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Georgy Cherkashov

Publications and source records attributed to Georgy Cherkashov.

3 recordsLinked to original sources

Changes in sediment source areas to the Amerasia Basin, Arctic Ocean, over the past 5.5 million years based on radiogenic isotopes (Sr, Nd, Pb) of detritus from ferromanganese crusts

Ferromanganese (FeMn) crusts provide a useful paleoenvironmental archive for studying the poorly understood climatic, oceanographic, and geologic evolution of the Arctic Ocean. This study is based on the identification and temporal reconstruction of sources and inferred transport pathways of terrigenous material in FeMn crusts collected from several sites across the Amerasia Basin. Samples from the Alpha Ridge (AR), Mendeleev Ridge (MR), and Chukchi Borderland (CB) have similar chemical compositions and high detrital contents. Sr, Nd, and Pb isotopic compositions of the terrigenous detritus extracted from the FeMn crust layers show spatial and temporal variability due to the variable proportions of inputs from the North American and East Siberian margins and local submarine outcrops. The temporal resolution is restricted by macroscopic crust layers, which represent times of significant changes in the depositional environment and are used to study first-order environmental changes. During the period of ca. 4.4 to 3.8 Myr ago, detritus in the MR area was derived mostly from the Laptev Sea. Then, until about 1.3 Myr ago, FeMn crusts from MR received a higher volcanic component sourced from the East Siberian Sea, with mixing of detritus from the Okhotsk-Chukotka volcanic belt (OCVB) area and possibly weathering of local MR outcrops, which is mostly High Arctic Large Igneous Province (HALIP) rocks. The period from about 1.3 Myr ago to the present reflects enhanced contributions of detritus from the Canadian Shield, approximately equal to the East Siberian contribution for the MR area. CB crusts show three main periods of distinct detrital input. During the period ca. 5.5–5.0 Myr ago, CB detritus was sourced from local submarine outcrops of the Jurassic-Cretaceous HALIP rocks and possibly from northeast Siberia, including OCVB rocks, while during the period from about 5.0 to 3.6 Myr ago, the CB FeMn crusts had a much greater input of detritus from the North American margin. After 3.6 Myr ago, the CB detritus shows a mixed composition predominantly sourced from North America with some material transported from the Bering Sea and smaller contributions from northeast Siberia. The AR crust was influenced mostly by detritus sourced from the Canadian Shield. This study shows that FeMn crusts from the Arctic ocean are a useful tool and archive for climate reconstruction and depositional history of this polar region.

Marine Geology

Mineral phase-element associations based on sequential leaching of ferromanganese crusts, Amerasia Basin Arctic Ocean

Ferromanganese (FeMn) crusts from Mendeleev Ridge, Chukchi Borderland, and Alpha Ridge, in the Amerasia Basin, Arctic Ocean, are similar based on morphology and chemical composition. The crusts are characterized by a two- to four-layered stratigraphy. The chemical composition of the Arctic crusts differs significantly from hydrogenetic crusts from elsewhere of global ocean by high mean Fe/Mn ratios, high As, Li, V, Sc, and Th concentrations, and high detrital contents. Here, we present element distributions through crust stratigraphic sections and element phase association using several complementary techniques such as SEM-EDS, LA-ICP-MS, and sequential leaching, a widely employed method of element phase association that dissolves mineral phases of different stability step-by-step: Exchangeable cations and Ca carbonates, Mn-oxides, Fe-hydroxides, and residual fraction. Sequential leaching shows that the Arctic crusts have higher contents of most elements characteristic of the aluminosilicate phase than do Pacific crusts. Elements have similar distributions between the hydrogenetic Mn and Fe phases in all the Arctic and Pacific crusts. The main host phases for the elements enriched in the Arctic crusts over Pacific crusts (Li, As, Th, and V) are the Mn-phase for Li and Fe-phase for As, Th, and V; those elements also have higher contents in the residual aluminosilicate phase. Thus, higher concentrations of Li, As, Th, and V likely occur in the dissolved and particulate phases in bottom waters where the Arctic crusts grow, which has been shown to be true for Sc, also highly enriched in the crusts. The phase distributions of elements within the crust layers is mostly consistent among the Arctic crusts, being somewhat different in element concentrations in the residual phase.

Minerals

Arctic deep-water ferromanganese-oxide deposits reflect the unique characteristics of the Arctic Ocean

Little is known about marine mineral deposits in the Arctic Ocean, an ocean dominated by continental shelf and basins semi-closed to deep-water circulation. Here, we present data for ferromanganese crusts and nodules collected from the Amerasia Arctic Ocean in 2008, 2009, and 2012 (HLY0805, HLY0905, HLY1202). We determined mineral and chemical compositions of the crusts and nodules and the onset of their formation. Water column samples from the GEOTRACES program were analyzed for dissolved and particulate scandium concentrations, an element uniquely enriched in these deposits. The Arctic crusts and nodules are characterized by unique mineral and chemical compositions with atypically high growth rates, detrital contents, Fe/Mn ratios, and low Si/Al ratios, compared to deposits found elsewhere. High detritus reflects erosion of submarine outcrops and North America and Siberia cratons, transport by rivers and glaciers to the sea, and distribution by sea ice, brines, and currents. Uniquely high Fe/Mn ratios are attributed to expansive continental shelves, where diagenetic cycling releases Fe to bottom waters, and density flows transport shelf bottom water to the open Arctic Ocean. Low Mn contents reflect the lack of a mid-water oxygen minimum zone that would act as a reservoir for dissolved Mn. The potential host phases and sources for elements with uniquely high contents are discussed with an emphasis on scandium. Scandium sorption onto Fe oxyhydroxides and Sc-rich detritus account for atypically high scandium contents. The opening of Fram Strait in the Miocene and ventilation of the deep basins initiated Fe-Mn crust growth ∼15 Myr ago.

Geochemistry, Geophysics, Geosystems