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E. R. Force

Publications and source records attributed to E. R. Force.

At least 19 recordsLinked to original sources

Mineral intergrowths replaced by "elbow-twinned" rutile in altered rocks

Some aggregates of rutile, classically considered to be "elbow" twinned, instead are topotactic replacements of ilmenite or other hexagonal titaniferous precursors. Twinned rutile can be differentiated from the reticulated rutile of topotactic replacements by the angle of prism intersections, junction morphology, and the overall form of the aggregate. In a special case of topotactic replacement of ilmenite, rutile forms pseudomorphs of "trellis"-textured ilmenite lamellae in {111} of precursor magnetite. We trace the progress of rutile formation through the alteration of fine-grained magnetite-bearing host rocks. The sequential two-step topotaxy from magnetite through ilmenite to rutile requires rutile prisms to parallel the intersections of {111} planes in precursor magnetite. Some coarse reticulated rutile may result from the same paragenetic sequence.

Canadian Mineralogist

Isotopic evidence for organic matter oxidation by manganese reduction in the formation of stratiform manganese carbonate ore

Unlike other marine-sedimentary manganese ore deposits, which are largely composed of manganese oxides, the primary ore at Molango (Hidalgo State, Mexico) is exclusively manganese carbonate (rhodochrosite, Mn-calcite, kutnahorite). Stable isotope studies of the carbonates from Molango provide critical new information relevant to the controversy over syngenetic and diagenetic models of stratiform manganese deposit formation. Negative δ 13 C values for carbonates from mineralized zones at Molango are strongly correlated with manganese content both on a whole rock scale and by mineral species. Whole rock δ 13 C data fall into three groups: high-grade ore = −16.4 to −11.5%.; manganese-rich, sub-ore-grade = −5.2 to 0%.; and unmineralized carbonates = 0 to +2.5%. (PDB). δ 18 O data show considerable overlap in values among the three groups: +4.8 to −2.8, −5.4 to −0.3%., and −7.4 to +6.2 (PDB), respectively. Isotopic data for individual co-existing minerals suggest a similar separation of δ 13 C values: δ 13 C values from calcite range from −1.1 to +0.7%. (PDB), whereas values from rhodochrosite are very negative, −12.9 to −5.5%., and values from kutnahorite or Mn-calcite are intermediate between calcite and rhodochrosite. 13 C data are interpreted to indicate that calcite ( i.e . unmineralized carbonate) formed from a normal marine carbon reservoir. However, 13 C data for the manganese-bearing carbonates suggest a mixed seawater and organic source of carbon. The presence of only trace amounts of pyrite suggests sulfate reduction may have played a minor part in oxidizing organic matter. It is possible that manganese reduction was the predominant reaction that oxidized organic matter and that it released organic-derived CO 2 to produce negative δ 13 C values and manganese carbonate mineralization.

Geochimica et Cosmochimica Acta

Resource assessments, geologic deposit models, and offshore minerals with an example of heavy-mineral sands

A resource assessment method for offshore minerals based on descriptive and grade-tonnage models is proposed. Historical development and applications of this method are summarized. Based on this approach, descriptive and quantitative deposit models for strand-line titanium placer deposits have been developed. Descriptive statistics were also computed using the worldwide deposit data set upon which the grade-tonnage models are based. Certain guidelines and limitations in applying onshore titanium deposit models to offshore assessment and exploration must, however, be observed. The descriptive model points out the specific features of strandline titanium placer deposits which can be of use in selection of areas for exploration; the grade-tonnage models display the expected size distribution for this type of deposit. Used with an estimate of expected number of deposits, this information can be applied to quantify probable values associated with deposits of this type within a given area.

NATO Science Series

A ground-water mixing model for the origin of the Imini manganese deposit (Cretaceous) of Morocco

Three beds of manganese oxide ore in a 10 m-thick dolomite unit are associated with diagenetic features, and, are accordingly also diagenetic in their present aspect. Whether primary or introduced, the Mn mineralogy is attributed to reactions between fresh and saline ground-waters as the zone of mixing passed through the dolomite unit during a period of falling sea-level. The succession of diagenetic changes is: 1) precursor carbonates, 2) dolomite-janggunite, 3) hollandite-pyrolusite-chert-calcite.-G.J.N.

Economic Geology

Borehole field calibration and measurement of low-concentration manganese by decay gamma rays

The manganese concentration in the Arundel clay formation, Prince Georges County, Maryland, was determined from a borehole by using delayed neutron activation. The neutrons were produced by a 100 mu g 252 Cf source. The 847 keV gamma ray of manganese was detected continuously, and its counting rate was measured at intervals of 15 s as the measuring sonde was moved at a rate of 0.5 cm/s. The technique measured the concentration ratio of manganese to aluminum. This ratio, when combined with an estimate of the aluminum concentration of the clay, made it possible to determine the percentage concentration of manganese without using a test-pit calibration facility. The measurements were made by using an NaI(Tl) scintillation detector and a Ge(HP) solid-state detector cooled by solid propane. A two-pass technique had to be used with the scintillation detector because Compton background from the 1 779 keV photopeak of aluminum masked the manganese line. The Compton background did not interfere when the solid-state detector was used. The borehole measurements compared favorably with a chemical core analysis and were unaffected by water in the borehole.

Geophysics

The provenance of rutile.

Most coarse detrital rutile is derived from high-grade metamorphic rocks. Contrary to a conventional assumption, independent rutile grains are particularly rare in igneous rocks except alkalic rocks. The use of rutile in the ZTR (zircon-tourmaline-rutile) index of mineralogic maturity is only partially valid, owing to its restricted provenance.

Journal of Sedimentary Petrology

Mineral resources of the Citico Creek Wilderness Study Area, Monroe County, Tennessee

The proposed Citico Creek Wilderness comprises about 5,670 hectares (56.7 km2) in the Cherokee National Forest south of the Little Tennessee River in easternmost Monroe County, Tennessee. Principal drainages are Citico Creek and Doublecamp Creek. Rocks of the study area include greenschist-facies arkosic metasandstone, metagraywacke, slate, and metaconglomerate of the Great Smoky Group of late Precambrian age. Minor deposits of unconsolidated Quaternary alluvium locally mantle the bedrock. Deformation is shown by asymmetric and overturned folds and by several major faults. More than 500 sample s of soil, rock, and stream sediment were collected and analyzed for 31 major, minor, and trace elements by semiquantitative spectrographic, atomic absorption, and fire assay methods No significant metal anomalies were detected. Concentrations of Cu, Co, As, Pb, and Zn slightly higher than background are found within sulfidic parts of a distinctive stratigraphic unit composed of graphitic slate and metagraywacke. Pyrite and pyrrhotite are the chief sulfide minerals, with traces o f accessory sphalerite, chalcopyrite, galena, and arsenopyrite occurring as microscopic intergrowths. A reconnaissance ground radiometric survey and subsequent neutron activation analyses of selected radioactive rock samples show that the sulfidic parts of the graphitic slate unit have a relatively high content of Th and U, but are not potentially economic. No metallic mineral resources appear to exist within the Citico Creek Wilderness Study Area. Resources of slate, silica, and stone are present, but they display no special qualities to differentiate them from other such material throughout the region. Ceramic evaluation tests on selected samples of slate indicate that the slate would have only marginal use for structural clay products such as brick and tile. Minor sand and gravel deposits occur along a few streams but are present in larger quantities and are more easily recovered in other areas.

Tennessee

Distribution of rutile in metamorphic rocks and implications for placer deposits

Pelitic units in the eastern Great Smoky Mountains of the North Carolina Blue Ridge contain rutile grains only in kyanite and higher zones. Adjacent non-pelitic rocks do not contain rutile at kyanite grade but commonly contain sphene. Detrital rutile breaks down at metamorphic grades lower than those at which metamorphic rutile forms. Similarly, pelitic rocks in southeastern Connecticut contain rutile grains above, but not below, the sillimanite isograd. Most non-pelitic rocks there contain rutile only in the hypersthene zone. The slight difference in behavior of rutile in the two terranes is attributed primarily to a slight difference in calcium content of the pelites. In both areas, rutile commonly appears first as inclusions in garnet. Geologic maps showing metamorphic and stratigraphic or compositional information should be useful as prospecting tools for placer deposits. A variety of rocks at granulite facies and pelitic rocks of the upper amphibolite facies contain rutile and these could provide an extensive source for rutile in rutile placer deposits. ?? 1978 Springer-Verlag.

Mineralium Deposita