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F.J. Flanagan

Publications and source records attributed to F.J. Flanagan.

13 recordsLinked to original sources
USGS1987

Mineralogy and instrumental neutron activation analysis of seven National Bureau of Standards and three Instituto de Pesquisas Tecnologicas clay reference samples

The concentrations of 3 oxides and 29 elements in 7 National Bureau of Standards (NBS) and 3 Instituto de Pesquisas Techno16gicas (IPT) reference clay samples were etermined by instrumental neutron activation analysis. The analytical work was designed to test the homogeneity of constituents in three new NBS reference clays, NBS-97b, NBS-98b, and NBS-679. The analyses of variance of 276 sets of data for these three standards show that the constituents are distributed homogeneously among bottles of samples for 94 percent of the sets of data. Three of the reference samples (NBS-97, NBS-97a, and NBS-97b) are flint clays; four of the samples (NBS-98, NBS-98a, NBS-98b, and IPT-32) are plastic clays, and three of the samples (NBS-679, IPT-28, and IPT-42) are miscellaneous clays (both sedimentary and residual). Seven clays are predominantly kaolinite; the other three clays contain illite and kaolinite in the approximate ratio 3:2. Seven clays contain quartz as the major nonclay mineral. The mineralogy of the flint and plastic clays from Missouri (NBS-97a and NBS-98a) differs markedly from that of the flint and plastic clays from Pennsylvania (NBS-97, NBS-97b, NBS-98, and NBS-98b). The flint clay NBS-97 has higher average chromium, hafnium, lithium, and zirconium contents than its replacement, reference sample NBS-97b. The differences between the plastic clay NBS-98 and its replacement, NBS-98b, are not as pronounced. The trace element contents of the flint and plastic clays from Missouri, NBS-97a and NBS-98a, differ significantly from those of the clays from Pennsylvania, especially the average rare earth element (REE) contents. The trace element contents of clay sample IPT-32 differ from those of the other plastic clays. IPT-28 and IPT-42 have some average trace element contents that differ not only between these two samples but also from all the other clays. IPT-28 has the highest summation of the average REE contents of the 10 samples. The uranium content of NBS-98a, 46 parts per million, is very much higher than that of the other clays. Plots of average REE contents of the flint and plastic clays, normalized to chondritic abundances, show that the clays from Missouri differ from the same types of clay from Pennsylvania. The plot of REE contents for the miscellaneous clays shows that the normalized means for the elements lanthanum through samarium for IPT-28 are much greater than those for the other miscellaneous clays. The means for the elements europium through lutetium are similar for all three miscellaneous clays.

Circular↗
USGS1974

Reference samples for the earth sciences

A revised list of reference samples of interest to geoscientists has been extended to include samples for the agronomist, the archaeologist and the environmentalist. In addition to the source from which standard samples may be obtained, references or pertinent notes for some samples are included. The number of rock reference samples is now almost adequate, and the variety of ore samples will soon be sufficient. There are very few samples for microprobe work. Oil shales will become more important because of the outlook for world petroleum resources. The dryland equivalent of a submarine basalt might be useful in studies of sea-floor spreading and of the geochemistry of basalts. The Na- and K-feldspars of BCS (British Chemical Standards—Bureau of Analysed Samples), NBS (National Bureau of Standards), and ANRT (Association Kationale de la Recherche Technique) could serve as trace-element standards if such data were available. Similarly, the present NBS flint and plastic clays, as well as their predecessors, might be useful for archaeological pottery studies. The International Decade for Ocean Exploration may stimulate the preparation of ocean-water standards for trace elements or pollutants and a standard for manganese nodules.

Geochimica et Cosmochimica Acta↗
USGS1973

The selenium content of U.S.G.S. standard rocks

Selenium was determined in duplicate portions from three bottles of six U.S.G.S. standard rocks by a spect rofluorimetric procedure. The following averages, as p.p.m. Se, were obtained: PCC-1, 0.031; GSP-1, 0.088; BCR-1, 0.12; SCo-1, 0.91; MAG-1, 1.3; and SGR-1, 3.7. One-way analysis of variance of the several sets of data showed no significant differences in the selenium content among bottles of any specific rock; these samples may be accepted as homogeneous for their selenium contents by this analytical method.

Chemical Geology↗
USGS1970

Sources of geochemical standards-II

A revised and enlarged list of rock, mineral, ore, industrial product, counting, and isotopic standards of interest to those in geochemistry and geology is presented. Samples in process are also included. Sources from which the samples may be obtained are listed.

Geochimica et Cosmochimica Acta↗
USGS1969

U.S. Geological Survey standards-II. First compilation of data for the new U.S.G.S. rocks

Rock analyses, determinations of major and minor constituents, and determinations of 57 trace elements reported by analysts throughout the world are presented for the new series of U.S. Geological Survey rock samples. Averages for both the constituents generally reported in a rock analysis and the trace elements are given. Variances of the distributions of data by rock analysts for several oxides in G-2 are compared with similar variances for G-l.

Geochimica et Cosmochimica Acta↗
USGS1967

U.S. Geological Survey silicate rock standards

The U.S. Geological Survey has processed six silicate rocks to provide new reference samples to supplement G-1 and W-1. Complete conventional, rapid rock, and spectrochemical analyses by the U.S. Geological Survey are reported for a granite (replacement for G-1), a granodiorite, an andesite, a peridotite, a dunite, and a basalt. Analyses of variance for nickel, chromium, copper, and zirconium in each rock sample showed that for these elements, the rocks can be considered homogeneous. Spectrochemical estimates are given for the nickel, chromium, copper, and zirconium contents of the samples. The petrography of five of the six rocks is described and CIPW norms are presented.

Geochimica et Cosmochimica Acta↗
USGS1957

Semi-quantitative spectrographic analysis and rank correlation in geochemistry

The rank correlation coefficient, r s , which involves less computation than the product-moment correlation coefficient, r , can be used to indicate the degree of relationship between two elements. The method is applicable in situations where the assumptions underlying normal distribution correlation theory may not be satisfied. Semi-quantitative spectrographic analyses which are reported as grouped or partly ranked data can be used to calculate rank correlations between elements.

Geochimica et Cosmochimica Acta↗
USGS1954

Tables for evaluating Bateman equation coefficients for radioactivity calculations

Tables of decay constants and functions thereof are presented to simplify the problem of calculating the constants involved in the Bateman equation. These tables make it possible to calculate any constant involved in any of the four radioactive series by a maximum of three mathematical operations, either by three divisions or by two multiplications and a division. They are useful and time-saving where a large number of such calculations are involved.

Analytical Chemistry↗