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F. Cuttitta

Publications and source records attributed to F. Cuttitta.

10 recordsLinked to original sources

New data on selected Ivory Coast tektites

Fourteen Ivory Coast tektites exhibit a range of bulk indices of refraction of 1.5156 to 1.5217 ± 0.0004 and of bulk specific gravities of 2.428 to 2.502 ±0.005. Seven of these Ivory Coast (IVC) tektites were analyzed for major and minor element content. Compared to tektites from other strewn fields, their SiO 2 content is low (67.2–69.1 %), A1 2 O 3 relatively high (15.8–16.8 %), and total iron relatively high but with a more restricted range (6.3–6.8 % as FeO). Their lime content is low (0.71–1.35%) compared to Australasian tektites but their MgO CaO "> MgOCaO ratio (about 3.1) is unusually high. All other tektite groups have Na 2 O K 2 O "> Na2OK2O ratios less than unity, but the Na 2 O K 2 O "> Na2OK2O ratio of the IVC tektites is slightly greater than unity. Their K Rb "> KRb ratios range from 200 to 256 and average 227, which is higher than those determined for Australasian tektites, but similar to some obtained for moldavites. The Li content (41–48 ppm) is about the same as that of the Australasian tektites, but the Cs and Rb are lower, being 1.9 to 2.9 and 57 to 86 ppm, respectively. The IVC tektites are high in Cr (260–375 ppm), Co (19–25 ppm) and Ni (101–167 ppm), and particularly in Pb (<10–18 ppm ), Cu (13–21 ppm) and Ga (14–23 ppm). The high Cr Ni "> CrNi ratios of the IVC tektites (range 2–3.6) are similar to those found for australites, philippinites and thailandites, but not the javanites and indochinites. Evaluation of these and other reported data show that compositional similarities between the IVC tektites and green or black Bosumtwi Crater glasses strongly support the hypothesis of a common impact origin—i.e. the Bosumtwi Crater site. Comparison of the IVC tektite composition with those of returned lunar materials (gabbros, basalts, breccia and soils) do not support a lunar origin for the Ivory Coast tektites.

Geochimica et Cosmochimica Acta

On the origin of lunar soil 12033

The lunar soil 12033 is compositionally distinctly different from both the local rocks at the Apollo 12 site and other lunar samples. It must be a recent deposit, else it would not have retained its identity. It contains a meteoritic component which is about 0.59 times as large as that in the more typical Apollo 12 soils. The amount of meteoritic component may be either a fortuitous residuum from the object which produced the 12033 material as crater ejecta, or 12033 may consist of a mixture of an exotic component with the local soil in approximately 41:59 proportions. The available evidence favors the latter interpretation.

Earth and Planetary Science Letters

Semimicro chemical and x-ray fluorescence analysis of lunar samples

Major and selected minor elements were determined in seven whole rock fragments, five portions of pulverized lunar rock, and the lunar soil. Three different rock types were represented: vesicular, fine-grained basaltic rocks; medium- to coarse-grained, vuggy gabbroic rocks; and breccia. The ranges (in percent) for the major constituents of the lunar samples are: SiO 2 , 38 to 42; Al 2 O 3 , 8 to 14; total iron as FeO, 15 to 20; MgO, 6 to 8; CaO, 10 to 12; Na 2 O, 0.5 to 1; K 2 O, 0.05 to 0.4; TiO 2 , 8 to 13; MnO, 0.2 to 0.3; and Cr 2 O 3 , 0.2 to 0.4. The high reducing capacity of the samples strongly suggests the presence of Ti(III).

Science

Antiferromagnetism of UO2⋅2H2O

Magnetic susceptibility measurements have been made on UO 2 · x H 2 O for x =1.78 to x =2.13, and from 77° to 375°K. As the value of x decreased the susceptibility increased. Both these data and structural arguments imply that the formula of this compound is U(OH) 4 rather than the dihydrate form. Based on this concept the data have been corrected for diamagnetism and also small amounts of UO 2 and H 2 O which were present. The molar susceptibility of U 4+ in U(OH) 4 is nearly an order of magnitude less than in other uranium compounds, and it is suggested that this is probably due to superexchange between adjacent uranium atoms through intervening oxygen atoms.

Journal of Chemical Physics

Determination of uranium in zircon

A routine fluorimetric procedure is described for the determination of trace amounts of uranium in zircon. It employs the direct extraction of uranyl nitrate with ethyl acetate using phosphate as a retainer for zirconium. Submicrogram amounts or uranium are separated in the presence of 100,000 times the amount of zirconium. The modified procedure has been worked out using synthetic mixtures of known composition and zircon. Results of analyses have an accuracy of 97–98% of the contained uranium and a standard deviation of less than 2.5%.

Analytica Chimica Acta

Retention of lead during oxidative ashing of selected naturally occurring carbonaceous substances

The amount of lead retained in the ash of lead-bearing carbonaceous material is essentially independent of the method of ashing. Samples containing lead in the range of 0.00X to 0.X per cent were ashed by ignition in a high-oxygen atmosphere and were also wet-ashed. The lead in the ash was determined colorimetrically. Results were the same by both methods, but the time required is 3 to 10 times less for the dry-ashing method.

Geochimica et Cosmochimica Acta

Some natural variations in the relative abundance of copper isotopes

The relative isotopic abundance of copper has been measured in a number of minerals and a few plant materials. Suites of samples from Michigan and the Colorado Plateau have been examined in more detail to determine if local variations due to isotopic exchange or diffusion could be found. The relative isotopic abundance of copper in specimens from several other localities was also determined. The variations noted were small but in some cases were felt to be significant because they were larger than the experimental error (0·1 per cent in the ratio). A total spread of −1 to +8 parts per mil compared to the standard was found in the specimens tested.

Geochimica et Cosmochimica Acta

Comparison of the isotopic abundance of U235 and U238 and the radium activity ratios in Colorado Plateau uranium ores

The isotopic abundances of uranium and the radium activity ratios of eleven samples of uranium ore from the Colorado Plateau have been measured. No significant variation in the isotopic abundance of the uranium was noted; with'in the experimental error, the average U 235 /U 238 ratio is 137.7. There is a significant variation in the Ra 226 /Ra 223 activity ratios (0.048−0.143), which indicates a relatively recent alteration of the ore samples. The variations do not, however, explain the lead-uranium and lead-lead age discrepancies.

Geochimica et Cosmochimica Acta

Determination of small and large amounts of fluorine in rocks

Gelatinous silica and aluminum ions retard the distillation of fluorine in the Willard and Winter distillation method. A generally applicable, simple method for the determination of fluorine in rocks containing aluminum or silicon or both as major constituents was desired. In the procedure developed, the sample is fused with a mixture of sodium carbonate and zinc oxide, leached with water, and filtered. The residue is granular and retains nearly all of the silica. The fluorine in the filtrate is distilled directly from a perchloric acid-phosphoric acid mixture. Phosphoric acid permits the quantitative distillation of fluorine in the presence of much aluminum at the usual distillation temperature and without the collection of large volumes of distillate. The fluorine is determined either by microtitration with thorium nitrate or colorimetrically with thoron. The procedure is rapid and has yielded excellent results on silicate rocks and on samples from the aluminum phosphate (leached) zone of the Florida phosphate deposits.

Analytical Chemistry