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F. G. Poole

Publications and source records attributed to F. G. Poole.

At least 19 recordsLinked to original sources

Sulfur- and oxygen-isotopes in sediment-hosted stratiform barite deposits

Sulfur- and oxygen-isotope analyses have been obtained for sediment-hosted stratiform barite deposits in Alaska, Nevada, Mexico, and China to examine the environment of formation of this deposit type. The barite is contained in sedimentary sequences as old as Late Neoproterozoic and as young as Mississippian. If previously published data for other localities are considered, sulfur- and oxygen-isotope data are now available for deposits spanning a host-rock age range of Late Neoproterozoic to Triassic. On a ??34S versus ??18O diagram, many deposits show linear or concave-upward trends that project down toward the isotopic composition of seawater sulfate. The trends suggest that barite formed from seawater sulfate that had been isotopically modified to varying degrees. The ??34S versus ??18O patterns resemble patterns that have been observed in the modern oceans in pore water sulfate and water column sulfate in some anoxic basins. However, the closest isotopic analog is barite mineralization that occurs at fluid seeps on modern continental margins. Thus the data favor genetic models for the deposits in which barium was delivered by seafloor seeps over models in which barium was delivered by sedimentation of pelagic organisms. The isotopic variations within the deposits appear to reflect bacterial sulfate reduction operating at different rates and possibly with different electron donors, oxygen isotope exchange between reduction intermediates and H2O, and sulfate availability. Because they are isotopically heterogeneous, sediment-hosted stratiform barite deposits are of limited value in reconstructing the isotopic composition of ancient seawater sulfate.

Geochimica et Cosmochimica Acta↗

Significance of detrital zircons in upper Devonian ocean-basin strata of the Sonora allochthon and Lower Permian synorogenic strata of the Mina Mexico foredeep, central Sonora, Mexico

U-Pb isotopic dating of detrital zircons from a conglomeratic barite sandstone in the Sonora allochthon and a calciclastic sandstone in the Mina Mexico foredeep of the Minas de Barita area reveals two main age groups in the Upper Devonian part of the Los Pozos Formation, 1.73-1.65 Ga and 1.44-1.42 Ga; and three main age groups in the Lower Permian part of the Mina Mexico Formation, 1.93-1.91 Ga, 1.45-1.42 Ga, and 1.1-1.0 Ga. Small numbers of zircons with ages of 2.72-2.65 Ga, 1.30-1.24 Ga, ca. 2.46 Ga, ca. 1.83 Ga, and ca. 0.53 Ga are also present in the Los Pozos sandstone. Detrital zircons ranging in age from 1.73 to 1.65 Ga are considered to have been derived from the Yavapai, Mojave, and Mazatzal Provinces and their transition zones of the southwestern United States and northwestern Mexico. The 1.45-1.30 Ga detrital zircons were probably derived from scattered granite bodies within the Mojave and Mazatzal basement rocks in the southwestern United States and northwestern Mexico, and possibly from the Southern and Eastern Granite-Rhyolite Provinces of the southern United States. The 1.24-1.0 Ga detrital zircons are believed to have been derived from the Grenville (Llano) Province to the east and northeast or from Grenvilleage intrusions or anatectites to the north. Several detrital zircon ages ranging from 2.72 to 1.91 Ga were probably derived originally from the Archean Wyoming Province and Early Paleoproterozoic rocks of the Lake Superior region. These older detrital zircons most likely have been recycled one or more times into the Paleozoic sandstones of central Sonora. The 0.53 Ga zircon is believed to have been derived from a Lower Cambrian granitoid or meta-morphic rock northeast of central Sonora, possibly in New Mexico and Colorado, or Oklahoma. Detrital zircon geochronology suggests that most of the detritus in both samples was derived from Laurentia to the north, whereas some detritus in the Permian synorogenic foredeep sequence was derived from the evolving accretionary wedge to the south. Compositional and sedimentological differences between the continental-rise Los Pozos conglomeratic barite sandstone and the foredeep Mina Mexico calciclastic sandstone imply different depositional and tectonic settings. ?? 2008 The Geological Society of America.

Special Paper of the Geological Society of America↗

Comparison of some sediment-hosted, stratiform barite deposits in China, the United States, and India

Shifts in world barite production since the 1980s have resulted in China becoming the world's largest barite-producing country followed by the US and India. Most barite produced for use in drilling fluids is derived from black shale- and chert-hosted, stratiform marine deposits. In China, Late Proterozoic to Early Cambrian marine barite deposits occur on the oceanic margins of the Yangtze platform, in the Qinling region in the north and the Jiangnan region in the south. Most US ore-grade deposits are in the Nevada barite belt; most commercial deposits occur in Ordovician and Devonian marine rocks along the western margin of the early Paleozoic North American continent. Production in India is predominantly from a single Middle Proterozoic deposit in a sedimentary basin located on Archean basement in Andrah Pradesh.The geologic and geochemical characteristics of the deposits are consistent with origins from a variety of sedimentary-exhalative processes, with biogenic processes contributing to the concentration of some seafloor barite. Linear distributions of clusters of lenticular deposits suggest a geographic relationship to syndepositional seafloor fault zones. Sulfur isotope data of the barite deposits range from values that are similar to coeval seawater sulfate to significantly higher ??34S values. Strontium isotope values of continental-margin-type deposits in Nevada and China are less radiogenic than those of cratonic-rift deposits (e.g. Meggen and Rammelsberg). Comparison of Lan/ Cen ratios of barite in the Qinling region of China with marine chert ratios suggests a relationship to hydrothermal fluids, whereas ratios from the Jiangnan region and Nevada can be interpreted as reflecting a biogenic influence.The California Borderland provides a potential modern analog where hydrothermal barium is being deposited on the seafloor in fault-block-bounded basins. Anoxic to dysaerobic conditions on some marine basin floors result from upwelling, nutrient-rich currents and high productivity in surface waters. In this setting, biogenic processes could contribute to the concentration of barium from hydrothermal sources. ?? 2003 Published by Elsevier B.V.

Ore Geology Reviews↗

Reinterpretation of the stratigraphy and structure of the Rancho Las Norias area, central Sonora, Mexico

New geologic mapping and fossil data in the vicinity of Rancho Las Norias, 30 km east of Hermosillo, Sonora, Mexico, show that rocks previously mapped as Precambrian instead are Paleozoic. Previous geologic maps of the Rancho Las Norias area show northeast-directed, southwest-dipping reverse or thrust faults deforming both Precambrian and Paleozoic rocks. The revised stratigraphy requires reinterpretation of some of these faults as high-angle normal or oblique-slip faults and the elimination of other faults. We agree with earlier geologic map interpretations that compressional structures have affected the Paleozoic rocks in the area, but our mapping suggests that the direction of compression is from southeast to northwest. Published by Elsevier Ltd.

Journal of South American Earth Sciences↗

Formation of modern and Paleozoic stratiform barite at cold methane seeps on continental margins

Stratiform (bedded) Paleozoic barite occurs as large conformable beds within organic- and chert-rich sediments; the beds lack major sulfide minerals and are the largest and most economically significant barite deposits in the geologic record. Existing models for the origin of bedded barite fail to explain all their characteristics: the deposits display properties consistent with an exhalative origin involving fluid ascent to the seafloor, but they lack appreciable polymetallic sulfide minerals and the corresponding strontium isotopic composition to support a hydrothermal vent source. A new mechanism of barite formation, along structurally controlled sites of cold fluid seepage in continental margins, involves barite remobilization in organic-rich, highly reducing sediments, transport of barium-rich fluids, and barite precipitation at cold methane seeps. The lithologic and depositional framework of Paleozoic and cold seep barite, as well as morphological, textural, and chemical characteristics of the deposits, and associations with chemosymbiotic fauna, all support a cold seep origin for stratiform Paleozoic barite. This understanding is highly relevant to paleoceanographic and paleotectonic studies, as well as to economic geology.

Geology↗

Middle Devonian to Early Carboniferous event stratigraphy of Devils Gate and Northern Antelope Range sections, Nevada, U.S.A

The classic type section of the Devils Gate Limestone at Devils Gate Pass is situated on the eastern slope of a proto-Antler forebulge that resulted from convergence of the west side of the North American continent with an ocean plate. The original Late Devonian forebulge, the site of which is now located between Devils Gate Pass and the Northern Antelope Range, separated the continental-rise to deep-slope Woodruff basin on the west from the backbulge Pilot basin on the east. Two connections between these basins are recorded by deeper water siltstone beds at Devils Gate; the older one is the lower tongue of the Woodruff Formation, which forms the basal unit of the upper member of the type Devils Gate, and the upper one is the overlying, thin lower member of the Pilot Shale. The forebulge and the backbulge Pilot basin originated during the middle Frasnian (early Late Devonian) Early hassi Zone, shortly following the Alamo Impact within the punctata Zone in southern Nevada. Evidence of this impact is recorded by coeval and reworked shocked quartz grains in the Northern Antelope Range and possibly by a unique bypass-channel or megatsunami-uprush sandy diamictite within carbonate-platform rocks of the lower member of the type Devils Gate Limestone. Besides the Alamo Impact and three regional events, two other important global events are recorded in the Devils Gate section. The semichatovae eustatic rise, the maximum Late Devonian flooding event, coincides with the sharp lithogenetic change at the discordant boundary above the lower member of the Devils Gate Limestone. Most significantly, the Devils Gate section contains the thickest and most complete rock record in North America across the late Frasnian linguiformis Zone mass extinction event. Excellent exposures include not only the extinction shale, but also a younger. Early triangularis Zone tsunamite breccia, produced by global collapse of carbonate platforms during a shallowing event that continued into the next younger Famennian Stage. The Northern Antelope Range section is located near the top of the west side of the proto-Antler forebulge. Because of its unusual, tectonically active location, unmatched at any other Nevada localities, this section records only four regional and global events during a timespan slightly longer than that of the Devils Gate section. The global semichatovae rise and late Frasnian mass extinction event are largely masked because of the depositional complexities resulting from this location.

Nevada↗

A problematic early tetrapod from the Mississippian of Nevada

We report here the discovery of a new taxon of Paleozoic tetrapod from the Late Mississippian of Nevada (330–340 Ma). It has a unique vertebral column with principal centra having vertical anterior and posterior faces, ventrally incomplete accessory centra located antero-dorsally in each centrum, and enlarged presacral/sacral vertebrae. The head and pectoral girdle were not preserved but the large femur, robust pelvic girdle and enlarged sacral vertebrae possibly indicate a terrestrial mode of life. This new form significantly extends the western geographic range of known Mississippian tetrapods. It presents a mosaic of primitive and derived features, indicating that continued revision of traditional accounts of vertebral homology and the early diversifications of Paleozoic tetrapods will be necessary.

Journal of Vertebrate Paleontology↗

Quantitative analysis versus semiquantitative optical emission spectrographic analysis of chromium, nickel, zinc, vanadium, and molybdenum in organic-rich Paleozoic marine strata, Western United States

Comparison of analytical results between the quantitative method and the semiquantitative six-step optical-emission spectrographic method commonly shows significantly lower values for the semiquantitative method. The lower values are most obvious for splits from the same samples of fine-grained organic-rich rocks where the concentrations of the metals chromium, nickel, zinc, vanadium, and molybdenum are greater than about 200 ppm (parts per million). Samples compared are Paleozoic marine rocks from the Western United States; they include the Permian Phosphoria Formation (Idaho, Montana, Utah, Wyoming), Mississippian Chainman Shale (Nevada and Utah), Mississippian Heath Formation (Montana), Mississippian Doughnut Formation (Utah), Devonian Woodruff Formation (Nevada), and Ordovician Vinini Formation (Nevada). The semiquantitative method consistently underestimates the concentration of the five metals studied by a factor of 1.7 to 2.7 and, thus, cannot be considered reliable for determining the concentration of metals in these rocks if the reported semiquantitative values exceed about 100 ppm. It is noteworthy that the most comprehensive analytical and statistical studies of metal concentrations in black shales of the United States have used the semiquantitative six-step optical-emission method of analysis.

Idaho, Montana, Nevada, Utah, Wyoming↗