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F. Mazdab

Publications and source records attributed to F. Mazdab.

3 recordsLinked to original sources

Dissolution-reprecipitation of igneous zircon in mid-ocean ridge gabbro, Atlantis Bank, Southwest Indian Ridge

Zircons recovered from oceanic gabbro exposed on Atlantis Bank, Southwest Indian Ridge, typically display oscillatory and sector zoning consistent with igneous crystallization from mafic magmas. In one rock (of twenty investigated), weak-oscillatory-zonation patterns are overprinted by secondary textural features characterized by mottled, convoluted and wavy internal zonation patterns that are frequently associated with secondary micron- to submicron-scale micro-porosity. These zircons are hosted in a felsic vein that intruded an oxide gabbro, both of which are cross-cut by monomineralic amphibole- and quartz-rich veinlets. Zircons with weak-oscillatory-zonation patterns record a weighted-average 206 Pb/ 238 U age of 12.76 ± 0.20 Ma (mswd = 1.5), and have high trace element concentrations [e.g., ΣREEs (∼ 0.4–2.2 wt.%), Y (∼ 0.6–2.8 wt.%), P (∼ 0.4–0.9 wt.%)], and Th/U (0.1–0.5). These zircons are anomalously old (≥1 Myr) relative to the magnetic age for this portion of oceanic crust (11.75 Ma). In contrast, zircons with non-igneous, secondary textures have a younger weighted-average 206 Pb/ 238 U age of 12.00 ± 0.16 Ma (mswd = 1.7), and have lower trace element concentrations [e.g., ΣREEs (∼ 0.2–0.8 wt.%), Y (∼ 0.3–1.0 wt.%), P (∼ 0.1–0.3 wt.%)], and slightly lower Th/U (0.1–0.3). The weighted-average age of these zircons is similar to the magnetic anomaly age, and other 206 Pb/ 238 U ages of nearby rocks. We do not observe a correlation between crystallographic misorientation, internal texture, or trace element chemistry. We suggest that the decrease in trace element concentrations associated with the development of non-igneous alteration textures is attributed to the purging of non-essential structural constituent cations from the zircon crystal lattice at amphibolite-facies conditions. The mechanism of alteration/re-equilibration was likely an interface-coupled dissolution–reprecipitation processes that affected pre-existing, anomalously old zircons during shallow-level magmatic construction of Atlantis Bank at ∼ 12.0 Ma.

Chemical Geology↗

Creation of a continent recorded in zircon zoning

We have discovered a robust microcrystalline record of the early genesis of North American lithosphere preserved in the U-Pb age and oxygen isotope zoning of zircons from a lower crustal paragneiss in the Neoarchean Superior province. Detrital igneous zircon cores with ??18O values of 5.1???-7.1??? record creation of primitive to increasingly evolved crust from 2.85 ?? 0.02 Ga to 2.67 ?? 0.02 Ga. Sharp chemical unconformity between cores and higher ??18O (8.4???-10.4???) metamorphic overgrowths as old as 2.66 ?? 0.01 Ga dictates a rapid sequence of arc unroofing, burial of detrital zircons in hydrosphere-altered sediment, and transport to lower crust late in upper plate assembly. The period to 2.58 ?? 0.01 Ga included ???80 m.y. of high-temperature (???700-650 ??C), nearly continuous overgrowth events reflecting stages in maturation of the subjacent mantle root. Huronian continental rifting is recorded by the youngest zircon tip growth at 2512 ?? 8 Ma (??? 600 ??C) signaling magma intraplating and the onset of rigid plate behavior. This >150 m.y. microscopic isotope record in single crystals demonstrates the sluggish volume diffusion of U, Pb, and O in zircon throughout protracted regional metamorphism, and the consequent advances now possible in reconstructing planetary dynamics with zircon zoning. ?? 2008 The Geological Society of America.

Geology↗

Thermometers and thermobarometers in granitic systems

The ability to determine the thermal and barometric history during crystallization and emplacement of granitic plutons has been enhanced by several new calibrations applicable to granitic mineral assemblages. Other existing calibrations for granitic plutons have continued to be popular and fairly robust. Recent advances include the trace element thermometers Ti-in-quartz, Ti-in-zircon, and Zr-in-sphene (titanite), which need to be further evaluated on the roles of reduced activities due to lack of a saturating phase, the effect of pressure dependence (particularly for the Ti-in-zircon thermometer), and how resistive these thermometers are to subsolidus reequilibration. As zircon and sphene are also hosts to radiogenic isotopes, these minerals potentially also provide new insights into the temperature - time history of magmas. When used in conjunction with pressure-sensitive mineral equilibria in the same rocks, a complete assessment of the P-T-t (pressure-temperature-time) path is possible given that the mineralogy of plutons can reflect crystallization over a range of pressure and temperature during ascent and emplacement and that many intrusions are now seen as forming over several millions of years during the protracted history of batholith construction. Accessory mineral saturation thermometers, such as those for zircon, apatite, and allanite, provide a different and powerful perspective, specifically that of the temperature of the onset of crystallization of these minerals, which can allow an estimate of the range of temperature between the liquidus and solidus of a given pluton. In assessment of the depth of crystallization and emplacement of granitic plutons, the Al-in-hornblende remains popular for metaluminous granites when appropriately corrected for temperature. For peraluminous granites, potential new calibrations exist for the assemblages bearing garnet, biotite, plagioclase, muscovite, and quartz. Other thermometers, based on oxygen abundance, and including Fe-Ti oxides, pyroxene, fayalitic olivine, quartz, sphene, and/or biotite, some of which have been recently revised, can provide additional information on temperature and oxygen fugacity. Oxygen fugacity can range over several orders of magnitude in different magmatic systems and can have profound influence on the mineralogy and mineral compositions in granitic magmas. It also forms the foundation of the popular magnetite- versus ilmenite-series granite classification. Copyright ?? Mineralogical Society of America.

Reviews in Mineralogy and Geochemistry↗