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Donald A. Goolsby

Publications and source records attributed to Donald A. Goolsby.

At least 19 recordsLinked to original sources
USGS2013

Transport of nitrate in the Mississippi river in July-August 1999

Lagrangian sampling was conducted on the Mississippi River in late July through early August 1999 to test the hypothesis that nitrate (NO 3 - ) is transported conservatively in the Mississippi River. Three different approaches were pursued to test the hypothesis: (1) a mass balance for NO 3 - was evaluated for evidence of net gains and losses, (2) stable isotopes of NO 3 - were measured (δ 15 N and δ 18 O) to determine if fractionation occurred, and (3) the concentrations of dissolved gases (N 2 O, N 2 and Ar) in river water were measured and compared to theoretical equilibrium concentrations. Integrated water samples and flow measurements were obtained at 10 sites on the Mississippi River and 7 sites near the mouths of major tributaries from northern Iowa to southern Louisiana, a distance of about 2,250 river kilometers. Mass balance calculations indicate that more than 80 percent of the NO 3 - mass discharged from the Mississippi River (1,930 metric tons/day) during the study period originated in the first 500 river kilometers of the study reach. The mass balance calculations also indicate that NO 3 - was not lost from the water column upstream of Vicksburg, MS, but that there might have been some loss of NO 3 - in the lower 700 kilometers of the study reach. The stable isotope ratios of N and O (δ 15 N and δ 18 O) of NO 3 - were consistent with mixing and transport in the absence of fractionating gains or losses. The concentrations of nitrogen (N 2 ) and argon (Ar) dissolved in river water decreased in the downstream direction, approximately in equilibrium with air at increasing temperatures, giving no evidence of gains or losses of N 2 by nitrogen fixation or denitrification. Nitrous oxide (N 2 O) concentrations in the Mississippi River were approximately 26 to 200 percent of air saturation, indicating relatively low net production by combination of nitrification and denitrification. Results from this study indicate that most (>90%) of the NO 3 - that entered the Mississippi River during July-August 1999 was transported to the Gulf of Mexico.

Mississippi River↗
USGS2011

Mississippi Basin nitrogen flux believed to cause Gulf hypoxia

An expanding hypoxic zone develops each spring and summer on the Louisiana-Texas shelf of the Gulf of Mexico, and nitrogen from the Mississippi River Basin has been implicated as one of the principal causes. Hypoxic conditions, which occur when dissolved oxygen concentrations are less than 2 mg/L, can cause stress or death in bottom-dwelling organisms that cannot leave the zone. The mid-summer extent of the hypoxic zone has more than doubled since it was first systematically mapped in 1985 [Rabalais et al., 1999]. The largest hypoxic zone measured to date occurred in 1999, when it reached ∼20,000 km 2 , about the size of the state of New Jersey [Rabalais, 1999].

Gulf of Mexico, Mississippi River Basin↗
USGS2008

Pesticides in air and rainwater in the midcontinental United States, 1995: Methods and data

Weekly composite high-volume air and wet-only deposition samples were collected from April through September 1995 at paired urban and agricultural areas in Mississippi, Iowa, and Minnesota, and at a background site in Michigan's Upper Peninsula. This report describes the methods used to collect, analyze, and quality assure the samples, and presents the results of all chemical analyses and quality control procedures. Each sample was analyzed for 49 compounds, including several pesticides not examined in previous atmospheric studies. Eighty-five percent of the herbicides, 70 percent of the insecticides, and 100 percent of the transformation products that were targeted for analysis were detected in one or more samples at each paired site.

Open-File Report↗
USGS2007

Evaluating the influence of source basins on downstream water quality in the Mississippi River

Chemical variability in the Mississippi River during water years 1989 to 1998 was evaluated using stream discharge and water‐quality data in conjunction with the DAFLOW/BLTM hydraulic model. Model simulations were used to identify subbasin contributions of water and chemical constituents to the Mississippi River upstream from its confluence with the Ohio and the Mississippi River and at the Atchafalaya Diversion in Louisiana. Concentrations of dissolved solids, sodium, and sulfate at the Thebes site showed a general decreasing trend, and concentrations of silica and nitrate showed a general increasing trend as the percentage of discharge from the Mississippi River upstream from Grafton increased. Concentrations of most chemical constituents in the Mississippi River at the Atchafalaya Diversion exhibited a decreasing trend as the percentage of water from the Ohio River increased. Regression models were used to evaluate the importance of the source of water to the water chemistry in the Mississippi River at Thebes and the Atchafalaya Diversion. The addition of terms in regression equations to account for the percent of water from sub‐basins improved coefficients of determination for predicting chemical concentrations by as much as nine percent at the Thebes site and by as much as 48 percent at the Atchafalaya Diversion site. The addition of source‐water terms to regression equations increased the estimated annual loads of nitrate and silica delivered from the Mississippi River Basin to the Gulf of Mexico by as much as 14 and 13 percent, respectively.

Journal of the American Water Resources Associatio↗
USGS2006

Hydrogeochemical effects of injecting wastes into a limestone aquifer near Pensacola, Florida

Acidic industrial wastes have been injected into deep wells in a limestone aquifer near Pensacola, Florida, since 1963. Prior geohydrologic studies in the area had indicated that the limestone aquifer contained nonpotable water and was overlain by an extensive clay confining layer. Two injection wells are presently being used to inject the waste at a rate of approximately 2,000 gallons per minute. The injection pressures are about 200 pounds per square inch. Over 3 billion gallons have been injected. Data from a current study indicate that the waste may extend outward about 1 mile from the injection wells, and pressure effects may extend outward more than 25 miles. Monitor wells show that pressure changes are following a predictable pattern. No wastes have been detected in a monitor well open to the Floridan aquifer immediately above the Bucatunna Clay Member of the Byram Formation and 100 feet from one of the injection wells. A monitor well open to the receiving formation was constructed about 1,300 feet south of the injection wells. Geochemical effects of the wastes were detected at this well about 10 months after injection began. In early 1968, the pH of the waste was lowered to about 3. Effects of this waste, which included a large increase in calcium, were detected at the monitor well about 5 months later.

Florida↗
USGS2005

Summary of significant results from studies of triazine herbicides and their degradation products in surface water, ground water, and precipitation in the midwestern United States during the 1990s

Nonpoint-source contamination of water resources from triazine herbicides has been a major water-quality issue during the 1990s in the United States. To address this issue, studies of surface water, ground water, and precipitation have been carried out by the U.S. Geological Survey in the Midwestern United States. Reconnaissance studies of 147 streams were conducted to determine the geographic and seasonal distribution of atrazine, cyanazine, propazine, and simazine. These studies showed that high concentrations of herbicides were flushed from cropland and transported through the stream system as pulses in response to spring and summer rainfall. The studies also revealed the persistence of herbicides and their degradation products in streams. An investigation of 76 reservoirs showed that the occurrence and temporal distribution of herbicides and their degradation products in reservoir outflow could be related to reservoir and drainage-basin characteristics, water and land use, herbicide use, and climate. Significant findings showed that concentrations of atrazine and its degradation products remained elevated all summer and into the fall and that recently applied atrazine mixed with atrazine applied the previous year as water moved through a reservoir. Reconnaissance studies of 303 ground-water wells were completed to determine hydrogeological and seasonal occurrence, concentration, and distribution of herbicides and their degradation products. Samples collected from across the Midwestern United States consistently revealed that triazine herbicide degradation products commonly were found more frequently than their parent herbicide and that ground-water age could be an important factor in explaining variations in herbicide contamination. A final study investigated precipitation in the Midwestern United States, northeast to the Atlantic Ocean, and northward to the Canadian border. It found that the highest herbicide concentrations in precipitation occurred following herbicide application to cropland. Atrazine was detected most often, followed by deethylatrazine, cyanazine, and deisoproplyatrazine. Mass deposition of herbicides by precipitation was greatest in areas where herbicide use was intense and decreased with distance from the Midwest. Findings of the 1990s studies include an improved understanding of the occurrence, persistence, chemistry, and transport of triazine herbicides and their degradation products in the hydrologic environment. A significant increase in knowledge of triazine herbicides and development and improvement of analytical methods were accomplished in the past decade. The results produced are not only significant for the present (2005) but provide an important data set for future use.

Midwest region↗
USGS2002

Relating net nitrogen input in the Mississippi River Basin to nitrate flux in the Lower Mississippi River--A comparison of approaches

A quantitative understanding of the relationship between terrestrial N inputs and riverine N flux can help guide conservation, policy, and adaptive management efforts aimed at preserving or restoring water quality. The objective of this study was to compare recently published approaches for relating terrestrial N inputs to the Mississippi River basin (MRB) with measured nitrate flux in the lower Mississippi River. Nitrogen inputs to and outputs from the MRB (1951 to 1996) were estimated from state-level annual agricultural production statistics and NO y (inorganic oxides of N) deposition estimates for 20 states that comprise 90% of the MRB. A model with water yield and gross N inputs accounted for 85% of the variation in observed annual nitrate flux in the lower Mississippi River, from 1960 to 1998, but tended to underestimate high nitrate flux and overestimate low nitrate flux. A model that used water yield and net anthropogenic nitrogen inputs (NANI) accounted for 95% of the variation in riverine N flux. The NANI approach accounted for N harvested in crops and assumed that crop harvest in excess of the nutritional needs of the humans and livestock in the basin would be exported from the basin. The U.S. White House Committee on Natural Resources and Environment (CENR) developed a more comprehensive N budget that included estimates of ammonia volatilization, denitrification, and exchanges with soil organic matter. The residual N in the CENR budget was weakly and negatively correlated with observed riverine nitrate flux. The CENR estimates of soil N mineralization and immobilization suggested that there were large (2000 kg N ha −1 ) net losses of soil organic N between 1951 and 1996. When the CENR N budget was modified by assuming that soil organic N levels have been relatively constant after 1950, and ammonia volatilization losses are redeposited within the basin, the trend of residual N closely matched temporal variation in NANI and was positively correlated with riverine nitrate flux in the lower Mississippi River. Based on results from applying these three modeling approaches, we conclude that although the NANI approach does not address several processes that influence the N cycle, it appears to focus on the terms that can be estimated with reasonable certainty and that are correlated with riverine N flux.

Journal of Environmental Quality↗
USGS2000

Occurrence and load of selected herbicides and metabolites in the lower Mississippi River

Analyses of water samples collected from the Mississippi River at Baton Rouge, Louisiana, during 1991–1997 indicate that hundreds of metric tons of herbicides and herbicide metabolites are being discharged annually to the Gulf of Mexico. Atrazine, metolachlor, and the ethane-sulfonic acid metabolite of alachlor (alachlor ESA) were the most frequently detected herbicides and, in general, were present in the largest concentrations. Almost 80% of the annual herbicide load to the Gulf of Mexico occurred during the growing season from May to August. The concentrations and loads of alachlor in the Mississippi River decreased dramatically after 1993 in response to decreased use in the basin. In contrast, the concentrations and loads of acetochlor increased after 1994, reflecting its role as a replacement for alachlor. The peak annual herbicide load occurred in 1993, when approximately 640 metric tons (t) of atrazine, 320 t of cyanazine, 215 t of metolachlor, 53 t of simazine, and 50 t of alachlor were discharged to the Gulf of Mexico. The annual loads of atrazine and cyanazine were generally 1–2% of the amount annually applied in the Mississippi River drainage basin; the annual loads of acetochlor, alachlor, and metolachlor were generally less than 1%. Despite a reduction in atrazine use, historical data do not indicate a long-term downward trend in the atrazine load to the Gulf of Mexico. Although a relation ( r 2 =0.62) exists between the atrazine load and stream discharge during May to August, variations in herbicide use and rainfall patterns within subbasins can have a large effect on herbicide loads in the Mississippi River Basin and probably explain a large part of the annual variation in atrazine load to the Gulf of Mexico.

Louisana, Mississippi↗
USGS1999

Monitoring the Water Quality of the Nation's Large Rivers: Mississippi River Basin NASQAN Program

The U.S. Geological Survey (USGS) has monitored water quality in the Mississippi River Basin as part of the National Stream Quality Accounting Network (NASQAN) since 1995, applying a basinwide perspective to understanding water quality on a regional scale (Hooper and others, 1997). The objectives of the Mississippi River Basin NASQAN Program are to provide an ongoing characterization of the concentrations and mass fluxes of sediment and chemicals at key locations in the basin, to determine regional source areas for these materials, and to assess the effect of human influences on observed concentrations and fluxes. NASQAN complements the ongoing USGS National Water-Quality Assessment (NAWQA) Program, which is performing a detailed assessment in 23 subbasins within the Mississippi River Basin (Hirsch and others, 1988). NASQAN monitors the large rivers in the Mississippi River Basin, downstream of NAWQA study units. NASQAN, in conjunction with NAWQA, can provide the data and information needed by other USGS programs, Federal and State agencies, other segments of the scientific community, and by the public to address the present and future status of water quality in the Mississippi River Basin.

Fact Sheet↗
USGS1997

Plan of study to determine if the isotopic ratios [delta]15 N and [delta]18 O can reveal the sources of nitrate discharged by the Mississippi River into the Gulf of Mexico

Nitrate and other nutrients discharged from the Mississippi River basin are suspected of causing a zone of depleted dissolved oxygen (hypoxic zone) in the Gulf of Mexico each summer. The hypoxic zone may have an adverse effect on aquatic life and commercial fisheries. Commercial fertilizers are the dominant source of nitrogen input to the Mississippi basin. Other nitrogen sources include animal waste, fixation of atmospheric nitrogen by legumes, precipitation, domestic and industrial effluent, and the soil. The inputs of nitrogen from most of these sources to the Mississippi basin can be estimated and the outputs in surface water can be measured. However, nitrogen from each source is affected differently by physical, chemical, and biological processes that control nitrogen cycling in terrestrial and aquatic systems. Hence, the relative contributions from the various sources of nitrogen to nitrate load in the Mississippi River are unknown because the different sources may not contribute proportionally to their inputs in the basin. It may be possible to determine the relative contributions of the major sources of nitrate in river water using the stable isotopic ratios d15N and d18O of the nitrate ion. A few researchers have used the d15N and/or d18O isotope ratios to determine sources of nitrate in ground water, headwater catchments, and small rivers, but little is known about the isotopic composition of nitrate in larger rivers. The objective of this study is to measure the isotopic composition of nitrate and suspended organic matter in the Mississippi River and its major tributaries, in discharge to the Gulf of Mexico, and in streamflow from smaller watersheds that have distinct sources of nitrogen (row crops, animal wastes, and urban effluents) or are minimally impacted by man (undeveloped). Samples from seven sites on the Mississippi River and its tributaries and from 17 sites in smaller watersheds within the Mississippi River basin will be analyzed for d15N and d18O of dissolved nitrate. Suspended sediment collected from these sites will also be analyzed to determine the d15N, d13C, and d34S of the suspended organic material. Six samples will be collected at each site during the winter, spring, and summer of 1996-97. Results from these samples will be used to identify seasonal and flow-related variability in d15N and d18O ratios from each site and may also help determine the principal sources of the nitrate entering the Gulf of Mexico.

Open-File Report↗
USGS1995

Relations between pesticide use and riverine flux in the Mississippi River Basin

In an intensive subcontimental study of pesticides in surface waters of the United States, concentrations of 26 high-use pesticides were measured at nine sites in the Mississippi River basin from May 1991 through March 1992. Calculated total fluxes were combined with agricultural-use data to estimate the percentage of applied pesticide reaching the mouths of the Mississippi River and six major tributaries. For most pesticides, the riverine flux was less than 2% of the mass applied agriculturally. The insecticide diazinon was detected frequently in rivers draining the three basins with the highest population densities, apparently as a result of urban use.

Mississippi River basin↗