Geology topics

David Bish

Publications and source records attributed to David Bish.

3 recordsLinked to original sources

USGS2024

Deformation-induced graphitization and muscovite recrystallization in a ductile fault zone

A suite of slate samples collected along a 2 km transect crossing the Lishan fault in central Taiwan were evaluated to assess the role of ductile deformation in natural graphitization at lower greenschist facies metamorphic conditions. The process of natural aromatization, or graphitization, of an organic precursor is well established as a thermally driven process; however, experimental studies have shown that the energy provided by deformation can substantially reduce the activation energy required for graphitization. This study provides a natural example of deformation-induced graphitization. A strain gradient approaching the Lishan fault was established by scanning electron microscope imaging and X-ray diffraction analysis of phyllosilicates and quartz that showed an increase in the strength of slaty cleavage development via dissolution-precipitation processes. Thermal conditions were constrained to be near isothermal using calcite-dolomite geothermometry. Raman spectroscopic results from carbonaceous material, including D1-full width-at-half-maximum (FWHM), G-FWHM, Raman band separation (RBS), and a lesser-known vibrational mode B 2g -FWHM, showed robust linear trends across the same sampling transect. However, the G-FWHM parameter showed a trend opposite of that expected from thermally driven graphitization. The Raman results are interpreted to reflect a strain-driven reduction in graphite crystallite size (decrease in G-FWHM) but improvement in structural ordering in individual coherent domains. A multiple linear regression with an R 2 value of 0.92 predicts the graphite D1-FWHM values from the XRD-derived ratio of muscovite populations and muscovite microstrain, demonstrating the concomitant recrystallization of silicates and carbonaceous material across the strain gradient, despite the disparate processes accommodating the deformation. This study demonstrates the role of deformation in natural graphitization and provides a new perspective on the use of graphite as a geothermometer in strongly deformed greenschist facies rocks.

Journal of Metamorphic Geology↗

USGS2022

A channel sampling strategy for measurement of mineral modal and chemical composition of drill cores: Application to lower oceanic crustal rocks from IODP Expedition 345 to the Hess Deep rift

We report a new sampling strategy for collecting representative samples of drill core. By splitting the core with a diamond saw into working and archive halves, the saw cuttings constitute a “channel” sample, the best subsample from which to obtain an average mineralogical and geochemical composition of a core. We apply this procedure to sampling core of the lower oceanic crust in the Hess Deep obtained during Expedition 345 of the Integrated Ocean Drilling Program (now International Ocean Discovery Program). Our results show that particles produced by sawing range from sand to clay sizes. Sand- and silt-sized cuttings can be sampled with a spatula, whereas clay-sized particles remained in suspension after 12 h and could be collected only by settling, aided by centrifuge. X-ray diffraction (XRD) analysis and Rietveld refinement show that phyllosilicates were fractionated into the clay-sized fraction. Thus, collection of both the sedimented fraction and the clay-sized suspended fraction (commonly > 15 wt % of the total) is necessary to capture the whole sample. The strong positive correlation between the recovered sample mass (in grams) and length of core cut demonstrates that this sampling protocol was uniform and systematic, with almost 1.4 g sediment produced per centimeter of core cut. We show that major-element concentrations of our channel samples compare favorably with the compositions of billet-sized samples analyzed aboard the JOIDES Resolution , but the results show that individual billet analyses are rarely representative of the whole core recovered. A final test of the validity of our methods comes from the strong positive correlation between the loss on ignition (LOI) values of our channel samples and the H 2 O contents calculated from the modal mineralogy obtained by X-ray diffraction and Rietveld refinement. This sampling procedure shows that grain-sized fractionation modifies both mineralogical and chemical compositions; nevertheless, this channel sampling method is a reliable method of obtaining representative samples of bulk cores. With the ever-increasing precision offered by modern analytical instrumentation, this sampling protocol allows the accuracy of the analytical results to keep pace.

Scientific Drilling↗

USGS2021

Unmixing multiple metamorphic muscovite age populations with powder X-ray diffraction and 40Ar/39Ar analysis

A combination of modal estimates from powder X-ray diffraction (XRD) experiments and argon isotopic data shows that muscovite 40 Ar/ 39 Ar total gas age correlates with muscovite composition near the retrograde Bald Mountain shear zone (BMSZ) in Claremont, New Hampshire, and that the shear zone was active at ∼245 Ma. Petrologic study demonstrates that chemical disequilibrium is preserved in muscovite grains in these samples. The recognition of this preservation is critical to the interpretation of the 40 Ar/ 39 Ar step-heating experiments, which never produce age plateaus and yield spectra with steps that range in age by ∼20 Ma. Petrographic, compositional, and crystallographic data all indicate that the age spectra reflect dissolution of metastable Na-rich muscovite and precipitation of stable Na-poor muscovite associated with deformation in the BMSZ.Comparison of whole rock and muscovite concentrate XRD patterns from individual samples demonstrates that the mineral separation process can fractionate these muscovite populations. Therefore, four muscovite concentrates of varying magnetic susceptibility were prepared from a single hand sample, analyzed by XRD, and dated. These four splits define a mixing line that resolves end-member ages of 244.5 ± 4.2 Ma and 302.5 ± 12.5 Ma (1σ). Although the ages are imprecise, the petrologically supported conclusion that these schists preserve two discrete ages is distinct from an interpretation that the spectra reflect cooling through closure at ∼270 Ma, as might be concluded in the absence of petrologic characterization. The XRD results also demonstrate that, even well above anchizone conditions, petrologic information relevant to 40 Ar/ 39 Ar dating is observable in subtle variations in the crystallography of muscovite grains.

New Hampshire↗