Tabulation of uranium and thorium data on the Mesozoic-Cenozoic intrusive rocks of known chemical composition in Colorado
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Geology topics
Publications and source records attributed to George Phair.
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Zircon separated from six rocks whose compositions spanned the range of differentiation in the Boulder Creek batholith yielded a “discordia” age of emplacement of 1725 m.y., close to the average PB 207 /Pb 206 age 1720 m.y.) and indicating that the constituent rocks are cogenetic within approximately ± 20 m.y. Statistical studies show that from 20 to 80 percent of the zircon in any one sample (1) is no-neuhedral, (2) has lower (length/width) ratios than the associated euhedral zircon, and (3) in direct contrast to the euhedral, increases markedly interior of the batholith toward contacts with the older metasediments and internal zones of contamination; it is inferred to have been “inherited” via assimilation. Unlike the noneuhedral fraction the euhedral zircon shows a linear decrease in length/width ratio with an increase in SiO 2 content of the containing rocks; it is inferred to be magmatic in origin. Regardless of the relative abundance of inherited versus magmatic zircon, all samples closely fit a single discordia chord, indicating that both zircon fractions formed at about the same time. This conclusion is compatible with field relationships that indicate the emplacement of the syntectonic Boulder Creek rocks took place during a period of metamorphism notable for the widespread development of new minerals in the country rocks. (1) Zircon from a Silver Plume Granite dike intruding the Boulder Creek batholith, (2) zircon from Silver Plume correlatives immediately to the north (Tilton and co-workers), and (3) uraninite from a probable Silver Plume correlative in the Central City district, together yield a sharply defined discordia age of emplacement of 1415 m.y. The separate “discordia” chords for the Boulder Creek and Silver Plume zirconconverge close to their lower intercepts with “concordia” indicative of a one-step lead loss during the Laramide disturbance. The Silver Plume “thermal event” left no age imprint on the Boulder Creek zircon, presumably because insufficient time had elapsed to produce significant metamictization.
The apparent ages (32 lead/alpha and 6 Pb 206 /U 238 ) of zircon as plotted on an isochron map of the Boulder Creek batholith define the following pattern: (1) very high ages (1600 to 1900 m.y.) within the outermost border zone on the southwest, south, and southeast; (2) transitional high ages (1300 to 1600 m.y.) within an inner border zone on the east and widening to the south and west to include about one-third of the batholith; (3) transitional low ages (1000 to 1300 m.y.) throughout much of the interior of the northern half; and (4) very low ages (1000 m.y. or less) limited to a small area within the northeast corner. The area of minimum age is shown to be part of the reduced-age aureole surrounding the 77 m.y. hornblende granodiorite stock at Jamestown that intrudes the Silver Plume Granite of the Longs Peak-St. Vrain batholith in the region immediately to the north of the minimum-age area of the Boulder Creek batholith. A southeastward elongation of the area of minimum age is attributed to channelway control of the solutions responsible for the recrystallization of the zircon by those northwest-trending breccia reefs that are cut by, or strike toward, the Laramide intrusion. Statistical studies of five zircon separates used for isotopic work showed that the frequency of grains having partial, or complete, rims of colorless zircon on purple to semiopaque zircon cores increased inversely with measured Pb 206 /U 238 age along a smooth curve that, when extrapolated, connected the point representing age of emplacement (0 percent rims) and the point representing the approximate age of re-crystallization (100 percent rims). Consequently, in the Boulder Creek zircon rim frequency gives a useful estimate of the amount of lead lost relative to uranium and thorium from a given sample during its recrystallization. The microstudy indicated: (1) the surface separating core and rim is a major discontinuity; (2) the greater part of the rims appear to be true overgrowths; and (3) the highest frequency of rims is found in the most metamict zircon. However, in any one sample a significant fraction of the most metamict zircon has been sheltered from reaction, presumably by inclusion within relatively impervious minerals, and remains free of rims. These observations coupled with the map evidence of selective channelway control point to warm solutions rather than dry heat as the agent of recrystallization and lead loss.
Allanite is abundant and commonly attains unusually large size as a late-replacement mineral in: (1) the comagnatic rocks of the Precambrian Boulder Creek batholith; (2) associated amphibolite xenoliths and related hybrid rocks; and (3) distinctly younger intrusions of Silver Plume Granite that cut the complex. Allanite porphyroblasts develop by replacement of biotite, probably in the presence of emanations from the rare earth-rich and thorium-rich Silver Plume Granite. The largest allanite crystals are made up of nearly isotropic (metamict) cores and birefringent (recrystallized) rims. Smaller crystals are made up exclusively of birefringent material. The maximum birefringence is shown to be that expectable in allanite of Late Cretaceous to early Tertiary age. As plotted on maps, the birefringence increases, and the thorium and uranium contents of the allanite decrease toward a Laramide stock. The variation in birefringence is, therefore, largely relatable to variations in the post-Laramide radiation dosage brought about by differences in the amounts of uranium and thorium lost during recrystallization. The recrystallized allanite is itself partly replaced by epidote which characteristically occurs as a border between allanite and biotite. Total rare-earth oxides for the eight samples of allanite analyzed range from 17.5 to 21.3 percent by weight. In 13 samples, thorium ranged from 0.50 to 1.14 percent by weight, and uranium from 54 to 158 parts pparts per million. Ranges in optical measurements for 20 samples using the spindle stage are: Nα = 1.719–1.759, Nβ = 1.731-1.774, N γ = 1.741–1.784, birefringence = 0.020–0.032, 2V X (calc.) 70°–84°. Ranges for unit-cell data obtained on 8 samples are: a = 8.948–8.985Å, b = 5.721-5.763Å, c = 10.184–10.240Å, β = 115°7.50′–115°25.89′ and volume = 473.02–478.43Å 3 . The average value for the ratio a:b:c = 1.561:1:1.778.
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The Copper King mine in Larimer County, Colo., in the northern part of the Front Range of Colorado, was opened in World War I in an unsuccessful attempt to mine copper and zinc ore. In 1949, following the discovery of pitchblende on the dump, the mine was reopened, and it was worked until 1953 for uranium. A total of 652 tons of ore that contained an average of 0.28 percent U 3 O 8 was shipped. The bedrock consists predominantly of biotite granite, part of the Precamblian Log Cabin batholith, and minor metasedimentary rocks -- biotite-quartz-plagioclase gneiss, amphibole skarn, biotite schist, quartzite, amphibolite, and biotite sköls. The metasedimentary rocks occur as inclusions that trend northeast, essentially parallel to the prevailing foliation in the granite. In places the metasedimentary rocks are crosscut sharply by the granite and form angular, steep-walled blocks in the granite. Faults, confined to a narrow easterly-trending zone through the mine, cut all the Precambrian rocks. Mineral deposits of two types are present at the mines 1) sulfide-magnetite ore and 2) a uranium deposit in a filled fissure that cuts the skarn. The sulfide-magnetite deposits are small and consist of pyrite, sphalerite, chalcopyrite, pyrrhotite, and at places magnetite. Alpha-helium age determinations on ore magnetite by Hurley indicate that the mineral assemblage is late Precambrian in age. The deposits are pyrometasomatic in origin and possibly related to the granite. The uranium deposit consists of pitchblende and associated vein-forming minerals that occur in the Copper King fault and locally in pyrite boxwork adjacent to the fault. Three phases of black pitchblende have been identified -- uraninite, "coffinite", and UO 3 -rich pitchblend. Colored secondary minerals are absent. The pitchblende occurs in a steeply plunging, tabular shoot between 45 and 135 feet below the surface that has a horizontal length of about 50 feet. Within the shoot the pitchblende occurs in pods or layers generally only a few feet in height and length and as much as a foot thick that are separated by nearly barren vein. The grade of the ore within the pods ranges from 0.2 percent uranium to as much as 20 percent but averages about 1 to 2 percent. Age determinations by the Pb 206 /U 238 and Pb 207 /U 235 methods on two samples of hard pitchblende from the vein, not from the pyrite boxwork, gave ages by the two methods after suitable common lead corrections, ranging from 55 to 76 million years, corresponding to an early Tertiary age. Diamond core drilling and reconnaissance for radioactivity have not disclosed other uranium deposits the Prairie Divide region; nevertheless, it seems likely that other deposits are present.
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The Copper King mine, in Larimer County, Colo., in the northern part of the Front Range of Colorado, was operated for a short time prior to World War II for copper and zino, but since 1949, when pitchblende was discovered on the mine dump, it has been worked for uranium. The bedrock in the mine area consists predominantly of pre-Cambrian (Silver Plums) granite with minor migmatite and metasediments--biotite-quartz-plagioclase gneiss, biotite schist, quartzite, amphibolite, amphibole skarn, and biotite skols. The metasediments occur as inclusions that trend northeast in the granite. This trend is essentially parallel to the prevailing foliation in the granite. At places the metasediments are crosscut sharply by the granite to form angular, partly discordant, steep-walled bodies in the granite. Faults, confined to a narrow zone that extends through the mine, cut both the pre-Cambrian rocks and the contained sulfide deposits. The Copper King fault, a breccia zone, contains a deposit of pitchblende; the other faults are believed to be later than the ore. The two types of mineral deposits--massive sulfide and pitchblende deposits--in the mine area, are of widely different mineralogy, age, and origin. The massive sulfide deposits are small and consist of pyrite, sphalerite, chalcopyrite, pyrrhotite, and in places magnetite in amphibole skarn, mice skols, and quartzite. The deposit at the Copper King mine has yielded small quantities of high-grade sphalerite ore. The massive sulfides are pyrometasomatic deposits of pre-Cambrian age. The pitchblende at the Copper King mine is principally in the Copper King vein, a tight, hard breccia zone that cuts through both granite and the massive sulfide deposit. A small part of the pitchblende is in small fractures near the vein and in boxwork pyrite adjacent to the vein; the post-ore faults, close to their intersection with the Copper King vein, contain some radioactive material, but elsewhere, so far as is known, they are barren. The pitchblende in the deposit forms a steeply plunging ore shoot that has a horizontal length of more than 50 feet and a vertical height of about 85 feet. The thickness of the ore shoot averages about 2 feet, but it ranges from a feather edge to about 4 feet. The hard pitch-blende is intimately intergrown with siderite; other gangue minerals include pyrite, quartz, and finely comminuted fragments of the wall rocks. The vein was repeatedly reopened during mineral deposition as shown by several stages of brecciation and recommended by the vein matter. The pitchblende deposit probably formed at intermediate temperatures and depths and, according to the Pb/U ratio, is about 60 million years old--an early Tertiary age.
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