Geology topics

David L. Kimbrough

Publications and source records attributed to David L. Kimbrough.

3 recordsLinked to original sources

USGS2021

The triple argon isotope composition of groundwater on ten-thousand-year timescales

Understanding the age and movement of groundwater is important for predicting the vulnerability of wells to contamination, constraining flow models that inform sustainable groundwater management, and interpreting geochemical signals that reflect past climate. Due to both the ubiquity of groundwater with order ten-thousand-year residence times and its importance for climate reconstruction of the last glacial period, there is a strong need for improving geochemical dating tools on this timescale. Whereas 14 C of dissolved inorganic carbon and dissolved 4 He are common age tracers for Late Pleistocene groundwater, each is limited by systematic uncertainties related to aquifer composition and lithology, and the extent of water-rock interaction. In principle, radiogenic 40 Ar in groundwater acquired from decay of 40 K in aquifer minerals should be insensitive to some processes that impact 14 C and 4 He and thus represent a useful, complementary age tracer. In practice, however, detection of significant radiogenic 40 Ar signals in groundwater has been limited to a small number of studies of extremely old groundwater (>100 ka). Here we present the first high-precision (<1‰) measurements of triple Ar isotopes ( 40 Ar, 38 Ar, 36 Ar) in groundwater. We introduce a model that distinguishes radiogenic 40 Ar from atmospheric 40 Ar by using the non-radiogenic Ar isotopes ( 36 Ar, 38 Ar) to correct for mass-dependent fractionation. Using this model, we investigate variability in radiogenic 40 Ar excess (Δ 40 Ar) across 58 groundwater samples collected from 36 wells throughout California (USA). We find that Δ 40 Ar ranges from ~0‰ (the expected minimum value) to +4.2‰ across three study areas near Fresno, San Diego, and the western Mojave Desert. Based on measurements from a network of 23 scientific monitoring wells in San Diego, we find evidence for a strong dependence of Δ 40 Ar on aquifer lithology. We suggest that Δ 40 Ar is fundamentally controlled by the weathering of old K-bearing minerals and thus reflects both the degree of groundwater-rock interaction, which is related to groundwater age, and the integrated flow through different geological formations. Future studies of Late Pleistocene groundwater may benefit from high-precision triple Ar isotope measurements as a new tool to better interpret 14 C- and 4 He-based constraints on groundwater age and flow.

Chemical Geology↗

USGS2015

Detrital zircon U-Pb provenance of the Colorado River: A 5 m.y. record of incision into cover strata overlying the Colorado Plateau and adjacent regions

New detrital zircon U-Pb age distributions from 49 late Cenozoic sandstones and Holocene sands (49 samples, n = 3922) record the arrival of extra-regional early Pliocene Colorado River sediment at Grand Wash (western USA) and downstream locations ca. 5.3 Ma and the subsequent evolution of the river’s provenance signature. We define reference age distributions for the early Pliocene Colorado River (n = 559) and Holocene Colorado River (n = 601). The early Pliocene river is distinguished from the Holocene river by (1) a higher proportion of Yavapai-Mazatzal zircon derived from Rocky Mountain basement uplifts relative to Grenville zircon from Mesozoic supra crustal rocks, and (2) distinctive (∼6%) late Eocene–Oligocene (40–23 Ma) zircon reworked from Cenozoic basins and volcanic fields in the southern Rocky Mountains and/or the eastern Green River catchment. Geologic relationships and interpretation of 135 published detrital zircon age distributions throughout the Colorado River catchment provide the interpretative basis for modeling evolution of the provenance signature. Mixture modeling based upon a modified formulation of the Kolmogorov-Smirnov statistic indicate a subtle yet robust change in Colorado River provenance signature over the past 5 m.y. During this interval the contribution from Cenozoic strata decreased from ∼75% to 50% while pre-Cretaceous strata increased from ∼25% to 50%. We interpret this change to reflect progressive erosional incision into plateau cover strata. Our finding is consistent with geologic and thermochronologic studies that indicate that maximum post–10 Ma erosion of the Colorado River catchment was concentrated across the eastern Utah–western Colorado region.

Geosphere↗

USGS2005

Radioisotopic and biostratigraphic age relations in the Coast Range Ophiolite, northern California: Implications for the tectonic evolution of the Western Cordillera

The Coast Range ophiolite (CRO) in northern California includes two distinct remnants. The Elder Creek ophiolite is a classic suprasubduction zone ophiolite with three sequential plutonic suites (layered gabbro, wehrlit-pyroxenite, quartz diorite), a mafic to felsic dike complex, and mafic-felsic volcanic rocks; the entire suite is cut by late mid-oceanic-ridge basalt (MORB) dikes and overlain by ophiolitic breccia. The Stonyford volcanic complex (SFVC) comprises three volcanic series with intercalated chert horizons that form a submarine volcano enclosed in sheared serpentinite. Structurally below this seamount are mélange blocks of CRO similar to Elder Creek. U/Pb zircon ages from plagiogranite and quartz diorites at Elder Creek range in age from 165 Ma to 172 Ma. U/Pb zircon ages obtained from CRO mélange blocks below the SFVC are similar (166–172 Ma). 40 Ar- 39 Ar ages of alkali basalt glass in the upper SFVC are all younger at ≈164 Ma. Radiolarians extracted from chert lenses intercalated with basalt in the SFVC indicate that the sedimentary strata range in age from Bathonian (Unitary Association Zone 6–6 of Baumgartner et al., 1995a ) near the base of the complex to late Callovian to early Kimmeridgian (Unitary Association Zones 8–10) in the upper part. The SFVC sedimentary record preserves evidence of a major faunal change wherein relatively small sized, polytaxic radiolarian faunas were replaced by very robust, oligo-taxic, nassellarian-dominated faunas that included Praeparvicingula spp. We suggest that CRO formation began after the early Middle Jurassic (172–180 Ma) collision of an exotic or fringing arc with North America and initiation of a new or reconfigured east-dipping subduction zone. The data show that the CRO formed prior to the Late Jurassic Nevadan orogeny, probably by rapid forearc extension above a nascent subduction zone. We infer that CRO spreading ended with the collision of an oceanic spreading center ca. 164 Ma, coincident with the oldest high-grade blocks in the structurally underlying Franciscan assemblage. We further suggest that the “classic” Nevadan orogeny represents a response to spreading center collision, with shallow subduction of young lithosphere causing the initial compressional deformation and with a subsequent change in North American plate motion to rapid northward drift (J2 cusp) causing sinistral transpression and transtension in the Sierra foothills. These data are not consistent with models for Late Jurassic arc collision in the Sierra foothills or a backarc origin for the CRO.

California↗