Geology topics

F.A. Frey

Publications and source records attributed to F.A. Frey.

9 recordsLinked to original sources

USGS2012

Minor and trace element geochemistry of volcanic rocks dredged from the Galapagos spreading center: Role of crystal fractionation and mantle heterogeneity

A wide range of rock types (abyssal tholeiite, Fe-Ti-rich basalt, andesite, and rhyodacite) were dredged from near 95°W and 85°W on the Galapagos spreading center. Computer modeling of major element compositions has shown that these rocks could be derived from common parental magmas by successive degrees of fractional crystallization. However, the P 2 O 5 /K 2 O ratio averages 0.83 at 95°W and 1.66 at 85°W and implies distinct mantle source compositions for the two areas. These source regions also have different rare earth element (REE) abundance patterns, with [La/Sm] EF = 0.67 at 95°W and 0.46 at 85°W. The sequence of fractionated lavas differs for the two areas and indicates earlier fractionation of apatite and titanomagnetite in the lavas from 95°W. The mantle source regions for these two areas are interpreted to be depleted in incompatible (and volatile?) elements, although the source region beneath 95°W is less severely depleted in La and K. Incompatible trace element abundances in 26 samples are used to infer that the range of Fe-Ti-rich basalt from 85°W represents 19 to 35% residual liquid following crystal fractionation of a mineral assemblage of plagioclase, clinopyroxene, and lesser olivine. The most highly differentiated samples have also had less than 1% titanomagnetite removed. Most samples from 85°W can be related to a common parental magma that contained approximately 9 wt % FeO*, 1 wt % TiO 2 , and had an Mg number (Mg# = 100 Mg/(Mg + Fe 2+ )) of about 65. Although the samples from 95°W cannot all be derived from a common parental magma, the inferred parental magmas may have been derived by varying degrees of partial melting of a common source. The fractionation sequence consists of two parts: an initial iron enrichment trend followed by a silica enrichment trend. We interpret the trace element data to indicate that the most iron rich lavas represent about 32% residual liquid derived by crystal fractionation of plagioclase, clinopyroxene, and lesser olivine from a parental magma with an Mg number of about 66. The silica enrichment trend results from crystallization of titanomagnetite and some apatite. Fractionation of pigeonite, which is a minor phase in the major element models, cannot be distinguished from clinopyroxene fractionation by using trace elements.

Journal of Geophysical Research Solid Earth↗

USGS1992

Ages, rare-earth element enrichment, and petrogenesis of tholeiitic and alkalic basalts from Kahoolawe Island, Hawaii

Kahoolawe Island, Hawaii (18×11 km), is a basaltic shield volcano with caldera-filling lavas, seven identified postshield vents, and at least two occurrences of apparent rejuvenated-stage eruptive. We examined 42 samples that represent all stages of Kahoolawe volcano stratigraphy for their petrography, whole-rock major-and trace-element contents, mineral compositions, and K−Ar ages. The two oldest shield samples have an average age of 1.34±0.08 Ma, and four postshield samples (3 are alkalic) average 1.15±0.03 Ma; ages of 1.08 and 0.99 Ma for two additional tholeiitic samples probably are minimum ages. Whole-rock major- and trace-element and mineral compositions of Kahoolawe shield and caldera-fill laves are generally similar to the lavas forming Kilauea and Mauna Loa tholeiitic shields, but in detail, Kahoolawe shield lavas have distinctive compositions. An unusual aspect of many postshield Ka-hoolawe lavas is anomalously high REE and Y abundances (up to 200 ppm La and 175 ppm Y) and negative Ce anomalies. These enrichments reflect surficial processes, where weathering and soil development promoted REE-Y transport at the weathering front. Major element abundances (MgO, 10–6 wt.%) for shield and caldera-fill basalts are consistent with fractionation of ol+px+pl in frequently replenished magma reservoirs. In general, tholeiitic basalts erupted from late vents are higher in SiO 2 than the shield lavas, and temporal differences in parental magma compositions are the likely explanation. Alkalic basalts that erupted from vents are comparable in composition to those at other Hawaiian volcanoes. Trace-element abundance ratios indicate that alkalic basalts represent either relatively lower degrees of melting of the shield source or a distinct source. Apparent rejuvenated-stage basalts (i.e., emplaced after substantial Kahoolawe erosion) are tholeiitic, unlike the rejuvenated-stages at other Hawaiian volcanoes (alkalic). Kahoolawe, like several other Hawaiian volcanoes, has intercalated tholeiitic and alkalic basalts in the postshield stage, but it is the only volcano that appears to have produced tholeiitic rejuvenated-stage lavas.

Hawaii↗

USGS1991

The tholeiite to alkalic basalt transition at Haleakala Volcano, Maui, Hawaii

Previous studies of alkalic lavas erupted during the waning growth stages (<0.9 Ma to present) of Haleakala volcano identified systematic temporal changes in isotopic and incompatible element abundance ratios. These geochemical trends reflect a mantle mixing process with a systematic change in the proportions of mixing components. We studied lavas from a 250-m-thick stratigraphic sequence in Honomanu Gulch that includes the oldest (∼1.1 Ma) subaerial basalts exposed at Haleakaka. The lower 200 m of section is intercalated tholeiitic and alkalic basalt with similar isotopic (Sr, Nd, Pb) and incompatible element abundance ratios (e.g., Nb/La, La/Ce, La/Sr, Hf/Sm, Ti/Eu). These lava compositions are consistent with derivation of alkalic and tholeiitic basalt by partial melting of a compositionally homogeneous, clinopyroxene-rich, garnet lherzolite source. The intercalated tholeiitic and alkalic Honomanu lavas may reflect a process which tapped melts generated in different portions of a rising plume, and we infer that the tholeiitic lavas reflect a melting range of ∼10% to 15%, while the intercalated alkalic lavas reflect a range of ∼6.5% to 8% melting. However, within the uppermost 50 m of section. 87 Sr/ 86 Sr decreases from 0.70371 to 0.70328 as eruption age decreased from ∼0.97 Ma to 0.78 Ma. We infer that as lava compositions changed from intercalated tholeiitic and alkalic lavas to only alkalic lavas at ∼0.93 Ma, the mixing proportions of source components changed with a MORB-related mantle component becoming increasingly important as eruption age decreased.

Hawaii↗

USGS1991

Subalkaline andesite from Valu Fa Ridge, a back-arc spreading center in southern Lau Basin: petrogenesis, comparative chemistry, and tectonic implications

Tholeiitic andesite was dredged from two sites on Valu Fa Ridge (VFR), a back-arc spreading center in Lau Basin. Valu Fa Ridge, at least 200 km long, is located 40-50 km west of the active Tofua Volcanic Arc (TVA) axis and lies about 150 km above the subducted oceanic plate. One or more magma chambers, traced discontinuously for about 100 km along the ridge axis, lie 3-4 km beneath the ridge. The mostly aphyric and glassy lavas had high volatile contents, as shown by the abundance and large sizes of vesicles. An extensive fractionation history is inferred from the high SiO2 contents and FeO* MgO ratios. Chemical data show that the VFR lavas have both volcanic arc and back-arc basin affinities. The volcanic arc characteristics are: (1) relatively high abundances of most alkali and alkaline earth elements; (2) low abundances of high field strength elements Nb and Ta; (3) high U/Th ratios; (4) similar radiogenic isotope ratios in VFR and TVA lavas, in particular the enrichment of 87Sr 86Sr relative to 206Pb 204Pb; (5) high 238U 230Th, 230Th 232Th, and 226Ra 230Th activity ratios; and (6) high ratios of Rb/Cs, Ba/Nb, and Ba/La. Other chemical characteristics suggest that the VFR lavas are related to MORB-type back-arc basin lavas. For example, VFR lavas have (1) lower 87Sr 86Sr ratios and higher 143Nd 144Nd ratios than most lavas from the TVA, except samples from Ata Island, and are similar to many Lau Basin lavas; (2) lower Sr/REE, Rb/Zr, and Ba/Zr ratios than in arc lavas; and (3) higher Ti, Fe, and V, and higher Ti/V ratios than arc lavas generally and TVA lavas specifically. Most characteristics of VFR lavas can be explained by mixing depleted mantle with either small amounts of sediment and fluids from the subducting slab and/or an older fragment of volcanic arc lithosphere. The eruption of subalkaline andesite with some arc affinities along a back-arc spreading ridge is not unique. Collision of the Louisville and Tonga ridges probably activated back-arc extension that ultimately led to the creation and growth of Valu Fa Ridge. Some ophiolitic fragments in circum-Pacific and circum-Tethyan allochthonous terranes, presently interpreted to have originated in volcanic arcs, may instead be fragments of lithosphere that formed during early stages of seafloor spreading in a back-arc basin. ?? 1991.

Chemical Geology↗

USGS1990

Trace-element and Sr, Nd, Pb, and O isotopic composition of Pliocene and Quaternary alkali basalts of the Patagonian Plateau lavas of southernmost South America

The Pliocene and Quaternary Patagonian alkali basalts of southernmost South America can be divided into two groups. The "cratonic" basalts erupted in areas of Cenozoic plateau volcanism and continental sedimentation and show considerable variation in 87Sr/86Sr (0.70316 to 0.70512), 143Nd/144Nd (e{open}Nd) and 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios (18.26 to 19.38, 15.53 to 15.68, and 38.30 to 39.23, respectively). These isotopic values are within the range of oceanic island basalts, as are the Ba/La, Ba/Nb, La/Nb, K/Rb, and Cs/Rb ratios of the "cratonic" basalts. In contrast, the "transitional" basalts, erupted along the western edge of the outcrop belt of the Pliocene and Quaternary plateau lavas in areas that were the locus of earlier Cenozoic Andean orogenic arc colcanism, have a much more restricted range of isotopic composition which can be approximated by 87Sr/86Sr=0.7039??0.0004, e{open}Nd, 206Pb/204Pb=18.60??0.08, 207Pb/204Pb=15.60??0.01, and 208Pb/204Pb=38.50??0.10. These isotopic values are similar to those of Andean orogenic are basalts and, compared to the "cratonic" basalts, are displaced to higher 87Sr/86Sr at a given 143Nd/144Nd and to higher 207Pb/204Pb at a given 208Pb/204Pb. The "transitional" basalts also have Ba/La, Ba/Nb, La/Nb, and Cs/Rb ratios higher than the "cratonic" and oceanic island basalts, although not as high as Andean orogenic are basalts. In contrast to the radiogenic isotopes, ??18O values for both groups of the Patagonian alkali basalts are indistinguishable and are more restricted than the range reported for Andean orogenic are basalts. Whole rock ??18O values calculated from mineral separates for both groups range from 5.3 to 6.5, while measured whole rock ??18O values range from 5.1 to 7.8. The trace element and isotopic data suggest that decreasing degrees of partial melting in association with lessened significance of subducted slabderived components are fundamental factors in the west to east transition from arc to back-arc volcanism in southern South America. The "cratonic" basalts do not contain the slab-derived components that impart the higher Ba/La, Ba/Nb, La/Nb, Cs/Rb, 87Sr/86Sr at a given 143Nd/144Nd, 207Pb/204Pb at a given 208Pb/204Pb, and ??18O to Andean orogenic arc basalts. Instead, these basalts are formed by relatively low degrees of partial melting of heterogeneous lower continental lithosphere and/or asthenosphere, probably due to thermal and mechanical pertubation of the mantle in response to subduction of oceanic lithosphere below the western margin of the continent. The "transitional" basalts do contain components added to their source region by either (1) active input of slab-derived components in amounts smaller than the contribution to the mantle below the arc and/or with lower Ba/La, Ba/Nb, La/Nb, and Cs/Rb ratios than below the arc due to progressive downdip dehydration of the subducted slab; or (2) subarc source region contamination processes which affected the mantle source of the "transitional" basalts earlier in the Cenozoic. ?? 1990 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

USGS1984

Geochemistry of tholeiitic and alkalic lavas from the Koolau Range, Oahu, Hawaii: Implications for Hawaiian volcanism

Lavas of the post-erosional, alkalic Honolulu Volcanics have significantly lower 87 Sr/ 86 Sr and higher 143 Nd/ 144 Nd than the older and underlying Koolau tholeiites which form the Koolau shield of eastern Oahu, Hawaii. Despite significant compositional variation within lavas forming the Honolulu Volcanics, these lavas are isotopically (Sr, Nd, Pb) very similar which contrasts with the isotopic heterogeneity of the Koolau tholeiites. Among Hawaiian tholeiitic suites, the Koolau lavas are geochemically distinct because of their lower iron contents and Sr and Nd isotopic ratios which range to bulk earth values. These geochemical data preclude simple models such as derivation of the Honolulu Volcanics and Koolau tholeiites from a common source by different degrees of melting or by mixing of two geochemically distinct sources. There may be no genetic relationship between the origin and evolution of these two lava suites; however, the trend shown by Koolau Range lavas of increasing 143 Nd/ 144 Nd and decreasing 87 Sr/ 86 Sr with decreasing eruption age and increasing alkalinity also occurs at Haleakala, East Molokai and Kauai volcanoes. A complex mixing model proposed for Haleakala lavas can account for the variations in Sr and Nd isotopic ratios and incompatible element abundances found in lavas from the Koolau Range. This model may reflect mixing and melting processes occurring during ascent of relatively enriched mantle through relatively depleted MORB-related lithosphere. Although two isotopically distinct components may be sufficient to explain Sr and Nd isotopic variations at individual Hawaiian volcanoes, more than two isotopically distinct materials are required to explain variations of Sr, Nd and Pb isotopic ratios in all Hawaiian lavas.

Hawaii↗

USGS1983

Geochemistry of diverse basalt types from Loihi Seamount, Hawaii: Petrogenetic implications

The wide variety of basalt types, tholeiitic to basanite, dredged from Loihi Seamount have minor and trace element abundances that are characteristic of subaerial Hawaiian basalts, thereby confirming that Loihi Seamount is a manifestation of the Hawaiian “hot spot”. Within the Loihi sample suite there are well-defined positive correlations among abundances of highly incompatible elements (P, K, Rb, Ba, Nb, light REE and Ta) and moderately incompatible elements (Sr, Ti, Zr and Hf) and between MgO, Ni and Cr. However, within the Loihi suite abundance ratios of geochemically similar elements (Zr/Hf, Nb/Ta and La/Ce) vary by factors of 1.2–1.5 and abundance ratios of highly incompatible elements such as P/Ce, P/Th, K/Rb, Ba/Th and La/Nb vary by factors of 1.2–2.5. These abundance ratios are not readily changed by different degrees of fractionation and melting. Therefore, we conclude that these samples are not genetically related by different degrees of melting of a compositionally homogeneous source.

Hawaii↗

USGS1983

A tale of two plutons: petrographic and mineralogic constraints on the petrogenesis of the Red Lake and Eagle Peak plutons, central Sierra Nevada, California

The two plutons are similar in age (K/Ar, 87-89 m.y.) and range in composition from granodiorite to granite. The Red Lake pluton is equigranular, has a locally greisened marginal zone, and shows only minor mineralogical and chemical zoning, whereas the Eagle Peak pluton is mineralogically, compositionally and texturally zoned, with an equigranular margin and a porphyritic core. Modal and normative trends within each pluton are consistent with separation of plagioclase and mafic minerals leading to a residual liquid enriched in quartz and alkali feldspar. The presence of homogeneous cores in the plagioclase, early titanite crystallization in the Red Lake magma and irregular hornblende compositions suggest that refractory material was present when the magmas were intruded. Inferred source regions for the two plutons are amphibolite for the Red Lake magma and a more biotite-rich amphibolite for the Eagle Peak magma.

California↗

USGS1982

Petrology and trace element geochemistry of the Honolulu volcanics, Oahu: Implications for the oceanic mantle below Hawaii

The Honolulu Volcanics comprises small volume, late-stage (post-erosional) vents along rifts cutting the older massive Koolau tholeütic shield on Oahu, Hawaii. Most of these lavas and tuff of the Honolulu Volcanics have geochemical features expected of near-primary magmas derived from a peridotite source containing Fo 87–89 olivine; e. g. 100 Mg/(Mg + Fe 2+ ) >65, >250 p. p. m. Ni, and presence of ultramafic mantle xenoliths at 18 of the 37 vents. Consequently, the geochemistry of the alkali olivine basalt, basanite, nephelinite and nepheline melilitite lavas and tuff of the Honolulu Volcanics have been used to deduce the composition of their mantle source and the conditions under which they were generated by partial melting in the mantle. Compositional trends in 30 samples establish that the magmas were derived by partial melting of a garnet (<10 per cent) Iherzolite source, which we infer to have been carbon-bearing, from analogy with experimental results. This source was isotopically homogeneous (Sr, Lanphere & Dalrymple, 1980; Pb, Sun, 1980; Nd, Roden et al ., 1981), and we infer that the source was compositionally uniform in all major-element oxides except TiO 2 , in compatible trace elements (Sc, V, Cr, Mn, Co and Ni), and in highly incompatible trace elements (P, Th, La, Ce). However, the source appears to have been heterogeneous in TiO 2 , Zr, Hf, Nb, and Ta, elements that were not strongly incompatible during partial melting. Some nepheline melilitite samples may be derived from a source with distinct Sc and heavy-rare-earth-elements (REE) abundances, or which had a phase or phases controlling the distribution of these elements. The relatively limited abundance range for several elements, such as Ti, Zr, Nb, is partly a consequence of the low degrees of melting inferred for the series (2 per cent for nepheline melilitite, 11 per cent for alkali olivine basalt), which failed to exhaust the source in minor residual phases. We infer that these residual phases probably included phlogopite, amphibole, and another Ti-rich phase (an oxide?), but not apatite.

Journal of Petrology↗