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Gordon B. Haxel

Publications and source records attributed to Gordon B. Haxel.

15 recordsLinked to original sources

Temporal and petrogenetic links between Mesoproterozoic alkaline and carbonatite magmas at Mountain Pass, California

Mountain Pass is the site of the most economically important rare earth element (REE) deposit in the United States. Mesoproterozoic alkaline intrusions are spatiotemporally associated with a composite carbonatite stock that hosts REE ore. Understanding the genesis of the alkaline and carbonatite magmas is an essential scientific goal for a society in which critical minerals are in high demand and will continue to be so for the foreseeable future. We present an ion microprobe study of zircon crystals in shonkinite and syenite intrusions to establish geochronological and geochemical constraints on the igneous underpinnings of the Mountain Pass REE deposit. Silicate whole-rock compositions occupy a broad spectrum (50–72 wt % SiO 2 ), are ultrapotassic (6–9 wt % K 2 O; K 2 O/Na 2 O = 2–9), and have highly elevated concentrations of REEs (La 500–1,100× chondritic). Zircon concordia 206 Pb/ 238 U- 207 Pb/ 235 U ages determined for shonkinite and syenite units are 1409 ± 8, 1409 ± 12, 1410 ± 8, and 1415 ± 6 Ma (2 σ ). Most shonkinite dikes are dominated by inherited Paleoproterozoic xenocrysts, but there are sparse primary zircons with 207 Pb/ 206 Pb ages of 1390–1380 ± 15 Ma for the youngest grains. Our new zircon U-Pb ages for shonkinite and syenite units overlap published monazite Th-Pb ages for the carbonatite orebody and a smaller carbonatite dike. Inherited zircons in shonkinite and syenite units are ubiquitous and have a multimodal distribution of 207 Pb/ 206 Pb ages that cluster in the range of 1785–1600 ± 10–30 Ma. Primary zircons have generally lower Hf (<11,000 ppm) and higher Eu/Eu* (>0.6), Th (>300 ppm), Th/U (>1), and Ti-in-zircon temperatures (>800°C) than inherited zircons. Oxygen isotope data reveals a large range in δ 18 O values for primary zircons, from mantle (5–5.5‰) to crustal and supracrustal (7–9‰). A couple of low- δ 18 O outliers (2‰) point to a component of shallow crust altered by meteoric water. The δ 18 O range of inherited zircons (5–10‰) overlaps that of the primary zircons. Our study supports a model in which alkaline and carbonatite magmatism occurred over tens of millions of years, repeatedly tapping a metasomatized mantle source, which endowed magmas with elevated REEs and other diagnostic components (e.g., F, Ba). Though this metasomatized mantle region existed for the duration of Mountain Pass magmatism, it probably did not predate magmatism by substantial geologic time (>100 m.y.), based on the similarity of 1500 Ma zircons with the dominantly 1800–1600 Ma inherited zircons, as opposed to the 1450–1350 Ma primary zircons. Mountain Pass magmas had diverse crustal inputs from assimilation of Paleoproterozoic and Mesoproterozoic igneous, metaigneous, and metasedimentary rocks. Crustal assimilation is only apparent from high spatial resolution zircon analyses and underscores the need for mineral-scale approaches in understanding the genesis of the Mountain Pass system.

California↗

Late Neogene deformation of the Chocolate Mountains Anticlinorium: Implications for deposition of the Bouse Formation and early evolution of the Lower Colorado River

Deformation related to late Neogene dextral shear can explain a shift from an estuarine to lacustrine depositional environment in the southern Bouse Formation north of Yuma, Arizona. We infer that late Neogene deformation in the Chocolate Mountain Anticlinorium (CMA) created a barrier that blocked an estuary inlet, and that pre-existing and possibly active structures subsequently controlled the local course of the lower Colorado River. Structural patterns summarized below suggest that the CMA absorbed transpressional strain caused by left-stepping segments of dextral faults of the San Andreas fault system and/or the eastern California shear zone and Gulf of California shear zone. For this hypothesis to be correct, about 200-250 m of post-6 Ma, pre- ~5.3 Ma uplift along the CMA crest would be required to cut off a marine inlet. The 220-km-long CMA, cored by the early Paleogene Orocopia Schist subduction complex, extends from the Orocopia Mountains (Calif.) southeastward through the Chocolate Mountains (parallel to the southern San Andreas fault). Where Highway 78 crosses the Chocolate Mountains (Fig. 1), the CMA turns eastward through the Black Mountain-Picacho area (Calif.) and Trigo Mountains (Ariz.) into southwest Arizona. It separates southernmost Bouse Formation outcrops of the Blythe basin from subsurface Bouse outcrops to the south in the Yuma area. South of Blythe basin the CMA is transected by the lower Colorado River along a circuitous path. Here we focus on the geology of an area between the central Chocolate Mountains and the Yuma Proving Grounds in Arizona. Specific landmarks include the southeast Chocolate Mountains, Midway Mountains, Peter Kane Mountain, Black Mountain, Picacho Peak, and Gavilan Hills. For simplicity, we refer to this as the eastern Chocolate Mountains.

Conference Paper↗

Mantle peridotite in newly discovered far-inland subduction complex, southwest Arizona: Initial report

The latest Cretaceous to early Palaeogene Orocopia Schist and related units are generally considered a low-angle subduction complex that underlies much of southern California and Arizona. A recently discovered exposure of Orocopia Schist at Cemetery Ridge west of Phoenix, Arizona, lies exceptionally far inland from the continental margin. Unexpectedly, this body of Orocopia Schist contains numerous blocks, as large as ~300 m, of variably serpentinized mantle peridotite. These are unique; elsewhere in the Orocopia and related schists, peridotite is rare and completely serpentinized. Peridotite and metaperidotite at Cemetery Ridge are of three principal types: (1) serpentinite and tremolite serpentinite, derived from dunite; (2) partially serpentinized harzburgite and olivine orthopyroxenite (collectively, harzburgite); and (3) granoblastic or schistose metasomatic rocks, derived from serpentinite, made largely of actinolite, calcic plagioclase, hercynite, and chlorite. In the serpentinite, paucity of relict olivine, relatively abundant magnetite (5%), and elevated Fe 3 + /Fe indicate advanced serpentinization. Harzburgite contains abundant orthopyroxene, only slightly serpentinized, and minor to moderate (1–15%) relict olivine. Mantle tectonite fabric is locally preserved. Several petrographic and geochemical characteristics of the peridotite at Cemetery Ridge are ambiguously similar to either abyssal or mantle-wedge (suprasubduction) peridotites and serpentinites. Least ambiguous are orthopyroxene compositions. Orthopyroxene is distinctively depleted in Al 2 O 3 , Cr 2 O 3 , and CaO, indicating mantle-wedge affinities. Initial interpretation of field and petrologic data suggests that the peridotite blocks in the Orocopia Schist subduction complex at Cemetery Ridge may be derived from the leading corner or edge of a mantle wedge, presumably in (pre-San Andreas fault) southwest California. However, derivation from a subducting plate is not precluded.

Arizona↗

Introduction to special section on the California-Arizona crustal transect: CACTIS, Part 3

The CACTIS (California‐Arizona Crustal Transect Interim Synthesis) workshop in May 1988 brought researchers together in Flagstaff, Arizona, to discuss the geologic evolution and crustal structure of the southern Cordillera between the San Andreas fault in southeastern California and the Colorado Plateau in Arizona [ Sass et al ., 1988]. The first set of papers resulting from the workshop appeared in the Journal of Geophysical Research (JGR) as the special CACTIS 1 section in January 1990 [ Howard et al ., 1990], and a second as CACTIS 2 in November 1990 [ Haxel et al ., 1990]. Twelve papers in this issue form part 3 of the CACTIS series. A final collection of papers will appear in the future as a joint special section with the California Consortium for Crustal Studies (CALCRUST).

Journal of Geophysical Research B: Solid Earth↗

Geology and geochemistry of Jurassic plutonic rocks, Baboquivari Mountains, south-central Arizona

Among the plutons of the Jurassic magmatic arc segment in southern Arizona, northern Sonora, and southern California, two distinctive rock types dominate, occurring together in numerous mountain ranges: porphyritic, titanite-bearing hornblende-biotite granodiorite; and biotite leucogranite. These characteristic rocks are particularly well preserved and well exposed around Kitt Peak, in the Baboquivari Mountains, southern Arizona. The Middle to early Late Jurassic Kitt Peak Plutonic Suite (KPPS) comprises three units: Aguirre Peak Quartz Diorite (APQD;<170 Ma, >=165 Ma, U-Pb), chiefly hornblende mesodiorite; Kitt Peak Granodiorite (KPGD; 165 Ma), hornblende-biotite granodiorite and monzogranite; and Pavo Kug Granite (PKG; 159 Ma), equigranular biotite leucogranite. This range also hosts a fourth, regionally unusual, Jurassic plutonic unit: the Baboquivari Peak Perthite Granite, related to post-arc, Late Jurassic crustal extension. Binary variation diagrams, incompatible element patterns, and REE spectra indicate APQD and KPGD are consanguineous. APQD basaltic mesodiorite evidently approximates the parental magma for the APQD–KPGD series. More evolved rocks of this series evidently formed by combinations of fractional crystallization and mixing with or assimilation of crustal material. PKG is less directly related to APQD and KPGD than these two are to one another.

Arizona, Sonora↗

Late Jurassic igneous rocks in south-central Arizona and north-central Sonora: Magmatic accompaniment of crustal extension

In Middle Jurassic time, the region of south-central Arizona and north-central Sonora was part of a continental magmatic arc. In early Late Jurassic time, this magmatic arc gradually gave way to a extensional regime. Late Jurassic rifting was accompanied by magmatism, typically small in volume relative to the preceding arc phase, and with mildly alkaline compositions. These igneous rocks, the 158- to 146-Ma Ko Vaya Suite, make up much or most of the Comobabi, Artesa, Quijotoa, and Brownell Mountains and Sierra del Cobre. The bimodal Ko Vaya Suite constitutes volcanic to shallow plutonic complexes comprising chiefly trachyandesite and volcanic wacke; monzodiorite; rhyolite porphyry; distinctive, compositionally and texturally heterogeneous, quartzpoor granite (the Ko Vaya Granite); A-type perthite granite and quartz syenite; aphyric intrusive rhyolite; and locally abundant hematite veins. Alteration, particularly potassic alteration, is widespread. Minimally altered samples of granite and quartz syenite have the composition of trachyte or trachydacite and alkali rhyolite. The Ko Vaya Suite is nonconformably overlain by the latest Jurassic Sand Wells Formation, approximately correlative with the Glance Conglomerate, the basal unit of the Bisbee Group. The Ko Vaya Suite is in some ways analogous to the coeval Independence dike swarm of eastern California, but less diffuse. We infer that the Ko Vaya Suite represents especially intense or focused Late Jurassic extensional magmatism.

Arizona, Sonora↗

Extensional reactivation of the Chocolate Mountains subduction thrust in the Gavilan Hills of southeastern California

The NE vergent Chocolate Mountains fault of south-eastern California has been interpreted as either a subduction thrust responsible for burial and prograde metamorphism of the ensimatic Orocopia Schist or as a normal fault involved in the exhumation of the schist. Our detailed structural analysis in the Gavilan Hills area provides new evidence to confirm the latter view. A zone of deformation is present at the top of the Orocopia Schist in which lineations are parallel to those in the upper plate of the Chocolate Mountains fault but oblique to ones at relatively deep levels in the schist. Both the Orocopia Schist and upper plate contain several generations of shear zones that show a transition from crystalloblastic through mylonitic to cataclastic textures. These structures formed during retrograde metamorphism and are considered to record the exhumation of the Orocopia Schist during early Tertiary time as a result of subduction return flow. The Gatuna fault, which places low-grade, supracrustal metasediments of the Winterhaven Formation above the gneisses of the upper plate, also seems to have been active at this time. Final unroofing of the Orocopia Schist occurred during early to middle Miocene regional extension and may have involved a second phase of movement on the Gatuna fault. Formation of the Chocolate Mountains fault during exhumation indicates that its top-to-the-NE sense of movement provides no constraint on the polarity of the Orocopia Schist subduction zone. This weakens the case for a previous model involving SW dipping subduction, while providing support for the view that the Orocopia Schist is a correlative of the Franciscan Complex.

California↗