Geology topics

David D. VanderMeulen

Publications and source records attributed to David D. VanderMeulen.

3 recordsLinked to original sources

USGS2024

Trace organic contaminants in U.S. national park surface waters: Prevalence and ecological context☆

Surface water samples were collected from 264 sites across 46 U.S national parks during the period of 2009–2019. The number of sites within each park ranged from 1 to 31 and the number of samples collected within each park ranged from 1 to 201. Samples were analyzed for up to 340 trace organic contaminants (TrOCs), including pharmaceuticals, personal care products, pesticides, and various contaminants indicative of anthropogenic influence (e.g., fragrances, surfactants, flame retardants). A total of 155 TrOCs was detected in at least one sample with concentrations ranging from the reporting level of 10 ng/L (multiple contaminants) to 11,900 ng/L (p-cresol). Except for bisphenol A, DEET, theobromine, and gabapentin, TrOCs were detected in <20% of samples. Despite the relatively low detection frequencies, when TrOCs were detected, concentrations were similar to those reported from other regional or national studies. We compared detected concentrations to bioactivity concentrations and water quality benchmarks, when available, to identify occurrences of elevated concentrations and to estimate the potential for biological effects to aquatic biota. Elevated concentrations of 27 TrOCs, mostly pesticides, were detected throughout the study. To gain insight regarding potential sources, we related watershed characteristics (e.g., land cover, presence of point sources) to the number of TrOCs detected at each site. We found that the presence of wastewater treatment plants and the proportion of the watershed classified as agricultural land were the most influential variables for describing the number of pharmaceuticals and the number of pesticides present, respectively. This study represents the largest-scale study characterizing the presence and magnitude of TrOCs in U.S. national park surface waters, to date. These data provide a baseline that can be used to inform future monitoring within the parks and to assess changes in water quality.

Environmental Pollution↗

USGS2021

Long-term trends in regional wet mercury deposition and lacustrine mercury concentrations in four lakes in Voyageurs National Park

Although anthropogenic mercury (Hg) releases to the environment have been substantially lowered in the United States and Canada since 1990, concerns remain for contamination in fish from remote lakes and rivers where atmospheric deposition is the predominant source of mercury. How have aquatic ecosystems responded? We report on one of the longest known multimedia data sets for mercury in atmospheric deposition: aqueous total mercury (THg aq ), methylmercury (MeHg aq ), and sulfate from epilimnetic lake-water samples from four lakes in Voyageurs National Park (VNP) in northern Minnesota; and total mercury (THg) in aquatic biota from the same lakes from 2001–2018. Wet Hg deposition at two regional Mercury Deposition Network sites (Fernberg and Marcell, Minnesota) decreased by an average of 22 percent from 1998–2018; much of the decreases occurred prior to 2009, with relatively flat trends since 2009. In the four VNP lakes, epilimnetic MeHg aq concentrations declined by an average of 44 percent and THg aq by an average of 27 percent. For the three lakes with long-term biomonitoring, temporal patterns in biotic THg concentrations were similar to patterns in MeHg aq concentrations; however, biotic THg concentrations declined significantly in only one lake. Epilimnetic MeHg aq may be responding both to a decline in atmospheric Hg deposition as well as a decline in sulfate deposition, which is an important driver of mercury methylation in the environment. Results from this case study suggest that regional- to continental-scale decreases in both mercury and sulfate emissions have benefitted aquatic resources, even in the face of global increases in mercury emissions.

Minnesota↗

USGS2017

Detection of microcystin and other cyanotoxins in lakes at Isle Royale National Park, Pictured Rocks National Lakeshore, and Sleeping Bear Dunes National Lakeshore, northern Michigan, 2012–13

Although cyanotoxins released during algal blooms have become an increasing concern in surface waters across the United States, the presence of cyanotoxins in northern Michigan lakes had not been evaluated in detail. The U.S. Geological Survey and National Park Service (NPS) led a 2-year study (2012 and 2013) to determine the presence of microcystin and other algal toxins in several inland lakes at Isle Royale National Park (hereafter referred to as ISRO, Pictured Rocks National Lakeshore (hereafter referred to as PIRO), and Sleeping Bear Dunes National Lakeshore (hereafter referred to as SLBE). Samples also were collected at four sites in Lake Michigan within the SLBE. The two analytical techniques used in the study were enzyme-linked immunosorbent assays (ELISA) for microcystin, cylindrospermopsin, and saxitoxin; and liquid chromatography/tandem mass spectrometry (LC/MS/MS) for a larger suite of algal toxins. Neither cylindrospermopsin nor saxitoxin were detected in the 211 samples. Microcystin was detected in 31 percent of samples (65 of 211 samples) analyzed by the ELISA method, but no sample results exceeded the World Health Organization recreational health advisory standard for microcystin (10 micrograms per liter [µg/L]). However, about 10 percent of the samples (21 of 211 samples) that were collected from PIRO and SLBE and were analyzed by ELISA for microcystin had concentrations greater than the U.S. Environmental Protection Agency (EPA) drinking water 10-day health advisory of 0.3 µg/L for children preschool age and younger (less than 6-years old). One sample collected in 2012 from SLBE exceeded the EPA drinking water 10-day health advisory of 1.6 µg/L for school-age children through adults (6-years old and older). In 2012, the highest concentration of 2.7 µg/L was detected in Florence Lake within SLBE. Many visitors enjoy recreation in or on the water and camp in the backcountry at these national parks where the most common source of drinking water is filtered surface water. Approximately 18 percent of the samples (39 of 211 samples) were analyzed by LC/MS/MS to confirm the ELISA results and to evaluate the samples for a larger suite of algal toxins. In general, the microcystin results between the ELISA and LC/MS/MS methods were similar; although, the ELISA results tended to be slightly higher than the summation of LC/MS/MS microcystin congeners. The slightly higher ELISA results might be because the ELISA microcystin method is reactive with the ADDA functional group common to all microcystins, and because not all microcystin congeners are included in the LC/MS/MS method. The LC/MS/MS method indicated that the congener microcystin-LR was the most frequently detected, followed by microcystin-WR and microcystin-YR. Sixteen of the lakes included in this study also were monitored by the NPS for nutrients. Total phosphorus (TP) concentrations were, on average, highest at the ISRO lakes, whereas total nitrogen (TN) concentrations were highest at SLBE. The average annual TN:TP ratios for the 16 lakes within the national park and national lakeshores ranged from ratios of 20 to 89. Overall, results indicated a slight increase in percentage of microcystin detections with an increase in the TN:TP ratio (R-squared 0.269 and 0.340, respectively [2012 and 2013 combined dataset] derived from linear regression). This study also indicated that even in the absence of visible algal blooms, microcystin may be present. Most microcystin concentrations did not exceed the EPA’s 10-day health advisory drinking-water benchmark. In general, these results provide a useful baseline with which to evaluate potential future changes in algal toxin concentrations.

Michigan↗