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Daniel R. Shawe

Publications and source records attributed to Daniel R. Shawe.

At least 19 recordsLinked to original sources

Reassessment of the volkonskoite-chromian smectite nomenclature problem.

The name volkonskoite was first used in 1830 to describe a bright blue-green, chromium-bearing clay material from the Okhansk region, west of the Ural Mountains, U.S.S.R. Since that time, the name has been applied to numerous members of the smectite group of clay minerals, although the reported chromium content has ranged from 1% to about 30% Cr 2 O 3 . The name has also been applied to some chromian chlorites. Because volkonskoite has been used for materials that differ not only in their chromium content but also in their basic structure, the species status of the mineral has been unclear. To resolve this uncertainty, two specimens of volkonskoite from (1) Mount Efimiatsk, the type locality in the Soviet Union (USNM 16308) and (2) the Okhansk region in the Perm Basin, U.S.S.R. (USNM R4820), were examined by several mineralogical techniques. Neotype sample 16308 has the following structural formula: (Ca 0.11 Mg 0.11 Fe 2+ 0.03 K 0.02 )(Cr 1.18 Mg 0.78 Fe 3+ 0.29 Ca 0.02 )(Si 3.50 Al 0.51 )O 10 (OH) 2 ⋅3.64H 2 O. Sample R4820 has the following structural formula: (Ca 0.25 Mg 0.05 Fe 2+ 0.01 K 0.03 Mn 0.01 )(Cr 1.07 Mg 0.75 Fe 3+ 0.35 (Si 3.59 Al 0.43 )O 10 (OH) 2 ⋅4.22H 2 O. Mössbauer spectroscopy indicates that 91% and 98% of the iron is present as Fe 3+ in samples 16308 and R4820, respectively. X-ray powder diffraction patterns of both samples have broad lines corresponding to minerals of the smectite group. On the basis of these data, volkonskoite appears to be a dioctahedral member of the smectite group that contains chromium as the dominant cation in the octahedral layer. Smectites containing less than this amount of octahedral chromium should not be called volkonskoite, but should be named by chemical element adjectives, e.g., chromian montmorillonite, chromian nontronite.

Clays and Clay Minerals

Geochronology and correlation of Tertiary volcanic and intrusive rocks in part of the southern Toquima Range, Nye County, Nevada

Extensive volcanic and intrusive igneous activity, partly localized along regional structural zones, characterized the southern Toquima Range, Nevada, in the late Eocene, Oligocene, and Miocene. The general chronology of igneous activity has been defined previously. This major episode of Tertiary magmatism began with emplacement of a variety of intrusive rocks, followed by formation of nine major calderas and associated with voluminous extrusive and additional intrusive activity. Emplacement of volcanic eruptive and collapse megabreccias accompanied formation of some calderas. Penecontemporaneous volcanism in central Nevada resulted in deposition of distally derived outflow facies ash-flow tuff units that are interleaved in the Toquima Range with proximally derived ash-flow tuffs. Eruption of the Northumberland Tuff in the north part of the southern Toquima Range and collapse of the Northumberland caldera occurred about 32.3 million years ago. The poorly defined Corcoran Canyon caldera farther to the southeast formed following eruption of the tuff of Corcoran Canyon about 27.2 million years ago. The Big Ten Peak caldera in the south part of the southern Toquima Range Tertiary volcanic complex formed about 27 million years ago during eruption of the tuff of Big Ten Peak and associated air-fall tuffs. The inferred Ryecroft Canyon caldera formed in the south end of the Monitor Valley adjacent to the southern Toquima Range and just north of the Big Ten Peak caldera in response to eruption of the tuff of Ryecroft Canyon about 27 million years ago, and the Moores Creek caldera just south of the Northumberland caldera developed at about the same time. Eruption of the tuff of Mount Jefferson about 26.8 million years ago was accompanied by collapse of the Mount Jefferson caldera in the central part of the southern Toquima Range. An inferred caldera, mostly buried beneath alluvium of Big Smoky Valley southwest of the Mount Jefferson caldera, formed about 26.5 million years ago with eruption of the tuff of Round Mountain. The Manhattan caldera south of the Mount Jefferson caldera and northwest of the Big Ten Peak caldera formed in association with eruption of a series of tuffs, principally the Round Rock Formation, mostly ash-flow tuff, about 24.4 million years ago. Extensive 40 Ar/ 39 Ar dating of about 60 samples that represent many of the Tertiary extrusive and intrusive rocks in the southern Toquima Range provides precise ages that refine the chronology of previously dated units. New geochronologic data indicate that the petrogenetically related Corcoran Canyon, Ryecroft Canyon, and Mount Jefferson calderas formed during a period of about 560,000 years. Electron microprobe analyses of phenocrysts from 20 samples of six dated units underscore inferred petrogenetic relations among some of these units. In particular, compositions of augite, hornblende, and biotite in tuffs erupted from the Corcoran Canyon, Ryecroft Canyon, and Mount Jefferson calderas are similar, which suggests that magmas represented by these tuffs have similar petrogenetic histories. The unique occurrence of hypersthene in Isom-type tuff confirms its derivation from a source beyond the southern Toquima Range.

Nevada

Geochemistry, geochronology, mineralogy, and geology suggest sources of and controls on mineral systems in the southern Toquima Range, Nye County, Nevada

Geochemistry maps showing the distribution and abundance of 18 elements in about 1,400 rock samples, both mineralized and unmineralized, from the southern Toquima Range, Nev., indicate major structural and lithologic controls on mineralization, and suggest sources of the elements. Radiometric age data, lead mineralogy and paragenesis data, and lead-isotope data supplement the geochemical and geologic data, providing further insight into timing, sources, and controls on mineralization. Major zones of mineralization are centered on structural margins of calderas and principal northwest-striking fault zones, as at Round Mountain, Manhattan, and Jefferson mining districts, and on intersections of low-angle and steep structures, as at Belmont mining district. Paleozoic sedimentary rocks, mostly limestones (at Manhattan, Jefferson, and Belmont districts), and porous Oligocene ash-flow tuffs (at Round Mountain district) host the major deposits, although all rock types have been mineralized as evidenced by numerous prospects throughout the area. Principal mineral systems are gold-silver at Round Mountain where about 7 million ounces of gold and more than 4 million ounces of silver has been produced; gold at Gold Hill in the west part of the Manhattan district where about a half million ounces of gold has been produced; gold-mercury-arsenic-antimony in the east (White Caps) part of the Manhattan district where a few hundred thousand ounces of gold has been produced; and silver-lead-antimony at Belmont where more than 150,000 ounces of silver has been produced. Lesser amounts of gold and silver have been produced from the Jefferson district and from scattered mines elsewhere in the southern Toquima Range. A small amount of tungsten was produced from mines in the granite of the Round Mountain pluton exposed east of Round Mountain, and small amounts of arsenic, antimony, and mercury have been produced elsewhere in the southern Toquima Range. All elements show unique distribution patterns that suggest specific sources and lithologic influences on deposition, as well as multiple episodes of mineralization. Principal episodes of mineralization are Late Cretaceous (molybdenum and tungsten in and near granite; silver at Belmont and Silver Point mines), early Oligocene [tourmaline and base- and precious-metals around the granodiorite of Dry Canyon stock as well as at Manhattan(?)], late Oligocene (gold at Round Mountain and Jefferson), and Miocene (gold at Manhattan). Most likely principal sources of molybdenum, tungsten, silver, and bismuth are Cretaceous granites; of antimony, arsenic, and mercury are intermediate-composition early Oligocene intrusives; and of gold are early and late Oligocene and early Miocene magmas of the volcanic cycle. Lead may have been derived principally from Cretaceous granitic magma and Paleozoic sedimentary rocks. Several areas prospective for undiscovered mineral deposits are suggested by spatial patterns of element distributions related to geologic features. The Manhattan district in the vicinity of the White Caps mine may be underlain by a copper-molybdenum porphyry system related to a buried stock; peripheral high-grade gold veins and skarn deposits may be present below deposits previously mined. The Jefferson district also may be underlain by a copper-molybdenum porphyry system related to a buried stock, it too with peripheral high-grade gold deposits. The Bald Mountain Canyon belt of small gold veins has potential for deeper deposits in buried porous ash-flow tuff similar to the huge Round Mountain low-grade gold-silver deposit. Several other areas have potential for a variety of mineral deposits. Altogether the geochemical, geochronologic, mineralogic, and geologic evidence suggests recurring mineralizing episodes of varied character, from Late Cretaceous to late Tertiary time, related to a long-lived hot spot deep in the crust or in the upper mantle. Granite plutons of Late Cretaceous age were minerali

Nevada

Gold in placer deposits

Man most likely first obtained gold from placer deposits, more than 6,000 years ago. Placers account for more than two-thirds of the total world gold supply, and roughly half of that mined in the States of California, Alaska, Montana, and Idaho. Placer deposits result from weathering and release of gold from lode deposits, transportation of the gold, and concentration of the gold dominantly in stream gravels. Unless preserved by burial, a placer subsequently may be eroded, and either dispersed or reconcentrated. California has produced more than 40 million troy ounces of gold from placers, both modern and fossil (Tertiary). The source of the great bulk of the gold is numerous quartz veins and mineralized zones of the Mother Lode and related systems in the western Sierra Nevada region. The gold-bearing lodes were emplaced in Carboniferous and Jurassic metamorphic rocks intruded by small bodies of Jurassic and Cretaceous igneous rocks. Mineralization occurred probably in Late Cretaceous time. Significant amounts of placer gold also were mined along the Salmon and Trinity Rivers in northern California. Source of the gold is lode deposits in Paleozoic and Mesozoic metamorphic rocks that were intruded by Mesozoic igneous rocks. Alaska has produced roughly 21 million ounces of gold from placer deposits. Most (about 13 million ounces) has come from the interior region, including 7,600,000 ounces from the Fairbanks district and 1,300,000 ounces from the Iditarod district. Lode sources are believed to be mostly quartz veins in Precambrian or Paleozoic metamorphic rocks intruded by small igneous bodies near Fairbanks, and shear zones in Tertiary(?) quartz monzonite stocks at Iditarod. The Seward Peninsula has produced more than 6 million ounces of placer gold, including about 4,000,000 ounces from the Nome district. Most of the gold was derived from raised beach deposits. Source of the gold probably is Tertiary-mineralized faults and joints in metamorphic rocks of late Precambrian age. The Helena-Last Chance district, Montana, produced nearly 1 million ounces of gold from placers that were derived from lode deposits in the contact zones of the Cretaceous Boulder batholith granitic rocks intruded into upper Precambrian, Paleozoic, and Mesozoic sedimentary rocks. The Virginia City-Alder Gulch district, Montana, produced more than 2,600,000 ounces of gold, nearly all from placer deposits derived from quartz veins of uncertain age in Archean gneisses and schists. The Boise basin district, Idaho, produced about 2,300,000 ounces of gold, mostly derived from quartz veins in quartz monzonite of the Cretaceous Idaho batholith.

Alaska, California, Idaho, Montana

Pb-Bi-Ag-Cu-(Hg) chemistry of galena and some associated sulfosalts. A review and some new data from Colorado California and Pennsylvania

Galena, associated with Pb-Bi-Ag sulfosalts and simple sulfides, contains varied amounts of Ag and Bi in the Dandy vein system, Idarado mine, Ouray, Colorado; the Jackass mine, Darwin District, California; and the Leadville district, Colorado. Silver- and bismuth-bearing galena associated with minor amounts of pyrite, chalcopyrite and sphalerite occur at the Pequea mine, Lancaster County, Pennsylvania. Ag and Bi contents in the Dandy suite of galena range from about 1.4 to 3.4 and 2.5 to 6.5 wt.% respectively, and are comparable or lower in galena from the other localities. Exsolved matildite is present in galena from the Dandy, Jackass and Leadville localities. The presence in significant amounts of both Ag and Bi in a Pb-rich sulfide system is necessary for formation of PbSss (galena solid-solution). If Ag (especially) and Bi (to a lesser extent) are absent, the galena formed will be essentially pure PbS. Some minor Sb may substitute for Bi. Compositional data for all of the galena samples are in agreement with a previously proposed linear relationship between a and Ag-Bi(Sb) content. Matildite and seven additional Pb-Bi-Ag-Cu sulfosalts have been identified from the Dandy vein system, based on electron-microprobe analyses and some X-ray powder-diffraction data.

Canadian Mineralogist

Age of volcanism, intrusion, and mineralization in the Thomas Range, Keg Mountain, and Desert Mountain, western Utah

Twenty-six new age determinations by the fission-track method establish a chronology for volcanism, intrusion, and mineralization in the Thomas Range, Keg Mountain, and Desert Mountain, in western Utah. The fission-track ages confirm D. R. Shawe's three-fold classification of igneous rocks. The oldest group of rocks consists of flows, agglomerates, and some ash-flow tuffs that were deposited 38-39 m.y. ago. The middle group contains widespread rhyolitic ash-flow tuffs that originated from local volcanic centers 30-32 m.y. ago. A dike emplaced along the probable ring-fracture zone of the Keg caldera about 31 m.y. ago indicates that caldera collapse occurred soon after eruption of ash-flow tuffs. Rocks believed to belong-to the middle group also were intruded by the quartz monzonite of Desert Mountain 27-30 m.y. ago. Little or no igneous activity took place within the next 20 m.y., during which time the region was strongly broken by Basin-and-Range faulting. Rhyolites of the youngest group were extruded 8-10 m.y. ago in the Keg Mountain area and 6-7 m.y. ago in the Thomas Range. The beryllium-fluorite mineralization at Spor Mountain occurred after the rhyolitic volcanism in the Thomas Range.

Utah