Geology Reports⌕ Search

Geology topics

E. R. Force

Publications and source records attributed to E. R. Force.

At least 19 recordsLinked to original sources

Laramide alteration of proterozoic diabase: A likely contributor of copper to porphyry systems in the dripping spring mountains area, Southeastern Arizona

Proterozoic diabase of the Dripping Spring range occurs as sills in the Proterozoic Apache Group and the Troy Quartzite and as intrustive sheets in basement rocks. The aggregate thickness of the diabase sills and intrusive sheets averages about 450 m in the part of the range showing little mid-Tertiary extension. Laramide alteration is of two types, dominated by chlorite and actinolite, respectively, and formed mostly from clinopyroxene. Actinolite-dominated assemblages are higher in Na and Ca. Hydrothermal biotite is common in the central areas of both alteration types. Laramide alteration forms two distribution patterns: a subsequent pattern centered on Laramide intrusions and small porphyry deposits, characterized by actinolitic alteration, and a more extensive branching linear pattern that follows Laramide structures, centered on the larger Ray porphyry deposit, extending toward other Laramide districts and showing both alteration types. Alteration has apparently mobilized copper and other metals from diabase. The freshest diabase samples average about 120 ppm copper with little variation. In chloritic alteration, about 100 ppm of this copper is expelled in the most completely altered rocks. In actinolitic alteration, diabase may either gain or lose copper during alteration. Chloritic alteration constitutes roughly 70 percent of the diabase alteration in the study area, where alteration averages 41 percent complete. This implies liberation of about 9X10 6 tons (t) copper from diabase alteration, significantly less than the 16X10 6 t copper in Laramide mineral deposits of the superdistrict Ray, Superior. Chilito. Christmas. However, diabase alteration may have been a significant component of the supply of copper to the Laramide mineral districts of the area. Synmineral magmatic sources of copper are not documented in this area. The distribution of Proterozoic diabase coincides with the central part of the southeastern Arizona copper province, which may thus owe much copper availability to an unusual abundance of diabase. However, many unanswered questions remain about metal supply from altering diabase.

Economic Geology↗

Mineral intergrowths replaced by "elbow-twinned" rutile in altered rocks

Some aggregates of rutile, classically considered to be "elbow" twinned, instead are topotactic replacements of ilmenite or other hexagonal titaniferous precursors. Twinned rutile can be differentiated from the reticulated rutile of topotactic replacements by the angle of prism intersections, junction morphology, and the overall form of the aggregate. In a special case of topotactic replacement of ilmenite, rutile forms pseudomorphs of "trellis"-textured ilmenite lamellae in {111} of precursor magnetite. We trace the progress of rutile formation through the alteration of fine-grained magnetite-bearing host rocks. The sequential two-step topotaxy from magnetite through ilmenite to rutile requires rutile prisms to parallel the intersections of {111} planes in precursor magnetite. Some coarse reticulated rutile may result from the same paragenetic sequence.

Canadian Mineralogist↗

Tilting history of the San Manuel-Kalamazoo porphyry system, southeastern Arizona

The Laramide San Manuel-Kalamazoo porphyry system of Arizona has been pivotal in concepts of both extensional tectonics and alteration-mineralization zoning. This paper reexamines the tilting history in light of new work in the region and reinterprets the geometry of the deposit. The porphyry mineralization occurs in and near an intrusion of Laramide San Manuel porphyry in Precambrian Oracle Granite. The area has an extremely complicated history of Tertiary crustal extension and fanglomerate deposition, but the blocks containing the two main fragments of the original orebody (separated by the San Manuel fault) were involved in only the later parts of this history and are less tilted than other nearby blocks. Originally horizontal features of mid-Tertiary age are tilted about 30 degrees , those of Laramide age about 35 degrees , and those of pre-Laramide age about 45 degrees to the northeast. Paleomagnetism of the porphyry intrusion itself suggests tilting of about 33 degrees . The data thus suggest that postemplacement tilt of the Laramide porphyry system was 30 degrees to 35 degrees and that virtually all of it was mid-Tertiary in age. An earlier interpretation of greater tilt magnitude was apparently based in part on correlation with adjacent areas showing greater tilt magnitude (as in the Tar Wash allochthon) and in part on a choice of cross section that gives the impression of a nearly recumbent attitude. However, Lowell's sections are oriented along the strike of both the orebodies and the productive porphyry intrusion, which are dipping tablo-cylindroidal bodies. Ore forms a hollow envelope whose inner margin has an aspect ratio of about >4.3 (length)/>2.5 (downdip height)/l (limb separation). The productive intrusion, around which ore is wrapped, has a similar aspect ratio in the same plane (strike N 58 degrees E, dip 47 degrees SE). Reconstruction of the original attitudes of intrusion and ore yields a common strike near N 75' E and a steep dip to the south. This is a common attitude for undisturbed productive porphyry dikes of Laramide age.

Arizona↗

Isotopic evidence for organic matter oxidation by manganese reduction in the formation of stratiform manganese carbonate ore

Unlike other marine-sedimentary manganese ore deposits, which are largely composed of manganese oxides, the primary ore at Molango (Hidalgo State, Mexico) is exclusively manganese carbonate (rhodochrosite, Mn-calcite, kutnahorite). Stable isotope studies of the carbonates from Molango provide critical new information relevant to the controversy over syngenetic and diagenetic models of stratiform manganese deposit formation. Negative δ 13 C values for carbonates from mineralized zones at Molango are strongly correlated with manganese content both on a whole rock scale and by mineral species. Whole rock δ 13 C data fall into three groups: high-grade ore = −16.4 to −11.5%.; manganese-rich, sub-ore-grade = −5.2 to 0%.; and unmineralized carbonates = 0 to +2.5%. (PDB). δ 18 O data show considerable overlap in values among the three groups: +4.8 to −2.8, −5.4 to −0.3%., and −7.4 to +6.2 (PDB), respectively. Isotopic data for individual co-existing minerals suggest a similar separation of δ 13 C values: δ 13 C values from calcite range from −1.1 to +0.7%. (PDB), whereas values from rhodochrosite are very negative, −12.9 to −5.5%., and values from kutnahorite or Mn-calcite are intermediate between calcite and rhodochrosite. 13 C data are interpreted to indicate that calcite ( i.e . unmineralized carbonate) formed from a normal marine carbon reservoir. However, 13 C data for the manganese-bearing carbonates suggest a mixed seawater and organic source of carbon. The presence of only trace amounts of pyrite suggests sulfate reduction may have played a minor part in oxidizing organic matter. It is possible that manganese reduction was the predominant reaction that oxidized organic matter and that it released organic-derived CO 2 to produce negative δ 13 C values and manganese carbonate mineralization.

Geochimica et Cosmochimica Acta↗

Resource assessments, geologic deposit models, and offshore minerals with an example of heavy-mineral sands

A resource assessment method for offshore minerals based on descriptive and grade-tonnage models is proposed. Historical development and applications of this method are summarized. Based on this approach, descriptive and quantitative deposit models for strand-line titanium placer deposits have been developed. Descriptive statistics were also computed using the worldwide deposit data set upon which the grade-tonnage models are based. Certain guidelines and limitations in applying onshore titanium deposit models to offshore assessment and exploration must, however, be observed. The descriptive model points out the specific features of strandline titanium placer deposits which can be of use in selection of areas for exploration; the grade-tonnage models display the expected size distribution for this type of deposit. Used with an estimate of expected number of deposits, this information can be applied to quantify probable values associated with deposits of this type within a given area.

NATO Science Series↗

A ground-water mixing model for the origin of the Imini manganese deposit (Cretaceous) of Morocco

Three beds of manganese oxide ore in a 10 m-thick dolomite unit are associated with diagenetic features, and, are accordingly also diagenetic in their present aspect. Whether primary or introduced, the Mn mineralogy is attributed to reactions between fresh and saline ground-waters as the zone of mixing passed through the dolomite unit during a period of falling sea-level. The succession of diagenetic changes is: 1) precursor carbonates, 2) dolomite-janggunite, 3) hollandite-pyrolusite-chert-calcite.-G.J.N.

Economic Geology↗

Borehole field calibration and measurement of low-concentration manganese by decay gamma rays

The manganese concentration in the Arundel clay formation, Prince Georges County, Maryland, was determined from a borehole by using delayed neutron activation. The neutrons were produced by a 100 mu g 252 Cf source. The 847 keV gamma ray of manganese was detected continuously, and its counting rate was measured at intervals of 15 s as the measuring sonde was moved at a rate of 0.5 cm/s. The technique measured the concentration ratio of manganese to aluminum. This ratio, when combined with an estimate of the aluminum concentration of the clay, made it possible to determine the percentage concentration of manganese without using a test-pit calibration facility. The measurements were made by using an NaI(Tl) scintillation detector and a Ge(HP) solid-state detector cooled by solid propane. A two-pass technique had to be used with the scintillation detector because Compton background from the 1 779 keV photopeak of aluminum masked the manganese line. The Compton background did not interfere when the solid-state detector was used. The borehole measurements compared favorably with a chemical core analysis and were unaffected by water in the borehole.

Geophysics↗

Geochemical survey of the Little Frog Roadless Area, Polk County, Tennessee

The Wilderness Act (Public Law 88-577, September 3, 1964) and related acts require the U.S. Geological Survey and the U.S. Bureau of Mines to survey certain areas on Federal lands to determine the mineral values, if any, that may be present. Results must be made available to the public and be submitted to the President and the Congress. This report presents the results of a geochemical survey of the Little Frog Roadless Area (08-277) in the Cherokee National Forest, Polk County, Tenn. The area was classified as a further planning area during the Second Roadless Area Review and Evaluation (RARE II) by the U.S. Forest Service, January 1979.

Tennessee↗