal ends of the hydrothermal system.

New York↗
USGS2020

Bedrock geologic map of the Springfield 7.5- x 15-minute quadrangle, Windsor County, Vermont, and Sullivan County, New Hampshire

The bedrock geology of the 7.5- by 15-minute Springfield quadrangle consists of highly deformed and metamorphosed Mesoproterozoic through Devonian metasedimentary and meta-igneous rocks. In the west, Mesoproterozoic gneisses of the Mount Holly Complex are the oldest rocks and form the eastern side of the Chester dome. The Moretown slice structurally overlies the Chester dome along the Keyes Mountain thrust fault which represents the Ordovician Taconic suture (Red Indian Line) between Laurentian and Ganderian crust. The allochthonous Cambrian through Ordovician Moretown slice includes the Moretown and Cram Hill Formations and the North River Igneous Suite. Silurian and Devonian metasedimentary and metavolcanic rocks of the Connecticut Valley trough (CVT) unconformably overlie the Moretown slice. Ordovician to Silurian and Devonian metasedimentary and meta-igneous rocks of the New Hampshire sequence structurally overlie the CVT along the Devonian, Acadian Monroe thrust fault. The oldest part of the New Hampshire sequence consists of Ordovician metamorphosed volcanic, plutonic, and sedimentary rocks of the Bronson Hill arc including the Ammonoosuc Volcanics, the Partridge Formation, and the Oliverian Plutonic Suite. The Ammonoosuc Volcanics are the base of the exposed arc section in the map area. The Bronson Hill arc rocks are exposed in fault-bounded structural belts, including the Monroe thrust sheet, the Claremont belt, the Sugar River and Unity domes, and the footwall of the Brennan Hill thrust fault. Silurian to Devonian metasedimentary rocks of the Clough Quartzite, and Fitch and Littleton Formations unconformably overlie the Bronson Hill arc rocks. Devonian granitic and pegmatitic dikes and sills of the New Hampshire Plutonic Suite intruded previously deformed rocks. Devonian, Acadian F 1 fold nappes have a sheath fold geometry and are truncated by multiple generations of faults. The Bronson Hill arc structurally overlies the CVT along the Acadian Monroe fault with preserved tectonic mélange in the footwall. Upright dome-stage F 2 folds post-date amphibolite facies metamorphism and locally developed into sheath folds in high-strain zones. F 3 folds exhibit sinistral rotation associated with Alleghanian lower-greenschist facies faults. Late Paleozoic Alleghanian to Mesozoic shear zones transpose stratigraphy, early structures, and peak metamorphic isograds. 40 Ar/ 39 Ar white-mica growth ages (300–250 million years before present [Ma]) indicate that retrograde deformation continued into the latest Paleozoic and earliest Mesozoic. Apatite fission track data show that brittle faults were active prior to about 100 Ma and experienced Late Cretaceous and even Paleocene re-activation. The bedrock geology was mapped to study the tectonic history of the area and to provide a framework for ongoing characterization of the bedrock of Vermont and New Hampshire. This Scientific Investigations Map of the Springfield 7.5- x 15-minute quadrangle consists of sheets 1 and 2 as well as a geographic information system (GIS) database that includes bedrock geologic units, faults, outcrops, and structural geologic information. Sheet 1 of the report includes a bedrock geologic map, a correlation of map units, and a description of map units. Sheet 2 includes a discussion of the geology, references cited, two cross sections from the geologic map on sheet 1, a tectonic map showing major structural features, and a structural domain map showing the orientation of brittle features.

New Hampshire, Vermont↗
USGS2020

Photoluminescence imaging of whole zircon grains on a petrographic microscope—An underused aide for geochronologic studies

The refractory nature of zircon to temperature and pressure allows even a single zircon grain to preserve a rich history of magmatic, metamorphic, and hydrothermal processes. Isotopic dating of micro-domains exposed in cross-sections of zircon grains allows us to interrogate this history. Unfortunately, our ability to select the zircon grains in a heavy mineral concentrate that records the most geochronologic information is limited by our inability to predict internal zonation from observations of whole grains. Here we document the use of a petrographic microscope to observe and image the photoluminescence (PL) response of whole zircon grains excited under ultraviolet (UV) light, and the utility of this PL response in selecting grains for geochronology. While zircon fluorescence has long been known, there is limited documentation of its utility for and application to geochronologic studies. Our observations of zircon from an un-metamorphosed igneous rock, two meta-igneous rocks, and a placer deposit show that variations in the PL color are readily observable in real-time, both among grains in a population of zircons and within single grains. Analyses of cross-sections of the same grains demonstrate that the changes in PL correlate with zoning in backscattered electron (BSE) and cathodoluminescence (CL) images as well as with changes in U + Th concentration and spectroscopic proxies for radiation damage. In other words, the whole grain PL provides a low-resolution preview of the U + Th zoning expected in a cross-sectioned grain. We demonstrate the usefulness of this “preview” in identifying and selecting the subset of zircon grains in a heavy mineral separate that has metamorphic rims of sufficient width to date by secondary ionization mass spectrometry (SIMS). The data are also used to place preliminary constraints on the age and U + Th concentrations at which a yellow PL response is observed in natural samples. The PL response of zircon is well-known among spectroscopists, and these simple applications demonstrate several ways in which the response might be more effectively used by geochronologists.

Minerals↗
USGS2020

Bedrock geologic map of the Mount Ascutney 7.5- x 15-minute quadrangle, Windsor County, Vermont, and Sullivan County, New Hampshire

The bedrock geology of the Mount Ascutney 7.5- x 15-minute quadrangle consists of highly deformed and metamorphosed Mesoproterozoic through Devonian metasedimentary and meta-igneous rocks intruded by rocks of the Mesozoic White Mountain Igneous Suite. In the west, Mesoproterozoic gneisses of the Mount Holly Complex are the oldest rocks and form the northeastern flank of the Chester dome. The allochthonous Cambrian through Ordovician rocks include the Moretown and Cram Hill Formations and the North River Igneous Suite; these rocks structurally overlie the Chester dome along the Keyes Mountain thrust fault. Silurian and Devonian metasedimentary and metavolcanic rocks of the Connecticut Valley trough (CVT) unconformably overlie the pre-Silurian rocks. The easternmost extent of the CVT in New Hampshire is exposed in the Meriden antiform. Ordovician to Silurian and Devonian metasedimentary rocks of the Bronson Hill anticlinorium structurally overlie the CVT along the Monroe thrust fault. The oldest part of the Bronson Hill anticlinorium, called the Bronson Hill arc, consists of Ordovician metamorphosed volcanic, plutonic, and sedimentary rocks of the Ammonoosuc Volcanics, the Partridge Formation, and the Oliverian Plutonic Suite. The rocks of the Bronson Hill arc may be partly correlative with the pre-Silurian rocks above the Chester dome and are exposed in two fault-bounded structural belts (Cornish City and Claremont belts) and in the Sugar River dome. Collectively, these belts form the regional Orfordville anticlinorium, Hardscrabble synclinorium, and the western part of the broader Bronson Hill anticlinorium in western New Hampshire. Silurian to Devonian metasedimentary rocks of the Clough Quartzite, and Fitch and Littleton Formations unconformably overlie the rocks of the Bronson Hill arc. Devonian granitic and pegmatitic dikes and sills of the New Hampshire Plutonic Suite intruded previously deformed rocks. Post-tectonic Cretaceous plutonic and volcanic rocks of the Ascutney Mountain Intrusive Complex underlie Mount Ascutney. Because of the historically significant scientific research, and its prominence in the landscape, Mount Ascutney is commonly regarded as Vermont’s most famous volcano. The bedrock geology was mapped to study the tectonic history of the area and to provide a framework for ongoing characterization of the bedrock of Vermont and New Hampshire. This Scientific Investigations Map of the Mount Ascutney 7.5- x 15-minute quadrangle consists of sheets 1 and 2 as well as a geographic information system (GIS) database that includes bedrock geologic units, faults, outcrops, structural geologic information, geochemistry, and photographs. Sheet 1 of the report includes a bedrock geologic map, a correlation of map units, and a description of map units. Sheet 2 includes a discussion of the geology, references, three cross sections from the geologic map on sheet 1, igneous rock geochemistry results of the main map units from the Mount Ascutney stock, a tectonic map showing major structural features, and a structural domain map showing the orientation and distribution of brittle features.

New Hampshire, Vermont↗
USGS2020

A transect through Vermont's most famous volcano - Mount Ascutney

The Cretaceous Ascutney Mountain igneous complex affords a classic exposure of the White Mountain Igneous Suite. Often called Vermont’s most famous volcano, Mount Ascutney (elev. 3,144 feet, 958 m) stands as a prominent monadnock in the Connecticut River Valley. The mountain often serves as an inspirational landmark, as it does when viewed from locations throughout the valley including the Saint-Gaudens National Historic Site (Walsh, 2017). The Ascutney Mountain igneous complex (Ratcliffe and others, 2011) consists of several mafic to felsic nested plutons including gabbro-diorite exposed at Little Ascutney to the west, and the Ascutney Mountain stock composed of syenite, granite, and related volcanic rocks underlying the main summit to the east (Fig. 1) (Schneiderman, 1989, 1991). Foland and Faul (1977) and Foland and others (1985) dated the gabbro-diorite complex at 125.5 to 122.2 Ma by K-Ar on biotite and by whole rock Rb/Sr, and dated the syenite-granite complex at 123.2 to 121.4 Ma by K-Ar on biotite. During the field trip we will visit the host rocks south of the mountain and the main rocks types of the Ascutney Mountain stock exposed near the summit and along the Mount Ascutney toll road. Mount Ascutney is the classic location where Daly (1903) discussed the evidence for piecemeal stoping as a pluton emplacement mechanism. This theory was later modified to favor cauldron subsidence, or ring-fracture stoping, as an alternative mode of emplacement (Chapman and Chapman, 1940). Our new mapping (Walsh and others, in press), which supersedes an earlier provisional study (Walsh and others, 1996a, b), supports the cauldron subsidence model, and shows that the main Ascutney Mountain stock is a funnel shaped composite pluton in agreement with geophysical data (Daniels, 1990). This field guide will primarily highlight the results of the new geologic mapping. This field guide is modified from a field trip presented in 2017 (Walsh, 2017). Additional stops have been added to examine the host rocks in the region south of the Ascutney Mountain stock. Two hikes are planned as part of this trip. Other NEIGC field trip guides to Mount Ascutney include Stoiber (1954) and Schneiderman (1988).

Vermont↗
USGS2019

Geochronology of the Oliverian Plutonic Suite and the Ammonoosuc Volcanics in the Bronson Hill arc: Western New Hampshire, USA

U-Pb zircon geochronology by sensitive high-resolution ion microprobe–reverse geometry (SHRIMP-RG) on 11 plutonic rocks and two volcanic rocks from the Bronson Hill arc in western New Hampshire yielded Early to Late Ordovician ages ranging from 475 to 445 Ma. Ages from Oliverian Plutonic Suite rocks that intrude a largely mafic lower section of the Ammonoosuc Volcanics ranged from 474.8 ± 5.2 to 460.2 ± 3.4 Ma. Metamorphosed felsic volcanic rocks from within the Ammonoosuc Volcanics yielded ages of 460.1 ± 2.4 and 455.0 ± 11 Ma. Younger Oliverian Plutonic Suite rocks that either intrude both the upper and lower Ammonoosuc Volcanics or Partridge Formation ranged in age from 456.1 ± 6.7 Ma to 445.2 ± 6.7 Ma. These new data and previously published results document extended magmatism for >30 m.y. The ages, along with the lack of mappable structural discontinuities between the plutons and their volcanic cover, suggest that the Bronson Hill arc was part of a relatively long-lived composite arc. The Early to Late Ordovician ages presented here overlap with previously determined igneous U-Pb zircon ages in the Shelburne Falls arc to the west, suggesting that the Bronson Hill arc and the Shelburne Falls arc could be part of one, long-lived composite arc system, in agreement with the interpretation that the Iapetus suture (Red Indian Line) lies to the west of the Shelburne Falls–Bronson Hill arc system.

New Hampshire↗
USGS2019

Syn-collisional exhumation of hot middle crust in the Adirondack Mountains (New York, USA): Implications for extensional orogenesis in the southern Grenville province

Extensional deformation in the lower to middle continental crust is increasingly recognized and shown to have significant impact on crustal architecture, magma emplacement, fluid flow, and ore deposits. Application of the concept of extensional strain to ancient orogenic systems, like the Grenville province of eastern North America, has helped decipher the structural evolution of these regions. The Marcy massif is a ~3000 km2 Mesoproterozoic anorthosite batholith in the Adirondack Mountains (New York, USA) of the southern Grenville province. Bedrock geology mapping at 1:24,000 scale paired with characterization of bedrock exposed by recent landslides provides a glimpse into the structural architecture of the massif and its margin. New data demonstrate granulite- to amphibolite-facies deformational fabrics parallel the margin of the batholith, and that the Marcy massif is draped by a southeast-directed detachment zone. Within the massif, strain is localized into mutually offsetting conjugate shear zones with antithetic kinematic indicators. These relationships indicate that strain was coaxial within the Marcy massif, and that subsimple shear components of strain were partitioned along its margin. In situ U–Th–total Pb monazite analysis shows that deformation around and over the Marcy massif occurred from 1070 to 1060 Ma during granulite-facies metamorphism, and monazite from all samples record evidence for fluid-mediated dissolution reprecipitation from 1050 to 980 Ma. We interpret that rocks cooled isobarically after accretionary orogenesis and emplacement of the anorthosite- mangerite- charnockitegranite plutonic suite at ca. 1160–1140 Ma. Gravitational collapse during the Ottawan phase of the Grenville orogeny initiated along a southeast-directed detachment zone (Marcy massif detachment zone), which accommodated intrusion of the Lyon Mountain Granite Gneiss, and facilitated substantial fluid flow that catalyzed the formation of major ore deposits in the Adirondack Highlands.

New York↗
USGS2019

Geochemistry and geophysics of iron oxide-apatite deposits and associated waste piles with implications for potential rare earth element resources from ore and historic mine waste in the eastern Adirondack Highlands, New York, USA

The iron oxide-apatite (IOA) deposits of the eastern Adirondack Highlands, New York, are historical high-grade magnetite mines that contain variable concentrations of rare earth element (REE)-bearing apatite crystals. The majority of the deposits are hosted within sodically altered Lyon Mountain granite gneiss, although some deposits occur within paragneiss, gabbro, anorthosite, or potassically altered Lyon Mountain granite gneiss. The IOA deposits and the waste and/or tailings piles associated with them have potential as an unconventional resource for REEs. Reprocessing of these piles would have the advantage of partial recycling of the waste material to produce a set of critical elements. Thirty-four ore, nine rock, 25 waste-pile, and four tailings-pile samples were collected and analyzed for major, minor, and trace elements. At the tailings- and waste-pile sites, composite samples were collected by combining 30 to >50 subsamples randomly distributed over each pile. The total REE content of the waste and tailings piles varied from approximately 10 to 22,000 ppm, whereas the ore sample concentrations ranged from approximately 15 to 48,000 ppm total REEs. A positive correlation exists between the total REE content of ore and its associated waste pile. Median light REE/heavy REE values were 2.14 for waste/tailings piles and 2.25 for ore, which is a substantial relative enrichment in the heavy REEs in comparison to many developed REE mines, such as the mined carbonatites of Bayan Obo, China, and Mountain Pass, California. Importantly, the ore and waste samples are significantly enriched in both Y and Nd compared to other REEs in the samples. Other minor components such as Th are also elevated. Airborne radiometric surveys show large positive eTh and eU anomalies corresponding to tailings piles. Although it is a limited data set, geochemical data of unaltered and altered host rocks suggest a speculative new model for IOA ore formation in the Adirondack Highlands that is consistent with the geology and previously published data. The ferroan ore-hosting Lyon Mountain granite gneiss underwent localized potassic alteration that enriched the altered rock in Fe, REEs, Th, and other metals. A later sodic alteration event affected the previously potassically altered Lyon Mountain granite gneiss, which increased rock porosity and remobilized Fe, REEs, and other elements from the host rock into the iron ore seams. The sodic fluids responsible for ore formation were enriched in F and Cl.

New York↗
USGS2016

Reaction softening by dissolution–precipitation creep in a retrograde greenschist facies ductile shear zone, New Hampshire, USA

We describe strain localization by a mixed process of reaction and microstructural softening in a lower greenschist facies ductile fault zone that transposes and replaces middle to upper amphibolite facies fabrics and mineral assemblages in the host schist of the Littleton Formation near Claremont, New Hampshire. Here, Na-poor muscovite and chlorite progressively replace first staurolite, then garnet, and finally biotite porphyroblasts as the core of the fault zone is approached. Across the transect, higher grade fabric-forming Na-rich muscovite is also progressively replaced by fabric-forming Na-poor muscovite. The mineralogy of the new phyllonitic fault-rock produced is dominated by Na-poor muscovite and chlorite together with late albite porphyroblasts. The replacement of the amphibolite facies porphyroblasts by muscovite and chlorite is pseudomorphic in some samples and shows that the chemical metastability of the porphyroblasts is sufficient to drive replacement. In contrast, element mapping shows that fabric-forming Na-rich muscovite is selectively replaced at high-strain microstructural sites, indicating that strain energy played an important role in activating the dissolution of the compositionally metastable muscovite. The replacement of strong, high-grade porphyroblasts by weaker Na-poor muscovite and chlorite constitutes reaction softening. The crystallization of parallel and contiguous mica in the retrograde foliation at the expense of the earlier and locally crenulated Na-rich muscovite-defined foliation destroys not only the metastable high-grade mineralogy, but also its stronger geometry. This process constitutes both reaction and microstructural softening. The deformation mechanism here was thus one of dissolution–precipitation creep, activated at considerably lower stresses than might be predicted in quartzofeldspathic rocks at the same lower greenschist facies conditions.

New Hampshire↗
USGS2016

Bedrock geologic map of the Hartland and North Hartland quadrangles, Windsor County, Vermont, and Sullivan and Grafton Counties, New Hampshire

The bedrock geology of the 7.5-minute Hartland and North Hartland quadrangles, Vermont-New Hampshire, consists of highly deformed and metamorphosed lower Paleozoic metasedimentary, metavolcanic, and metaplutonic rocks of the Bronson Hill anticlinorium (BHA) and the Connecticut Valley trough (CVT). Rocks of the Orfordville anticlinorium on this map occupy the western part of the broader BHA. In the BHA, the Ordovician Ammonoosuc Volcanics and graphitic, sulfidic metapelite of the Partridge Formation are intruded by Ordovician plutonic rocks of the Oliverian Plutonic Suite. The Ordovician rocks are collectively referred to as the Bronson Hill arc. The Ordovician rocks are overlain by the Silurian to Devonian Clough, Fitch, and Littleton Formations. On this map, rocks of the CVT occupy the eastern part of the broader CVT. In the CVT in Vermont, the Silurian to Devonian Shaw Mountain, Waits River, and Gile Mountain Formations form an unconformable autochthonous to parautochthonous cover sequence on the pre-Silurian rocks of the Rowe-Hawley zone above Precambrian basement rocks of the Mount Holly Complex. On this map, however, only the Waits River and Gile Mountain Formations are exposed. Syn- to postmetamorphic rocks include quartz veins and Cretaceous dikes of the White Mountain Igneous Suite. Rocks of the BHA occur in a thrust sheet floored by the Monroe fault, which carried a deformed section of plutonic rocks, Ammonoosuc Volcanics, Partridge Formation, Clough Quartzite, and the Fitch and Littleton Formations. The Monroe thrust sheet placed the BHA rocks over the CVT during an early Acadian F 1 nappe-stage event prior to peak metamorphism at lower amphibolite facies conditions. Upper and lower plate truncations, mylonite, and local mélange characterize the Monroe fault. F 2 doming deformed the Monroe thrust sheet, folded earlier isograds, and created the Meriden antiform and Lebanon dome. Lower greenschist facies (Acadian to Alleghanian) faults such as the Sumner Falls shear zone truncated peak-metamorphic assemblages, isograds, and older F 1 folds and faults. Late-stage F 3 folds show preferred left-lateral rotation sense and are probably related to late dome-stage Alleghanian deformation or motion along lower greenschist facies faults. The youngest deformation is characterized by Mesozoic brittle faulting and spatially associated kink bands along the Ammonoosuc fault zone, followed by subsequent jointing. Currently major economic natural resource activities are related to aggregate quarrying in the Ammonoosuc Volcanics at Twin State Sand and Gravel in Hartford, Vt., and Lebanon Crushed Stone in Lebanon, N.H. This report consists of sheets 1 and 2 as well as an online geographic information systems database that includes contacts of bedrock geologic units, faults, outcrops, structural geologic information, and photographs. Sheet 2 of this report shows three cross sections, a tectonic map, and two brittle features maps that show measured outcrop-scale strike and dip results with summary stereonets and rose diagrams.

New Hampshire, Vermont↗
USGS2016

Geochemistry and origin of metamorphosed mafic rocks from the Lower Paleozoic Moretown and Cram Hill Formations of North-Central Vermont: Delamination magmatism in the western New England appalachians

The Moretown Formation, exposed as a north-trending unit that extends from northern Vermont to Connecticut, is located along a critical Appalachian litho-tectonic zone between the paleomargin of Laurentia and accreted oceanic terranes. Remnants of magmatic activity, in part preserved as metamorphosed mafic rocks in the Moretown Formation and the overlying Cram Hill Formation, are a key to further understanding the tectonic history of the northern Appalachians. Field relationships suggest that the metamorphosed mafic rocks might have formed during and after Taconian deformation, which occurred at ca . 470 to 460 Ma. Geochemistry indicates that the sampled metamorphosed mafic rocks were mostly basalts or basaltic andesites. The rocks have moderate TiO 2 contents (1–2.5 wt %), are slightly enriched in the light-rare earth elements relative to the heavy rare earths, and have negative Nb-Ta anomalies in MORB-normalized extended rare earth element diagrams. Their chemistry is similar to compositions of basalts from western Pacific extensional basins near volcanic arcs. The metamorphosed mafic rocks of this study are similar in chemistry to both the pre-Silurian Mount Norris Intrusive Suite of northern Vermont, and also to some of Late Silurian rocks within the Lake Memphremagog Intrusive Suite, particularly the Comerford Intrusive Complex of Vermont and New Hampshire. Both suites may be represented among the samples of this study. The geochemistry of all samples indicates that parental magmas were generated in supra-subduction extensional environments during lithospheric delamination.

American Journal of Science↗
USGS2015

Identification of groundwater nitrate contamination from explosives used in road construction: Isotopic, chemical, and hydrologic evidence

Explosives used in construction have been implicated as sources of NO 3 – contamination in groundwater, but direct forensic evidence is limited. Identification of blasting-related NO 3 – can be complicated by other NO 3 – sources, including agriculture and wastewater disposal, and by hydrogeologic factors affecting NO 3 – transport and stability. Here we describe a study that used hydrogeology, chemistry, stable isotopes, and mass balance calculations to evaluate groundwater NO 3 – sources and transport in areas surrounding a highway construction site with documented blasting in New Hampshire. Results indicate various groundwater responses to contamination: (1) rapid breakthrough and flushing of synthetic NO 3 – (low δ 15 N, high δ 18 O) from dissolution of unexploded NH 4 NO 3 blasting agents in oxic groundwater; (2) delayed and reduced breakthrough of synthetic NO 3 – subjected to partial denitrification (high δ 15 N, high δ 18 O); (3) relatively persistent concentrations of blasting-related biogenic NO 3 – derived from nitrification of NH 4 + (low δ 15 N, low δ 18 O); and (4) stable but spatially variable biogenic NO 3 – concentrations, consistent with recharge from septic systems (high δ 15 N, low δ 18 O), variably affected by denitrification. Source characteristics of denitrified samples were reconstructed from dissolved-gas data (Ar, N 2 ) and isotopic fractionation trends associated with denitrification (Δδ 15 N/Δδ 18 O ≈ 1.31). Methods and data from this study are expected to be applicable in studies of other aquifers affected by explosives used in construction.

Environmental Science & Technology↗
USGS2015

Bedrock geologic map of the Worcester South quadrangle, Worcester County, Massachusetts

The bedrock geology of the 7.5-minute Worcester South quadrangle, Massachusetts, consists of deformed Neoproterozoic to Paleozoic crystalline metamorphic and intrusive igneous rocks in three fault-bounded terranes (zones), including the Avalon, Nashoba, and Merrimack zones (Zen and others, 1983). This quadrangle spans the easternmost occurrence of Ganderian margin arc-related rocks (Nashoba zone) in the southern New England part of the northern Appalachians, and coincides with the trailing edge of Ganderia (Merrimack and Nashoba zones) where it structurally overlies Avalonia (Hibbard and others, 2006; Pollock and others, 2012; van Staal and others, 2009, 2012). Neoproterozoic intrusive rocks and minor metasedimentary rocks crop out in the Avalon zone and structurally underlie the rocks of the Nashoba zone along the Bluddy Bluff fault. Due to poor exposure, the position of the Bloody Bluff fault is not well-constrained and its location is partly extrapolated from mapping in adjacent areas (Barosh, 2005; Walsh and others, 2011a). Cambrian intrusive rocks and Cambrian to Silurian metasedimentary and metavolcanic rocks crop out in the Nashoba zone, and are overlain by largely Silurian metasedimentary rocks of the Merrimack zone along the Clinton-Newbury fault. Ordovician to Permian(?) plutonic rocks intrude the Merrimack and Nashoba zone rocks. Paleozoic metamorphism in the Merrimack and Nashoba zones peaked during Salinic, Acadian, and Neoacadian orogenesis from the Silurian to Mississippian (Wintsch and others, 2007; Stroud and others, 2009; Walsh and others, 2011a; Hepburn and others, 2014). Metamorphism in the Avalon zone peaked during Alleghanian orogenesis in the Mississippian to Permian (Wintsch and others, 1992, 1993, 2001; Attenoukon, 2008). Evidence for garnet-grade extensional Alleghanian mylonitization showing normal motion along the Clinton-Newbury fault occurred after presumed original terrane juxtaposition by left-lateral Acadian thrusting (Goldstein, 1994). Subsequent post-peak metamorphic deformation produced outcrop-scale open folds and weak cleavage, local faults, veins, shear bands, and pegmatite dikes. Locally, along re-activated ductile faults such as the Bloody Bluff fault and along the Wekepeke fault, late Paleozoic to Mesozoic mainly brittle normal fault motion led to the current configuration of fault-bounded lithotectonic terranes (Goldstein, 1982, 1994, 1998; Goldstein and Hepburn, 1999; Goldsmith, 1991; Attenoukon, 2008; Wintsch and others, 2012). The youngest deformation includes kink bands, brittle faults, and joints. The bedrock geology was mapped to study the tectonic history of the area and to provide a framework for ongoing hydrogeologic characterization of the fractured bedrock of Massachusetts. This report presents mapping by Gregory J. Walsh and Arthur J. Merschat from 2008 to 2010. The report consists of a map and GIS database, both of which are available for download at http://dx.doi.org/ 10.3133/sim3345. The database includes contacts of bedrock geologic units, faults, outcrop locations, structural information, and photographs.

Massachusetts↗
USGS2014

Telescoping metamorphic isograds: Evidence from 40Ar/39A dating in the Orange-Milford belt, southern Connecticut

New 40 Ar/ 39 Ar ages for hornblende and muscovite from the Orange-Milford belt in southern Connecticut reflect cooling from Acadian amphibolite facies metamorphism between ∼380 to 360 Ma followed by retrograde recrystallization of fabric-forming muscovite and chlorite during lower greenschist facies Alleghanian transpression at ∼280 Ma. Reported field temperature and pressure gradients are improbably high for these rocks and a NW metamorphic field gradient climbing from chlorite-grade to staurolite-grade occurs over less than 5 km. Simple tilting cannot account for this compressed isograd spacing given the geothermal gradient of ∼20 °C/km present at the time of regional metamorphism. However, post-metamorphic transpression could effectively telescope the isograds by stretching the belt at an oblique angle to the isograd traces. Textures in the field and in thin section reveal several older prograde schistosities overprinted by lower greenschist facies fabrics. The late cleavages commonly occur at the scale of ∼100 μm and these samples contain multiple age populations of white mica. 40 Ar/ 39 Ar analysis of these poly-metamorphic samples with mixed muscovite populations yield climbing or U-shaped age spectra. The ages of the low temperature steps are late Paleozoic, while the ages of the older steps are late Devonian. These results support our petrologic interpretation that the younger cleavage developed under metamorphic conditions below the closure temperature for Ar diffusion in muscovite, that is, in the lower greenschist facies. The correlation of a younger regionally reproducible age population with a pervasive retrograde muscovite ± chlorite cleavage reveals an Alleghanian (∼280 Ma) overprint on the Acadian metamorphic gradient (∼380 Ma). Outcrop-scale structures including drag folds and imbricate boudins suggest that Alleghanian deformation and cleavage development occurred in response to dextral transpression along a northeast striking boundary. Alleghanian oblique collision of accreting terranes from the northeast would have resulted in northeast-southwest dextral transpression against the New York promontory. This deformation was responsible for crystallization of pervasive retrograde muscovite + chlorite cleavages and associated telescoping of the Acadian metamorphic isograds in southern Connecticut at ∼280 Ma.

Connecticut↗
USGS2014

Neoproterozoic–Cambrian stratigraphic framework of the Anti-Atlas and Ouzellagh promontory (High Atlas), Morocco

In the last two decades, great progress has been made in the geochronological, chrono- and chemostratigraphic control of the Neoproterozoic and Cambrian from the Anti-Atlas Ranges and the Ouzellagh promontory (High Atlas). As a result, the Neoproterozoic is lithostratigraphically subdivided into: (i) the Lkest-Taghdout Group (broadly interpreted at c. 800–690 Ma) representative of rift-to-passive margin conditions on the northern West African craton; (ii) the Iriri (c. 760–740 Ma), Bou Azzer (c. 762–697 Ma) and Saghro (c. 760?–610 Ma) groups, the overlying Anezi, Bou Salda, Dadès and Tiddiline formations localized in fault-grabens, and the Ouarzazate Supergroup (c. 615–548 Ma), which form a succession of volcanosedimentary complexes recording the onset of the Pan-African orogeny and its aftermath; and (iii) the Taroudant (the Ediacaran–Cambrian boundary lying in the Tifnout Member of the Adoudou Formation), Tata, Feijas Internes and Tabanite groups that have recorded development of the late Ediacaran–Cambrian Atlas Rift. Recent discussions of Moroccan strata to select new global GSSPs by the International Subcommissions on Ediacaran and Cambrian Stratigraphy have raised the stratigraphic interest in this region. A revised and updated stratigraphic framework is proposed here to assist the tasks of both subcommissions and to fuel future discussions focused on different geological aspects of the Neoproterozoic–Cambrian time span.

Journal of African Earth Sciences↗
USGS2014

Bedrock geologic map of the Uxbridge quadrangle, Worcester County, Massachusetts, and Providence County, Rhode Island

The bedrock geology of the 7.5-minute Uxbridge quadrangle consists of Neoproterozoic metamorphic and igneous rocks of the Avalon zone. In this area, rocks of the Avalon zone lie within the core of the Milford antiform, south and east of the terrane-bounding Bloody Bluff fault zone. Permian pegmatite dikes and quartz veins occur throughout the quadrangle. The oldest metasedimentary rocks include the Blackstone Group, which represents a Neoproterozoic peri-Gondwanan marginal shelf sequence. The metasedimentary rocks are intruded by Neoproterozoic arc-related plutonic rocks of the Rhode Island batholith. This report presents mapping by G.J. Walsh. The complete report consists of a map, text pamphlet, and GIS database. The map and text pamphlet are available only as downloadable files (see frame at right). The GIS database is available for download in ESRI™ shapefile and Google Earth™ formats, and includes contacts of bedrock geologic units, faults, outcrops, structural geologic information, geochemical data, and photographs.

Massachusetts, Rhode Island↗
USGS2013

Bedrock geologic map of the Nashua South quadrangle, Hillsborough County, New Hampshire, and Middlesex County, Massachusetts

The bedrock geology of the 7.5-minute Nashua South quadrangle consists primarily of deformed Silurian metasedimentary rocks of the Berwick Formation. The metasedimentary rocks are intruded by a Late Silurian to Early Devonian diorite-gabbro suite, Devonian rocks of the Ayer Granodiorite, Devonian granitic rocks of the New Hampshire Plutonic Suite including pegmatite and the Chelmsford Granite, and Jurassic diabase dikes. The bedrock geology was mapped to study the tectonic history of the area and to provide a framework for ongoing hydrogeologic characterization of the fractured bedrock of Massachusetts and New Hampshire. This report presents mapping by G.J. Walsh and R.H. Jahns and zircon U-Pb geochronology by J.N. Aleinikoff. The complete report consists of a map, text pamphlet, and GIS database. The map and text pamphlet are only available as downloadable files (see frame at right). The GIS database is available for download in ESRI TM shapefile and Google Earth TM formats, and includes contacts of bedrock geologic units, faults, outcrops, structural geologic information, photographs, and a three-dimensional model.

Massachusetts, New Hampshire↗