Geology topics

Edward R. Landa

Publications and source records attributed to Edward R. Landa.

22 records · Page 2Linked to original sources

USGS1995

Remediation of uranium contaminated soils with bicarbonate extraction and microbial U(VI) reduction

A process for concentrating uranium from contaminated soils in which the uranium is first extracted with bicarbonate and then the extracted uranium is precipitated with U(VI)-reducing microorganisms was evaluated for a variety of uranuum-contaminated soils. Bicarbonate (100 mM) extracted 20–94% of the uranium that was extracted with nitric acid. The U(VI)-reducing microorganism, Desulfovibrio desulfuricans reduced the U(VI) to U(IV) in the bicarbonate extracts. In some instances unidentified dissolved extracted components, presumably organics, gave the extract a yellow color and inhibited U(VI) reduction and/or the precipitation of U(IV). Removal of the dissolved yellow material with the addition of hydrogen peroxide alleviated this inhibition. These results demonstrate that bicarbonate extraction of uranium from soil followed by microbial U(VI) reduction might be an effective mechanism for concentrating uranium from some contaminated soils.

Journal of Industrial Microbiology↗

USGS1995

Sorption and coprecipitation of trace concentrations of thorium with various minerals under conditions simulating an acid uranium mill effluent environment

Sorption of thorium by pre-existing crystals of anglesite (PbSO 4 ), apatite (Ca 5 (PO 4 ) 3 (HO)), barite (BaSO 4 ), bentonite (Na 0.7 Al 3.3 Mg 0.7 Si 8 O 20 (OH) 4 ), celestite (SrSO 4 ), fluorite (CaF 2 ), galena (PbS), gypsum (CaSO 4 ·2H 2 O), hematite (Fe 2 O 3 ), jarosite (KFe 3 (SO 4 ) 2 (OH) 6 ), kaolinite (Al 2 O 3 ·2SiO 2 ·2H 2 O), quartz (SiO 2 ) and sodium feldspar (NaAlSi 3 O 8 ) was studied under conditions that simulate an acidic uranium mill effluent environment. Up to 100% removal of trace quantitiees of thorim (approx. 1.00 ppm in 0.01 N H 2 SO 4 ) from solution occurred within 3 h with fluorite and within 48 h in the case of bentonite. Quartz, jarosite, hematite, sodium feldspar, gypsum and galena removed less than 15% of the thorium from solution. In the coprecipitation studies, barite, anglesite, gypsum and celestite were formed in the presence of thorium (approx. 1.00 ppm). Approximately all of the thorium present in solution coprecipitated with barite and celestite; 95% coprecipitated with anglesite and less than 5% with gypsum under similar conditions. When jarosite was precipitated in the presence of thorium, a significant amount of thorium (78%) was incorporated in the precipitate.

Inorganica Chimica Acta↗

USGS1992

Leaching of uranium from glass and ceramic foodware and decorative items

Beginning as early as the first century A. D. and continuing until at least the 1970s, uranium was used as a coloring agent in glass and in ceramic glazes. The leaching of uranium from such items is of interest as some were designed for food storage or serving. Thirty-three glass items and two ceramic items were leached sequentially with deionized water, dilute acetic acid, and 1 M nitric acid to assess realistic and worst-case scenario leaching by foods and beverages. The maximum quantity of uranium leached from the uranium-bearing glasses was about 30 µg L-1, while that from the ceramic-glazed items was about 300,000 µg L-1.

Health Physics↗

USGS1985

Dissolution of alkaline earth sulfates in the presence of montmorillonite

In a study of the effect of montmorillonite on the dissolution of BaSO4 (barite), SrSO4 (celestite), and 226Ra from U mill tailings, it was found that: (1) More of these substances dissolve in an aqueous system that contains montmorillonite than dissolve in a similar system without clay, due to the ion exchange properties of the clay; (2) Na-montmorillonite is more effective in aiding dissolution than is Ca-montmorillonite; (3) the amount of Ra that moves from mill tailings to an exchanger increases as solution sulfate activity decreases. Leaching experiments suggest that 226Ra from H2SO4-circuit U mill tailings from Edgemont, South Dakota, is not present as pure Ra sulfate or as an impurity in anhydrite or gypsum; it is less soluble, and probably occurs as a trace constituent in barite.

Water, Air, & Soil Pollution↗