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G. G. Ehrlich

Publications and source records attributed to G. G. Ehrlich.

12 recordsLinked to original sources

Chemical changes in an industrial waste liquid during post-injection movement in a limestone aquifer, Pensacola, Florida

An industrial waste liquid containing organonitrile compounds and nitrate ion has been injected into the lower limestone of the Floridan aquifer near Pensacola, Florida since June 1975. Chemical analyses of water from monitor wells and backflow from the injection well indicate that organic carbon compounds are converted to CO 2 and nitrate is converted to N 2 . These transformations are caused by bacteria immediately after injection, and are virtually completed within 100 m of the injection well. The zone near the injection well behaves like an anaerobic filter with nitrate respiring bacteria dominating the microbial flora in this zone. Sodium thiocyanate contained in the waste is unaltered during passage through the injection zone and is used to detect the degree of mixing of injected waste liquid with native water at a monitor well 312 m (712 ft) from the injection well. The dispersivity of the injection zone was calculated to be 10 m (33 ft). Analyses of samples from the monitor well indicate 80 percent reduction in chemical oxygen demand and virtually complete loss of organonitriles and nitrate from the waste liquid during passage from the injection well to the monitor well. Bacterial densities were much lower at the monitor well than in backflow from the injection well.

Florida

Degradation of phenolic contaminants in ground water by anaerobic bacteria: St. Louis Park, Minnesota

Coal-tar derivatives from a coal-tar distillation and wood-treating plant that operated from 1918 to 1972 at St. Louis Park, Minnesota contaminated the near-surface ground water. Solutions of phenolic compounds and a water-immiscible mixture of polynuclear aromatic compounds accumulated in wetlands near the plant site and entered the aquifer. The concentration of phenolic compounds in the aqueous phase under the wetlands is about 30 mg/1 but decreases to less than 0.2 mg/1 at a distance of 430 m immediately downgradient from the source. Concentrations of naphthalene (the predominant polynuclear compound in the ground water) and sodium (selected as a conservative tracer) range from about 20 mg/1 and 430 mg/1 in the aqueous phase at the source to about 2 mg/1 and 120 mg/1 at 430 m downgradient, respectively. Phenolic compounds and naphthalene are disappearing faster than expected if only dilution were occurring. Sorption of phenolic compounds on aquifer sediments is negligible but naphthalene is slightly sorbed. Anaerobic biodegradation of phenolic compounds is primarily responsible for the observed attenuation. Methane was found only in water samples from the contaminated zone (2-20 mg/1). Methane-producing bacteria were found only in water from the contaminated zone. Methane was produced in laboratory cultures of contaminated water inoculated with bacteria from the contaminated zone. Evidence for anaerobic biodegradation of naphthalene under either field or laboratory conditions was not obtained.

Minnesota

Subsurface injection of treated sewage into a saline-water aquifer at St. Petersburg, Florida - Water-quality changes and potential for recovery of injected sewage

The city of St. Petersburg is testing subsurface injection of treated sewage into the Floridan aquifer as a means of eliminating discharge of sewage to surface waters and as a means of storing treated sewage for future nonpotable reuse. The injection zone at the test site at the start of injection contained saline water with chloride concentrations ranging from 14,000 to 20,000 milligrams per liter (mg/l). Treated sewage with a mean chloride concentration of 170 mg/ml was injected through a single well for 12 months at a mean rate of 4.7 x 105 cubic feet per day. The volume of water injected during the year was 1.7x108 cubic feet. Dissolved oxygen was contained in the sewage prior to injection. Water removed from the injection zone during injection was essentially free of oxygen. Probable growth of denitrifying bacteria and, thus, microbial denitrification, was suggested by bacterial counts in water from two observation wells that were close to the injection well. The volume fraction of treated sewage in water from wells located 35 feet and 733 feet from the injection well and open to the upper part of the injection zone stabilized at about 0.9 and 0.75, respectively. Chloride concentrations stabilized at about 1,900 mg/l in water from the well that was 35 feet from the injection well and stabilized at about 4,000 mg/l in water from the well that was 733 feet from the injection well. These and other data suggest that very little near injection-quality treated sewage would be recoverable from storage in the injection zone.The city of St. Petersburg is testing subsurface injection of treated sewage into the Floridan aquifer as a means of eliminating discharge of sewage to surface waters and as a means of storing treated sewage for future nonpotable reuse. The injection zone at the test site at the start of injection contained saline water with chloride concentrations ranging from 14,000 to 20,000 milligrams per liter (mg/l). Data suggest that very little near injection-quality treated sewage would be recoverable from storage in the injection zone.

Florida

Phenolic contamination in the sand-and-gravel aquifer from a surface impoundment of wood treatment wastes, Pensacola, Florida

Creosote and pentachlorophenol wastewaters discharged to unlined surface impoundments have resulted in groundwater contamination in the vicinity of an industrial site near Pensacola, Florida. Total phenol concentrations of 36,000 microgm/liter have been detected 40 ft below land surface in a test hole 100 ft south of an overflow impoundment but less than 10 microgm/liter 90 ft below land surface. Samples collected in test holes 1,350 ft downgradient from the surface impoundments and 100 ft north of Pensacola Bay, above and immediately below a clay lens, indicate that phenol contaminated groundwater may not be discharging directly into Pensacola Bay. Phenol concentrations exceeding 20 microgm/liter were detected in samples from a drainage ditch discharging directly into Bayou Chico. Microbiological data collected near the test site suggest that an anaerobic methanogenic ecosystem contributes to a reduction in phenol concentrations in groundwater. A laboratory study using bacteria isolated from the study site indicates that phenol, 2-methylphenol, and 3-methylphenol are significantly degraded and that methanogenesis reduces total phenol concentrations in laboratory digestors by 45%. Pentachlorophenol may inhibit methanogenesis at concentrations exceeding 0.45 milligm/liter. (USGS)

Water-Resources Investigations Report

Reconnaissance for microbial activity in the Magothy aquifer, Bay Park, New York, four years after artificial recharge

Tertiary-treated sewage effluent was injected into the Magothy aquifer at Bay Park, Long Island, N.Y., between 1968 and 1973. In 1977, the microbial flora in water samples from the injection well and from three nearby wells were surveyed. Differences in the composition of the microbial flora among the four wells were found. A bacterial community dominated by facultative and obligate anaerobes, including two Clostridium species and methanogenic bacteria, was found at a well 6.1 m from the injection well. By contrast, except for isolation of Clostridium sphenoides from a well 30 m away, only obligate aerobes and facultative anaerobes were found in water from the injection well and the 30 m well. Only a small number of obligate aerobes were found in samples from a well 61 m away. These results suggest that nutrients in the recharge water formed an organically enriched zone to at least a distance of 6.1 m from the point of injection but not as far as 61 m. Extensive pumping at the end of the injection program apparently removed exogeneous nutrients near the injection well.

New York

Artificial recharge through a well in fissured carbonate rock, west St. Paul, Minnesota

The Prairie du Chien Group was injected with 2,754,000 gallons (368,200 cubic feet), or 10,430 cubic metres, of municipally treated water at about 100 gallons per minute (13.4 cubic feet per minute), or 6.3 litres per second, for 20 days. The injection-pipe system was designed to utilize pipe friction rather than a remote-controlled valve in the well to maintain positive pressure and eliminate air entrainment in the injection water and the escape cf dissolved gasses from the water. During the 20-day injection period the temperature of the injection water declined gradually from 15.0 ° to 11.2 ° C, and the flow rate decreased from 108 to 90 gallons per minute (6.8 to 5.7 litres per second). Analyses of test data were, in some instances, based upon hydrologic judgement as well as observations. Results of aquifer tests before and after injections indicated that the transmissivity had decreased 18 percent during the intervening injection periods; however, the specific capacity remained the same, indicating no change in transmissivity during pumping. Analysis of water-level changes in observation wells during injection indicated a reduction in transmissivity of more than 50 percent; however, the specific capacity of the injection well decreased only about 5 percent during injection. A comparison of water-level changes with the discharge or recharge rates of the three tests showed that the water-level changes in the two observation wells tapping the Prairie du Chien Group during the injection test were greater than those projected from the two aouifer pumping tests. The deviations in the water-level changes and in the analysis of aquifer-test data indicate that the methods used to analyze data from these wells may not be wholly applicable, inasmuch as anisotropic and nonhomogeneous conditions prevail in at least the Prairie du Chien part of the aquifer. The native water and the injected water averaged 0.8 and 25 milligrams per litre chloride, respectively. The chloride, utilized as a tracer, showed that the injected water was detected only in the lower part of the nearest observation well, 99 feet (30.2 metres) from the injection well. The chemistry of the water and the rock formation showed little likelihood of plugging of the recharge well by chemical precipitation. Microbiological phenomena apparently did not become a significant factor in the recharge test. The hydraulic gradient of the aquifer in October and December 1971 (before and after injection) was estimated to be N. 36 ° E., 0.0013, and N. 39 ° E., 0.0012, respectively, on the basis of measurements of water levels in the three wells in the Prairie du Chien Group. The single-well tracer-dilution method of calculation showed a hydraulic gradient of 0.0016. A longitudinal dispersivity of 280 feet (85 metres) was calculated. Such a value of dispersivity is typical of fractured reservoirs and shows that the Prairie du Chien Group is a heterogeneous aquifer. The injection test demonstrated that it is hydrologically feasible to recharge the Prairie du Chien Group and the Jordan Sandstone artificially through wells completed in the Prairie du Chien Group. The fissures in the Prairie du Chien Group act as conduits through which water spreads. The water passes into the Jordan Sandstone from the Prairie du Chien over a larger area than it would if it were injected directly into the Jordan.

Minnesota

Microbiological aspects of ground-water recharge injection of purified unchlorinated sewage effluent at Bay Park, Long Island, N. Y.

Unchlorinated, tertiary-treated sewage effluent was injected through a well at Bay Park, Long Island, N.Y., into a sand aquifer at a rate of 340 gpm for 10 days. Massive, biologically produced slime deposits formed in the filter pack immediately adjacent to the well screen. Observed head buildup in the recharge well was correlated with the formation of these deposits. Comparison of results from this test with results of earlier tests suggests that formation of these deposits may be avoided by addition of chlorine to the injectant.

New York