Geology topics

Elizabeth H. Shadwick

Publications and source records attributed to Elizabeth H. Shadwick.

2 recordsLinked to original sources

USGS2020

Challenges in quantifying air-water carbon dioxide flux using estuarine water quality data: Case study for Chesapeake Bay

Estuaries play an uncertain but potentially important role in the global carbon cycle via CO 2 outgassing. The uncertainty mainly stems from the paucity of studies that document the full spatial and temporal variability of estuarine surface water partial pressure of carbon dioxide ( p CO 2 ). Here, we explore the potential of utilizing the abundance of pH data from historical water quality monitoring programs to fill the data void via a case study of the mainstem Chesapeake Bay (eastern United States). We calculate p CO 2 and the air-water CO 2 flux at monthly resolution from 1998 to 2018 from tidal fresh to polyhaline waters, paying special attention to the error estimation. The biggest error is due to the pH measurement error, and errors due to the gas transfer velocity, temporal sampling, the alkalinity mixing model, and the organic alkalinity estimation are 72%, 27%, 15%, and 5%, respectively, of the error due to pH. Seasonal, interannual, and spatial variability in the air-water flux and surface p CO 2 is high, and a correlation analysis with oxygen reveals that this variability is driven largely by biological processes. Averaged over 1998–2018, the mainstem bay is a weak net source of CO 2 to the atmosphere of 1.2 (1.1, 1.4) mol m −2 yr −1 (best estimate and 95% confidence interval). Our findings suggest that the abundance of historical pH measurements in estuaries around the globe should be mined in order to constrain the large spatial and temporal variability of the CO 2 exchange between estuaries and the atmosphere.

Maryland, Virginia↗

USGS2020

Alkalinity in tidal tributaries of the Chesapeake Bay

Despite the important role of alkalinity in estuarine carbon cycling, the seasonal and decadal variability of alkalinity, particularly within multiple tidal tributaries of the same estuary, is poorly understood. Here we analyze more than 26,000 alkalinity measurements, mostly from the 1980s and 1990s, in the major tidal tributaries of the Chesapeake Bay, a large, coastal-plain estuary of eastern North America. The long-term means of alkalinity in tidal-fresh waters vary by a factor of 6 among seven tidal tributaries, reflecting the alkalinity of non-tidal rivers draining to these estuaries. At 25 stations, mostly in the Potomac River Estuary, we find significant long-term increasing trends that exceed the trends in the non-tidal rivers upstream of those stations. Box model calculations in the Potomac River Estuary indicate that the main cause of the estuarine trends is a declining alkalinity sink. The magnitude of this sink is consistent with a simple model of calcification by the invasive bivalve Corbicula fluminea. More generally, in tidal tributaries fed by high-alkalinity non-tidal rivers, alkalinity is consumed, with sinks ranging from 8 to 27% of the upstream input. In contrast, tidal tributaries that are fed by low-alkalinity non-tidal rivers have sources of alkalinity amounting to 34 to 171% of the upstream input. For a single estuarine system, the Chesapeake Bay has diverse alkalinity dynamics and can thus serve as a laboratory for studying the numerous processes influencing alkalinity among the world’s estuaries.

Maryland, Virginia↗