Geology topics

Gregory F. McIsaac

Publications and source records attributed to Gregory F. McIsaac.

5 recordsLinked to original sources

USGS2026

Spatially consistent but temporally divergent changes in nitrate and phosphorus loads and yields in Illinois watersheds, 1997–2022

Illinois contributes substantial nutrient loads to the Gulf of America, warranting watershed-scale assessment. This study estimated nitrate-nitrogen (nitrate-N) and total phosphorus (TP) loads and yields for 49 Illinois 8-digit hydrologic unit code (HUC8) watersheds draining to the Mississippi River Basin from 1997–2022, comparing recent (2018–2022) to baseline (1997–2011) conditions. Estimates included point and nonpoint source contributions, dissolved phosphorus, and water yields. During the recent period, nonpoint sources dominated nutrient export (82% nitrate-N, 78% TP), though point sources drove high yields in the Chicago area. Spatially, nonpoint source nutrient hotspots persisted with nitrate-N yields highest in east-central and northern Illinois and TP yields higher in southern and western Illinois. Temporally, statewide nitrate-N loads decreased 9%, while TP loads increased 27%. Nitrate-N yields increased in 22 HUC8s and decreased in 20, while TP yields increased in 32 HUC8s and decreased in 9. For both nutrients, baseline yields were negatively correlated with yield changes, indicating high-yielding watersheds tended toward larger decreases or smaller increases. Water yields increased 19% on average but were weakly correlated with nutrient yield changes ( r = 0.23 and 0.20 for nitrate-N and TP). These results reveal spatially persistent yet temporally divergent nutrient export across Illinois, with contrasting nitrate-N and TP trajectories for nonpoint sources.

Illinois↗

USGS2025

How do hydrological variability and human activities control the spatiotemporal changes of riverine nitrogen export in the Upper Mississippi River Basin?

Excessive nitrogen export from agricultural watersheds remains a critical water quality challenge, with the Upper Mississippi River Basin (UMRB) significantly contributing to downstream eutrophication and hypoxia in the Gulf. This study investigates the spatiotemporal dynamics of riverine nitrate plus nitrite (NO 3 – + NO 2 – -N) export across the UMRB at high spatial resolution (12-digit Hydrologic Unit Codes or HUC12 subwatershed scale) during 2001–2020 and quantifies the effects of anthropogenic activities and hydrological variability on riverine NO 3 – + NO 2 – -N export changes in the region between 2001–2005 and 2016–2020. Our results revealed hotspots of substantial increases in NO 3 – + NO 2 – -N yields across the UMRB, with distinct regional patterns in driving factors. Over the entire UMRB, NO 3 – + NO 2 – -N yields increased by 9.7 kg/ha/yr on average from 2001–2005 to 2016–2020, with anthropogenic activities contributing 4.8 kg/ha/yr and hydrological variability contributing 4.9 kg/ha/yr. The northern and western UMRB had combined influences from both anthropogenic activities and hydrological variability, while the east-central regions had predominantly hydrologically driven changes. Agricultural sources, including fertilizer, manure, and biological nitrogen fixation, collectively contributed over 80% of NO 3 – + NO 2 – -N loading throughout the basin. This framework for disentangling human and hydrological impacts provides critical insights for developing effective and targeted watershed management strategies to reduce nutrient losses and improve water quality.

Upper Mississippi River Basin↗

USGS2025

Diverging trends in nitrate and phosphorus loads and yields across Illinois watersheds, 1997–2022

Illinois is a major contributor of nutrients to the northern Gulf of Mexico. As such, the State of Illinois initiated efforts to curb nutrient runoff over the last several decades. To evaluate progress towards these reductions, water-quality data were used to estimate incremental loads and yields of nitrate plus nitrite (NO3) and total phosphorus (TP) from 1997–2022 for 49 Illinois watersheds, defined using eight-digit hydrologic unit codes (HUC8), draining to the Mississippi River Basin. To estimate changes in NO3 and TP loads, recent loads from the period 2018 through 2022 were compared to baseline loads from 1997 through 2011. Nonpoint and point source loads, dissolved phosphorus (DP) loads, and water yields were also estimated. The sum of the incremental NO3 loads from the 49 HUC8s decreased 9% despite a 19% increase in water yield. Much of this decline occurred in HUC8s that had NO3 yields greater than 17 pounds per acre per year (lbs/acre/yr) during a 1997–2011 baseline period. The sum of all incremental HUC8 TP loads increased 25% despite a 27% reduction in point source discharge. Loads and yields were substantially larger for both NO3 and TP in the Chicago area. Outside the Chicago area, central and northern Illinois had higher NO3 yields than southern Illinois and a reverse pattern for TP where higher yields occur in southern Illinois. Nonpoint sources made up an estimated 82% and 78% of the NO3 and TP yields, respectively, across the HUC8s. In general, point source yields have mostly decreased over time, while nonpoint source yields varied depending on location and reflect the changes in the total yield.

Illinois↗

USGS2022

Spatial and temporal variations in phosphorus loads in the Illinois River Basin, Illinois USA

Total phosphorus (TP) loads in many rivers in the north-central United States have increased, including the Illinois River at Valley City, Illinois, USA, which increased 39% from the periods 1989–1996 to 2015–2019 despite efforts to reduce loads from point and nonpoint sources. Here, we quantify long-term variations in phosphorus (P) loads in the Illinois River and its tributaries and identify factors that may be causing the variations. We calculated river loads of dissolved (DP) and particulate P (PP), total and volatile suspended solids (TSS and VSS), and other potentially related constituents at 41 locations. DP loads generally increased and PP and TSS loads generally decreased from 1989–1996 to 2015–2019. During 1989–1996, P accumulated in the lower basin between Marseilles and Valley City (excluding monitored tributaries). This portion of the basin is very flat and accumulates sediment. During 2015–2019, this section shifted from being a net sink to being a net source of P, accounting for 78% of the increased TP load at Valley City. We present evidence supporting several mechanisms that could have caused this shift: increased DP and chloride loads, reduced sulfate and nitrate concentrations influencing ionic strength and redox potential in the sediments, and increased VSS loads at Valley City possibly indicating greater algal production and contributing to hypoxia in lower river sediments. Additional research is needed to quantify the relative importance of these mechanisms.

Illinois, Indiana, Wisconsin↗

USGS2002

Relating net nitrogen input in the Mississippi River Basin to nitrate flux in the Lower Mississippi River--A comparison of approaches

A quantitative understanding of the relationship between terrestrial N inputs and riverine N flux can help guide conservation, policy, and adaptive management efforts aimed at preserving or restoring water quality. The objective of this study was to compare recently published approaches for relating terrestrial N inputs to the Mississippi River basin (MRB) with measured nitrate flux in the lower Mississippi River. Nitrogen inputs to and outputs from the MRB (1951 to 1996) were estimated from state-level annual agricultural production statistics and NO y (inorganic oxides of N) deposition estimates for 20 states that comprise 90% of the MRB. A model with water yield and gross N inputs accounted for 85% of the variation in observed annual nitrate flux in the lower Mississippi River, from 1960 to 1998, but tended to underestimate high nitrate flux and overestimate low nitrate flux. A model that used water yield and net anthropogenic nitrogen inputs (NANI) accounted for 95% of the variation in riverine N flux. The NANI approach accounted for N harvested in crops and assumed that crop harvest in excess of the nutritional needs of the humans and livestock in the basin would be exported from the basin. The U.S. White House Committee on Natural Resources and Environment (CENR) developed a more comprehensive N budget that included estimates of ammonia volatilization, denitrification, and exchanges with soil organic matter. The residual N in the CENR budget was weakly and negatively correlated with observed riverine nitrate flux. The CENR estimates of soil N mineralization and immobilization suggested that there were large (2000 kg N ha −1 ) net losses of soil organic N between 1951 and 1996. When the CENR N budget was modified by assuming that soil organic N levels have been relatively constant after 1950, and ammonia volatilization losses are redeposited within the basin, the trend of residual N closely matched temporal variation in NANI and was positively correlated with riverine nitrate flux in the lower Mississippi River. Based on results from applying these three modeling approaches, we conclude that although the NANI approach does not address several processes that influence the N cycle, it appears to focus on the terms that can be estimated with reasonable certainty and that are correlated with riverine N flux.

Journal of Environmental Quality↗