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E.E. Angino

Publications and source records attributed to E.E. Angino.

6 recordsLinked to original sources

Leaching characteristics of a high-calcium fly ash as a function of pH: A potential source of selenium toxicity

Using a modified extraction procedure, the effect of pH on the leaching of selected elements from Ca-rich (Type C) power plant fly ash was studied. Continuous additions of acetic acid were used to maintain pH values of fly ash slurries at 4.0, 6.0 and 8.0 for 24 h and an additional set was leached at its natural pH (average 11.8) value. Analyses for Se, As, Ca, Cd, Cr, Fe, Na and Pb showed that the highest concentrations occur in the leachate at pH 4.0 and decline with increasing pH. Concentrations of Cr and Fe increased slightly between neutral and high pH. Arsenic, Cd, Cr, Pb and Se concentrations exceeded the Environmental Protection Agency's toxicity criteria at pH 4.0. Selenium was above its toxicity level at pH values near 7 but the other elements were below their respective toxicity levels near neutral pH. Because recent studies show adverse effects of Se on aquatic life at far lower concentrations than the current Environmental Protection Agency's standard, high-Ca, power plant fly ashes represent a potentially hazardous pollutant to surface and subsurface waters.

Applied Geochemistry

Population dynamics of pond zooplankton, I. Diaptomus pallidus Herrick

The simultaneous and lag relationships between 27 environmental variables and seven population components of a perennial calanoid copepod were examined by simple and partial correlations and stepwise regression. The analyses consistently explained more than 70% of the variation of a population component. The multiple correlation coefficient (R) usually was highest in no lag or in 3-week or 4-week lag except for clutch size in which R was highest in 1-week lag. Population control, egg-bearing, and clutch size were affected primarily by environmental components categorized as weather; food apparently was relatively minor in affecting population control or reproduction. ?? 1973 Dr. W. Junk B.V. Publishers.

Hydrobiologia

Population dynamics of pond zooplankton II Daphnia ambigua Scourfield

Calcium was the most important of 27 environmental components affecting density for a 50 week period. Simultaneous stepwise regression accounted for more variability in total number/1 and in the number of ovigerous females/1 than did any of the lag analyses; 1-week lag accounted for the greatest amount of variability in clutch size. Total number and clutch size were little affected by measures of food. ?? 1973 Dr. W. Junk b.v. Publishers.

Hydrobiologia

Arsenic in detergents: Possible danger and pollution hazard

Arsenic at a concentration of 10 to 70 parts per million has been detected in several common presoaks and household detergents. Arsenic values of 2 to 8 parts per billion have been measured in the Kansas River. These concentrations are close to the amount (10 parts per billion) recommended by the United States Public Health Service as a drinking-water standard.

Science

Chemical composition of selected Kansas brines as an aid to interpreting change in water chemistry with depth

Chemical analyses of approximately 1,881 samples of water from selected Kansas brines define the variations of water chemistry with depth and aquifer age. The most concentrated brines are found in the Permian rocks which occupy the intermediate section of the geologic column of this area. Salinity decreases below the Permian until the Ordovician (Arbuckle) horizon is reached and then increases until the Precambrian basement rocks are reached. Chemically, the petroleum brines studied in this small area fit the generally accepted pattern of an increase in calcium, sodium and chloride content with increasing salinity. They do not fit the often-predicted trend of increases in the calcium to chloride ratio, calcium content and salinity with depth and geologic age. The calcium to chloride ratio tends to be asymptotic to about 0.2 with increasing chloride content. Sulfate tends to decrease with increasing calcium content. Bicarbonate content is relatively constant with depth. If many of the hypotheses concerning the chemistry of petroleum brines are valid, then the brines studied are anomolous. An alternative lies in accepting the thesis that exceptions to these hypotheses are rapidly becoming the rule and that indeed we still do not have a valid and general hypothesis to explain the origin and chemistry of petroleum brines.

Kansas

Observed variations in the strontium concentration of sea water

On samples obtained from five widely separated areas of the North Atlantic Ocean 91 determinations of strontium were made. These include surface and deep-water samples from both the cold North Atlantic area and the warm subtropical Caribbean area. The results differ from many of the previously reported values for strontium in sea water. It appears that the more correct value for soluble strontium in sea water is less than the commonly accepted figure of 8.0–8.2 mg/l and most likely lies between 7.2 and 7.8 mg/l. The use of an “average” figure for strontium in sea water should be discouraged as it is clear that the soluble strontium content in sea water does vary considerably; consequently the assumption of a “constant” strontium/chlorinity ratio in the ocean is in error.

Chemical Geology